CN106186948A - A kind of rapid-hardening waterproofing and leakage-stopping mortar and preparation method thereof - Google Patents

A kind of rapid-hardening waterproofing and leakage-stopping mortar and preparation method thereof Download PDF

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Publication number
CN106186948A
CN106186948A CN201610557378.0A CN201610557378A CN106186948A CN 106186948 A CN106186948 A CN 106186948A CN 201610557378 A CN201610557378 A CN 201610557378A CN 106186948 A CN106186948 A CN 106186948A
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China
Prior art keywords
mortar
leakage
add
hour
rapid
Prior art date
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Withdrawn
Application number
CN201610557378.0A
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Chinese (zh)
Inventor
乔启信
金自海
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ANHUI LANGKAIQI BUILDING MATERIALS Co Ltd
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ANHUI LANGKAIQI BUILDING MATERIALS Co Ltd
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Priority to CN201610557378.0A priority Critical patent/CN106186948A/en
Publication of CN106186948A publication Critical patent/CN106186948A/en
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Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/04Portland cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B20/00Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
    • C04B20/02Treatment
    • C04B20/023Chemical treatment
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • C04B2111/27Water resistance, i.e. waterproof or water-repellent materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/50Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

Abstract

The invention discloses a kind of rapid-hardening waterproofing and leakage-stopping mortar, add nano zine oxide and carried out organically-modified, reduce surface and can make it have facially amphiphilic, utilize three-dimensional protective effect to make nano zinc oxide particles be homogeneously dispersed in mortar to be difficult to reunite, improve the comprcssive strength of product, the most compound with polymer styrene-acrylic emulsion and polypropylene fibre again, by physics and chemical action, improve polypropylene fibre surface can, cohesive force between itself and mortar is improved, inhibit the generation of micro-crack in early days well, thus improve the impermeability of product, rupture strength and durability;The present invention also will add in raw material other effective additives of compatibility again after flyash modified to, the each component of mortar is uniformly dispersed not free settling, significantly improve the water resistance of leak stopping mortar and shorten its rapid hardening speed, the characteristic that waterproofing and leakage-stopping mortar has height water-fast, impervious, crack resistance is strong, caking property is high prepared, from solving leakage problems at all.

Description

A kind of rapid-hardening waterproofing and leakage-stopping mortar and preparation method thereof
Technical field
The present invention relates to building material technical field, particularly relate to a kind of rapid-hardening waterproofing and leakage-stopping mortar and making side thereof Method.
Background technology
Leakage of buildings problem is the common quality defect that building more highlights, and tracing it to its cause is architectural engineering xoncrete structure Because the reasons such as autogenous shrinkage, temperature deformation, design defect or construction produce crack, cause seepage, thus cause roof leakage, wall Wall seepage, rendering layer obscission, not only upset orthobiosis and the work of people, and directly influence whole solitary building In service life, waterproofing and leakage-stopping mortar arises at the historic moment.Waterproofing and leakage-stopping mortar, with high grade cement, sand, stone as raw material, mixes multiple high score Sub-additive, by adjusting match ratio, is improved cement pore structure, increases various raw-material density, or shunk by compensation Improve the anti-crack and anti-seepage ability of concrete.
Waterproofing and leakage-stopping mortar is widely used in China, and manufacturing enterprise is numerous, from the point of view of base material essence, mainly with aluminate Cement based or portland cement sill are base material.Aluminate cement later strength in wet condition can reduce, and silicate There is length setting time, early strength development and slowly and produce the fundamental issues such as contraction after hardening in cement, thus increasing is added in research The new waterproof leak stopping mortar of strong material is significant.
Polypropylene fibre has the advantage such as easy construction, with low cost, resistance to chemical attack, mixes as reinforcing material In cement mortar, it is possible to reduce mortar is the generation of micro-crack in hardening process, and stop or delay it to extend, thus effectively carrying The tensile strength of high mortar.But polypropylene fibre smooth surface, surface can without any active group on low, strand, and Surface hydrophobicity, causes it poor with cement matrix adhesive property.Exist simultaneously as PP fiber reinforced cement mortar is internal A large amount of holes, cause cement-hydrate, polypropylene fibre and aggregate interracial contact abundant not, reduce the durable of cement mortar Performance, these all have influence on polypropylene fibre application effect in cement-based material, constrain its range of application.To this end, it is " poly- The tacryl impact on polymer cement mortar performance " use a certain amount of styrene-acrylic emulsion of admixture to PP fiber reinforced cement sand Slurry is modified, and result shows: admixture polypropylene fibre and styrene-acrylic emulsion are remarkably improved the rupture strength of cement mortar simultaneously And anti-permeability performance, when polypropylene fiber is 0.6kg/m3, styrene-acrylic emulsion volume is when being 10%, compared with benchmark mortar specimen, Its 28d rupture strength and impermeability pressure increase 29.20% and 400% respectively.But, use the water that the processing method in literary composition obtains The comprcssive strength of cement mortar is low, also needs to be modified.
Nano material possesses skin effect, small-size effect, quantum size effect, macroparticle tunnel-effect, and these are special Different character makes it in polymer modification, improves in coating, binder performance and becomes irreplaceable material, and the present invention uses nanometer Material adds in raw material to styrene-acrylic emulsion is the most modified, with improve product comprcssive strength, water-fast impervious, anticorrosion is resistance to always The performances such as change, but these special natures of nano material there is also certain limitation, such as due to small size can be big than table Easily reunite, cause disperseing uneven, thus be necessary to be then added in raw material, to change the nano material added is in addition modified The all technical of kind product.
Summary of the invention
The object of the invention is contemplated to make up the defect of prior art, it is provided that a kind of rapid-hardening waterproofing and leakage-stopping mortar and system thereof Make method.
The present invention is achieved by the following technical solutions:
A kind of rapid-hardening waterproofing and leakage-stopping mortar, is prepared by the raw materials in: Portland cement 23-25, quartz sand 50-52, flyash 18-20, polypropylene fibre 3-5, acrylic fiber 2-4, styrene-acrylic emulsion 6-8, polymethyl methacrylate 5- 7, butyl titanate 14-16, dimethylaniline 3.5-3.8, sodium hexameta phosphate 0.4-0.7, calcium nitrate 0.3-0.5, nano oxidized Zinc 1.4-1.7, suitable quantity of water.
The manufacture method of described a kind of rapid-hardening waterproofing and leakage-stopping mortar, comprises the following steps:
(1) under nitrogen protection by butyl titanate heated and boiled, add nano zine oxide and keep temperature to stir 1-2 hour, mistake Filter, washing are dried, at subzero 15-20 DEG C freezing 3-5 hour, add sodium hexameta phosphate and pulverize prepared organically-modified receive Rice zinc oxide;
(2) being put into by flyash in 60-80 DEG C of ultrasonic disperse 1-2 hour in concentrated hydrochloric acid, washing is to neutral, and 30-50 DEG C of vacuum is done Dry, add dimethylaniline ultrasonic disperse and within 2-3 hour, obtain aminated modified coal ash, add the poly-methyl-prop of molten condition E pioic acid methyl ester, keeps temperature ultrasonic disperse 30-50 minute, and modified coal ash is ground to obtain in cooling;
(3) styrene-acrylic emulsion being heated to 80-90 DEG C, addition polypropylene fibre, acrylic fiber, organic modified nano zinc oxide are put Enter high mixer high speed to stir 1-2 hour, be cooled to room temperature, add Portland cement, quartz sand, modified coal ash and He grinds 1-2 hour at residual components, and discharging, wherein the ratio of mud is 1: 0.4.
The invention have the advantage that the present invention adds nano zine oxide and carried out organically-modified, reducing surface can make It has facially amphiphilic, thus utilizes three-dimensional protective effect to make nano zinc oxide particles be homogeneously dispersed in mortar and be difficult to Reunite, improve the comprcssive strength of product, more compound with polymer styrene-acrylic emulsion and polypropylene fibre, by physics and change Effect, improve polypropylene fibre surface can so that the cohesive force between itself and mortar improves further, inhibits well early The generation of phase micro-crack, thus improve the impermeability of product, rupture strength and durability;The present invention is also by after flyash modified Add in raw material other effective additives of compatibility again to so that each component of mortar is uniformly dispersed not free settling, hence it is evident that improve stifled Leaking the water resistance of mortar and shorten its rapid hardening speed, prepared waterproofing and leakage-stopping mortar has height water-fast, impervious, crack resistance By force, characteristic that caking property is high, from solving leakage problems at all.
Detailed description of the invention
A kind of rapid-hardening waterproofing and leakage-stopping mortar, is prepared by the raw materials in: Portland cement 23, quartz sand 50, flyash 18, polypropylene fibre 3, acrylic fiber 2, styrene-acrylic emulsion 6, polymethyl methacrylate 5, butyl titanate 14, Dimethylaniline 3.5, sodium hexameta phosphate 0.4, calcium nitrate 0.3, nano zine oxide 1.4, suitable quantity of water.
The manufacture method of described a kind of rapid-hardening waterproofing and leakage-stopping mortar, comprises the following steps:
(1) under nitrogen protection by butyl titanate heated and boiled, add nano zine oxide and keep temperature to stir 1-2 hour, mistake Filter, washing are dried, at subzero 15-20 DEG C freezing 3-5 hour, add sodium hexameta phosphate and pulverize prepared organically-modified receive Rice zinc oxide;
(2) being put into by flyash in 60-80 DEG C of ultrasonic disperse 1-2 hour in concentrated hydrochloric acid, washing is to neutral, and 30-50 DEG C of vacuum is done Dry, add dimethylaniline ultrasonic disperse and within 2-3 hour, obtain aminated modified coal ash, add the poly-methyl-prop of molten condition E pioic acid methyl ester, keeps temperature ultrasonic disperse 30-50 minute, and modified coal ash is ground to obtain in cooling;
(3) styrene-acrylic emulsion being heated to 80-90 DEG C, addition polypropylene fibre, acrylic fiber, organic modified nano zinc oxide are put Enter high mixer high speed to stir 1-2 hour, be cooled to room temperature, add Portland cement, quartz sand, modified coal ash and He grinds 1-2 hour at residual components, and discharging, wherein the ratio of mud is 1: 0.4.
Utilizing the present invention to prepare its 28d rupture strength of waterproofing and leakage-stopping mortar is that 8.51MPa, 28d comprcssive strength is 44.11MPa, impermeability pressure is 1.11 MPa.

Claims (2)

1. a rapid-hardening waterproofing and leakage-stopping mortar, it is characterised in that be prepared by the raw materials in: Portland cement 23-25, quartz sand 50-52, flyash 18-20, polypropylene fibre 3-5, acrylic fiber 2-4, styrene-acrylic emulsion 6-8, poly-methyl Acrylic acid methyl ester. 5-7, butyl titanate 14-16, dimethylaniline 3.5-3.8, sodium hexameta phosphate 0.4-0.7, calcium nitrate 0.3- 0.5, nano zine oxide 1.4-1.7, suitable quantity of water.
The manufacture method of a kind of rapid-hardening waterproofing and leakage-stopping mortar the most according to claim 1, it is characterised in that include following Step:
(1) under nitrogen protection by butyl titanate heated and boiled, add nano zine oxide and keep temperature to stir 1-2 hour, mistake Filter, washing are dried, at subzero 15-20 DEG C freezing 3-5 hour, add sodium hexameta phosphate and pulverize prepared organically-modified receive Rice zinc oxide;
(2) being put into by flyash in 60-80 DEG C of ultrasonic disperse 1-2 hour in concentrated hydrochloric acid, washing is to neutral, and 30-50 DEG C of vacuum is done Dry, add dimethylaniline ultrasonic disperse and within 2-3 hour, obtain aminated modified coal ash, add the poly-methyl-prop of molten condition E pioic acid methyl ester, keeps temperature ultrasonic disperse 30-50 minute, and modified coal ash is ground to obtain in cooling;
(3) styrene-acrylic emulsion being heated to 80-90 DEG C, addition polypropylene fibre, acrylic fiber, organic modified nano zinc oxide are put Enter high mixer high speed to stir 1-2 hour, be cooled to room temperature, add Portland cement, quartz sand, modified coal ash and He grinds 1-2 hour at residual components, and discharging, wherein the ratio of mud is 1: 0.4.
CN201610557378.0A 2016-07-15 2016-07-15 A kind of rapid-hardening waterproofing and leakage-stopping mortar and preparation method thereof Withdrawn CN106186948A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107337406A (en) * 2017-07-19 2017-11-10 合肥广民建材有限公司 Low temperature resistant waterproofing and leakage-stopping mortar of a kind of cold-resistant and preparation method thereof
CN113620681A (en) * 2021-08-10 2021-11-09 河南省禹志建设工程有限公司 Slow-seepage-resistant waterproof leaking stoppage mortar and preparation method thereof

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103819153A (en) * 2013-12-31 2014-05-28 安徽省美域节能环保技术应用有限公司 Anti-freeze composite cement mortar

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103819153A (en) * 2013-12-31 2014-05-28 安徽省美域节能环保技术应用有限公司 Anti-freeze composite cement mortar

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107337406A (en) * 2017-07-19 2017-11-10 合肥广民建材有限公司 Low temperature resistant waterproofing and leakage-stopping mortar of a kind of cold-resistant and preparation method thereof
CN113620681A (en) * 2021-08-10 2021-11-09 河南省禹志建设工程有限公司 Slow-seepage-resistant waterproof leaking stoppage mortar and preparation method thereof

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Application publication date: 20161207