CN106220962A - A kind of aging-resistant mineral fibres filling-foam stone corrugating media and preparation method thereof - Google Patents

A kind of aging-resistant mineral fibres filling-foam stone corrugating media and preparation method thereof Download PDF

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Publication number
CN106220962A
CN106220962A CN201610675266.5A CN201610675266A CN106220962A CN 106220962 A CN106220962 A CN 106220962A CN 201610675266 A CN201610675266 A CN 201610675266A CN 106220962 A CN106220962 A CN 106220962A
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stone
corrugating media
wollastonite
aging
colophonium
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李俊俊
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Anqing Audi Stex Packaging Co Ltd
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Anqing Audi Stex Packaging Co Ltd
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Priority to CN201610675266.5A priority Critical patent/CN106220962A/en
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/06—Polyethene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C44/00—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
    • B29C44/20—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles for articles of indefinite length
    • B29C44/28—Expanding the moulding material on continuous moving surfaces without restricting the upwards growth of the foam
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C59/00—Surface shaping of articles, e.g. embossing; Apparatus therefor
    • B29C59/02—Surface shaping of articles, e.g. embossing; Apparatus therefor by mechanical means, e.g. pressing
    • B29C59/04—Surface shaping of articles, e.g. embossing; Apparatus therefor by mechanical means, e.g. pressing using rollers or endless belts
    • B29C59/046—Surface shaping of articles, e.g. embossing; Apparatus therefor by mechanical means, e.g. pressing using rollers or endless belts for layered or coated substantially flat surfaces
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/06—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent
    • C08J9/10—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent developing nitrogen, the blowing agent being a compound containing a nitrogen-to-nitrogen bond
    • C08J9/102—Azo-compounds
    • C08J9/103—Azodicarbonamide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/36—After-treatment
    • C08J9/365—Coating
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K9/00—Use of pretreated ingredients
    • C08K9/08—Ingredients agglomerated by treatment with a binding agent
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
    • C09D127/02—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
    • C09D127/12—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • C09D127/18—Homopolymers or copolymers of tetrafluoroethene
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18—Fireproof paints including high temperature resistant paints
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2016/00—Articles with corrugations or pleats
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00—Foams characterized by the expanding agent
    • C08J2203/04—N2 releasing, ex azodicarbonamide or nitroso compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/04—Homopolymers or copolymers of ethene
    • C08J2323/06—Polyethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2427/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2427/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2427/12—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • C08J2427/18—Homopolymers or copolymers of tetrafluoroethylene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2217—Oxides; Hydroxides of metals of magnesium
    • C08K2003/2224—Magnesium hydroxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2237—Oxides; Hydroxides of metals of titanium
    • C08K2003/2241—Titanium dioxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/011—Nanostructured additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/02—Flame or fire retardant/resistant
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00—Applications
    • C08L2203/14—Applications used for foams

Abstract

The invention discloses a kind of aging-resistant mineral fibres filling-foam stone corrugating media and preparation method thereof, it is characterised in that be made up of the raw material of following weight portion: calcium carbonate 15 20, nano titanium oxide 12, kieselguhr 15 20, antioxidant DNP 12, wollastonite 15 20, polyethylene 30 40, azodicarbonamide 0.5 1, glutinous rice flour 12, Colophonium alcoholic solution 50 60, ptfe emulsion 30 40, Mg (OH)2 35, polyacrylate dispersion 5 10, dilute sulfuric acid 30 40, dodecyl sodium sulfate 12, ethanol 5 10；The stone corrugating media that the present invention prepares has that pore is the finest and closely woven, the feature of light weight, improves its water proof fire retardant, moisture-proof, antibiotic so that it is can preferably be applied to packaging field；Coating coordinates the antioxidant of interpolation, improves the ageing resistace of this corrugated paper.

Description

A kind of aging-resistant mineral fibres filling-foam stone corrugating media and preparation method thereof
Technical field
The present invention relates to stone paper field, be specifically related to a kind of aging-resistant mineral fibres filling-foam stone corrugating media And preparation method thereof.
Technical background
Corrugated paper, also known as corrugated cardboard, is bonded by least one of which corrugated paper and one layer of boxboard, has preferable bullet Property and extensibility, mainly for the manufacture of carton, other packaging material of the sandwich and delicate articles of carton.Traditional corrugated paper General employing local method straw pulp and waste paper, through making beating, are formed like the base board of manila board, then machining make to roll into corrugated, so After be bonded with boxboard at adhesive such as its surface sodium silicate.Along with the continuous enhancing of whole world low-carbon environment-friendly consciousness, people Be devoted to more and more to research and develop green material, stone paper as a kind of novel environment friendly synthetic paper at home and abroad by Gradually receive attention and development.The primary raw material of stone paper is a large amount of stone powder, a small amount of resin and some auxiliary agents, main by these Want raw material through mixing, modified, pelletize, extrude, the technique such as stretching i.e. can be made into stone paper.Stone paper is made corrugated paper, knot The advantage having closed stone paper and corrugated paper, tensile strength is big, folding damage resistibility can good, tearing strength is high, water-fast, oil resistant, Chemical resistance highlights, and has the most wide application space in packaging material field.
Peak utilizes calcium carbonate, polyethylene and azodicarbonamide in " preparation of foaming stone paper and performance detection ", Through high speed cold, the technique such as mixed, melting mixing is prepared for a kind of foaming stone paper, but what this stone paper used as packaging Time, there is also water proof fire retardant poor performance, the shortcoming of flexible poor toughness.
Summary of the invention
Based on above thinking, it is an object of the invention to provide a kind of water proof fire retardant, and good springiness, flexible good, tool There are the tensile strength of excellence and the stone paper of incompressible intensity and preparation method thereof.
The technical problem to be solved uses following technical scheme to realize:
A kind of aging-resistant mineral fibres filling-foam stone corrugating media, it is characterised in that by the raw material system of following weight portion Become:
Calcium carbonate 15-20, nano titanium oxide 1-2, kieselguhr 15-20, antioxidant DNP 1-2, wollastonite 15-20, polyethylene 30-40, azodicarbonamide 0.5-1, glutinous rice flour 1-2, Colophonium alcoholic solution 50-60, ptfe emulsion 30-40, Mg (OH)2 3-5, polyacrylate dispersion 5-10, dilute sulfuric acid 30-40, dodecyl sodium sulfate 1-2, ethanol 5-10；
Described ptfe emulsion solid content is 30-45%；Polyacrylate dispersion solid content is 30-50%；Dilute sulfuric acid concentration For 30-50%；Colophonium alcoholic solution solid content is 50-70%；The wollastonite of raphioid fiber crystal structure selected by wollastonite.
Described a kind of aging-resistant mineral fibres filling-foam stone corrugating media and preparation method thereof, by following steps Make:
A. kieselguhr is added stirring acidifying 2-3h in dilute sulfuric acid, then filters, after drying, by the kieselguhr obtained, silicon ash Stone, calcium carbonate and Colophonium alcoholic solution send into fluidized-bed reactor, set fluidized-bed reactor temperature as 40-70 DEG C, by sky Wollastonite, calcium carbonate, kieselguhr are suspended among the fluid of motion by gas, so that acicular wollastonite is interspersed in diatomaceous micro- Hole, its gap calcium carbonate-filled, make three be formed by the effect of Colophonium and there is the compound particles of fibrous-network structure, and Colophonium is had to wrap up；
B., at 80-100 DEG C, glutinous rice flour, azodicarbonamide, dodecyl sodium sulfate are joined in polyethylene, in stirring Stirring in machine, be subsequently adding step a gained compound particles, proceed to single screw extrusion machine after mix homogeneously, extrusion is pre-to be sent out Bubble paper membrane, by controlling carry-over pinch rolls, is carried out the longitudinal stretching of about 2 times, is entered by pre-hot-rolling and hot-pressing roller prefoam paper membrane Row foaming, thus obtain microcellular foam material；
C. by Mg (OH)2, nano titanium oxide join in ethanol, in ultrasonic disperse system high speed disperse 50-100 min After, regulation ultrasonic temperature is 40-70 DEG C, adds polyacrylate dispersion, high speed dispersion 70-130 min, obtains Mg (OH)2Outstanding Turbid liquid, through sucking filtration, dries, pulverizes and obtain the modified Mg (OH) of powder2；
D. by powdered modified for step c gained Mg (OH)2Join in ptfe emulsion, add antioxidant DNP, stirring Uniformly, make fireproof coating and be applied to step b gained microcellular foam material surface, be then processed to form waveform by corrugated roller Foaming stone corrugating media.
Described a kind of aging-resistant mineral fibres filling-foam stone corrugating media and preparation method thereof, its feature exists In, extruder temperature controls at 150-180 DEG C, and the temperature of pre-hot-rolling controls at 130-160 DEG C, and the temperature of hot-pressing roller controls 160-220℃。
The invention has the beneficial effects as follows: interspersed being connected with diatomaceous by acicular wollastonite, calcium carbonate fills up its space, Ensure that the space structure of fiber, the kieselguhr of almost spherical has elastic buffer, makes stone corrugating media have fibrous web-like Supportive and condrapable nature, be simultaneously introduced Colophonium, is possible not only to promote that acicular wollastonite, kieselguhr are netted with what calcium carbonate was formed The holding of space structure, and be conducive to its dispersion in polyethylene and fusion；Add azodicarbonamide foaming agent and ten Dialkyl sulfonates so as to get stone corrugating media have that pore is the finest and closely woven, the feature of light weight, facilitate the fortune after packaging Defeated, save the energy；Use polyacrylate dispersion modified magnesium hydroxide, improve its dispersibility in ptfe emulsion and Stability, is coated stone corrugating media by this emulsion, improves its water proof fire retardant, moisture-proof, antibiotic so that it is can be more Good is applied to packaging field；Coating coordinates the antioxidant of interpolation, improves the ageing resistace of this corrugated paper.
Detailed description of the invention
For the technological means making the present invention realize, creation characteristic, reach purpose and be easy to understand with effect, below knot Close specific embodiment, the present invention is expanded on further.
Embodiment
A kind of aging-resistant mineral fibres filling-foam stone corrugating media, it is characterised in that former by following weight portion Material is made:
Calcium carbonate 15, nano titanium oxide 2, kieselguhr 20, antioxidant DNP 2, wollastonite 20, polyethylene 40, azo two formyl Amine 1, glutinous rice flour 2, Colophonium alcoholic solution 60, ptfe emulsion 40, Mg (OH)2 5, polyacrylate dispersion 10, dilute sulfuric acid 40, dodecyl sodium sulfate 2, ethanol 10；
Described ptfe emulsion solid content is 30-45%；Polyacrylate dispersion solid content is 30-50%；Dilute sulfuric acid concentration For 30-50%；Colophonium alcoholic solution solid content is 50-70%；The wollastonite of raphioid fiber crystal structure selected by wollastonite.
Described a kind of aging-resistant mineral fibres filling-foam stone corrugating media and preparation method thereof, by following steps Make:
A. kieselguhr is added stirring acidifying 2-3h in dilute sulfuric acid, then filters, after drying, by the kieselguhr obtained, silicon ash Stone, calcium carbonate and Colophonium alcoholic solution send into fluidized-bed reactor, set fluidized-bed reactor temperature as 40-70 DEG C, by sky Wollastonite, calcium carbonate, kieselguhr are suspended among the fluid of motion by gas, so that acicular wollastonite is interspersed in diatomaceous micro- Hole, its gap calcium carbonate-filled, make three be formed by the effect of Colophonium and there is the compound particles of fibrous-network structure, and Colophonium is had to wrap up；
B., at 80-100 DEG C, glutinous rice flour, azodicarbonamide, dodecyl sodium sulfate are joined in polyethylene, in stirring Stirring in machine, be subsequently adding step a gained compound particles, proceed to single screw extrusion machine after mix homogeneously, extrusion is pre-to be sent out Bubble paper membrane, by controlling carry-over pinch rolls, is carried out the longitudinal stretching of about 2 times, is entered by pre-hot-rolling and hot-pressing roller prefoam paper membrane Row foaming, thus obtain microcellular foam material；
C. by Mg (OH)2, nano titanium oxide join in ethanol, in ultrasonic disperse system high speed disperse 50-100 min After, regulation ultrasonic temperature is 40-70 DEG C, adds polyacrylate dispersion, high speed dispersion 70-130 min, obtains Mg (OH)2Outstanding Turbid liquid, through sucking filtration, dries, pulverizes and obtain the modified Mg (OH) of powder2；
D. by powdered modified for step c gained Mg (OH)2Join in ptfe emulsion, add antioxidant DNP, stirring Uniformly, make fireproof coating and be applied to step b gained microcellular foam material surface, be then processed to form waveform by corrugated roller Foaming stone corrugating media.
Described a kind of aging-resistant mineral fibres filling-foam stone corrugating media and preparation method thereof, its feature exists In, extruder temperature controls at 150-180 DEG C, and the temperature of pre-hot-rolling controls at 130-160 DEG C, and the temperature of hot-pressing roller controls 160-220℃。
The technical specification of the present invention is:
Laterally average tensile strength >=150MPa；Longitudinal average tensile strength >=250MPa；Transverse breakage percentage elongation >=130MPa； Longitudinal elongation at break rate >=120Mpa.

Claims (3)

1. an aging-resistant mineral fibres filling-foam stone corrugating media, it is characterised in that by the raw material of following weight portion Make:
Calcium carbonate 15-20, nano titanium oxide 1-2, kieselguhr 15-20, antioxidant DNP 1-2, wollastonite 15-20, polyethylene 30-40, azodicarbonamide 0.5-1, glutinous rice flour 1-2, Colophonium alcoholic solution 50-60, ptfe emulsion 30-40, Mg (OH)2 3-5, polyacrylate dispersion 5-10, dilute sulfuric acid 30-40, dodecyl sodium sulfate 1-2, ethanol 5-10；
Described ptfe emulsion solid content is 30-45%；Polyacrylate dispersion solid content is 30-50%；Dilute sulfuric acid concentration For 30-50%；Colophonium alcoholic solution solid content is 50-70%；The wollastonite of raphioid fiber crystal structure selected by wollastonite.
A kind of aging-resistant mineral fibres filling-foam stone corrugating media the most according to claim 1 and preparation side thereof Method, is made up of following steps:
A. kieselguhr is added stirring acidifying 2-3h in dilute sulfuric acid, then filters, after drying, by the kieselguhr obtained, silicon ash Stone, calcium carbonate and Colophonium alcoholic solution send into fluidized-bed reactor, set fluidized-bed reactor temperature as 40-70 DEG C, by sky Wollastonite, calcium carbonate, kieselguhr are suspended among the fluid of motion by gas, so that acicular wollastonite is interspersed in diatomaceous micro- Hole, its gap calcium carbonate-filled, make three be formed by the effect of Colophonium and there is the compound particles of fibrous-network structure, and Colophonium is had to wrap up；
B., at 80-100 DEG C, glutinous rice flour, azodicarbonamide, dodecyl sodium sulfate are joined in polyethylene, in stirring Stirring in machine, be subsequently adding step a gained compound particles, proceed to single screw extrusion machine after mix homogeneously, extrusion is pre-to be sent out Bubble paper membrane, by controlling carry-over pinch rolls, is carried out the longitudinal stretching of about 2 times, is entered by pre-hot-rolling and hot-pressing roller prefoam paper membrane Row foaming, thus obtain microcellular foam material；
C. by Mg (OH)2, nano titanium oxide join in ethanol, in ultrasonic disperse system high speed disperse 50-100 min After, regulation ultrasonic temperature is 40-70 DEG C, adds polyacrylate dispersion, high speed dispersion 70-130 min, obtains Mg (OH)2Outstanding Turbid liquid, through sucking filtration, dries, pulverizes and obtain the modified Mg (OH) of powder2；
D. by powdered modified for step c gained Mg (OH)2Join in ptfe emulsion, add antioxidant DNP, stirring Uniformly, make fireproof coating and be applied to step b gained microcellular foam material surface, be then processed to form waveform by corrugated roller Foaming stone corrugating media.
A kind of aging-resistant mineral fibres filling-foam stone corrugating media the most according to claim 2 and preparation side thereof Method, it is characterised in that extruder temperature controls at 150-180 DEG C, the temperature of pre-hot-rolling controls at 130-160 DEG C, hot-pressing roller Temperature controls at 160-220 DEG C.
CN201610675266.5A 2016-08-17 2016-08-17 A kind of aging-resistant mineral fibres filling-foam stone corrugating media and preparation method thereof Pending CN106220962A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107100030A (en) * 2017-05-24 2017-08-29 青岛榕信工贸有限公司 A kind of coating latex for being used to prepare foaming extrusion coating paper

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102060564A (en) * 2010-11-16 2011-05-18 成都新柯力化工科技有限公司 Light-weight environmental-friendly stone paper and preparation method thereof
CN202826606U (en) * 2012-04-17 2013-03-27 天象集团有限责任公司 Environment-friendly flame-retardant wallpaper
CN104448388A (en) * 2014-11-03 2015-03-25 成都新柯力化工科技有限公司 Special calcium metasilicate fiber for rich mineral paper and preparation method of special calcium metasilicate fiber

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CN102060564A (en) * 2010-11-16 2011-05-18 成都新柯力化工科技有限公司 Light-weight environmental-friendly stone paper and preparation method thereof
CN202826606U (en) * 2012-04-17 2013-03-27 天象集团有限责任公司 Environment-friendly flame-retardant wallpaper
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CN107100030A (en) * 2017-05-24 2017-08-29 青岛榕信工贸有限公司 A kind of coating latex for being used to prepare foaming extrusion coating paper
CN107100030B (en) * 2017-05-24 2018-11-09 青岛榕信工贸有限公司 A kind of coating latex being used to prepare foaming extrusion coating paper

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Application publication date: 20161214