CN106191805B - 一种磁性石墨烯复合薄膜的制备方法 - Google Patents
一种磁性石墨烯复合薄膜的制备方法 Download PDFInfo
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- CN106191805B CN106191805B CN201610427253.6A CN201610427253A CN106191805B CN 106191805 B CN106191805 B CN 106191805B CN 201610427253 A CN201610427253 A CN 201610427253A CN 106191805 B CN106191805 B CN 106191805B
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- copper foil
- metal foil
- composite film
- carbon nano
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- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 127
- 229910021389 graphene Inorganic materials 0.000 title claims abstract description 74
- 239000002131 composite material Substances 0.000 title claims abstract description 50
- 230000005291 magnetic effect Effects 0.000 title claims abstract description 36
- 238000002360 preparation method Methods 0.000 title claims abstract description 13
- 238000005229 chemical vapour deposition Methods 0.000 claims abstract description 73
- 239000002041 carbon nanotube Substances 0.000 claims abstract description 27
- 229910021393 carbon nanotube Inorganic materials 0.000 claims abstract description 27
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 25
- 238000011065 in-situ storage Methods 0.000 claims abstract description 23
- 239000011889 copper foil Substances 0.000 claims description 128
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 110
- 239000000243 solution Substances 0.000 claims description 76
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims description 57
- 239000007789 gas Substances 0.000 claims description 46
- 229910052751 metal Inorganic materials 0.000 claims description 45
- 239000002184 metal Substances 0.000 claims description 45
- 239000011888 foil Substances 0.000 claims description 39
- 238000005530 etching Methods 0.000 claims description 38
- 239000000126 substance Substances 0.000 claims description 38
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 37
- 239000012298 atmosphere Substances 0.000 claims description 34
- 239000002109 single walled nanotube Substances 0.000 claims description 29
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 claims description 28
- 239000011259 mixed solution Substances 0.000 claims description 23
- 239000002079 double walled nanotube Substances 0.000 claims description 20
- 229910001868 water Inorganic materials 0.000 claims description 17
- 239000002048 multi walled nanotube Substances 0.000 claims description 12
- 239000002245 particle Substances 0.000 claims description 12
- 238000011068 loading method Methods 0.000 claims description 11
- 239000007864 aqueous solution Substances 0.000 claims description 10
- 239000008367 deionised water Substances 0.000 claims description 10
- 229910021641 deionized water Inorganic materials 0.000 claims description 10
- 229910044991 metal oxide Inorganic materials 0.000 claims description 9
- 150000004706 metal oxides Chemical class 0.000 claims description 9
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 8
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 claims description 8
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 claims description 8
- SZVJSHCCFOBDDC-UHFFFAOYSA-N ferrosoferric oxide Chemical group O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 claims description 7
- 239000004094 surface-active agent Substances 0.000 claims description 7
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims description 6
- 238000004140 cleaning Methods 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 5
- 239000002270 dispersing agent Substances 0.000 claims description 4
- 238000010438 heat treatment Methods 0.000 claims description 4
- 239000011261 inert gas Substances 0.000 claims description 4
- UPWOEMHINGJHOB-UHFFFAOYSA-N cobalt(III) oxide Inorganic materials O=[Co]O[Co]=O UPWOEMHINGJHOB-UHFFFAOYSA-N 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 239000000758 substrate Substances 0.000 claims description 3
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 claims description 2
- 229910002064 alloy oxide Inorganic materials 0.000 claims description 2
- 239000012153 distilled water Substances 0.000 claims description 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 2
- 150000005826 halohydrocarbons Chemical class 0.000 claims description 2
- GNMQOUGYKPVJRR-UHFFFAOYSA-N nickel(III) oxide Inorganic materials [O-2].[O-2].[O-2].[Ni+3].[Ni+3] GNMQOUGYKPVJRR-UHFFFAOYSA-N 0.000 claims description 2
- PZFKDUMHDHEBLD-UHFFFAOYSA-N oxo(oxonickeliooxy)nickel Chemical compound O=[Ni]O[Ni]=O PZFKDUMHDHEBLD-UHFFFAOYSA-N 0.000 claims description 2
- LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 claims 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims 2
- 229920001400 block copolymer Polymers 0.000 claims 1
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 claims 1
- 238000000034 method Methods 0.000 abstract description 25
- 241000234282 Allium Species 0.000 abstract description 11
- 235000002732 Allium cepa var. cepa Nutrition 0.000 abstract description 11
- 230000005294 ferromagnetic effect Effects 0.000 abstract description 10
- 239000002923 metal particle Substances 0.000 abstract description 7
- 229920000642 polymer Polymers 0.000 abstract description 7
- 230000003287 optical effect Effects 0.000 abstract description 5
- 230000005389 magnetism Effects 0.000 abstract description 3
- 230000003647 oxidation Effects 0.000 abstract description 3
- 238000007254 oxidation reaction Methods 0.000 abstract description 3
- 238000011031 large-scale manufacturing process Methods 0.000 abstract description 2
- 239000011358 absorbing material Substances 0.000 abstract 1
- 239000011159 matrix material Substances 0.000 abstract 1
- 239000002082 metal nanoparticle Substances 0.000 abstract 1
- 230000020477 pH reduction Effects 0.000 abstract 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 19
- 238000005086 pumping Methods 0.000 description 14
- 238000004528 spin coating Methods 0.000 description 12
- 238000001816 cooling Methods 0.000 description 7
- -1 graphite alkene Chemical class 0.000 description 6
- 238000009210 therapy by ultrasound Methods 0.000 description 6
- 239000011248 coating agent Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 229910002804 graphite Inorganic materials 0.000 description 4
- 239000010439 graphite Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 239000002356 single layer Substances 0.000 description 4
- 238000004377 microelectronic Methods 0.000 description 3
- 229910021392 nanocarbon Inorganic materials 0.000 description 3
- 230000000694 effects Effects 0.000 description 2
- 239000002086 nanomaterial Substances 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 229910021524 transition metal nanoparticle Inorganic materials 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000001335 aliphatic alkanes Chemical group 0.000 description 1
- SWLVFNYSXGMGBS-UHFFFAOYSA-N ammonium bromide Chemical compound [NH4+].[Br-] SWLVFNYSXGMGBS-UHFFFAOYSA-N 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000003421 catalytic decomposition reaction Methods 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 238000003486 chemical etching Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 239000011258 core-shell material Substances 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000001000 micrograph Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920000428 triblock copolymer Polymers 0.000 description 1
- 238000001132 ultrasonic dispersion Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/22—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of inorganic material, other than metallic material
- C23C16/26—Deposition of carbon only
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/01—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes on temporary substrates, e.g. substrates subsequently removed by etching
Landscapes
- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Carbon And Carbon Compounds (AREA)
Abstract
Description
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Priority Applications (1)
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CN201610427253.6A CN106191805B (zh) | 2016-06-06 | 2016-06-06 | 一种磁性石墨烯复合薄膜的制备方法 |
Applications Claiming Priority (1)
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CN201610427253.6A CN106191805B (zh) | 2016-06-06 | 2016-06-06 | 一种磁性石墨烯复合薄膜的制备方法 |
Publications (2)
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CN106191805A CN106191805A (zh) | 2016-12-07 |
CN106191805B true CN106191805B (zh) | 2020-12-08 |
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CN201610427253.6A Active CN106191805B (zh) | 2016-06-06 | 2016-06-06 | 一种磁性石墨烯复合薄膜的制备方法 |
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Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
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CN107858663B (zh) * | 2017-11-15 | 2019-06-11 | 上海上大瑞沪微系统集成技术有限公司 | 一种利用cvd方法直接在铜粉表面包覆石墨烯的方法 |
CN108220908B (zh) * | 2017-12-18 | 2019-11-05 | 中国科学院兰州化学物理研究所 | 一种摩擦界面原位形成石墨烯和洋葱实现超滑的方法 |
CN114203326B (zh) * | 2021-12-13 | 2024-04-30 | 中国核动力研究设计院 | 石墨烯封装超薄镍-63辐射源薄膜及其制备方法、应用 |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN103058172A (zh) * | 2013-01-15 | 2013-04-24 | 清华大学 | 一种碳纳米管-石墨烯复合材料的制备方法 |
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2016
- 2016-06-06 CN CN201610427253.6A patent/CN106191805B/zh active Active
Patent Citations (1)
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CN103058172A (zh) * | 2013-01-15 | 2013-04-24 | 清华大学 | 一种碳纳米管-石墨烯复合材料的制备方法 |
Non-Patent Citations (2)
Title |
---|
Carbon-coated a-Fe2O3 nanostructures for efficient anode of Li-ion battery;Xiaoxin Lv等;《Journal of Materials Chemistry A》;20151231;全文 * |
基于碳纳米管—石墨烯—泡沫镍三维复合结构的超级电容器电极制备与性能;朱国银;《中国优秀硕士学位论文全文数据库(电子期刊)》;20150515;第20、22-23页 * |
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Effective date of registration: 20211228 Address after: 4011121 802, block D, Qilin, No. 55-2, middle section of Huangshan Avenue, Dazhulin street, Liangjiang New Area, Yubei District, Chongqing Patentee after: Chongqing Zhizhe Information Technology Co.,Ltd. Address before: 400044 No. 174 Sha Jie street, Shapingba District, Chongqing Patentee before: Chongqing University |
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Effective date of registration: 20220124 Address after: 401329 Building 1, No. 21, Fengsheng Road, Jinfeng Town, high tech Zone, Jiulongpo District, Chongqing Patentee after: Chongqing jintianyi New Energy Technology Co.,Ltd. Address before: 4011121 802, block D, Qilin, No. 55-2, middle section of Huangshan Avenue, Dazhulin street, Liangjiang New Area, Yubei District, Chongqing Patentee before: Chongqing Zhizhe Information Technology Co.,Ltd. |
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Effective date of registration: 20240315 Address after: 3N028, 3rd Floor, G5 District, Liangjiang Smart Innovation Valley, No. 70 Yunhe Road, Shuitu Street, Beibei District, Chongqing, 400799 (Cluster Registration) Patentee after: Chongqing Jiabaoxiang Technology Co.,Ltd. Country or region after: China Address before: 401329 Building 1, No. 21, Fengsheng Road, Jinfeng Town, high tech Zone, Jiulongpo District, Chongqing Patentee before: Chongqing jintianyi New Energy Technology Co.,Ltd. Country or region before: China |