CN106221391A - A kind of anti-settling type based white primer and preparation method thereof - Google Patents
A kind of anti-settling type based white primer and preparation method thereof Download PDFInfo
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- CN106221391A CN106221391A CN201610714733.0A CN201610714733A CN106221391A CN 106221391 A CN106221391 A CN 106221391A CN 201610714733 A CN201610714733 A CN 201610714733A CN 106221391 A CN106221391 A CN 106221391A
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- based white
- white primer
- type based
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- thickening agent
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
- C09D125/02—Homopolymers or copolymers of hydrocarbons
- C09D125/04—Homopolymers or copolymers of styrene
- C09D125/08—Copolymers of styrene
- C09D125/14—Copolymers of styrene with unsaturated esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
- C09D127/02—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
- C09D127/12—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention provides a kind of anti-settling type based white primer and preparation method thereof, wherein, the component of this anti-settling type based white primer and weight thereof be: emulsion 45 ~ 50 parts, wetting agent 0.3 ~ 0.5 part, defoamer A 0.1 ~ 0.2 part, DPM 2 ~ 4 parts, DPNB 1 ~ 3 part, dispersant 1 ~ 3 part, titanium dioxide 10 ~ 16 parts, Pulvis Talci 18 ~ 22 parts, thickening agent A 0.04 ~ 0.06 part, thickening agent B 0.1 ~ 0.3 part, defoamer B 0.15 ~ 0.35 part, grinding auxiliary agent 0.5 ~ 1.5 part, 8 ~ 10 parts of water.The anti-settling type based white primer prepared according to preparation method of the present invention, as the priming paint of a kind of practicality, not only has the performance that traditional based white primer is had, and it has the effect of significant anti-settling;Therefore, anti-settling type based white primer of the present invention and preparation method thereof is respectively provided with good application prospect and market potential.
Description
Technical field
The invention belongs to chemistry painting industry field, be specifically related to a kind of anti-settling type based white primer and preparation method thereof.
Background technology
Water-based white primer, owing to needing preferable fillibility and covering power, needs to add a large amount of pigment, filler;Further,
In preparation process, even if water-based white primer is uniformly dispersed, prolongation over time, containing more powder, spacing in paint liquid
Less and do not have enough repulsive forces to be also easily caused again to reunite;Therefore, under the influence of gravity factor, based white primer can be caused
Settle, have a strong impact on outward appearance and the use of water-based white primer.
Therefore, develop the water-based white primer of a kind of brand-new formula, to obtaining the effect of anti-settling, be that people researched and developed by coating
One of research emphasis that member is current.
Summary of the invention
For shortcomings and deficiencies present in above-mentioned prior art, in conjunction with above-mentioned reason, inventor have developed a kind of energy
Realizing the water-based white primer of anti-settling effect, this water-based white primer will have thixotropic low sheraing thickening agent and increase with middle high shear
Thick dose of compounding use according to a certain percentage, again to promoting its thermodynamic stability while giving the workability that water paint is good
There is remarkable result.
Therefore, a first aspect of the present invention, it is provided that a kind of anti-settling type based white primer, the weight of its each component is such as
Under:
Emulsion 45 ~ 50
Wetting agent 0.3 ~ 0.5
Defoamer A 0.1 ~ 0.2
DPM 2~4
DPNB 1~3
Dispersant 1 ~ 3
Titanium dioxide 10 ~ 16
Pulvis Talci 18 ~ 22
Thickening agent A 0.04 ~ 0.06
Thickening agent B 0.1 ~ 0.3
Defoamer B 0.15 ~ 0.35
Grinding auxiliary agent 0.5 ~ 1.5
Water 8 ~ 10;
Wherein, thickening agent A is bentonite, and thickening agent B is polyurethanes thickening agent.
Preferably, the weight of each component of above-mentioned anti-settling type based white primer is as follows:
Emulsion 48
Wetting agent 0.4
Defoamer A 0.15
DPM 3
DPNB 2
Dispersant 2
Titanium dioxide 13
Pulvis Talci 21
Thickening agent A 0.05
Thickening agent B 0.2
Defoamer B 0.25
Grinding auxiliary agent 1
Water 9.
It is further preferred that in above-mentioned anti-settling type based white primer, described bentonite is bentonite LT.
It is further preferred that in above-mentioned anti-settling type based white primer, described polyurethanes thickening agent is XS71 thickening agent.
What deserves to be explained is, bentonite LT is produced by this company of hamming, and XS71 thickening agent is domestic general commodity name;This
Outward, when using bentonite LT and XS71 thickening agent to carry out compounding, bentonite LT and the ratio of XS71 thickening agent can be regulated and controled as required
Example, to regulate and control suitable viscosity, but need to ensure that thixotropic index is more than 2.5 just can be anti-settling.
It is further preferred that in above-mentioned anti-settling type based white primer, described emulsion selected from following any one: styrene-acrylic emulsion, benzene
Third true mineral varnish emulsion, acrylic acid ester emulsion, organosilicon-modified acrylate emulsion, water-base fluorocarbon emulsion.
It is further preferred that in above-mentioned anti-settling type based white primer, described wetting agent is selected from any one or more group following
Close: anion surfactant, EPE polyol EPE, polyoxyethylene-type surfactant.
It is further preferred that in above-mentioned anti-settling type based white primer, described defoamer A and described defoamer B is independently of one another
Selected from following any one: mineral oil antifoam agent, organic silicon defoamer, polyether surfactant.
It is further preferred that in above-mentioned anti-settling type based white primer, described dispersant be Acrylates dispersant and/or
5040 dispersants.
It is further preferred that in above-mentioned anti-settling type based white primer, described grinding auxiliary agent is aqueous grinding auxiliary agent.
A second aspect of the present invention, it is provided that the preparation method of anti-settling type based white primer described in a kind of first aspect present invention,
Comprise the following steps:
First, in high-speed stirred cylinder, it is sequentially added into described emulsion, described wetting agent, described defoamer A, described DPM, described
DPNB and described dispersant, use the mixing speed of 500-800 rpm to be sufficiently stirred for 5 ~ 8 minutes, mix homogeneously;Then, to this
High-speed stirred cylinder is sequentially added into described titanium dioxide, described Pulvis Talci, described thickening agent A, described thickening agent B, described defoamer
B, described grinding auxiliary agent, use the mixing speed of 2000-2500 rpm to be sufficiently stirred for 20 ~ 50 minutes, high degree of dispersion;Then, to
This high-speed stirred cylinder injects described water, and uses the mixing speed of 1000-1200 rpm to be sufficiently stirred for 5 ~ 8 minutes;Finally, quiet
Put, froth breaking, filter, discharging.
As can be seen here, the filler used at the bottom of conventional white is more, is difficult to dispersion, it usually needs auxiliary rheological agents is under higher rotation speed
Dispersion, and the present invention uses and has the compounding use of suitable thixotropic auxiliary rheological agents, plays while improving dispersing uniformity
Anti-settling effect.
In sum, the anti-settling type based white primer prepared according to preparation method of the present invention, as the end of a kind of practicality
Paint, not only has the performance that traditional based white primer is had, and it has the effect of significant anti-settling;Therefore, institute of the present invention
Anti-settling type based white primer stated and preparation method thereof is respectively provided with good application prospect and market potential.
Detailed description of the invention
Below in conjunction with detailed description of the invention, the present invention is further elaborated, but the present invention is not limited to following embodiment party
Formula.
First aspect, the invention provides a kind of anti-settling type based white primer, and the weight of its each component is as follows:
Emulsion 45 ~ 50
Wetting agent 0.3 ~ 0.5
Defoamer A 0.1 ~ 0.2
DPM 2~4
DPNB 1~3
Dispersant 1 ~ 3
Titanium dioxide 10 ~ 16
Pulvis Talci 18 ~ 22
Thickening agent A 0.04 ~ 0.06
Thickening agent B 0.1 ~ 0.3
Defoamer B 0.15 ~ 0.35
Grinding auxiliary agent 0.5 ~ 1.5
Water 8 ~ 10;
Wherein, thickening agent A is bentonite, and thickening agent B is polyurethanes thickening agent.
In a preferred embodiment, the weight of each component of above-mentioned anti-settling type based white primer is as follows:
Emulsion 48
Wetting agent 0.4
Defoamer A 0.15
DPM 3
DPNB 2
Dispersant 2
Titanium dioxide 13
Pulvis Talci 21
Thickening agent A 0.05
Thickening agent B 0.2
Defoamer B 0.25
Grinding auxiliary agent 1
Water 9.
In a further preferred embodiment, described bentonite is bentonite LT.
In a further preferred embodiment, described polyurethanes thickening agent is XS71 thickening agent.
In a further preferred embodiment, described emulsion selected from following any one: the true mineral varnish of styrene-acrylic emulsion, phenylpropyl alcohol
Emulsion, acrylic acid ester emulsion, organosilicon-modified acrylate emulsion, water-base fluorocarbon emulsion.
In a further preferred embodiment, described wetting agent is selected from any one or more combination following: cloudy from
Sub-surface activating agent, EPE polyol EPE, polyoxyethylene-type surfactant.
In a further preferred embodiment, described defoamer A and described defoamer B is each independently selected from following
Any one: mineral oil antifoam agent, organic silicon defoamer, polyether surfactant.
In a further preferred embodiment, described dispersant is Acrylates dispersant and/or 5040 dispersions
Agent.
In a further preferred embodiment, described grinding auxiliary agent is aqueous grinding auxiliary agent.
A second aspect of the present invention, it is provided that the preparation method of anti-settling type based white primer described in a kind of first aspect present invention,
Comprise the following steps:
First, in high-speed stirred cylinder, it is sequentially added into described emulsion, described wetting agent, described defoamer A, described DPM, described
DPNB and described dispersant, use the mixing speed of 500-800 rpm to be sufficiently stirred for 5 ~ 8 minutes, mix homogeneously;Then, to this
High-speed stirred cylinder is sequentially added into described titanium dioxide, described Pulvis Talci, described thickening agent A, described thickening agent B, described defoamer
B, described grinding auxiliary agent, use the mixing speed of 2000-2500 rpm to be sufficiently stirred for 20 ~ 50 minutes, high degree of dispersion;Then, to
This high-speed stirred cylinder injects described water, and uses the mixing speed of 1000-1200 rpm to be sufficiently stirred for 5 ~ 8 minutes;Finally, quiet
Put, froth breaking, filter, discharging.
Step in the preparation method of following anti-settling type based white primer is conventional method, described raw material if no special instructions
The most all can be either commercially available from open.
Embodiment 1
First, be sequentially added in high-speed stirred cylinder phenylpropyl alcohol true mineral varnish emulsion, anion surfactant, mineral oil antifoam agent,
DPM, DPNB and 5040 dispersants, use the mixing speed of 500 rpm to be sufficiently stirred for 6 minutes, mix homogeneously;Then, high to this
Speed a mixing bowl in be sequentially added into titanium dioxide, Pulvis Talci, bentonite LT, XS71 thickening agent, organic silicon defoamer, aqueous polishing help
Agent, uses the mixing speed of 2000 rpm to be sufficiently stirred for 30 minutes, high degree of dispersion;Then, in this high-speed stirred cylinder, inject water,
And use the mixing speed of 1200 rpm to be sufficiently stirred for 5 minutes;Finally, stand, froth breaking, filter, discharging, prepare anti-settling type white background
Paint.Wherein, each component and weight thereof are as follows:
Phenylpropyl alcohol true mineral varnish emulsion 48
Anion surfactant 0.4
Mineral oil antifoam agent 0.1
DPM 2
DPNB 1
5040 dispersants 2
Titanium dioxide 13
Pulvis Talci 20
Bentonite LT 0.04
XS71 thickening agent 0.1
Organic silicon defoamer 0.18
Aqueous grinding auxiliary agent 0.5
Water 8.
Embodiment 2
First, be sequentially added in high-speed stirred cylinder water-base fluorocarbon emulsion, EPE polyol EPE, organic silicon defoamer,
DPM, DPNB and Acrylates dispersant, use the mixing speed of 700 rpm to be sufficiently stirred for 5 minutes, mix homogeneously;Then,
Be sequentially added into titanium dioxide in this high-speed stirred cylinder, Pulvis Talci, bentonite LT, XS71 thickening agent, organic silicon defoamer, aqueous are beaten
Milling aid, uses the mixing speed of 2400 rpm to be sufficiently stirred for 40 minutes, high degree of dispersion;Then, note in this high-speed stirred cylinder
Enter water, and use the mixing speed of 1000 rpm to be sufficiently stirred for 8 minutes;Finally, stand, froth breaking, filter, discharging, prepare anti-settling
Type based white primer.Wherein, each component and weight thereof are as follows:
Water-base fluorocarbon emulsion 48
EPE polyol EPE 0.4
Organic silicon defoamer 0.15
DPM 3
DPNB 2
Acrylates dispersant 2
Titanium dioxide 13
Pulvis Talci 21
Bentonite LT 0.05
XS71 thickening agent 0.2
Polyether surfactant 0.25
Aqueous grinding auxiliary agent 1
Water 9.
Embodiment 3
First, in high-speed stirred cylinder, styrene-acrylic emulsion, polyoxyethylene-type surfactant, polyethers surface activity it are sequentially added into
Agent, DPM, DPNB and 5040 dispersants, use the mixing speed of 800 rpm to be sufficiently stirred for 8 minutes, mix homogeneously;Then, to this
High-speed stirred cylinder is sequentially added into titanium dioxide, Pulvis Talci, bentonite LT, XS71 thickening agent, mineral oil antifoam agent, aqueous polishing help
Agent, uses the mixing speed of 2500 rpm to be sufficiently stirred for 20 minutes, high degree of dispersion;Then, in this high-speed stirred cylinder, inject water,
And use the mixing speed of 1200 rpm to be sufficiently stirred for 6 minutes;Finally, stand, froth breaking, filter, discharging, prepare anti-settling type white background
Paint.Wherein, each component and weight thereof are as follows:
Styrene-acrylic emulsion 45
Polyoxyethylene-type surfactant 0.3
Polyether surfactant 0.1
DPM 3
DPNB 1
5040 dispersants 1
Titanium dioxide 10
Pulvis Talci 18
Bentonite LT 0.05
XS71 thickening agent 0.15
Mineral oil antifoam agent 0.25
Aqueous grinding auxiliary agent 0.5
Water 8.
Embodiment 4
First, in high-speed stirred cylinder, acrylic acid ester emulsion, polyoxyethylene-type surfactant, mineral oil froth breaking it are sequentially added into
Agent, DPM, DPNB and Acrylates dispersant, use the mixing speed of 500 rpm to be sufficiently stirred for 8 minutes, mix homogeneously;Connect
, in this high-speed stirred cylinder, be sequentially added into titanium dioxide, Pulvis Talci, bentonite LT, XS71 thickening agent, organic silicon defoamer, water
Property grinding auxiliary agent, uses the mixing speed of 2000 rpm to be sufficiently stirred for 50 minutes, high degree of dispersion;Then, to this high-speed stirred cylinder
Middle injection water, and use the mixing speed of 1100 rpm to be sufficiently stirred for 7 minutes;Finally, stand, froth breaking, filter, discharging, prepare
Anti-settling type based white primer.Wherein, each component and weight thereof are as follows:
Acrylic acid ester emulsion 50
Polyoxyethylene-type surfactant 0.45
Mineral oil antifoam agent 0.2
DPM 4
DPNB 3
Acrylates dispersant 2.5
Titanium dioxide 15
Pulvis Talci 20
Bentonite LT 0.06
XS71 thickening agent 0.3
Organic silicon defoamer 0.3
Aqueous grinding auxiliary agent 1.5
Water 10.
Additionally, inventor has carried out the detection of anti-settling property to described anti-settling type based white primer: use anti-settling type of the present invention
The product spray plate that based white primer prepares is tested, and plate face is smooth without granule, takes 300g and puts into hot at 50 DEG C in tank storage 7 days,
Being observed, result product is without gel, without soft heavy, without skinning again;Separately take 300g normal temperature storage to be observed after 1 month, knot
Fruit product is without gel, without soft heavy, without skinning.
Being described in detail the specific embodiment of the present invention above, but it is intended only as example, the present invention does not limit
It is formed on particular embodiments described above.To those skilled in the art, any equivalent modifications that the present invention is carried out and
Substitute the most all among scope of the invention.Therefore, the impartial conversion made without departing from the spirit and scope of the invention and
Amendment, all should contain within the scope of the invention.
Claims (10)
1. an anti-settling type based white primer, it is characterised in that the weight of its each component is as follows:
Emulsion 45 ~ 50
Wetting agent 0.3 ~ 0.5
Defoamer A 0.1 ~ 0.2
DPM 2~4
DPNB 1~3
Dispersant 1 ~ 3
Titanium dioxide 10 ~ 16
Pulvis Talci 18 ~ 22
Thickening agent A 0.04 ~ 0.06
Thickening agent B 0.1 ~ 0.3
Defoamer B 0.15 ~ 0.35
Grinding auxiliary agent 0.5 ~ 1.5
Water 8 ~ 10;
Wherein, thickening agent A is bentonite, and thickening agent B is polyurethanes thickening agent.
Anti-settling type based white primer the most according to claim 1, it is characterised in that the weight of its each component is as follows:
Emulsion 48
Wetting agent 0.4
Defoamer A 0.15
DPM 3
DPNB 2
Dispersant 2
Titanium dioxide 13
Pulvis Talci 21
Thickening agent A 0.05
Thickening agent B 0.2
Defoamer B 0.25
Grinding auxiliary agent 1
Water 9.
Anti-settling type based white primer the most according to claim 1 and 2, it is characterised in that described bentonite is bentonite LT.
Anti-settling type based white primer the most according to claim 1 and 2, it is characterised in that described polyurethanes thickening agent is XS71
Thickening agent.
Anti-settling type based white primer the most according to claim 1 and 2, it is characterised in that described emulsion selected from following any one: benzene
Acrylic emulsion, phenylpropyl alcohol true mineral varnish emulsion, acrylic acid ester emulsion, organosilicon-modified acrylate emulsion, water-base fluorocarbon emulsion.
Anti-settling type based white primer the most according to claim 1 and 2, it is characterised in that described wetting agent selected from following any one
Or multiple combination: anion surfactant, EPE polyol EPE, polyoxyethylene-type surfactant.
Anti-settling type based white primer the most according to claim 1 and 2, it is characterised in that described defoamer A and described defoamer B
Be each independently selected from following any one: mineral oil antifoam agent, organic silicon defoamer, polyether surfactant.
Anti-settling type based white primer the most according to claim 1 and 2, it is characterised in that described dispersant is that Acrylates divides
Powder and/or 5040 dispersants.
Anti-settling type based white primer the most according to claim 1 and 2, it is characterised in that described grinding auxiliary agent is that aqueous polishing helps
Agent.
10. the preparation method according to the anti-settling type based white primer according to any one of claim 1 ~ 9, it is characterised in that bag
Include following steps:
First, in high-speed stirred cylinder, it is sequentially added into described emulsion, described wetting agent, described defoamer A, described DPM, described
DPNB and described dispersant, use the mixing speed of 500-800 rpm to be sufficiently stirred for 5 ~ 8 minutes, mix homogeneously;Then, to this
High-speed stirred cylinder is sequentially added into described titanium dioxide, described Pulvis Talci, described thickening agent A, described thickening agent B, described defoamer
B, described grinding auxiliary agent, use the mixing speed of 2000-2500 rpm to be sufficiently stirred for 20 ~ 50 minutes, high degree of dispersion;Then, to
This high-speed stirred cylinder injects described water, and uses the mixing speed of 1000-1200 rpm to be sufficiently stirred for 5 ~ 8 minutes;Finally, quiet
Put, froth breaking, filter, discharging.
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
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CN108587434A (en) * | 2018-06-01 | 2018-09-28 | 江苏清陶能源科技有限公司 | A kind of coating and preparation method thereof improving stability and solid component is avoided to settle |
CN110724414A (en) * | 2019-10-08 | 2020-01-24 | 武汉长弢新材料有限公司 | Stain-resistant high-temperature-resistant water-based paint and preparation method thereof |
CN111500125A (en) * | 2020-05-15 | 2020-08-07 | 中华制漆(新丰)有限公司 | Water-based white primer and preparation method thereof |
CN113801578A (en) * | 2021-08-18 | 2021-12-17 | 瑞霖(厦门)化工有限公司 | Multifunctional oily white primer and preparation method thereof |
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CN104098967A (en) * | 2013-04-10 | 2014-10-15 | 展辰涂料集团股份有限公司 | Water-based high-filling white paint |
CN104371451A (en) * | 2014-10-29 | 2015-02-25 | 广东巴德士化工有限公司 | Single-component water-based dip-coating sealing white primer |
CN104403429A (en) * | 2014-11-14 | 2015-03-11 | 三棵树涂料股份有限公司 | Interior and exterior wall priming paint and preparation method thereof |
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CN104098967A (en) * | 2013-04-10 | 2014-10-15 | 展辰涂料集团股份有限公司 | Water-based high-filling white paint |
CN103540202A (en) * | 2013-09-28 | 2014-01-29 | 三棵树涂料股份有限公司 | Thinning-free one-time brush-molded latex paint finishing coat and preparation method thereof |
CN104371451A (en) * | 2014-10-29 | 2015-02-25 | 广东巴德士化工有限公司 | Single-component water-based dip-coating sealing white primer |
CN104403429A (en) * | 2014-11-14 | 2015-03-11 | 三棵树涂料股份有限公司 | Interior and exterior wall priming paint and preparation method thereof |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108587434A (en) * | 2018-06-01 | 2018-09-28 | 江苏清陶能源科技有限公司 | A kind of coating and preparation method thereof improving stability and solid component is avoided to settle |
CN110724414A (en) * | 2019-10-08 | 2020-01-24 | 武汉长弢新材料有限公司 | Stain-resistant high-temperature-resistant water-based paint and preparation method thereof |
CN111500125A (en) * | 2020-05-15 | 2020-08-07 | 中华制漆(新丰)有限公司 | Water-based white primer and preparation method thereof |
CN113801578A (en) * | 2021-08-18 | 2021-12-17 | 瑞霖(厦门)化工有限公司 | Multifunctional oily white primer and preparation method thereof |
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Address after: No.578 Xiasheng Road, Jinshan District, Shanghai, 201500 Applicant after: Shanghai Libang Changrunfa Coatings Co., Ltd. Address before: No.578 Xiasheng Road, Jinshan District, Shanghai, 201500 Applicant before: Shanghai Changrunfa Paint Co., Ltd. |
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Application publication date: 20161214 |