CN106199781A - A kind of flexible method making curved surface bionic compound eyes structure - Google Patents

A kind of flexible method making curved surface bionic compound eyes structure Download PDF

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Publication number
CN106199781A
CN106199781A CN201610808686.6A CN201610808686A CN106199781A CN 106199781 A CN106199781 A CN 106199781A CN 201610808686 A CN201610808686 A CN 201610808686A CN 106199781 A CN106199781 A CN 106199781A
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photoresist
time
curved surface
method making
flexible method
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CN106199781B (en
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李木军
黄胜洲
沈连婠
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University of Science and Technology of China USTC
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    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B3/00Simple or compound lenses
    • G02B3/0006Arrays
    • G02B3/0012Arrays characterised by the manufacturing method
    • G02B3/0018Reflow, i.e. characterized by the step of melting microstructures to form curved surfaces, e.g. manufacturing of moulds and surfaces for transfer etching
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B3/00Simple or compound lenses
    • G02B3/0006Arrays
    • G02B3/0012Arrays characterised by the manufacturing method
    • G02B3/0031Replication or moulding, e.g. hot embossing, UV-casting, injection moulding

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  • Physics & Mathematics (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Photosensitive Polymer And Photoresist Processing (AREA)

Abstract

The invention discloses a kind of flexible method making curved surface bionic compound eyes structure, step is as follows: three layers of positive photoresist of spin coating on substrate, and wherein the photoresist of bottom and top layer is AZ4620 photoresist, and intermediate layer is S1813 photoresist;Carrying out twice maskless lithography, expose three layer photoetching glue for the first time completely, second time only exposes the photoresist of intermediate layer and top layer;Development obtains preliminary multilevel hierarchy;Being carried out continuously twice thermal reflux to process, ordinary hot backflow for the first time obtains the big lens arrangement of compound eye, and second time is inverted contactless hot reflux and is obtained the lenslet array array structure of distribution on the big lens of compound eye.The advantages such as the present invention has that technological operation is simple, the process-cycle is short, low cost and controlled shape, it is possible to well meet the requirement of big view field imaging.

Description

A kind of flexible method making curved surface bionic compound eyes structure
Technical field
The present invention relates to optical bionic field, particularly to a kind of flexible method making curved surface bionic compound eyes structure.
Background technology
Bionic compound eyes has that volume is little, lightweight, visual field is big, highly sensitive, the advantage such as can test the speed, national defense and military and the people Have a wide range of applications with in industry.For the angle of visual field curved surface bionic compound eyes more than plane bionic compound eyes, make at present Make curved surface bionic compound eyes structure main method and have Ultraprecision Machining, curved surface photoetching process and two-photon femtosecond laser direct write skill Art etc..
Wherein Ultraprecision Machining is owing to its equipment cost is high, operation requires height, and the size for processing has necessarily Restriction, be usually no more than micron order.Curved surface photoetching process generally comprises sessile drop method and gray level mask photoetching process, for sessile drop method by In the restriction of droplet process precision, single lens size is extremely difficult to less than 1 millimeter;And for gray level mask photoetching process, although Undersized lens arrangement can be produced in theory, but the method is complicated when curved surface gray level mask plate designs, and is fabricated to This is higher.Apply wider two-photon femtosecond laser direct writing technology at present, although processing dimension is unrestricted, can reach nanoscale Precision, but its equipment cost is higher, and working (machining) efficiency is relatively low.
Summary of the invention
It is an object of the invention to provide a kind of flexible method making curved surface bionic compound eyes structure, it is to avoid directly at song The complexity of little eyelens is made in the substrate of face, various by utilizing DMD mask-free photolithography technology to generate simply and easily Ommatidium graphic structure, and utilize the difference of two kinds of photoresisted glass softening temperatures (Tg) to carry out hot reflux process, the method has Have that technological operation is simple, the process-cycle is short, the advantage such as low cost and controlled shape, it is possible to well meet big view field imaging Requirement.
It is an object of the invention to be achieved through the following technical solutions:
A kind of flexible method making curved surface bionic compound eyes structure, main hot by DMD mask-free photolithography technology and classification Technique of backflow completes, particularly as follows:
Step 1: the photoresist of three layers of two kinds of different-thickness of spin coating on substrate, bottom and top layer are the first photoresists, Intermediate layer is that glass transition temperature Tg is at least above the first another photoresist of more than tens degrees Celsius;Wherein, bottom Thickness is at least above an order of magnitude than top layer thickness, and top layer is below several microns, and bottom is more than tens microns, as slow Rush the very thin thickness in intermediate layer, at 1~2 micrometer ranges;
Step 2: use DMD (DMD) the mask-free photolithography technology in micro-optic process technology, carry out twice Maskless lithography, exposes three layer photoetching glue for the first time completely, and second time only exposes the photoresist of intermediate layer and top layer;
Step 3: development obtains bottom microtrabeculae figure and top layer and the microtrabeculae in intermediate layer or positive six prism graphic arrays;
Step 4: being carried out continuously twice thermal reflux and process, ordinary hot backflow for the first time obtains the big lens arrangement of compound eye, Its basal diameter scope is hundreds of micron to 1.5 millimeters;Second time is inverted contactless hot reflux and is obtained dividing on the big lens of compound eye The lenslet array array structure of cloth, its basal diameter scope is 20 microns to 100 microns.
The photoresist of described bottom and top layer is AZ4620 photoresist, and intermediate layer is S1813 photoresist.
The substrate of described step 1 uses any one in silicon, quartz glass.
When the bottom photoresist of described step 1 can fully reflux, its thickness is directly proportional to bottom microtrabeculae pattern diameter pass System, will i.e. be greater than 1/10 times of compound eye big lens base radius as far as possible higher than the critical thickness under the big lens sizes of required compound eye Size.
The double exposure mask pattern of described step 2 is virtual digit mask pattern, instead of traditional physical mask version Figure, thus avoid design and the making of mask plate;Exposure mask figure is circular array, for the second time mask graph for the first time For any one in circle, square, regular hexagon.
In described step 3 during development, developer solution uses alkaline-based developer;Developing time is 2-8 minute.
Described alkaline-based developer is any one in AZ 400K (1:4), TMAH.
In described step 4, the temperature of hot reflux for the first time is equal to or a little higher than glass transition temperature Tg so that hot reflux temperature Degree maintains between Tg to Tg+5 DEG C of scope;Second time is inverted the contactless hot reflux photoresist gap with hot plate at 0.5 milli Rice is to 1 millimeter of scope, the biggest or the least reflowing result all can be caused to be deteriorated.
In described step 4, hot reflux for the first time and second time hot reflux time be respectively within 5 minutes and 1 minute with Interior scope.
The technique effect of the present invention is embodied in:
The curved compound eye structure produced by invention have volume little, lightweight (owing to being micron-sized processing, difference In macroscopic view compound eye structural processing, so volume and weight is the least, seldom mention concrete scope), low cost, knot The features such as structure is controlled and processing technology is simple.Owing to, in the present invention, mainly using micro-optic process technology, ultraprecise can be broken through The technology such as processing size limitation, it is achieved that volume advantage little, lightweight.Owing to, in invention, twice without mask pattern Exposure uses DMD (DMD) mask-free photolithography technology, can design required lens easily and fast and cover Film pattern, it is to avoid the making of physical mask plate, it is achieved that low cost, the advantage of structure-controllable.In inventing, final compound eye Being formed of lens is mainly completed by twice hot reflux technology, it is achieved that the simple advantage of processing technology.
Accompanying drawing explanation
Fig. 1 is the flow chart of manufacture method of the present invention;
Fig. 2 is processing technology schematic diagram of the present invention;
Fig. 3 is mask-free photolithography processing unit (plant) schematic diagram of the present invention;
Fig. 4 is bionic compound eyes of the present invention big lens mask pattern.
Fig. 5 is bionic compound eyes lenslet mask pattern of the present invention.
In figure: 1-silicon substrate, 2-AZ4620 photoresist, 3-S1813 photoresist, the small column of 4-second time exposure, 5-the The big cylinder of single exposure, 6-hot plate, the big lens of 7-compound eye, 8-pad, the lenslet 10-high voltage mercury lamp of 9-compound eye, 11-liquid Body light guide, 12-light collimation adapter, 13-DMD chip, 14-cylinder mirror, 15-Amici prism, 16-CCD camera, 17-calculates Machine, 18-reflecting mirror, 19-projection microscope head, 20-X, Y-axis moveable platform.
Detailed description of the invention
The present invention does a step below in conjunction with the accompanying drawings describe in detail.
As it is shown in figure 1, the manufacture method of curved surface bionic compound eyes structure of the present invention, particularly as follows:
Step 1 is three layers of positive photoresist of spin coating on substrate, and wherein the photoresist of bottom and top layer is AZ4620 photoresist, Intermediate layer is S1813 photoresist;
Step 2 carries out twice maskless lithography, exposes three layer photoetching glue for the first time completely, second time only expose intermediate layer and The photoresist of top layer;
Step 3 development obtains preliminary multilevel hierarchy;
Step 4 is carried out continuously twice thermal reflux and processes, and ordinary hot refluxes and obtains big eyelens structure for the first time, and second The contactless hot reflux of secondary inversion obtains the ommatidium array structure thereof of distribution on big eyelens.
The substrate of described step 1 uses any one in silicon, quartz glass;
When the bottom AZ4620 photoresist of described step 1 can fully reflux, its thickness is directly proportional to molded lens diameter Relation, be as far as possible higher than the critical thickness under required lens sizes;
The first time exposure mask figure of described step 2 is circular array, and mask graph can be circular, positive four for the second time Any one in limit shape, regular hexagon;
The double exposure of described step 2 completes on DMD maskless lithography platform, can complete institute easily and fast Need the exposure of mask pattern;
Alkaline-based developer used by described step 3 is any one in AZ400K (1:4), TMAH;
The temperature of the first time hot reflux of described step 4 to be equal to or a little higher than glass transition temperature (Tg) so that it is at 5 DEG C Within.And the gap of second time hot reflux photoresist and hot plate is 1 millimeter, the biggest or the least reflowing result all can be caused to be deteriorated;
An embodiment be given below:
The present embodiment includes: a diameter of 500 microns of curved substrate spheric curvature, thickness is 40 microns, on curved substrate A diameter of 20 microns of lenslet, thickness is 10 microns, in the curved compound eye structure such as Fig. 2 that the making of this embodiment obtains shown in (d).
The present embodiment is made by following steps:
The first step: three layers of positive photoresist of spin coating on substrate.
Clean and dring silicon substrate (1), difference three layers of positive photoresist of spin coating, wherein bottom and the light of top layer on substrate Photoresist is AZ4620 photoresist (2), and intermediate layer is S1813 photoresist (3).And the thickness of bottom is 34 microns, top layer thickness is 6.5 microns, middle thickness is 1.5 microns, and the photoresist for bottom uses twice spin coating to obtain the glue-line that glue is thick.
Second step: be carried out continuously twice and expose without mask pattern, mask pattern lens arra figure as big in Fig. 4 and figure respectively Shown in 5 lenslet array figures.Wherein Fig. 4 is shown that the big lens arra of a diameter of 500 microns, and Fig. 5 is a diameter of 20 micro- The lenslet array of rice.Utilizing the exposure stage of Fig. 3 such as to carry out continuous exposure, corresponding exposure wavelength is 365 nanometers, exposure Dosage is 1260 MJs every square centimeter and 250 MJs every square centimeter respectively.Under this exposure dose, expose the most completely thoroughly Three layer photoetching glue, second time only exposes the photoresist of intermediate layer and top layer;
3rd step: development obtains preliminary multilevel hierarchy, is formed such as the big cylinder 5 in Fig. 2 and small cylinder 4.Used Developer solution is AZ400K (1:4) alkaline-based developer, during development a length of 5 minutes.
4th step: be carried out continuously twice thermal reflux and process.By obtaining at hot plate 6 ordinary hot reflux technique for the first time The big lens arrangement of compound eye 7, second time is inverted contactless hot reflux and is obtained the ommatidium lens arrangement 9 of distribution on the big lens of compound eye. Owing to the glass transition temperature of AZ4620 and S1813 photoresist is 115 degrees Celsius and 170 degrees Celsius respectively, therefore for the first time In ordinary hot reflux technique, parameter is set to: temperature 115 degrees Celsius, 40 seconds time;Second time is inverted contactless hot reflux work Skill parameter is set to: temperature 130 degrees Celsius, 20 seconds time, and gap length is 1 millimeter, i.e. the thickness of pad 8.By this backflow The process of technique, can obtain the curved surface bionic compound eyes structure of design after natural cooling.
In a word, present invention, avoiding the complexity directly making little eyelens on curved substrate, by utilizing numeral micro- Mirror device (DMD) mask-free photolithography technology can generate various ommatidium graphic structure simply and easily, and utilizes two kinds of photoetching The difference of glue glass transition temperature (Tg) carries out hot reflux process, have that technological operation is simple, the process-cycle is short, low cost and The advantages such as controlled shape, it is possible to well meet the requirement of big view field imaging.
As it will be easily appreciated by one skilled in the art that and the foregoing is only presently preferred embodiments of the present invention, not in order to Limit the present invention, all any amendment, equivalent and improvement etc. made within the spirit and principles in the present invention, all should comprise Within protection scope of the present invention.

Claims (9)

1. the flexible method making curved surface bionic compound eyes structure, it is characterised in that comprise the following steps:
Step 1: the photoresist of three layers of two kinds of different-thickness of spin coating on substrate, bottom and top layer are the first photoresists, middle Layer is that glass transition temperature Tg is at least above the first another photoresist of more than tens degrees Celsius;Wherein, underlayer thickness Being at least above an order of magnitude than top layer thickness, top layer is below several microns, and bottom is more than tens microns, as in buffering The very thin thickness of interbed, at 1~2 micrometer ranges;
Step 2: use DMD (DMD) the mask-free photolithography technology in micro-optic process technology, carries out twice without covering Film exposes, and exposes three layer photoetching glue for the first time completely, and second time only exposes the photoresist of intermediate layer and top layer;
Step 3: development obtains bottom microtrabeculae figure and top layer and the microtrabeculae in intermediate layer or positive six prism graphic arrays;
Step 4: being carried out continuously twice thermal reflux and process, ordinary hot backflow for the first time obtains the big lens arrangement of compound eye, its end Face diameter range is hundreds of micron to 1.5 millimeters;Second time is inverted contactless hot reflux and is obtained distribution on the big lens of compound eye Lenslet array array structure, its basal diameter scope is 20 microns to 100 microns.
The flexible method making curved surface bionic compound eyes structure the most according to claim 1, it is characterised in that: described bottom and The photoresist of top layer is AZ4620 photoresist, and intermediate layer is S1813 photoresist.
The flexible method making curved surface bionic compound eyes structure the most according to claim 1, it is characterised in that: described step 1 Substrate use in silicon, quartz glass any one.
The flexible method making curved surface bionic compound eyes structure the most according to claim 1, it is characterised in that: described step 1 Bottom photoresist when can fully reflux, its thickness is proportional with bottom microtrabeculae pattern diameter, be as far as possible higher than required Critical thickness under the big lens sizes of compound eye, is i.e. greater than 1/10 times of compound eye big lens base radius size.
The flexible method making curved surface bionic compound eyes structure the most according to claim 1, it is characterised in that: described step 2 Double exposure mask pattern be virtual digit mask pattern, instead of traditional physical mask domain shape, thus avoid and cover The design of lamina membranacea and making;Exposure mask figure is circular array for the first time, for the second time mask graph be circle, square, Any one in regular hexagon.
The flexible method making curved surface bionic compound eyes structure the most according to claim 1, it is characterised in that: described step 3 During middle development, developer solution uses alkaline-based developer;Developing time is 2-8 minute.
The flexible method making curved surface bionic compound eyes structure the most according to claim 6, it is characterised in that: described alkalescence shows Shadow liquid is any one in AZ 400K (1:4), TMAH.
The flexible method making curved surface bionic compound eyes structure the most according to claim 1, it is characterised in that: described step 4 In, the temperature of hot reflux for the first time is equal to or a little higher than glass transition temperature Tg so that hot reflux temperature maintains Tg to Tg+5 Between DEG C scope;Second time is inverted the gap of contactless hot reflux photoresist and hot plate 0.5 millimeter to 1 millimeter scope, too Big or the least reflowing result all can be caused to be deteriorated.
The flexible method making curved surface bionic compound eyes structure the most according to claim 1, it is characterised in that: described step 4 In, the time of hot reflux for the first time and second time hot reflux is scope within 5 minutes and within 1 minute respectively.
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Cited By (7)

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Publication number Priority date Publication date Assignee Title
CN110568530A (en) * 2019-09-11 2019-12-13 北京理工大学 Curved surface bionic compound eye processing method based on die forming
CN111060997A (en) * 2020-01-19 2020-04-24 西安交通大学 Method for manufacturing multistage fly-eye lens
CN113126453A (en) * 2021-04-23 2021-07-16 东北师范大学 Femtosecond laser direct writing and DMD maskless photoetching composite processing method
CN113341663A (en) * 2021-06-28 2021-09-03 中国科学院物理研究所 Controllable processing method of spherical microstructure with any curvature
CN114895389A (en) * 2022-04-25 2022-08-12 安徽工程大学 Method for flexibly manufacturing multi-focus micro-lens array structure
CN115327680A (en) * 2022-08-08 2022-11-11 苏州华太电子技术股份有限公司 Lens preparation method
CN117872517A (en) * 2024-03-11 2024-04-12 广东工业大学 Curved fly-eye lens and preparation method thereof

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Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110568530A (en) * 2019-09-11 2019-12-13 北京理工大学 Curved surface bionic compound eye processing method based on die forming
CN111060997A (en) * 2020-01-19 2020-04-24 西安交通大学 Method for manufacturing multistage fly-eye lens
WO2021143148A1 (en) * 2020-01-19 2021-07-22 西安交通大学 Method for manufacturing multi-stage compound eye lens
CN113126453A (en) * 2021-04-23 2021-07-16 东北师范大学 Femtosecond laser direct writing and DMD maskless photoetching composite processing method
CN113341663A (en) * 2021-06-28 2021-09-03 中国科学院物理研究所 Controllable processing method of spherical microstructure with any curvature
CN113341663B (en) * 2021-06-28 2022-07-08 中国科学院物理研究所 Controllable processing method of spherical microstructure with any curvature
CN114895389A (en) * 2022-04-25 2022-08-12 安徽工程大学 Method for flexibly manufacturing multi-focus micro-lens array structure
CN115327680A (en) * 2022-08-08 2022-11-11 苏州华太电子技术股份有限公司 Lens preparation method
CN115327680B (en) * 2022-08-08 2023-09-01 苏州华太电子技术股份有限公司 Lens preparation method
CN117872517A (en) * 2024-03-11 2024-04-12 广东工业大学 Curved fly-eye lens and preparation method thereof

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