CN106219491B - 基于热能及副产品回收利用的综合法二氧化氯制备工艺 - Google Patents
基于热能及副产品回收利用的综合法二氧化氯制备工艺 Download PDFInfo
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- CN106219491B CN106219491B CN201610598182.6A CN201610598182A CN106219491B CN 106219491 B CN106219491 B CN 106219491B CN 201610598182 A CN201610598182 A CN 201610598182A CN 106219491 B CN106219491 B CN 106219491B
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- tower
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- electrolyte
- chlorine dioxide
- hydrogen
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- OSVXSBDYLRYLIG-UHFFFAOYSA-N dioxidochlorine(.) Chemical compound O=Cl=O OSVXSBDYLRYLIG-UHFFFAOYSA-N 0.000 title claims abstract description 283
- 239000004155 Chlorine dioxide Substances 0.000 title claims abstract description 133
- 235000019398 chlorine dioxide Nutrition 0.000 title claims abstract description 133
- 230000015572 biosynthetic process Effects 0.000 title claims abstract description 45
- 238000003786 synthesis reaction Methods 0.000 title claims abstract description 45
- 238000000034 method Methods 0.000 title claims abstract description 27
- 230000008569 process Effects 0.000 title claims abstract description 23
- 239000006227 byproduct Substances 0.000 title claims abstract description 20
- 239000003792 electrolyte Substances 0.000 claims abstract description 156
- 238000006243 chemical reaction Methods 0.000 claims abstract description 95
- BZSXEZOLBIJVQK-UHFFFAOYSA-N 2-methylsulfonylbenzoic acid Chemical compound CS(=O)(=O)C1=CC=CC=C1C(O)=O BZSXEZOLBIJVQK-UHFFFAOYSA-N 0.000 claims abstract description 82
- 238000005868 electrolysis reaction Methods 0.000 claims abstract description 56
- 239000000203 mixture Substances 0.000 claims abstract description 11
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 212
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 211
- 239000000243 solution Substances 0.000 claims description 150
- 239000012530 fluid Substances 0.000 claims description 130
- 239000007788 liquid Substances 0.000 claims description 106
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Inorganic materials [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 106
- 239000001257 hydrogen Substances 0.000 claims description 100
- 229910052739 hydrogen Inorganic materials 0.000 claims description 100
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 70
- 239000000460 chlorine Substances 0.000 claims description 70
- 229910052801 chlorine Inorganic materials 0.000 claims description 70
- 239000007789 gas Substances 0.000 claims description 70
- 239000003513 alkali Substances 0.000 claims description 52
- 230000008676 import Effects 0.000 claims description 49
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 45
- 238000010521 absorption reaction Methods 0.000 claims description 44
- 238000003860 storage Methods 0.000 claims description 35
- 229910001868 water Inorganic materials 0.000 claims description 25
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 24
- 239000013589 supplement Substances 0.000 claims description 23
- 229910000041 hydrogen chloride Inorganic materials 0.000 claims description 22
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 claims description 22
- 238000002360 preparation method Methods 0.000 claims description 21
- 238000001816 cooling Methods 0.000 claims description 20
- 239000011780 sodium chloride Substances 0.000 claims description 20
- 239000007921 spray Substances 0.000 claims description 12
- 230000001105 regulatory effect Effects 0.000 claims description 10
- 238000007710 freezing Methods 0.000 claims description 9
- 230000008014 freezing Effects 0.000 claims description 9
- 230000006641 stabilisation Effects 0.000 claims description 9
- 238000011105 stabilization Methods 0.000 claims description 9
- 239000002253 acid Substances 0.000 claims description 8
- 150000003839 salts Chemical class 0.000 claims description 8
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 6
- 239000000284 extract Substances 0.000 claims description 6
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 5
- 150000002431 hydrogen Chemical class 0.000 claims description 5
- 238000005086 pumping Methods 0.000 claims description 5
- 229910052719 titanium Inorganic materials 0.000 claims description 5
- 239000010936 titanium Substances 0.000 claims description 5
- 238000005406 washing Methods 0.000 claims description 5
- 239000003643 water by type Substances 0.000 claims description 5
- 239000004408 titanium dioxide Substances 0.000 claims description 3
- 241000790917 Dioxys <bee> Species 0.000 claims description 2
- 239000007864 aqueous solution Substances 0.000 claims description 2
- 230000008859 change Effects 0.000 claims description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims 2
- 239000011734 sodium Substances 0.000 claims 2
- 229910052708 sodium Inorganic materials 0.000 claims 2
- 239000012295 chemical reaction liquid Substances 0.000 claims 1
- XTEGARKTQYYJKE-UHFFFAOYSA-N chloric acid Chemical compound OCl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-N 0.000 claims 1
- 229940005991 chloric acid Drugs 0.000 claims 1
- 230000001934 delay Effects 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 abstract description 9
- 239000000498 cooling water Substances 0.000 abstract description 7
- 238000010438 heat treatment Methods 0.000 abstract description 4
- 238000004134 energy conservation Methods 0.000 abstract description 2
- 230000007613 environmental effect Effects 0.000 abstract 1
- 230000005611 electricity Effects 0.000 description 8
- 230000003139 buffering effect Effects 0.000 description 4
- 238000004140 cleaning Methods 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 238000005201 scrubbing Methods 0.000 description 4
- BAZAXWOYCMUHIX-UHFFFAOYSA-M sodium perchlorate Chemical compound [Na+].[O-]Cl(=O)(=O)=O BAZAXWOYCMUHIX-UHFFFAOYSA-M 0.000 description 4
- 229910001488 sodium perchlorate Inorganic materials 0.000 description 4
- 239000006096 absorbing agent Substances 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000009434 installation Methods 0.000 description 3
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 2
- DYQYUSJWAQCEFN-UHFFFAOYSA-N Cl(=O)=O.Cl Chemical compound Cl(=O)=O.Cl DYQYUSJWAQCEFN-UHFFFAOYSA-N 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- 238000004659 sterilization and disinfection Methods 0.000 description 2
- 230000033228 biological regulation Effects 0.000 description 1
- 239000012267 brine Substances 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- QBWCMBCROVPCKQ-UHFFFAOYSA-N chlorous acid Chemical compound OCl=O QBWCMBCROVPCKQ-UHFFFAOYSA-N 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- 230000029087 digestion Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 239000008246 gaseous mixture Substances 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 239000002068 microbial inoculum Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 238000012806 monitoring device Methods 0.000 description 1
- 230000008520 organization Effects 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B11/00—Oxides or oxyacids of halogens; Salts thereof
- C01B11/02—Oxides of chlorine
- C01B11/022—Chlorine dioxide (ClO2)
- C01B11/023—Preparation from chlorites or chlorates
- C01B11/025—Preparation from chlorites or chlorates from chlorates without any other reaction reducing agent than chloride ions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/002—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by condensation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
- B01D53/1418—Recovery of products
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
- B01D53/1493—Selection of liquid materials for use as absorbents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
- B01D53/18—Absorbing units; Liquid distributors therefor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/26—Drying gases or vapours
- B01D53/265—Drying gases or vapours by refrigeration (condensation)
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/24—Halogens or compounds thereof
- C25B1/26—Chlorine; Compounds thereof
- C25B1/265—Chlorates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/20—Halogens or halogen compounds
- B01D2257/204—Inorganic halogen compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Geology (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
Abstract
Description
Claims (12)
Priority Applications (1)
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CN201610598182.6A CN106219491B (zh) | 2016-07-27 | 2016-07-27 | 基于热能及副产品回收利用的综合法二氧化氯制备工艺 |
Applications Claiming Priority (1)
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CN201610598182.6A CN106219491B (zh) | 2016-07-27 | 2016-07-27 | 基于热能及副产品回收利用的综合法二氧化氯制备工艺 |
Publications (2)
Publication Number | Publication Date |
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CN106219491A CN106219491A (zh) | 2016-12-14 |
CN106219491B true CN106219491B (zh) | 2018-02-27 |
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CN201610598182.6A Active CN106219491B (zh) | 2016-07-27 | 2016-07-27 | 基于热能及副产品回收利用的综合法二氧化氯制备工艺 |
Country Status (1)
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CN (1) | CN106219491B (zh) |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4079123A (en) * | 1976-12-30 | 1978-03-14 | Hooker Chemicals & Plastics Corporation | Process for the production of chlorine dioxide |
CN101024493A (zh) * | 2007-02-09 | 2007-08-29 | 中北大学 | 一种二氧化氯气体发生装置 |
CN203253340U (zh) * | 2013-04-28 | 2013-10-30 | 广西博世科环保科技股份有限公司 | 综合法二氧化氯制备系统的尾气处理装置 |
CN204170437U (zh) * | 2014-10-09 | 2015-02-25 | 广西博世科环保科技股份有限公司 | 用于综合法二氧化氯制备系统的稀氯酸盐溶液蒸发器 |
CN105401163A (zh) * | 2014-09-08 | 2016-03-16 | 大幸药品株式会社 | 电解式二氧化氯气体制造装置 |
-
2016
- 2016-07-27 CN CN201610598182.6A patent/CN106219491B/zh active Active
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4079123A (en) * | 1976-12-30 | 1978-03-14 | Hooker Chemicals & Plastics Corporation | Process for the production of chlorine dioxide |
CN101024493A (zh) * | 2007-02-09 | 2007-08-29 | 中北大学 | 一种二氧化氯气体发生装置 |
CN203253340U (zh) * | 2013-04-28 | 2013-10-30 | 广西博世科环保科技股份有限公司 | 综合法二氧化氯制备系统的尾气处理装置 |
CN105401163A (zh) * | 2014-09-08 | 2016-03-16 | 大幸药品株式会社 | 电解式二氧化氯气体制造装置 |
CN204170437U (zh) * | 2014-10-09 | 2015-02-25 | 广西博世科环保科技股份有限公司 | 用于综合法二氧化氯制备系统的稀氯酸盐溶液蒸发器 |
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Publication number | Publication date |
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CN106219491A (zh) | 2016-12-14 |
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Application publication date: 20161214 Assignee: Guangxi Kexin environmental treatment Co.,Ltd. Assignor: GUANGXI BOSSCO ENVIRONMENTAL PROTECTION TECHNOLOGY Co.,Ltd. Contract record no.: X2023980034951 Denomination of invention: Comprehensive preparation process of chlorine dioxide based on thermal energy and by-product recycling Granted publication date: 20180227 License type: Common License Record date: 20230424 |
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Address after: 242300 intersection of Dongcheng Avenue and Dongcheng Road, heli Park, Ningguo Economic and Technological Development Zone, Ningguo City, Xuancheng City, Anhui Province Patentee after: Anhui Boshike Environmental Protection Technology Co.,Ltd. Country or region after: China Address before: 530007 12 Kexing Road, XiXiangTang high tech Zone, Nanning, the Guangxi Zhuang Autonomous Region Patentee before: GUANGXI BOSSCO ENVIRONMENTAL PROTECTION TECHNOLOGY Co.,Ltd. Country or region before: China |
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Effective date of registration: 20240430 Address after: 242300 intersection of Dongcheng Avenue and Dongcheng Road, heli Park, Ningguo Economic and Technological Development Zone, Ningguo City, Xuancheng City, Anhui Province Patentee after: Anhui Boshike Environmental Protection Technology Co.,Ltd. Country or region after: China Patentee after: Guangxi Boshike Environmental Technology Co.,Ltd. Address before: 242300 intersection of Dongcheng Avenue and Dongcheng Road, heli Park, Ningguo Economic and Technological Development Zone, Ningguo City, Xuancheng City, Anhui Province Patentee before: Anhui Boshike Environmental Protection Technology Co.,Ltd. Country or region before: China |
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PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
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Denomination of invention: Comprehensive method for chlorine dioxide preparation based on thermal energy and by-product recovery and utilization Granted publication date: 20180227 Pledgee: China Construction Bank Corporation Nanning New City Branch Pledgor: Anhui Boshike Environmental Protection Technology Co.,Ltd.|Guangxi Boshike Environmental Technology Co.,Ltd. Registration number: Y2024450000051 |