CN107100030A - A kind of coating latex for being used to prepare foaming extrusion coating paper - Google Patents
A kind of coating latex for being used to prepare foaming extrusion coating paper Download PDFInfo
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- CN107100030A CN107100030A CN201710374757.0A CN201710374757A CN107100030A CN 107100030 A CN107100030 A CN 107100030A CN 201710374757 A CN201710374757 A CN 201710374757A CN 107100030 A CN107100030 A CN 107100030A
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- Prior art keywords
- foaming
- layer
- paper
- coating
- latex
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Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/56—Macromolecular organic compounds or oligomers thereof obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D21H19/58—Polymers or oligomers of diolefins, aromatic vinyl monomers or unsaturated acids or derivatives thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/40—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
- B41M5/42—Intermediate, backcoat, or covering layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
- B41M5/52—Macromolecular coatings
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
- B41M5/52—Macromolecular coatings
- B41M5/5218—Macromolecular coatings characterised by inorganic additives, e.g. pigments, clays
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
- B41M5/52—Macromolecular coatings
- B41M5/5263—Macromolecular coatings characterised by the use of polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/38—Coatings with pigments characterised by the pigments
- D21H19/385—Oxides, hydroxides or carbonates
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/06—Paper forming aids
- D21H21/12—Defoamers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M2205/00—Printing methods or features related to printing methods; Location or type of the layers
- B41M2205/40—Cover layers; Layers separated from substrate by imaging layer; Protective layers; Layers applied before imaging
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Inorganic Chemistry (AREA)
- Laminated Bodies (AREA)
- Paper (AREA)
- Wrappers (AREA)
Abstract
It is an object of the invention to provide a kind of coating latex for being used to prepare foaming extrusion coating paper, gas, which easily breaks through PE or PP layers, when intensive blow point after existing leaching membrane paper foaming and foaming are solved with the extrusion coating paper of latex preparation causes this deficiency of foaming damage layer, be conducive to printing the holding of effect simultaneously after printing, so as to make up the deficiencies in the prior art.Coating latex provided by the present invention, includes acrylate polymer 33 55%, defoamer 1% 2%, titanium oxide (5 20 μm of particle diameter) 24% 35%, deionized water 20% 30%.Foaming extrusion coating paper prepared by coating latex prepared by the present invention overcomes the shortcoming of foaming layer foaming damage layer caused by gas easily breaks through PE or PP layers when blow point is intensive and fires of existing blistering paper, and then provides complete continuously printing surface for printing, maintain good printing effect and visual effect.
Description
Technical field
The invention belongs to food-grade field of packaging material, and in particular to a kind of painting for being used to prepare foaming extrusion coating paper
Cloth latex.
Background technology
Polymeric packaging material is often requested to have choke, protection against the tide because content is different, guarantor is fragrant, prevent fat migration etc.
A variety of functions；The packaging material of single variety can not usually meet this requirement, therefore, and polymer composite is in packaging field
It is widely used, particularly in terms of packing articles.Different use requirements can be met from different barrier packaging materials.
Large-scale foaming extrusion coating paper is mostly leaching membrane paper foaming on existing market, and so-called leaching membrane paper is exactly by polyethylene
(PE), polypropylene (PP) class plastic pellet is coated in the composite of paper surface by casting machine, and main feature is exactly that this is answered
Condensation material with grease proofing, waterproof (relative) and be able to can be sealed；And i.e. it is exactly leaching membrane layer PE or PP that leaching membrane paper foaming is basic
Layer foaming.But gas, which easily breaks through PE or PP layers, when existing leaching membrane paper has intensive blow point and foaming causes the damage layer that foams
Shortcoming, cause printing effect undesirable.
It is an object of the invention to provide a kind of coating latex for being used to prepare foaming extrusion coating paper, the extrusion coating paper of preparation has more
Good printing effect.
The content of the invention
It is an object of the invention to provide a kind of coating latex for being used to prepare foaming extrusion coating paper, with prepared by the latex being combined
Gas, which easily breaks through PE or PP layers, when paper solves intensive blow point after existing leaching membrane paper foaming and foaming causes foaming layer to break
This bad deficiency, while being conducive to printing the holding of effect after printing, so as to make up the deficiencies in the prior art.
Coating latex provided by the present invention, includes acrylate polymer 33-55%, defoamer 1%-2%, oxidation
Titanium (5-20 μm of particle diameter) 24%-35%, deionized water 20%-30%；
As the preferred of embodiment, acrylate polymer preferred mass number 33%,；
As the preferred of embodiment, defoamer, preferred mass number is 1%；
As the preferred of embodiment, the mass fraction of titanium oxide (5-20 μm of particle diameter) is 29%.
The coating latex of the present invention is used to prepare foaming extrusion coating paper.
Foaming extrusion coating paper prepared by the coating latex prepared by the present invention overcomes the foaming layer of existing blistering paper because of foaming
Point is intensive and gas easily breaks through PE or PP layers the shortcoming for causing foaming damage layer when firing, and then completely connects to print to provide
Continuous printing surface, maintains good printing effect and visual effect.
Brief description of the drawings
Fig. 1：The layer structure schematic diagram of the foaming extrusion coating paper of the present invention；
Fig. 2：The schematic perspective view for the product that the foaming compound of the present invention is made；
Fig. 3：The foaming comparison diagram of foaming extrusion coating paper prepared by the embodiment of the present invention 1；
Fig. 4：The product printing effect comparison diagram that the foaming compound of the present invention is made.
Embodiment
Leaching membrane paper foaming used at present in order to reach it is heat-insulated, every a variety of functions of cold and Comfortable attractive, and use will drench
Blow point is intensive after film layer PE or PP foaming materials, but the foaming of existing leaching membrane paper and gas easily breaks through PE or PP layers when foaming
The damage layer that foams is caused, while not being conducive to printing the holding of effect after printing.
In order to overcome the shortcomings of more than existing leaching membrane paper, the present invention is using food-grade leaching membrane paper as base material, with one kind coating glue
Breast is raw material, using different layer structures so that foaming extrusion coating paper can be more intensive because of blow point enough and gas appearance when firing
Easily PE or PP layers is broken through the shortcoming for causing foaming damage layer, while good printing effect can also be kept.
The acrylate polymer used in the specific embodiment of the invention is by Henkel KGaA company with article No. topwin6859
Sell.
Defoamer used is the organic oil based food level defoamer that DOW Chemical is produced in the embodiment of the present invention, and the trade mark is
Airase 4500。
The technical scheme is further described with reference to the accompanying drawings and examples.
Embodiment 1
As depicted in figs. 1 and 2, it is a kind of Novel foaming extrusion coating paper, including first layer is made up of medium density polyethylene MDPE
Barrier layer 1, second layer food-grade is packed for ply of paper 2, the foaming layer 3 that third layer is made up of low density polyethylene, the 4th
Coating layer 4, the outside of third layer foaming layer 3 is applied to using gravure technique by the coating layer 4 that layer is made up of latex coating.Wherein
Coating layer 4 includes acrylate polymer (Henkel V-6859) 33%, defoamer 2%, titanium oxide (5-20 μm of particle diameter) 35%, gone
Ionized water 30%；
Above-mentioned coating latex is used to prepare foaming extrusion coating paper：
Its specific preparation method is：With foaming layer 3, food-grade packaging ply of paper 2 and barrier layer 1 constitute 40+250+20 grams/
Square metre the grade packaged leaching membrane paper of food do base material, one layer of coating layer 4 of gravure, wherein coating layer in 40 grams of foaming layers 3 of the paper
Acrylate polymer (Henkel V-6859) 33%；Defoamer 2%；Titanium oxide (5-20 μm of particle diameter) 35%；Deionized water 30%,
Print speed printing speed is 100 ms/min, and composite at a temperature of 65 DEG C through drying after printing, and the thickness of coating layer 4 is 8um, using infrared
Foam process, 165 DEG C of blowing temperature.
Embodiment 2
As depicted in figs. 1 and 2, it is a kind of Novel foaming extrusion coating paper, including first layer is made up of medium density polyethylene MDPE
Barrier layer 1, second layer food-grade is packed for ply of paper 2, the foaming layer 3 that third layer is made up of low density polyethylene, the 4th
Coating layer 4, the outside of third layer foaming layer 3 is applied to using gravure technique by the coating layer 4 that layer is made up of latex coating.
Its specific preparation method is：With foaming layer 3, food-grade packaging ply of paper 2 and barrier layer 1 constitute 40+280+20 grams/
Square metre packaging for foodstuff leaching membrane paper do base material, one layer of coating layer of gravure, wherein coating layer propylene in 40 grams of foaming layers of the paper
Acid ester polymer (Henkel V-6859) 33%, defoamer 2%, titanium oxide (5-20 μm of particle diameter) 35%, deionized water 30%, printing
Speed is 100 ms/min, and the drying temperature of composite is 65 DEG C after printing, and coating thickness is 8um, using infrared foaming
Technique is foamed, 165 DEG C of blowing temperature.
Embodiment 3
As depicted in figs. 1 and 2, it is a kind of Novel foaming extrusion coating paper, including first layer is made up of medium density polyethylene MDPE
Barrier layer 1, second layer food-grade is packed for ply of paper 2, the foaming layer 3 that third layer is made up of low density polyethylene, the 4th
Coating layer 4, the outside of third layer foaming layer 3 is applied to using gravure technique by the coating layer 4 that layer is made up of latex coating.
Its specific preparation method is：With foaming layer 3, food-grade packaging ply of paper 2 and barrier layer 1 constitute 40+300+20 grams/
Square metre packaging for foodstuff leaching membrane paper do base material, one layer of coating layer of gravure, wherein coating layer propylene in 40 grams of foaming layers of the paper
Acid ester polymer (Henkel V-6859) 33%, defoamer 2%, titanium oxide (5-20 μm of particle diameter) 35%, deionized water 30%, printing
Speed is 100 ms/min, and the drying temperature of composite is 65 DEG C after printing, and coating thickness is 8um, using infrared foaming
Technique is foamed, 165 DEG C of blowing temperature.
Embodiment 4
As depicted in figs. 1 and 2, it is a kind of Novel foaming extrusion coating paper, including first layer is made up of medium density polyethylene MDPE
Barrier layer 1, second layer food-grade is packed for ply of paper 2, the foaming layer 3 that third layer is made up of low density polyethylene, the 4th
Coating layer 4, the outside of third layer foaming layer 3 is applied to using gravure technique by the coating layer 4 that layer is made up of latex coating.
Its specific preparation method is：With foaming layer 3, food-grade packaging ply of paper 2 and barrier layer 1 constitute 40+250+20 grams/
Square metre packaging for foodstuff leaching membrane paper do base material, one layer of coating layer of gravure, wherein coating layer propylene in 40 grams of foaming layers of the paper
Acid ester polymer (Henkel V-6859) 55%, defoamer 1%, titanium oxide (5-20 μm of particle diameter) 24%, deionized water 20%, printing
Speed is 100 ms/min, and the drying temperature of composite is 65 DEG C after printing, and coating thickness is 8um, using infrared foaming
Technique, 165 DEG C of blowing temperature.
Embodiment 5
As depicted in figs. 1 and 2, it is a kind of Novel foaming extrusion coating paper, including first layer is made up of medium density polyethylene MDPE
Barrier layer 1, second layer food-grade is packed for ply of paper 2, the foaming layer 3 that third layer is made up of low density polyethylene, the 4th
Coating layer 4, the outside of third layer foaming layer 3 is applied to using gravure technique by the coating layer 4 that layer is made up of latex coating.
Its specific preparation method is：With foaming layer 3, food-grade packaging ply of paper 2 and barrier layer 1 constitute 40+280+20 grams/
Square metre packaging for foodstuff leaching membrane paper do base material, one layer of coating layer of gravure, wherein coating layer propylene in 40 grams of foaming layers of the paper
Acid ester polymer (Henkel V-6859) 55%, defoamer 1%, titanium oxide (5-20 μm of particle diameter) 24%, deionized water 20%, printing
Speed is 100 ms/min, and the drying temperature of composite is 65 DEG C after printing, and coating thickness is 8um, using infrared foaming
Technique, 165 DEG C of blowing temperature.
Embodiment 6
As depicted in figs. 1 and 2, it is a kind of Novel foaming extrusion coating paper, including first layer is made up of medium density polyethylene MDPE
Barrier layer 1, second layer food-grade is packed for ply of paper 2, the foaming layer 3 that third layer is made up of low density polyethylene, the 4th
Coating layer 4, the outside of third layer foaming layer 3 is applied to using gravure technique by the coating layer 4 that layer is made up of latex coating.
Its specific preparation method is：With foaming layer 3, food-grade packaging ply of paper 2 and barrier layer 1 constitute 40+300+20 grams/
Square metre packaging for foodstuff leaching membrane paper do base material, one layer of coating layer of gravure, wherein coating layer propylene in 40 grams of foaming layers of the paper
Acid ester polymer (Henkel V-6859) 55%, defoamer 1%, titanium oxide (5-20 μm of particle diameter) 24%, deionized water 20%, printing
Speed is 100 ms/min, and the drying temperature of composite is 65 DEG C after printing, and coating thickness is 8um, using infrared foaming
Technique, 165 DEG C of blowing temperature.
Embodiment 7
As depicted in figs. 1 and 2, it is a kind of Novel foaming extrusion coating paper, including first layer is made up of medium density polyethylene MDPE
Barrier layer 1, second layer food-grade is packed for ply of paper 2, the foaming layer 3 that third layer is made up of low density polyethylene, the 4th
Coating layer 4, the outside of third layer foaming layer 3 is applied to using gravure technique by the coating layer 4 that layer is made up of latex coating.
Its specific preparation method is：With foaming layer 3, food-grade packaging ply of paper 2 and barrier layer 1 constitute 40+250+20 grams/
Square metre packaging for foodstuff leaching membrane paper do base material, one layer of coating layer of gravure, wherein coating layer propylene in 40 grams of foaming layers of the paper
Acid ester polymer (Henkel V-6859) 40%, defoamer 1%, titanium oxide (5-20 μm of particle diameter) 29%, deionized water 30%, printing
Speed is 100 ms/min, and the drying temperature of composite is 65 DEG C after printing, and coating thickness is 8um, using infrared foaming
Technique, 165 DEG C of blowing temperature.
Embodiment 8
As depicted in figs. 1 and 2, it is a kind of Novel foaming extrusion coating paper, including first layer is made up of medium density polyethylene MDPE
Barrier layer 1, second layer food-grade is packed for ply of paper 2, the foaming layer 3 that third layer is made up of low density polyethylene, the 4th
Coating layer 4, the outside of third layer foaming layer 3 is applied to using gravure technique by the coating layer 4 that layer is made up of latex coating.
Its specific preparation method is：With foaming layer 3, food-grade packaging ply of paper 2 and barrier layer 1 constitute 40+280+20 grams/
Square metre packaging for foodstuff leaching membrane paper do base material, one layer of coating layer of gravure, wherein coating layer propylene in 40 grams of foaming layers of the paper
Acid ester polymer (Henkel V-6859) 40%, defoamer 1%, titanium oxide (5-20 μm of particle diameter) 29%, deionized water 30%, printing
Speed is 100 ms/min, and the drying temperature of composite is 65 DEG C after printing, and coating thickness is 8um, using infrared foaming
Technique, 165 DEG C of blowing temperature.
Embodiment 9
As depicted in figs. 1 and 2, it is a kind of Novel foaming extrusion coating paper, including first layer is made up of medium density polyethylene MDPE
Barrier layer 1, second layer food-grade is packed for ply of paper 2, the foaming layer 3 that third layer is made up of low density polyethylene, the 4th
Coating layer 4, the outside of third layer foaming layer 3 is applied to using gravure technique by the coating layer 4 that layer is made up of latex coating.
Its specific preparation method is：With foaming layer 3, food-grade packaging ply of paper 2 and barrier layer 1 constitute 40+300+20 grams/
Square metre packaging for foodstuff leaching membrane paper do base material, one layer of coating layer of gravure, wherein coating layer propylene in 40 grams of foaming layers of the paper
Acid ester polymer (Henkel V-6859) 40%, defoamer 1%, titanium oxide (5-20 μm of particle diameter) 29%, deionized water 30%, printing
Speed is 100 ms/min, and the drying temperature of composite is 65 DEG C after printing, and coating thickness is 8um, using infrared foaming
Technique, 165 DEG C of blowing temperature.
Embodiment 10：
The foaming extrusion coating paper prepared with the embodiment of the present invention is detected that testing result is as shown in figure 3, left side is the present invention
The foaming effect figure of prepared foaming extrusion coating paper, right side is existing leaching membrane paper foaming effect figure, compared with existing leaching membrane paper,
Without abscess fracture phenomena after the foaming extrusion coating paper foaming being made.As shown in figure 4, left side is the foaming extrusion coating paper prepared by the present invention
Printing effect figure after foaming, foaming layer is not destroyed, so maintaining good printing effect.Right side is drenched to be existing
Printing effect figure after the foaming of film paper, because blow point is intensive and PE or PP layers is broken through and cause foaming layer to break by gas during foaming
It is bad, and then by printing ink damage layer, thin out wait of color also occur and negatively affect, cause final printing effect undesirable.
The effect of the blistering paper prepared to other embodiments detects that physicochemical property is similar to Example 1, shows this hair
Bright blistering paper has similar physicochemical property.
Claims (5)
1. one kind coating latex, described coating latex includes acrylate polymer 33-55%, defoamer 1%-2%, oxygen
Change titanium (5-20 μm of particle diameter) 24%-35%, deionized water 20%-30.
2. latex is coated with as claimed in claim 1, it is characterised in that the described acrylate polymer being coated with latex
Mass fraction is 33%.
3. latex is coated with as claimed in claim 1, it is characterised in that the mass fraction of described defoamer is 1%.
4. latex is coated with as claimed in claim 1, it is characterised in that the mass fraction of described titanium oxide (5-20 μm of particle diameter)
For 29%.
5. application of the coating latex in foaming extrusion coating paper is prepared described in claim 1.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710374757.0A CN107100030B (en) | 2017-05-24 | 2017-05-24 | A kind of coating latex being used to prepare foaming extrusion coating paper |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710374757.0A CN107100030B (en) | 2017-05-24 | 2017-05-24 | A kind of coating latex being used to prepare foaming extrusion coating paper |
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| Publication Number | Publication Date |
|---|---|
| CN107100030A true CN107100030A (en) | 2017-08-29 |
| CN107100030B CN107100030B (en) | 2018-11-09 |
Family
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| CN201710374757.0A Active CN107100030B (en) | 2017-05-24 | 2017-05-24 | A kind of coating latex being used to prepare foaming extrusion coating paper |
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Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2006094849A1 (en) * | 2005-03-10 | 2006-09-14 | Degussa Gmbh | Aqueous coating substance compositions for decorative paint effects |
| CN101875420A (en) * | 2009-04-30 | 2010-11-03 | 翁文桂 | Isolation laminated packaging material |
| CN102925084A (en) * | 2012-11-21 | 2013-02-13 | 哈尔滨工业大学 | Multi-purpose strippable acrylate adhesive microporous material and preparation method thereof |
| CN103396687A (en) * | 2013-06-27 | 2013-11-20 | 中科院广州化学有限公司 | Paint containing siloxane organic fluorine modified (methyl) acrylate polymer emulsion |
| CN103396717A (en) * | 2013-07-25 | 2013-11-20 | 佛山市三水灏诚合成树脂有限公司 | Wallpaper water-based paint, preparation method thereof and wallpaper |
| CN205062570U (en) * | 2015-10-26 | 2016-03-02 | 中山市东森纸业有限公司 | Can scribble synthetic paper material and paper container |
| CN106220962A (en) * | 2016-08-17 | 2016-12-14 | 安庆奥迪斯丹包装有限公司 | A kind of aging-resistant mineral fibres filling-foam stone corrugating media and preparation method thereof |
-
2017
- 2017-05-24 CN CN201710374757.0A patent/CN107100030B/en active Active
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2006094849A1 (en) * | 2005-03-10 | 2006-09-14 | Degussa Gmbh | Aqueous coating substance compositions for decorative paint effects |
| CN101875420A (en) * | 2009-04-30 | 2010-11-03 | 翁文桂 | Isolation laminated packaging material |
| CN102925084A (en) * | 2012-11-21 | 2013-02-13 | 哈尔滨工业大学 | Multi-purpose strippable acrylate adhesive microporous material and preparation method thereof |
| CN103396687A (en) * | 2013-06-27 | 2013-11-20 | 中科院广州化学有限公司 | Paint containing siloxane organic fluorine modified (methyl) acrylate polymer emulsion |
| CN103396717A (en) * | 2013-07-25 | 2013-11-20 | 佛山市三水灏诚合成树脂有限公司 | Wallpaper water-based paint, preparation method thereof and wallpaper |
| CN205062570U (en) * | 2015-10-26 | 2016-03-02 | 中山市东森纸业有限公司 | Can scribble synthetic paper material and paper container |
| CN106220962A (en) * | 2016-08-17 | 2016-12-14 | 安庆奥迪斯丹包装有限公司 | A kind of aging-resistant mineral fibres filling-foam stone corrugating media and preparation method thereof |
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| Publication number | Publication date |
|---|---|
| CN107100030B (en) | 2018-11-09 |
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