CN106279894A - A kind of mineral fibres filling-foam stone corrugating media of cracking resistance and preparation method thereof - Google Patents
A kind of mineral fibres filling-foam stone corrugating media of cracking resistance and preparation method thereof Download PDFInfo
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- CN106279894A CN106279894A CN201610675267.XA CN201610675267A CN106279894A CN 106279894 A CN106279894 A CN 106279894A CN 201610675267 A CN201610675267 A CN 201610675267A CN 106279894 A CN106279894 A CN 106279894A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C44/00—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
- B29C44/34—Auxiliary operations
- B29C44/60—Measuring, controlling or regulating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/92—Measuring, controlling or regulating
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/0427—Coating with only one layer of a composition containing a polymer binder
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/06—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent
- C08J9/10—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent developing nitrogen, the blowing agent being a compound containing a nitrogen-to-nitrogen bond
- C08J9/102—Azo-compounds
- C08J9/103—Azodicarbonamide
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
- C09D127/02—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
- C09D127/12—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
- C09D127/18—Homopolymers or copolymers of tetrafluoroethene
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92504—Controlled parameter
- B29C2948/92704—Temperature
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/04—N2 releasing, ex azodicarbonamide or nitroso compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2205/00—Foams characterised by their properties
- C08J2205/04—Foams characterised by their properties characterised by the foam pores
- C08J2205/044—Micropores, i.e. average diameter being between 0,1 micrometer and 0,1 millimeter
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/04—Homopolymers or copolymers of ethene
- C08J2323/06—Polyethene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2427/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
- C08J2427/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
- C08J2427/12—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
- C08J2427/18—Homopolymers or copolymers of tetrafluoroethylene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
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Abstract
Mineral fibres filling-foam stone corrugating media that the invention discloses a kind of cracking resistance and preparation method thereof, it is characterised in that be made up of the raw material of following weight portion: polyethylene glycol oxide 24, calcium carbonate 15 20, hard paraffin 12, kieselguhr 15 20, wollastonite 15 20, polyethylene 30 40, azodicarbonamide 0.5 1, nylon fiber 12, Colophonium alcoholic solution 50 60, ptfe emulsion 30 40, Mg (OH)2 35, polyacrylate dispersion 5 10, dilute sulfuric acid 30 40, dodecyl sodium sulfate 12, ethanol 5 10;The stone corrugating media that the present invention prepares has that pore is the finest and closely woven, the feature of light weight, improves its water proof fire retardant, moisture-proof, antibiotic so that it is can preferably be applied to packaging field;By the addition of polyethylene glycol oxide, improve the performance of corrugating media cracking resistance.
Description
Technical field
The present invention relates to stone paper field, be specifically related to the mineral fibres filling-foam stone corrugating media of a kind of cracking resistance
And preparation method thereof.
Technical background
Corrugated paper, also known as corrugated cardboard, is bonded by least one of which corrugated paper and one layer of boxboard, has preferable bullet
Property and extensibility, mainly for the manufacture of carton, other packaging material of the sandwich and delicate articles of carton.Traditional corrugated paper
General employing local method straw pulp and waste paper, through making beating, are formed like the base board of manila board, then machining make to roll into corrugated, so
After be bonded with boxboard at adhesive such as its surface sodium silicate.Along with the continuous enhancing of whole world low-carbon environment-friendly consciousness, people
Be devoted to more and more to research and develop green material, stone paper as a kind of novel environment friendly synthetic paper at home and abroad by
Gradually receive attention and development.The primary raw material of stone paper is a large amount of stone powder, a small amount of resin and some auxiliary agents, main by these
Want raw material through mixing, modified, pelletize, extrude, the technique such as stretching i.e. can be made into stone paper.Stone paper is made corrugated paper, knot
The advantage having closed stone paper and corrugated paper, tensile strength is big, folding damage resistibility can good, tearing strength is high, water-fast, oil resistant,
Chemical resistance highlights, and has the most wide application space in packaging material field.
Peak utilizes calcium carbonate, polyethylene and azodicarbonamide in " preparation of foaming stone paper and performance detection ",
Through high speed cold, the technique such as mixed, melting mixing is prepared for a kind of foaming stone paper, but what this stone paper used as packaging
Time, there is also water proof fire retardant poor performance, the shortcoming of flexible poor toughness.
Summary of the invention
Based on above thinking, it is an object of the invention to provide a kind of water proof fire retardant, and good springiness, flexible good, tool
There are the tensile strength of excellence and the stone paper of incompressible intensity and preparation method thereof.
The technical problem to be solved uses following technical scheme to realize:
The mineral fibres filling-foam stone corrugating media of a kind of cracking resistance, it is characterised in that by the raw material system of following weight portion
Become:
Polyethylene glycol oxide 2-4, calcium carbonate 15-20, hard paraffin 1-2, kieselguhr 15-20, wollastonite 15-20, polyethylene 30-
40, azodicarbonamide 0.5-1, nylon fiber 1-2, Colophonium alcoholic solution 50-60, ptfe emulsion 30-40, Mg
(OH)2 3-5, polyacrylate dispersion 5-10, dilute sulfuric acid 30-40, dodecyl sodium sulfate 1-2, ethanol 5-10;
Described ptfe emulsion solid content is 30-45%;Polyacrylate dispersion solid content is 30-50%;Dilute sulfuric acid concentration
For 30-50%;Colophonium alcoholic solution solid content is 50-70%;The wollastonite of raphioid fiber crystal structure selected by wollastonite.
Mineral fibres filling-foam stone corrugating media of described a kind of cracking resistance and preparation method thereof, by following steps
Make:
A. kieselguhr is added stirring acidifying 2-3h in dilute sulfuric acid, then filters, after drying, by the kieselguhr obtained, silicon ash
Stone, calcium carbonate and Colophonium alcoholic solution send into fluidized-bed reactor, set fluidized-bed reactor temperature as 40-70 DEG C, by sky
Wollastonite, calcium carbonate, kieselguhr are suspended among the fluid of motion by gas, so that acicular wollastonite is interspersed in diatomaceous micro-
Hole, its gap calcium carbonate-filled, make three be formed by the effect of Colophonium and there is the compound particles of fibrous-network structure, and
Colophonium is had to wrap up;
B., at 80-140 DEG C, azodicarbonamide, dodecyl sodium sulfate are joined in polyethylene, adds polyoxygenated
Ethylene, stirs in blender, is subsequently adding step a gained compound particles and nylon fiber, proceeds to after mix homogeneously
Single screw extrusion machine, extrudes prefoam paper membrane, by controlling carry-over pinch rolls, prefoam paper membrane carries out the longitudinal stretching of about 2 times,
Foamed by pre-hot-rolling and hot-pressing roller, thus obtain microcellular foam material;
C. by Mg (OH)2Join in ethanol, after ultrasonic disperse system high speed dispersion 50-100 min, regulate ultrasonic temperature
Degree, for 40-70 DEG C, adds polyacrylate dispersion, high speed dispersion 70-130 min, obtains Mg (OH)2Suspension, through sucking filtration, baking
Dry, pulverizing obtains the modified Mg (OH) of powder2;
D. by powdered modified for step c gained Mg (OH)2Join in ptfe emulsion, add paraffin, stir,
Make fireproof coating and be applied to step b gained microcellular foam material surface, be then processed to form the foaming of waveform by corrugated roller
Stone corrugating media.
Mineral fibres filling-foam stone corrugating media of described a kind of cracking resistance and preparation method thereof, its feature exists
In, extruder temperature controls at 150-180 DEG C, and the temperature of pre-hot-rolling controls at 130-160 DEG C, and the temperature of hot-pressing roller controls
160-220℃。
The invention has the beneficial effects as follows: interspersed being connected with diatomaceous by acicular wollastonite, calcium carbonate fills up its space,
Ensure that the space structure of fiber, the kieselguhr of almost spherical has elastic buffer, makes stone corrugating media have fibrous web-like
Supportive and condrapable nature, be simultaneously introduced Colophonium, is possible not only to promote that acicular wollastonite, kieselguhr are netted with what calcium carbonate was formed
The holding of space structure, and be conducive to its dispersion in polyethylene and fusion;Add azodicarbonamide foaming agent and ten
Dialkyl sulfonates so as to get stone corrugating media have that pore is the finest and closely woven, the feature of light weight, facilitate the fortune after packaging
Defeated, save the energy;Use polyacrylate dispersion modified magnesium hydroxide, improve its dispersibility in ptfe emulsion and
Stability, is coated stone corrugating media by this emulsion, improves its water proof fire retardant, moisture-proof, antibiotic so that it is can be more
Good is applied to packaging field;By the addition of polyethylene glycol oxide, improve the performance of corrugating media cracking resistance.
Detailed description of the invention
For the technological means making the present invention realize, creation characteristic, reach purpose and be easy to understand with effect, below knot
Close specific embodiment, the present invention is expanded on further.
Embodiment
The mineral fibres filling-foam stone corrugating media of a kind of cracking resistance, it is characterised in that former by following weight portion
Material is made:
Polyethylene glycol oxide 4, calcium carbonate 20, hard paraffin 2, kieselguhr 20, wollastonite 20, polyethylene 40, azodicarbonamide 1,
Nylon fiber 2, Colophonium alcoholic solution 60, ptfe emulsion 40, Mg (OH)2 5, polyacrylate dispersion 10, dilute sulfuric acid 40,
Dodecyl sodium sulfate 2, ethanol 10;
Described ptfe emulsion solid content is 30-45%;Polyacrylate dispersion solid content is 30-50%;Dilute sulfuric acid concentration
For 30-50%;Colophonium alcoholic solution solid content is 50-70%;The wollastonite of raphioid fiber crystal structure selected by wollastonite.
Mineral fibres filling-foam stone corrugating media of described a kind of cracking resistance and preparation method thereof, by following steps
Make:
A. kieselguhr is added stirring acidifying 2-3h in dilute sulfuric acid, then filters, after drying, by the kieselguhr obtained, silicon ash
Stone, calcium carbonate and Colophonium alcoholic solution send into fluidized-bed reactor, set fluidized-bed reactor temperature as 40-70 DEG C, by sky
Wollastonite, calcium carbonate, kieselguhr are suspended among the fluid of motion by gas, so that acicular wollastonite is interspersed in diatomaceous micro-
Hole, its gap calcium carbonate-filled, make three be formed by the effect of Colophonium and there is the compound particles of fibrous-network structure, and
Colophonium is had to wrap up;
B., at 80-140 DEG C, azodicarbonamide, dodecyl sodium sulfate are joined in polyethylene, adds polyoxygenated
Ethylene, stirs in blender, is subsequently adding step a gained compound particles and nylon fiber, proceeds to after mix homogeneously
Single screw extrusion machine, extrudes prefoam paper membrane, by controlling carry-over pinch rolls, prefoam paper membrane carries out the longitudinal stretching of about 2 times,
Foamed by pre-hot-rolling and hot-pressing roller, thus obtain microcellular foam material;
C. by Mg (OH)2Join in ethanol, after ultrasonic disperse system high speed dispersion 50-100 min, regulate ultrasonic temperature
Degree, for 40-70 DEG C, adds polyacrylate dispersion, high speed dispersion 70-130 min, obtains Mg (OH)2Suspension, through sucking filtration, baking
Dry, pulverizing obtains the modified Mg (OH) of powder2;
D. by powdered modified for step c gained Mg (OH)2Join in ptfe emulsion, add paraffin, stir,
Make fireproof coating and be applied to step b gained microcellular foam material surface, be then processed to form the foaming of waveform by corrugated roller
Stone corrugating media.
Mineral fibres filling-foam stone corrugating media of described a kind of cracking resistance and preparation method thereof, its feature exists
In, extruder temperature controls at 150-180 DEG C, and the temperature of pre-hot-rolling controls at 130-160 DEG C, and the temperature of hot-pressing roller controls
160-220℃。
The technical specification of the present invention is:
Laterally average tensile strength >=150MPa;Longitudinal average tensile strength >=250MPa;Transverse breakage percentage elongation >=130MPa;
Longitudinal elongation at break rate >=120Mpa.
Claims (3)
1. the mineral fibres filling-foam stone corrugating media of a cracking resistance, it is characterised in that by the raw material of following weight portion
Make:
Polyethylene glycol oxide 2-4, calcium carbonate 15-20, hard paraffin 1-2, kieselguhr 15-20, wollastonite 15-20, polyethylene 30-
40, azodicarbonamide 0.5-1, nylon fiber 1-2, Colophonium alcoholic solution 50-60, ptfe emulsion 30-40, Mg
(OH)2 3-5, polyacrylate dispersion 5-10, dilute sulfuric acid 30-40, dodecyl sodium sulfate 1-2, ethanol 5-10;
Described ptfe emulsion solid content is 30-45%;Polyacrylate dispersion solid content is 30-50%;Dilute sulfuric acid concentration
For 30-50%;Colophonium alcoholic solution solid content is 50-70%;The wollastonite of raphioid fiber crystal structure selected by wollastonite.
The mineral fibres filling-foam stone corrugating media of a kind of cracking resistance the most according to claim 1 and preparation side thereof
Method, is made up of following steps:
A. kieselguhr is added stirring acidifying 2-3h in dilute sulfuric acid, then filters, after drying, by the kieselguhr obtained, silicon ash
Stone, calcium carbonate and Colophonium alcoholic solution send into fluidized-bed reactor, set fluidized-bed reactor temperature as 40-70 DEG C, by sky
Wollastonite, calcium carbonate, kieselguhr are suspended among the fluid of motion by gas, so that acicular wollastonite is interspersed in diatomaceous micro-
Hole, its gap calcium carbonate-filled, make three be formed by the effect of Colophonium and there is the compound particles of fibrous-network structure, and
Colophonium is had to wrap up;
B., at 80-140 DEG C, azodicarbonamide, dodecyl sodium sulfate are joined in polyethylene, adds polyoxygenated
Ethylene, stirs in blender, is subsequently adding step a gained compound particles and nylon fiber, proceeds to after mix homogeneously
Single screw extrusion machine, extrudes prefoam paper membrane, by controlling carry-over pinch rolls, prefoam paper membrane carries out the longitudinal stretching of about 2 times,
Foamed by pre-hot-rolling and hot-pressing roller, thus obtain microcellular foam material;
C. by Mg (OH)2Join in ethanol, after ultrasonic disperse system high speed dispersion 50-100 min, regulate ultrasonic temperature
For 40-70 DEG C, add polyacrylate dispersion, high speed dispersion 70-130 min, obtain Mg (OH)2Suspension, through sucking filtration, baking
Dry, pulverizing obtains the modified Mg (OH) of powder2;
D. by powdered modified for step c gained Mg (OH)2Join in ptfe emulsion, add paraffin, stir,
Make fireproof coating and be applied to step b gained microcellular foam material surface, be then processed to form the foaming of waveform by corrugated roller
Stone corrugating media.
The mineral fibres filling-foam stone corrugating media of a kind of cracking resistance the most according to claim 2 and preparation side thereof
Method, it is characterised in that extruder temperature controls at 150-180 DEG C, the temperature of pre-hot-rolling controls at 130-160 DEG C, hot-pressing roller
Temperature controls at 160-220 DEG C.
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CN101696290A (en) * | 2009-11-03 | 2010-04-21 | 四川剑南春(集团)有限责任公司 | High-lubrication wear-resisting polyolefin material, high-lubrication wear-resisting polyolefin pipe and preparation method thereof |
CN102060564A (en) * | 2010-11-16 | 2011-05-18 | 成都新柯力化工科技有限公司 | Light-weight environmental-friendly stone paper and preparation method thereof |
CN202826606U (en) * | 2012-04-17 | 2013-03-27 | 天象集团有限责任公司 | Environment-friendly flame-retardant wallpaper |
CN104448388A (en) * | 2014-11-03 | 2015-03-25 | 成都新柯力化工科技有限公司 | Special calcium metasilicate fiber for rich mineral paper and preparation method of special calcium metasilicate fiber |
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2016
- 2016-08-17 CN CN201610675267.XA patent/CN106279894A/en active Pending
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Publication number | Priority date | Publication date | Assignee | Title |
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CN101696290A (en) * | 2009-11-03 | 2010-04-21 | 四川剑南春(集团)有限责任公司 | High-lubrication wear-resisting polyolefin material, high-lubrication wear-resisting polyolefin pipe and preparation method thereof |
CN102060564A (en) * | 2010-11-16 | 2011-05-18 | 成都新柯力化工科技有限公司 | Light-weight environmental-friendly stone paper and preparation method thereof |
CN202826606U (en) * | 2012-04-17 | 2013-03-27 | 天象集团有限责任公司 | Environment-friendly flame-retardant wallpaper |
CN104448388A (en) * | 2014-11-03 | 2015-03-25 | 成都新柯力化工科技有限公司 | Special calcium metasilicate fiber for rich mineral paper and preparation method of special calcium metasilicate fiber |
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