CN106242420A - A kind of anti-cracking waterproof leak stopping mortar and preparation method thereof - Google Patents

A kind of anti-cracking waterproof leak stopping mortar and preparation method thereof Download PDF

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Publication number
CN106242420A
CN106242420A CN201610556758.2A CN201610556758A CN106242420A CN 106242420 A CN106242420 A CN 106242420A CN 201610556758 A CN201610556758 A CN 201610556758A CN 106242420 A CN106242420 A CN 106242420A
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CN
China
Prior art keywords
mortar
hour
modified
stainless steel
steel slag
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Pending
Application number
CN201610556758.2A
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Chinese (zh)
Inventor
乔启信
金自海
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ANHUI LANGKAIQI BUILDING MATERIALS Co Ltd
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ANHUI LANGKAIQI BUILDING MATERIALS Co Ltd
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Priority to CN201610556758.2A priority Critical patent/CN106242420A/en
Publication of CN106242420A publication Critical patent/CN106242420A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/04Portland cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • C04B2111/27Water resistance, i.e. waterproof or water-repellent materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/34Non-shrinking or non-cracking materials
    • C04B2111/343Crack resistant materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/72Repairing or restoring existing buildings or building materials

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

The invention discloses a kind of anti-cracking waterproof leak stopping mortar, add nano silicon and carried out organically-modified, reduce surface and can make it have facially amphiphilic, utilize three-dimensional protective effect to make nanoparticle be homogeneously dispersed in mortar to be difficult to reunite, improve the comprcssive strength of product, the most compound with polymer styrene-acrylic emulsion and polypropylene fibre again, by physics and chemical action, improve polypropylene fibre surface can, cohesive force between itself and mortar is improved further, inhibit the generation of micro-crack in early days, thus improve the impermeability of product, rupture strength and durability;The present invention also adds in raw material other effective additives of compatibility again to by modified for stainless steel slag so that each component of mortar is uniformly dispersed not free settling, hence it is evident that improve the water resistance of leak stopping mortar, the advantage that prepared waterproofing and leakage-stopping mortar has cracking resistance length in service life.

Description

A kind of anti-cracking waterproof leak stopping mortar and preparation method thereof
Technical field
The present invention relates to building material technical field, particularly relate to a kind of anti-cracking waterproof leak stopping mortar and preparation method thereof.
Background technology
Leakage of buildings problem is the common quality defect that building more highlights, and tracing it to its cause is architectural engineering xoncrete structure Because the reasons such as autogenous shrinkage, temperature deformation, design defect or construction produce crack, cause seepage, thus cause roof leakage, wall Wall seepage, rendering layer obscission, not only upset orthobiosis and the work of people, and directly influence whole solitary building In service life, waterproofing and leakage-stopping mortar arises at the historic moment.Waterproofing and leakage-stopping mortar, with high grade cement, sand, stone as raw material, mixes multiple high score Sub-additive, by adjusting match ratio, is improved cement pore structure, increases various raw-material density, or shunk by compensation Improve the anti-crack and anti-seepage ability of concrete.
Waterproofing and leakage-stopping mortar is widely used in China, and manufacturing enterprise is numerous, from the point of view of base material essence, mainly with aluminate Cement based or portland cement sill are base material.Aluminate cement later strength in wet condition can reduce, and silicate There is length setting time, early strength development and slowly and produce the fundamental issues such as contraction after hardening in cement, thus increasing is added in research The new waterproof leak stopping mortar of strong material is significant.
Polypropylene fibre has the advantage such as easy construction, with low cost, resistance to chemical attack, mixes as reinforcing material In cement mortar, it is possible to reduce mortar is the generation of micro-crack in hardening process, and stop or delay it to extend, thus effectively carrying The tensile strength of high mortar.But polypropylene fibre smooth surface, surface can without any active group on low, strand, and Surface hydrophobicity, causes it poor with cement matrix adhesive property.Exist simultaneously as PP fiber reinforced cement mortar is internal A large amount of holes, cause cement-hydrate, polypropylene fibre and aggregate interracial contact abundant not, reduce the durable of cement mortar Performance, these all have influence on polypropylene fibre application effect in cement-based material, constrain its range of application.To this end, it is " poly- The tacryl impact on polymer cement mortar performance " use a certain amount of styrene-acrylic emulsion of admixture to PP fiber reinforced cement sand Slurry is modified, and result shows: admixture polypropylene fibre and styrene-acrylic emulsion are remarkably improved the rupture strength of cement mortar simultaneously And anti-permeability performance, when polypropylene fiber be 0.6kg/m3, styrene-acrylic emulsion volume be 10% time, compared with benchmark mortar specimen, Its 28d rupture strength and impermeability pressure increase 29.20% and 400% respectively.But, use the water that the processing method in literary composition obtains The comprcssive strength of cement mortar is low, also needs to be modified.
Nano material possesses skin effect, small-size effect, quantum size effect, macroparticle tunnel-effect, and these are special Different character makes it in polymer modification, improves in coating, binder performance and becomes irreplaceable material, and the present invention uses nanometer Material adds in raw material to styrene-acrylic emulsion is the most modified, with improve product comprcssive strength, water-fast impervious, anticorrosion is resistance to always The performances such as change, but these special natures of nano material there is also certain limitation, such as due to small size can be big than table Easily reunite, cause disperseing uneven, thus be necessary to be then added in raw material, to change the nano material added is in addition modified The all technical of kind product.
Summary of the invention
The object of the invention is contemplated to make up the defect of prior art, it is provided that a kind of anti-cracking waterproof leak stopping mortar and making thereof Method.
The present invention is achieved by the following technical solutions:
A kind of anti-cracking waterproof leak stopping mortar, is prepared by the raw materials in: Portland cement 21-24, zeolite powder 13- 15, Kaolin 15-17, stainless steel slag 43-45, polypropylene fibre 3.7-4.6, sepiolite fibre 2.6-3.5, styrene-acrylic emulsion 9- 10, butyl acrylate 10-11, diethylenetriamines 3.4-3.6, Lauxite 2.3-2.6, nano silicon 1.2-1.3, sugar Calcium 1.8-2.1, anhydrous sodium sulfate 0.3-0.5, suitable quantity of water.
The manufacture method of described a kind of anti-cracking waterproof leak stopping mortar, comprises the following steps:
(1) under nitrogen protection by butyl acrylate heated and boiled, add nano silicon and keep temperature to stir 1-2 hour, Filtration, washing after drying, add sepiolite fibre and grind 40-50 minute, and freezing 3-5 hour at subzero 15-20 DEG C prepares and have Machine modified manometer silicon dioxide;
(2) stainless steel slag is put into after high-temperature process in 60-80 DEG C of ultrasonic disperse 1-2 hour in concentrated hydrochloric acid, washing to neutral, 30-50 DEG C of vacuum drying, adds diethylenetriamines ultrasonic disperse and within 2-3 hour, obtains aminated modified stainless steel slag, add The Lauxite of molten condition, keeps temperature ultrasonic disperse 30-50 minute, and modified stainless steel slag is ground to obtain in cooling;
(3) styrene-acrylic emulsion is heated to 80-90 DEG C, adds polypropylene fibre, anhydrous sodium sulfate, organically-modified nano-silica SiClx Put into high mixer high speed to stir 1-2 hour, be cooled to room temperature, add Portland cement, zeolite powder, modified stainless steel slag And other residual componentss grind 1-2 hour, discharging, wherein the ratio of mud is 1: 0.4.
The invention have the advantage that the present invention adds nano silicon and carried out organically-modified, reduce surface energy Make it have facially amphiphilic, utilize three-dimensional protective effect to make nanoparticle be homogeneously dispersed in mortar and be difficult to reunite, carry The high comprcssive strength of product, more compound with polymer styrene-acrylic emulsion and polypropylene fibre, by physics and chemical action, Improve polypropylene fibre surface can so that the cohesive force between itself and mortar improves further, it is suppressed that the product of micro-crack in early days Raw, thus improve the impermeability of product, rupture strength and durability;The present invention also adds raw material to by modified for stainless steel slag In other effective additives of compatibility again so that each component of mortar is uniformly dispersed not free settling, hence it is evident that improve the anti-of leak stopping mortar Aqueous energy, the advantage that prepared waterproofing and leakage-stopping mortar has cracking resistance length in service life.
Detailed description of the invention
A kind of anti-cracking waterproof leak stopping mortar, is prepared by the raw materials in: Portland cement 21, zeolite powder 13, Kaolin 15, stainless steel slag 43, polypropylene fibre 3.7, sepiolite fibre 2.6, styrene-acrylic emulsion 9, butyl acrylate 10, two Ethylenetriamine 3.4, Lauxite 2.3, nano silicon 1.2, sugar calcium 1.8, anhydrous sodium sulfate 0.3, suitable quantity of water.
The manufacture method of described a kind of anti-cracking waterproof leak stopping mortar, comprises the following steps:
(1) under nitrogen protection by butyl acrylate heated and boiled, add nano silicon and keep temperature to stir 1-2 hour, Filtration, washing after drying, add sepiolite fibre and grind 40-50 minute, and freezing 3-5 hour at subzero 15-20 DEG C prepares and have Machine modified manometer silicon dioxide;
(2) stainless steel slag is put into after high-temperature process in 60-80 DEG C of ultrasonic disperse 1-2 hour in concentrated hydrochloric acid, washing to neutral, 30-50 DEG C of vacuum drying, adds diethylenetriamines ultrasonic disperse and within 2-3 hour, obtains aminated modified stainless steel slag, add The Lauxite of molten condition, keeps temperature ultrasonic disperse 30-50 minute, and modified stainless steel slag is ground to obtain in cooling;
(3) styrene-acrylic emulsion is heated to 80-90 DEG C, adds polypropylene fibre, anhydrous sodium sulfate, organically-modified nano-silica SiClx Put into high mixer high speed to stir 1-2 hour, be cooled to room temperature, add Portland cement, zeolite powder, modified stainless steel slag And other residual componentss grind 1-2 hour, discharging, wherein the ratio of mud is 1: 0.4.
Utilizing the present invention to prepare its 28d rupture strength of waterproofing and leakage-stopping mortar is that 8.54MPa, 28d comprcssive strength is 44.24MPa, impermeability pressure is 1.14 MPa.

Claims (2)

1. an anti-cracking waterproof leak stopping mortar, it is characterised in that be prepared by the raw materials in: Portland cement 21-24, zeolite powder 13-15, Kaolin 15-17, stainless steel slag 43-45, polypropylene fibre 3.7-4.6, sepiolite fibre 2.6- 3.5, styrene-acrylic emulsion 9-10, butyl acrylate 10-11, diethylenetriamines 3.4-3.6, Lauxite 2.3-2.6, nano-silica SiClx 1.2-1.3, sugar calcium 1.8-2.1, anhydrous sodium sulfate 0.3-0.5, suitable quantity of water.
The manufacture method of a kind of anti-cracking waterproof leak stopping mortar the most according to claim 1, it is characterised in that include following step Rapid:
(1) under nitrogen protection by butyl acrylate heated and boiled, add nano silicon and keep temperature to stir 1-2 hour, Filtration, washing after drying, add sepiolite fibre and grind 40-50 minute, and freezing 3-5 hour at subzero 15-20 DEG C prepares and have Machine modified manometer silicon dioxide;
(2) stainless steel slag is put into after high-temperature process in 60-80 DEG C of ultrasonic disperse 1-2 hour in concentrated hydrochloric acid, washing to neutral, 30-50 DEG C of vacuum drying, adds diethylenetriamines ultrasonic disperse and within 2-3 hour, obtains aminated modified stainless steel slag, add The Lauxite of molten condition, keeps temperature ultrasonic disperse 30-50 minute, and modified stainless steel slag is ground to obtain in cooling;
(3) styrene-acrylic emulsion is heated to 80-90 DEG C, adds polypropylene fibre, anhydrous sodium sulfate, organically-modified nano-silica SiClx Put into high mixer high speed to stir 1-2 hour, be cooled to room temperature, add Portland cement, zeolite powder, modified stainless steel slag And other residual componentss grind 1-2 hour, discharging, wherein the ratio of mud is 1: 0.4.
CN201610556758.2A 2016-07-15 2016-07-15 A kind of anti-cracking waterproof leak stopping mortar and preparation method thereof Pending CN106242420A (en)

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107337406A (en) * 2017-07-19 2017-11-10 合肥广民建材有限公司 Low temperature resistant waterproofing and leakage-stopping mortar of a kind of cold-resistant and preparation method thereof
CN109943301A (en) * 2019-03-28 2019-06-28 中国石油大学(华东) Resin emulsion sealing agent composition and preparation method thereof and the application in fracture formation
CN110526655A (en) * 2019-10-17 2019-12-03 福州大学 A kind of cement-based self-leveling Wear-resisting terrace material and preparation method thereof of Modified Nickel slag preparation
CN110982415A (en) * 2019-12-20 2020-04-10 唐丽琪 Silane modified anti-settling polyurethane waterproof coating and preparation method thereof
CN112537923A (en) * 2020-12-10 2021-03-23 朱梓莹 Anti-seepage cement mortar and preparation process thereof
CN115070939A (en) * 2022-07-22 2022-09-20 山东科扬机械有限公司 Preparation method of dry-mixed mortar

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103819153A (en) * 2013-12-31 2014-05-28 安徽省美域节能环保技术应用有限公司 Anti-freeze composite cement mortar
CN105236884A (en) * 2015-09-07 2016-01-13 安徽朗凯奇建材有限公司 Polymer cement waterproofing mortar

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103819153A (en) * 2013-12-31 2014-05-28 安徽省美域节能环保技术应用有限公司 Anti-freeze composite cement mortar
CN105236884A (en) * 2015-09-07 2016-01-13 安徽朗凯奇建材有限公司 Polymer cement waterproofing mortar

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107337406A (en) * 2017-07-19 2017-11-10 合肥广民建材有限公司 Low temperature resistant waterproofing and leakage-stopping mortar of a kind of cold-resistant and preparation method thereof
CN109943301A (en) * 2019-03-28 2019-06-28 中国石油大学(华东) Resin emulsion sealing agent composition and preparation method thereof and the application in fracture formation
CN110526655A (en) * 2019-10-17 2019-12-03 福州大学 A kind of cement-based self-leveling Wear-resisting terrace material and preparation method thereof of Modified Nickel slag preparation
CN110526655B (en) * 2019-10-17 2021-08-31 福州大学 Cement-based self-leveling wear-resistant floor material prepared from modified nickel slag and preparation method thereof
CN110982415A (en) * 2019-12-20 2020-04-10 唐丽琪 Silane modified anti-settling polyurethane waterproof coating and preparation method thereof
CN112537923A (en) * 2020-12-10 2021-03-23 朱梓莹 Anti-seepage cement mortar and preparation process thereof
CN115070939A (en) * 2022-07-22 2022-09-20 山东科扬机械有限公司 Preparation method of dry-mixed mortar
CN115070939B (en) * 2022-07-22 2023-01-31 山东科扬机械有限公司 Preparation method of dry-mixed mortar

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