CN106186951A - A kind of wear-resisting waterproofing and leakage-stopping mortar and preparation method thereof - Google Patents

A kind of wear-resisting waterproofing and leakage-stopping mortar and preparation method thereof Download PDF

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Publication number
CN106186951A
CN106186951A CN201610557721.1A CN201610557721A CN106186951A CN 106186951 A CN106186951 A CN 106186951A CN 201610557721 A CN201610557721 A CN 201610557721A CN 106186951 A CN106186951 A CN 106186951A
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CN
China
Prior art keywords
mortar
wear
hour
leakage
stone powder
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610557721.1A
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Chinese (zh)
Inventor
乔启信
金自海
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ANHUI LANGKAIQI BUILDING MATERIALS Co Ltd
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ANHUI LANGKAIQI BUILDING MATERIALS Co Ltd
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Priority to CN201610557721.1A priority Critical patent/CN106186951A/en
Publication of CN106186951A publication Critical patent/CN106186951A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/04Portland cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B20/00Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
    • C04B20/02Treatment
    • C04B20/023Chemical treatment
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • C04B2111/2038Resistance against physical degradation
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • C04B2111/27Water resistance, i.e. waterproof or water-repellent materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/50Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

The invention discloses a kind of wear-resisting waterproofing and leakage-stopping mortar, add nano silica fume and carried out organically-modified, reduce surface and can make it have facially amphiphilic, thus utilize three-dimensional protective effect to make nanoparticle be homogeneously dispersed in mortar and be difficult to reunite, improve comprcssive strength and the anti-wear performance of product, the most compound with polymer styrene-acrylic emulsion and polypropylene fibre again, by physics and chemical action, improve polypropylene fibre surface can, cohesive force between itself and mortar is improved further, inhibit the generation of micro-crack in early days, improve the impermeability of product, rupture strength and durability;The present invention also adds in raw material other effective additives of compatibility again to by modified for medical stone powder, the each component of mortar is uniformly dispersed not free settling, significantly improving the water resistance of leak stopping mortar and shorten its rapid hardening speed, preparation technology of the present invention is simple, easy construction, have the performances such as microdilatancy performance is good, self-healing properties is good, wear-resisting after curing molding.

Description

A kind of wear-resisting waterproofing and leakage-stopping mortar and preparation method thereof
Technical field
The present invention relates to building material technical field, particularly relate to a kind of wear-resisting waterproofing and leakage-stopping mortar and preparation method thereof.
Background technology
Leakage of buildings problem is the common quality defect that building more highlights, and tracing it to its cause is architectural engineering xoncrete structure Because the reasons such as autogenous shrinkage, temperature deformation, design defect or construction produce crack, cause seepage, thus cause roof leakage, wall Wall seepage, rendering layer obscission, not only upset orthobiosis and the work of people, and directly influence whole solitary building In service life, waterproofing and leakage-stopping mortar arises at the historic moment.Waterproofing and leakage-stopping mortar, with high grade cement, sand, stone as raw material, mixes multiple high score Sub-additive, by adjusting match ratio, is improved cement pore structure, increases various raw-material density, or shunk by compensation Improve the anti-crack and anti-seepage ability of concrete.
Waterproofing and leakage-stopping mortar is widely used in China, and manufacturing enterprise is numerous, from the point of view of base material essence, mainly with aluminate Cement based or portland cement sill are base material.Aluminate cement later strength in wet condition can reduce, and silicate There is length setting time, early strength development and slowly and produce the fundamental issues such as contraction after hardening in cement, thus increasing is added in research The new waterproof leak stopping mortar of strong material is significant.
Polypropylene fibre has the advantage such as easy construction, with low cost, resistance to chemical attack, mixes as reinforcing material In cement mortar, it is possible to reduce mortar is the generation of micro-crack in hardening process, and stop or delay it to extend, thus effectively carrying The tensile strength of high mortar.But polypropylene fibre smooth surface, surface can without any active group on low, strand, and Surface hydrophobicity, causes it poor with cement matrix adhesive property.Exist simultaneously as PP fiber reinforced cement mortar is internal A large amount of holes, cause cement-hydrate, polypropylene fibre and aggregate interracial contact abundant not, reduce the durable of cement mortar Performance, these all have influence on polypropylene fibre application effect in cement-based material, constrain its range of application.To this end, it is " poly- The tacryl impact on polymer cement mortar performance " use a certain amount of styrene-acrylic emulsion of admixture to PP fiber reinforced cement sand Slurry is modified, and result shows: admixture polypropylene fibre and styrene-acrylic emulsion are remarkably improved the rupture strength of cement mortar simultaneously And anti-permeability performance, when polypropylene fiber be 0.6kg/m3, styrene-acrylic emulsion volume be 10% time, compared with benchmark mortar specimen, Its 28d rupture strength and impermeability pressure increase 29.20% and 400% respectively.But, use the water that the processing method in literary composition obtains The comprcssive strength of cement mortar is low, also needs to be modified.
Nano material possesses skin effect, small-size effect, quantum size effect, macroparticle tunnel-effect, and these are special Different character makes it in polymer modification, improves in coating, binder performance and becomes irreplaceable material, and the present invention uses nanometer Material adds in raw material to styrene-acrylic emulsion is the most modified, with improve product comprcssive strength, water-fast impervious, anticorrosion is resistance to always The performances such as change, but these special natures of nano material there is also certain limitation, such as due to small size can be big than table Easily reunite, cause disperseing uneven, thus be necessary to be then added in raw material, to change the nano material added is in addition modified The all technical of kind product.
Summary of the invention
The object of the invention is contemplated to make up the defect of prior art, it is provided that a kind of wear-resisting waterproofing and leakage-stopping mortar and making thereof Method.
The present invention is achieved by the following technical solutions:
A kind of wear-resisting waterproofing and leakage-stopping mortar, is prepared by the raw materials in: Portland cement 24-26, river sand 49- 51, medical stone powder 13-14, white carbon black 17-19, banana fiber 2-3, polypropylene fibre 3.6-4.5, styrene-acrylic emulsion 8-10, calcium sulfate 0.4-0.6, nano silica fume 2.1-2.4, IPPP 3-4, vinyltrimethoxy silane 7-9, suitable quantity of water.
The manufacture method of described a kind of wear-resisting waterproofing and leakage-stopping mortar, comprises the following steps:
(1) under nitrogen protection by vinyltrimethoxy silane heated and boiled, add nano silica fume and keep temperature stirring 1-2 little Time, filtering, wash after drying, addition banana fiber, white carbon black grind 30-40 minute, freezing 3-5 hour at subzero 15-20 DEG C, Prepare organic modified nano silica flour;
(2) medical stone powder is put in 60-80 DEG C of ultrasonic disperse 1-2 hour in concentrated hydrochloric acid, washing to neutral, 30-50 DEG C of vacuum It is dried, adds IPPP ultrasonic disperse and within 2-3 hour, obtain modified medical stone powder;
(3) styrene-acrylic emulsion being heated to 80-90 DEG C, addition polypropylene fibre, organic modified nano silica flour are put in high mixer high Speed stirring 1-2 hour, is cooled to room temperature, adds Portland cement, modified medical stone powder and other residual componentss and grinds 1-2 Hour, discharging, wherein the ratio of mud is 1: 0.4.
The invention have the advantage that the present invention adds nano silica fume and carried out organically-modified, reduce surface and can make it Have facially amphiphilic, thus utilize three-dimensional protective effect to make nanoparticle be homogeneously dispersed in mortar and be difficult to reunite, carry The comprcssive strength of high product and anti-wear performance, more compound with polymer styrene-acrylic emulsion and polypropylene fibre, pass through physics And chemical action, improve polypropylene fibre surface can so that the cohesive force between itself and mortar improves further, it is suppressed that in early days The generation of micro-crack, improves the impermeability of product, rupture strength and durability;The present invention is also by modified for medical stone powder interpolation Other effective additives of compatibility again in raw material so that each component of mortar is uniformly dispersed not free settling, hence it is evident that improve leak stopping sand The water resistance of slurry also shortens its rapid hardening speed, preparation technology of the present invention is simple, easy construction, have after curing molding micro-swollen The performances such as swollen performance is good, self-healing properties is good, wear-resisting.
Detailed description of the invention
A kind of wear-resisting waterproofing and leakage-stopping mortar, is prepared by the raw materials in: Portland cement 24, river sand 49, Medical stone powder 13, white carbon black 17, banana fiber 2, polypropylene fibre 3.6, styrene-acrylic emulsion 8, calcium sulfate 0.4, nano silica fume 2.1, phosphorus Acid triisopropyl phenyl ester 3, vinyltrimethoxy silane 7, suitable quantity of water.
The manufacture method of described a kind of wear-resisting waterproofing and leakage-stopping mortar, comprises the following steps:
(1) under nitrogen protection by vinyltrimethoxy silane heated and boiled, add nano silica fume and keep temperature stirring 1-2 little Time, filtering, wash after drying, addition banana fiber, white carbon black grind 30-40 minute, freezing 3-5 hour at subzero 15-20 DEG C, Prepare organic modified nano silica flour;
(2) medical stone powder is put in 60-80 DEG C of ultrasonic disperse 1-2 hour in concentrated hydrochloric acid, washing to neutral, 30-50 DEG C of vacuum It is dried, adds IPPP ultrasonic disperse and within 2-3 hour, obtain modified medical stone powder;
(3) styrene-acrylic emulsion being heated to 80-90 DEG C, addition polypropylene fibre, organic modified nano silica flour are put in high mixer high Speed stirring 1-2 hour, is cooled to room temperature, adds Portland cement, modified medical stone powder and other residual componentss and grinds 1-2 Hour, discharging, wherein the ratio of mud is 1: 0.4.
Utilizing the present invention to prepare its 28d rupture strength of waterproofing and leakage-stopping mortar is that 8.57MPa, 28d comprcssive strength is 44.27MPa, impermeability pressure is 1.17 MPa.

Claims (2)

1. a wear-resisting waterproofing and leakage-stopping mortar, it is characterised in that be prepared by the raw materials in: Portland cement 24-26, river sand 49-51, medical stone powder 13-14, white carbon black 17-19, banana fiber 2-3, polypropylene fibre 3.6-4.5, phenylpropyl alcohol breast Liquid 8-10, calcium sulfate 0.4-0.6, nano silica fume 2.1-2.4, IPPP 3-4, vinyltrimethoxy silane 7- 9, suitable quantity of water.
The manufacture method of a kind of wear-resisting waterproofing and leakage-stopping mortar the most according to claim 1, it is characterised in that include following step Rapid:
(1) under nitrogen protection by vinyltrimethoxy silane heated and boiled, add nano silica fume and keep temperature stirring 1-2 little Time, filtering, wash after drying, addition banana fiber, white carbon black grind 30-40 minute, freezing 3-5 hour at subzero 15-20 DEG C, Prepare organic modified nano silica flour;
(2) medical stone powder is put in 60-80 DEG C of ultrasonic disperse 1-2 hour in concentrated hydrochloric acid, washing to neutral, 30-50 DEG C of vacuum It is dried, adds IPPP ultrasonic disperse and within 2-3 hour, obtain modified medical stone powder;
(3) styrene-acrylic emulsion being heated to 80-90 DEG C, addition polypropylene fibre, organic modified nano silica flour are put in high mixer high Speed stirring 1-2 hour, is cooled to room temperature, adds Portland cement, modified medical stone powder and other residual componentss and grinds 1-2 Hour, discharging, wherein the ratio of mud is 1: 0.4.
CN201610557721.1A 2016-07-15 2016-07-15 A kind of wear-resisting waterproofing and leakage-stopping mortar and preparation method thereof Pending CN106186951A (en)

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Application Number Priority Date Filing Date Title
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108689662A (en) * 2018-06-20 2018-10-23 河南阳光防水科技有限公司 Nano-silicon anti-leakage blocking agent
CN115182387A (en) * 2022-06-13 2022-10-14 武汉三源特种建材有限责任公司 New and old concrete interface waterproof structure and construction method

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103819153A (en) * 2013-12-31 2014-05-28 安徽省美域节能环保技术应用有限公司 Anti-freeze composite cement mortar

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103819153A (en) * 2013-12-31 2014-05-28 安徽省美域节能环保技术应用有限公司 Anti-freeze composite cement mortar

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108689662A (en) * 2018-06-20 2018-10-23 河南阳光防水科技有限公司 Nano-silicon anti-leakage blocking agent
CN115182387A (en) * 2022-06-13 2022-10-14 武汉三源特种建材有限责任公司 New and old concrete interface waterproof structure and construction method
CN115182387B (en) * 2022-06-13 2024-04-09 武汉三源特种建材有限责任公司 Waterproof structure of new and old concrete interface and construction method

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Application publication date: 20161207