CN106172438B - Bactericidal composition - Google Patents

Bactericidal composition Download PDF

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Publication number
CN106172438B
CN106172438B CN201610569806.1A CN201610569806A CN106172438B CN 106172438 B CN106172438 B CN 106172438B CN 201610569806 A CN201610569806 A CN 201610569806A CN 106172438 B CN106172438 B CN 106172438B
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bacterium azoles
evil bacterium
evil
fluoxastrobin
methoxy acrylic
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CN106172438A (en
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张志伟
王礼文
陈佛祥
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Hunan Agricultural University Heartale Chemurgy Co ltd
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Guangdong Zhongxun Agri Science Corp
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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/82—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with three ring hetero atoms
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/36—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/44—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
    • A01N37/50—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids the nitrogen atom being doubly bound to the carbon skeleton
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/74—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
    • A01N43/78—1,3-Thiazoles; Hydrogenated 1,3-thiazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/88—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms six-membered rings with three ring hetero atoms
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
    • A01N47/24—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing the groups, or; Thio analogues thereof

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  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention discloses a kind of bactericidal compositions containing Er Lv Evil bacterium azoles and methoxy acrylic bactericide, the weight ratio of the one kind of methoxy acrylic bactericide in benzothiostrobin, phenylsulfonyl ester, fluoxastrobin, Fluoxastrobin, pyraclostrobin, trifloxystrobin or ZEN 90160, Er Lv Evil bacterium azoles and methoxy acrylic bactericide is 20:1~1:20.Bactericidal composition of the present invention can be used for preventing the multiple diseases such as late blight, powdery mildew, downy mildew, banded sclerotial blight, gray mold, brown spot, the anthracnose on crops, compared with existing single formulation, obvious synergy, bactericidal effect is outstanding, wide sterilization spectrum, lasting period is long, to Crop securify, while reducing Pesticide use amount, reduce residual quantity of the pesticide on crops, the pollution to environment is alleviated, the generation of pathogen drug resistance has been delayed, increases the Pesticide use service life.

Description

Bactericidal composition
Technical field
The present invention relates to pesticide sterilizing composite and its application fields, specifically with Er Lv Evil bacterium azoles and methoxy propyl Alkene bactericide of phosphate (phosphinium) ester is the binary complex of active constituent compounding, is mainly used in the prevention of disease on crops.
Background technology
Er Lv Evil bacterium azoles is Yi Zhong oxazole sulfone series bactericidal agents, and chemical name is：2- methyl sulfuryl -5- (2,4 dichloro benzenes Base) -1,3,4- oxadiazoles, molecular structure is shown below, and is the fungicide of a kind of novel low-toxicity, safety, to potato evening The fungal diseases such as epidemic disease have preferable control effect.In practical application, there are the defects that fungicidal spectrum is relatively narrow for it, are used alone Shi Wufa solves the problems, such as that multiple diseases mixing occurs on crops.
Methoxy acrylic acid series bactericidal agent is fungicide kind newly developed in recent years, and the active group of this series bactericidal agent is Methoxy acrylic acid (ester/amide) mainly acts on the cytochrome b el compounds in the mitochondrial respiratory chain of fungi, prevents Electron transmission to inhibit fungi to grow, have protect, treat, rooting out, permeating, systemic activity, and can in plant, it is native It degrades quickly in earth and water.As methoxy acrylic bactericide is largely used continuously, more and more pathogens are to it Drug resistance is produced, and use cost is high, so limiting promoting the use of a large area for methoxy acrylic acid series bactericidal agent.
Benzothiostrobin, English common name：Benzothiostrobin, chemical name：(E) -2- [2- (5- methoxyl group benzos Thiazole -2- sulfidomethyls) phenyl] -3- methoxy-methyl acrylates.Benzothiostrobin has wide sterilization spectrum, and bactericidal activity is high, amount of application Low, the advantages that lasting period is long, has protection and therapeutic effect, has to diseases such as powdery mildew, downy mildew on crops superior Preventive effect.
Phenylsulfonyl ester, chemical name：(E) -2- [2- (2,5- dimethyl phenoxies toluene)-phenyl] -3- methoxyl group propylene Sour methyl esters, phenylsulfonyl ester are wide spectrum, the systemic fungicide developed by Zhejiang chemical research institute, and bactericidal activity is higher, has both protection And therapeutic effect, it can be used for preventing the diseases such as powdery mildew, downy mildew, anthracnose.
Fluoxastrobin, English common name：Fluoxastrobin, chemical name：{ [6- (2- chlorophenoxies) -5- fluorine is phonetic by 2- Pyridine -4- bases oxygen] phenyl } (5,6- dihydros-Isosorbide-5-Nitrae, 2 Yi dioxazine -3- bases) ketone 0- methyloximes.Fluoxastrobin is Bayer crop section The absorbability cauline leaf process fungicide of company report, it is wide using optimum period, no matter in fungal infection early stage, or in mycelia Growth period can provide extraordinary protection and therapeutic effect, can effectively prevent cereal crop, potato, vegetables and coffee Nearly all fungal disease such as rust, glume blight, powdery mildew, downy mildew etc. in equal crops.
Fluoxastrobin, English common name：Azoxystrobin, chemical name：(E) [[6- (2- cyano-benzene oxygens) is phonetic by 2- by 2- Pyridine -4- bases oxygen] phenyl] -3- methoxy-methyl acrylates.Efficiently, wide spectrum can almost prevent all fungal diseases, such as dialogue Powder disease, rust, glume blight, net blotch, downy mildew, rice blast etc. have good activity, have and protect, root out, permeating and interior Suction acts on, and can inhibit the sprouting of spore and the growth of mycelia.It can be used for cauline leaf process, seed treatment, can also carry out at soil Reason.
Pyraclostrobin, English common name：Pyraclostrobin, chemical name：N- { 2- [1- (4- chlorphenyls) -1H- Pyrazole-3-yl oxygen methyl] phenyl } (N- methoxyl groups) carbamate.A variety of fungal pathogens, wide sterilization spectrum, to more can be prevented and kill off Kind crop, including wheat, grape, fruit tree, the multiple diseases of vegetables are effective, are mainly used for preventing uncinula necator, downy mildew；It is small Wheat powdery mildew, rust；Leaf rust of barley；The black leaf cecospora spot of banana；Tomato morning, late blight etc..
Trifloxystrobin, English common name：Trifloxystrobin, chemical name：Methyl (E) methoxyl group imido grpup-{ (E)- α-[1- (the fluoro- m- tolyls of α, α-three)-ethyleneimino oxygroup]-o-tolyl } ethyl acetate.Trifloxystrobin is that Beyer Co., Ltd opens Hair has protection, treatment, infiltration and excellent conductive performance, resistance of rainwater washing against, is the foliage fungicide of a wide spectrum, high Effect property and good crop-selective allow it to effectively prevent temperate zone, the disease on subtropical crop.It can be used for preventing rust Disease, downy mildew, scab of apple, damping-off, powdery mildew etc..
ZEN 90160, English common name：Picoxystrobin, chemical name：(E) -3- methoxyl groups -2- { 2- [6- (trifluoros Methyl) -2- pyridine oxygen methyls] phenyl } methyl acrylate.ZEN 90160 is Syngenta Co., Ltd's exploitation, which, which has, absorbs Speed is fast, and systemic activity is sick to wheat leaf blight, net blotch and moire disease etc. compared with existing methoxy acrylate fungicide Evil has stronger therapeutic effect.
The independent continuous use for a long time of pesticide easy tos produce resistance risk and dosage and increases risk, so increase cost and Carrying capacity of environment, and the composition with notable synergistic function is filtered out by agriculture chemical compounding, Pesticide use can not only be reduced Amount reduces use cost, reduces resistance risk, moreover it is possible to reduce potential environmental risk.
Invention content
The purpose of the present invention is to provide a kind of component is reasonable, obvious synergy, bactericidal effect is outstanding, fungicidal spectrum Extensively, the lasting period is long, and drug cost is low, pathogen can be delayed to develop immunity to drugs, and to the bactericidal composition of Crop securify.
Another object of the present invention is to provide above-mentioned bactericidal composition prevention crops on late blight, powdery mildew, frost Application in mildew, banded sclerotial blight, gray mold, brown spot, anthracnose.
Technical scheme of the present invention：To achieve the above object, present invention offer is a kind of containing Er Lv Evil bacterium azoles and methoxyl group The bactericidal composition of acrylic bactericide, by two chlorine Evil bacterium azoles of the first active constituent and the second active constituent methoxyl group propylene Bactericide of phosphate (phosphinium) ester and auxiliary agent composition, methoxy acrylic bactericide be selected from benzothiostrobin, phenylsulfonyl ester, fluoxastrobin, One kind in Fluoxastrobin, pyraclostrobin, trifloxystrobin or ZEN 90160, Er Lv Evil bacterium azoles and methoxy acrylic bactericide Weight ratio be 20:1~1:The total weight percentage of 20, Er Lv Evil bacterium azoles and methoxy acrylic bactericide in the composition Content is 1%~85%.
Auxiliary agent described in bactericidal composition of the present invention includes solvent, emulsifier, wetting agent, dispersant, antifreezing agent, thickening Agent, disintegrant, binder, antifoaming agent, preservative, stabilizer, cyst material, synergist, poisoning palliative, bleeding agent, filler Deng, be all in pesticidal preparations commonly use or allow the ingredient used, be not particularly limited, specific ingredient and dosage are according to recipe requirements It is determined by testing.
The solvent is selected from acetone, butanone, cyclohexanone, toluene, dimethylbenzene, trimethylbenzene, durene, methyl naphthalene, oleic acid first Ester, ethyl acetate, fatty acid methyl ester, loose base oil, soybean oil, rapeseed oil, biodiesel, ethyl alcohol, normal propyl alcohol, isopropanol, the third two Alcohol, glycerine, n-butanol, isooctanol, sec-Butyl Acetate, dimethyl carbonate, diesel oil, white oil, machine oil, disalt base ester, N- methyl The mixture of one or more of pyrrolidones, DMAC N,N' dimethyl acetamide, deionized water etc..
The emulsifier be selected from agriculture breast 400, agriculture breast 500, agriculture breast 600, Nongru-700, NP series, 0201B, 0203B, 2201, peaceful breast 31, peaceful breast 33, peaceful breast 37,0202,0202C, APES sulfosuccinate, castor-oil plant Oily polyoxyethylene ether, aliphatic acid polyethenoxy ether, polyoxyethylene aliphatic alcohol ether, ethoxy castor oil, polymethyl acrylate, fat The mixture of one or more of acid polyethylene glycol ester, trilaurin polyoxyethylene ether etc..
The wetting agent be selected from naphthalene sulfonate, lauryl sodium sulfate, Teepol, fatty alcohol polyoxyethylene ether, One or both of nonylphenol polyoxyethylene ether, sorbitan fatty acid ester polyoxyethylene ether, alkylsulfonate etc. with On mixture.
The dispersant be selected from sodium lignin sulfonate, calcium lignosulfonate, Sodium Polyacrylate, di-2-ethylhexylphosphine oxide naphthalene sulfonate, Alkyl benzene sulfonate calcium salt, alkylbenzenesulfonate amine salt, sodium methylene bis-naphthalene sulfonate formaldehyde condensation products, polyoxyethylene polyoxypropylene block In copolymer, carboxymethyl cellulose, polyvinyl alcohol, polyvinylpyrrolidone, sodium tripolyphosphate, alkylnaphthalene sulfonate condensation polymer etc. One or more kinds of mixtures.
The antifreezing agent is in ethylene glycol, propylene glycol, glycerine, polyethylene glycol, sorbierite, urea, inorganic salts etc. One or more kinds of mixtures.
It is fine that the thickener is selected from xanthans, gelatin, Arabic gum, polyvinyl alcohol, bentonite, aluminium-magnesium silicate, carboxymethyl Tie up the mixture of one or more of element, carboxyethyl cellulose, methylcellulose etc..
The disintegrant is selected from ammonium sulfate, urea, starch and its derivative, low-substituted hydroxypropyl cellulose, polyethylene pyrrole One or more of the medium mixture of pyrrolidone, sodium alginate, calcium chloride, sodium chloride, magnesium chloride, aluminium chloride.
The binder is selected from glucose, sucrose, hydroxyethyl cellulose, soluble starch, polyethylene glycol, Methyl cellulose Element, polycarboxylic acid and water-soluble high-molecular compound sodium carboxymethylcellulose, polyvinyl alcohol, paraffin, gypsum, hydroxypropyl methyl are fine Tie up the mixture of one or more of element, polyacrylamide etc..
The antifoaming agent is selected from silicone oil, silicone compound, C10- 20 saturated fat acids compounds, C8-10Aliphatic alcohols, The mixture of one or more of hexanol, butanol, octanol etc..
The preservative is in formaldehyde, benzoic acid, sodium benzoate, potassium sorbate, Kathon CG Kathon, isothiazolinone etc. One or more kinds of mixtures.
The stabilizer is selected from sodium citrate, resorcinol, epoxidized soybean oil, epoxychloropropane, epoxidized linseed oil, season penta The mixture of one or more of tetrol, xylitol, butylated hydroxy anisole etc..
The cyst material is selected from polyurethane, poly Toluene-2,4-diisocyanate, 4- diisocyanate, poly- allyl acetate, O-phthalic Acid cellulose ester, polyacrylate, polyamide, function groups aminoplast, for ethyl cellulose, hydroxyethyl cellulose, second The mixture of one or more of diamines, kayexalate etc..
The synergist be selected from dregs of beans, chlorinated aliphatic, Butacide, organosilicon, Octacide 264, alkyl carbonate, azone, The mixture of one or more of polyether-modified trisiloxanes etc..
The poisoning palliative is selected from the mixed of one or more of gibberellic acid, study on brassinolide, compound sodium nitrophenolate etc. Close object.
The bleeding agent is selected from dialkyl group succinic acid fat sulfonate sodium, ester sodium sulfonate, azone, ethylene oxide and higher aliphatic Condensation product, aliphatic alcohol sulfate, sodium alkyl benzene sulfonate, alkyl benzyl dimethyl ammonium chloride, alky pyridinium halides, the alkyl of alcohol The mixture of one or more of amine oxide etc..
The filler be selected from white carbon, kaolin, bentonite, precipitated calcium carbonate, gypsum, attapulgite, urea, sucrose, The mixture of one or more of diatomite, ammonium sulfate, potassium dihydrogen phosphate, clay, sepiolite etc..
Bactericidal composition of the present invention can be prepared into a variety of application forms used in suitable agricultural production, relatively good agent Type has microcapsule suspending agent, suspending agent, aqueous emulsion, microemulsion, water dispersible granules, wettable powder, ultra low volume liquids.
The production technology of the various application forms of bactericidal composition belongs to existing known technology, and details are not described herein.
Compared with the prior art, the advantages of the present invention are as follows：
1, Er Lv Evil bacterium azoles and methoxy acrylic bactericide compounding have significant synergistic function, compared with list The control effect significantly improved to disease on crops is used alone in agent, expands fungicidal spectrum.
2, Er Lv Evil bacterium azoles and methoxy acrylic bactericide two kinds of active components compounding, reduce Pesticide use Amount, reduces use cost, alleviates the pollution to environment.
3, Er Lv Evil bacterium azoles and methoxy acrylic bactericide two kinds of active components compounding, the mutual not phase of the mechanism of action Together, action site increases, and has delayed the generation of pathogen drug resistance, has increased the service life of pesticide.
Specific implementation mode
To better understand the essence of the present invention, present disclosure is described further with reference to embodiment, But limitation of the present invention cannot be considered as, it is as described below to be only used for explaining the present invention, for without departing from spirit of that invention and principle Modification, replacement or the improvement made, belong to the scope of protection of present invention.
(1) Formulation Example
Embodiment 1：22% Er Lv Evil bacterium azoles benzothiostrobin microcapsule suspending agents
Following substance is weight percentage：Er Lv Evil bacterium azoles 11%, benzothiostrobin 11%, poly Toluene-2,4-diisocyanate, 4- bis- are different Cyanate (cyst material) 10%, hydroxyethyl cellulose (cyst material) 5%, sec-Butyl Acetate (solvent) 10%, alkyl phenol are poly- Ethylene oxide ether sulfosuccinates (emulsifier) 5%, sodium methylene bis-naphthalene sulfonate formaldehyde condensation products (dispersant) 5%, benzoic acid Sodium (preservative) 0.5%, deionized water complements to 100%.Above-mentioned material is mixed, in proportion after polymerisation, you can 22% Er Lv Evil bacterium azoles benzothiostrobin microcapsule suspending agents are made.
Embodiment 2：30% Er Lv Evil bacterium azoles phenylsulfonyl ester microcapsule suspending agents
Following substance is weight percentage：Two chlorine Evil bacterium azoles 25%, phenylsulfonyl ester 5%, poly- allyl acetate (cyst wall material Material) 8%, hydroxyethyl cellulose (cyst material) 5%, sec-Butyl Acetate (solvent) 10%, alkyl phenol polyoxyethylene ether sulfo group amber Amber acid esters (emulsifier) 5%, alkylbenzenesulfonate amine salt (dispersant) 5%, sodium benzoate (preservative) 0.5%, deionized water are mended Enough to 100%.Above-mentioned material is mixed, in proportion after polymerisation, you can 30% Er Lv Evil bacterium azoles phenylate bacterium are made Ester micro capsule suspending agent.
Embodiment 3：20% Er Lv Evil bacterium azoles fluoxastrobin microcapsule suspending agents
Following substance is weight percentage：Two chlorine Evil bacterium azoles 5%, fluoxastrobin 15%, poly- allyl acetate (cyst wall material Material) 8%, ethylenediamine (cyst material) 10%, sec-Butyl Acetate (solvent) 10%, ethoxy castor oil (emulsifier) 5%, alkyl Benzene sulfonic acid amine salt (dispersant) 5%, sodium benzoate (preservative) 0.5%, deionized water complements to 100%.Above-mentioned material is pressed Ratio is mixed, after polymerisation, you can 20% Er Lv Evil bacterium azoles fluoxastrobin microcapsule suspending agents are made.
Embodiment 4：24% Er Lv Evil bacterium azoles Fluoxastrobin microcapsule suspending agents
Following substance is weight percentage：Two chlorine Evil bacterium azoles 4%, Fluoxastrobin 20%, poly- allyl acetate (cyst wall material Material) 8%, ethylenediamine (cyst material) 10%, dimethyl carbonate (solvent) 10%, ethoxy castor oil (emulsifier) 5%, poly- third Olefin(e) acid sodium (dispersant) 6%, isothiazolinone (preservative) 0.3%, deionized water complements to 100%.By above-mentioned material press than Example is mixed, after polymerisation, you can 24% Er Lv Evil bacterium azoles Fluoxastrobin microcapsule suspending agents are made.
Embodiment 5：28% Er Lv Evil bacterium azoles pyraclostrobin microcapsule suspending agents
Following substance is weight percentage：Er Lv Evil bacterium azoles 12%, pyraclostrobin 16%, phthalate, cellulose Ester (cyst material) 10%, kayexalate (cyst material) 5%, dimethyl carbonate (solvent) 10%, ethoxylated castor Oily (emulsifier) 5%, Sodium Polyacrylate (dispersant) 6%, potassium sorbate (preservative) 0.3%, deionized water complements to 100%.Above-mentioned material is mixed, in proportion after polymerisation, you can 28% Er Lv Evil bacterium azoles pyraclostrobins are made Microcapsule suspending agent.
Embodiment 6：18% Er Lv Evil bacterium azoles trifloxystrobin microcapsule suspending agents
Following substance is weight percentage：Er Lv Evil bacterium azoles 17%, trifloxystrobin 1%, phthalate, cellulose ester (capsule Wall material) 10%, ethyl cellulose (cyst material) 8%, dimethyl carbonate (solvent) 10%, ethoxy castor oil (emulsification Agent) 5%, alkylnaphthalene sulfonate condensation polymer (dispersant) 5%, potassium sorbate (preservative) 0.3%, deionized water complements to 100%.Above-mentioned material is mixed, in proportion after polymerisation, you can 18% Er Lv Evil bacterium azoles trifloxystrobin micro-capsules are made Suspending agent.
Embodiment 7：15% Er Lv Evil bacterium azoles ZEN 90160 microcapsule suspending agents
Following substance is weight percentage：Er Lv Evil bacterium azoles 6%, ZEN 90160 9%, phthalate, cellulose ester (cyst material) 10%, ethyl cellulose (cyst material) 8%, fatty acid methyl ester (solvent) 10%, trilaurin are poly- Ethylene oxide ether (emulsifier) 5%, alkylnaphthalene sulfonate condensation polymer (dispersant) 5%, potassium sorbate (preservative) 0.3%, go from Sub- water complements to 100%.Above-mentioned material is mixed, in proportion after polymerisation, you can 15% Er Lv Evil bacterium azoles is made ZEN 90160 microcapsule suspending agent.
Embodiment 8：32% Er Lv Evil bacterium azoles benzothiostrobin suspending agents
Following substance is weight percentage：Er Lv Evil bacterium azoles 8%, benzothiostrobin 24%, polyoxyethylene polyoxypropylene are embedding Section copolymer (dispersant) 5%, Teepol (wetting agent) 5%, isothiazolinone (preservative) 0.3%, silicone oil (defoaming Agent) 0.2%, xanthans (thickener) 1.5%, ethylene glycol (antifreezing agent) 3%, deionized water supplies 100%.Above-mentioned material is pressed Ratio mixes, after being uniformly dispersed through high speed shear, being sanded in sand mill, you can it is outstanding that 32% Er Lv Evil bacterium azoles benzothiostrobins are made Floating agent.
Embodiment 9：20% Er Lv Evil bacterium azoles phenylsulfonyl ester suspending agents
Following substance is weight percentage：Er Lv Evil bacterium azoles 10%, phenylsulfonyl ester 10%, sodium methylene bis-naphthalene sulfonate first Aldehyde condensate (dispersant) 6%, Teepol (wetting agent) 5%, Kathon CG Kathon (preservative) 0.5%, silicone oil (defoaming Agent) 0.2%, xanthans (thickener) 1.5%, ethylene glycol (antifreezing agent) 3%, deionized water supplies 100%.Above-mentioned material is pressed Ratio mixes, after being uniformly dispersed through high speed shear, being sanded in sand mill, you can it is outstanding that 20% Er Lv Evil bacterium azoles phenylsulfonyl esters are made Floating agent.
Embodiment 10：16% Er Lv Evil bacterium azoles fluoxastrobin suspending agents
Following substance is weight percentage：Er Lv Evil bacterium azoles 4%, fluoxastrobin 12%, sodium methylene bis-naphthalene sulfonate first Aldehyde condensate (dispersant) 6%, nonylphenol polyoxyethylene ether (wetting agent) 5%, Kathon CG Kathon (preservative) 0.5%, C10-20It is full With fatty acid compound (antifoaming agent) 0.1%, xanthans (thickener) 1.5%, ethylene glycol (antifreezing agent) 3%, deionized water Supply 100%.Above-mentioned material is mixed in proportion, be uniformly dispersed through high speed shear, in sand mill be sanded after, you can be made 16% Er Lv Evil bacterium azoles fluoxastrobin suspending agents.
Embodiment 11：26% Er Lv Evil bacterium azoles Fluoxastrobin suspending agents
Following substance is weight percentage：Er Lv Evil bacterium azoles 12%, Fluoxastrobin 14%, alkylnaphthalene sulfonate condensation polymer (dispersant) 8%, nonylphenol polyoxyethylene ether (wetting agent) 5%, Kathon CG Kathon (preservative) 0.5%, C10-20Saturated fatty acid Class compound (antifoaming agent) 0.1%, Arabic gum (thickener) 1.5%, polyethylene glycol (antifreezing agent) 2%, deionized water is supplied 100%.Above-mentioned material is mixed in proportion, be uniformly dispersed through high speed shear, in sand mill be sanded after, you can be made 26% dichloro Evil bacterium azoles Fluoxastrobin suspending agents.
Embodiment 12：20% Er Lv Evil bacterium azoles pyraclostrobin suspending agents
Following substance is weight percentage：Er Lv Evil bacterium azoles 18%, pyraclostrobin 2%, calcium lignosulfonate (dispersion Agent) 5%, nonylphenol polyoxyethylene ether (wetting agent) 5%, benzoic acid (preservative) 0.3%, C10-20Saturated fat acids compound (antifoaming agent) 0.1%, Arabic gum (thickener) 1.5%, polyethylene glycol (antifreezing agent) 2%, deionized water supplies 100%.It will Above-mentioned material mixes in proportion, be uniformly dispersed through high speed shear, in sand mill be sanded after, you can be made 20% Er Lv Evil bacterium azoles Pyraclostrobin suspending agent.
Embodiment 13：24% Er Lv Evil bacterium azoles trifloxystrobin suspending agents
Following substance is weight percentage：Er Lv Evil bacterium azoles 20%, trifloxystrobin 4%, calcium lignosulfonate (dispersant) 5%, sorbitan fatty acid ester polyoxyethylene ether (wetting agent) 6%, benzoic acid (preservative) 0.3%, C10-20Saturated fat Fat acid compounds (antifoaming agent) 0.1%, aluminium-magnesium silicate (thickener) 1.5%, sorbierite (antifreezing agent) 2%, deionized water are mended Foot 100%.Above-mentioned material is mixed in proportion, be uniformly dispersed through high speed shear, in sand mill be sanded after, you can be made 24% 2 Lv Evil bacterium azoles trifloxystrobin suspending agents.
Embodiment 14：27% Er Lv Evil bacterium azoles chlorfenapyr suspending agents
Following substance is weight percentage：Er Lv Evil bacterium azoles 20%, ZEN 90160 7%, calcium lignosulfonate (dispersion Agent) 5%, fatty alcohol polyoxyethylene ether (wetting agent) 5%, benzoic acid (preservative) 0.3%, silicone compound (antifoaming agent) 0.1%, aluminium-magnesium silicate (thickener) 1.5%, sorbierite (antifreezing agent) 2%, deionized water supplies 100%.Above-mentioned material is pressed Ratio mixes, after being uniformly dispersed through high speed shear, being sanded in sand mill, you can it is outstanding that 27% Er Lv Evil bacterium azoles ZEN 90160s are made Floating agent.
Embodiment 15：45% Er Lv Evil bacterium azoles benzothiostrobin aqueous emulsions
Following substance is weight percentage：Er Lv Evil bacterium azoles 40%, benzothiostrobin 5%, trimethylbenzene (solvent) 5%, carbon Dimethyl phthalate (solvent) 10%, peaceful newborn No. 33 (emulsifiers) 8%, epoxidized soybean oil (stabilizer) 3%, glycerine (antifreezing agent) 2%, C10-20Saturated fat acids compound (antifoaming agent) 0.3%, potassium sorbate (preservative) 0.3%, carboxyethyl cellulose (increase Thick dose) 1%, deionized water supplies 100%.Above-mentioned material is mixed in proportion, after high shear agitation is uniform, you can be made 45% Er Lv Evil bacterium azoles benzothiostrobin aqueous emulsions.
Embodiment 16：40% Er Lv Evil bacterium azoles phenylsulfonyl ester aqueous emulsions
Following substance is weight percentage：Er Lv Evil bacterium azoles 35%, phenylsulfonyl ester 5%, dimethylbenzene (solvent) 5%, carbon Dimethyl phthalate (solvent) 10%, aliphatic acid polyethenoxy ether (emulsifier) 7%, butylated hydroxy anisole (stabilizer) 2%, second two Alcohol (antifreezing agent) 2%, C10-20Saturated fat acids compound (antifoaming agent) 0.3%, potassium sorbate (preservative) 0.3%, carboxylic second Base cellulose (thickener) 1%, deionized water supplies 100%.Above-mentioned material is mixed in proportion, it is uniform through high shear agitation Afterwards, you can 40% Er Lv Evil bacterium azoles phenylsulfonyl ester aqueous emulsions are made.
Embodiment 17：42% Er Lv Evil bacterium azoles fluoxastrobin aqueous emulsions
Following substance is weight percentage：Er Lv Evil bacterium azoles 21%, fluoxastrobin 21%, cyclohexanone (solvent) 5%, carbon Dimethyl phthalate (solvent) 10%, aliphatic acid polyethenoxy ether (emulsifier) 7%, butylated hydroxy anisole (stabilizer) 2%, second two Alcohol (antifreezing agent) 2%, C10-20Saturated fat acids compound (antifoaming agent) 0.3%, potassium sorbate (preservative) 0.3%, poly- second Enol (thickener) 1.5%, deionized water supplies 100%.Above-mentioned material is mixed in proportion, it is uniform through high shear agitation Afterwards, you can 42% Er Lv Evil bacterium azoles fluoxastrobin aqueous emulsions are made.
Embodiment 18：33% Er Lv Evil bacterium azoles azoxystrobin water emulsions
Following substance is weight percentage：Er Lv Evil bacterium azoles 15%, Fluoxastrobin 18%, cyclohexanone (solvent) 5%, acetic acid Secondary butyl ester (solvent) 10%, Nongru-700 (emulsifier) 7%, butylated hydroxy anisole (stabilizer) 2%, ethylene glycol (antifreezing agent) 2%, C10-20Saturated fat acids compound (antifoaming agent) 0.3%, Kathon CG Kathon (preservative) 0.2%, polyvinyl alcohol (thickening Agent) 1.5%, deionized water supplies 100%.Above-mentioned material is mixed in proportion, after high shear agitation is uniform, you can be made 33% Er Lv Evil bacterium azoles azoxystrobin water emulsions.
Embodiment 19：38% Er Lv Evil bacterium azoles pyraclostrobin aqueous emulsions
Following substance is weight percentage：Er Lv Evil bacterium azoles 10%, pyraclostrobin 28%, cyclohexanone (solvent) 5%, Disalt base ester (solvent) 10%, Nongru-700 (emulsifier) 7%, epoxidized soybean oil (stabilizer) 2%, ethylene glycol (antifreezing agent) 2%, C10-20Saturated fat acids compound (antifoaming agent) 0.3%, Kathon CG Kathon (preservative) 0.2%, methylcellulose (thickening Agent) 1.5%, deionized water supplies 100%.Above-mentioned material is mixed in proportion, after high shear agitation is uniform, you can be made 38% Er Lv Evil bacterium azoles pyraclostrobin aqueous emulsions.
Embodiment 20：32% Er Lv Evil bacterium azoles trifloxystrobin water emulsions
Following substance is weight percentage：Er Lv Evil bacterium azoles 22%, trifloxystrobin 10%, cyclohexanone (solvent) 5%, oleic acid Methyl esters (solvent) 10%, fatty acid polyethylene glycol ester (emulsifier) 8%, epoxidized soybean oil (stabilizer) 2%, ethylene glycol are (antifreeze Agent) 2%, silicone compound (antifoaming agent) 0.2%, Kathon CG Kathon (preservative) 0.2%, methylcellulose (thickener) 1.5%, deionized water supplies 100%.Above-mentioned material is mixed in proportion, after high shear agitation is uniform, you can be made 32% Er Lv Evil bacterium azoles trifloxystrobin water emulsions.
Embodiment 21：48% Er Lv Evil bacterium azoles ZEN 90160 aqueous emulsions
Following substance is weight percentage：Er Lv Evil bacterium azoles 28%, ZEN 90160 20%, cyclohexanone (solvent) 5%, pine Base oil (solvent) 8%, fatty acid polyethylene glycol ester (emulsifier) 8%, pentaerythrite (stabilizer) 3%, ethylene glycol (antifreezing agent) 2%, silicone compound (antifoaming agent) 0.2%, Kathon CG Kathon (preservative) 0.2%, gelatin (thickener) 1%, deionized water Supply 100%.Above-mentioned material is mixed in proportion, after high shear agitation is uniform, you can 48% Er Lv Evil bacterium are made Azoles ZEN 90160 aqueous emulsion.
Embodiment 22：36% Er Lv Evil bacterium azoles benzothiostrobin microemulsions
Following substance is weight percentage：Er Lv Evil bacterium azoles 20%, benzothiostrobin 16%, cyclohexanone (solvent) 10%, Sec-Butyl Acetate (solvent) 5%, polyoxyethylene aliphatic alcohol ether (emulsifier) 10%, epoxidized linseed oil (stabilizer) 3%, Butacide (synergist) 2%, ethylene glycol (antifreezing agent) 2%, silicone oil (antifoaming agent) 0.3%, deionized water supply 100%.By above-mentioned material It mixes in proportion, after high shear agitation is uniform, you can 36% Er Lv Evil bacterium azoles benzothiostrobin microemulsions are made.
Embodiment 23：28% Er Lv Evil bacterium azoles phenylsulfonyl ester microemulsions
Following substance is weight percentage：Er Lv Evil bacterium azoles 11%, phenylsulfonyl ester 17%, trimethylbenzene (solvent) 10%, Sec-Butyl Acetate (solvent) 5%, polyoxyethylene aliphatic alcohol ether (emulsifier) 10%, resorcinol (stabilizer) 2.5%, Butacide (synergist) 2%, ethylene glycol (antifreezing agent) 2%, silicone oil (antifoaming agent) 0.3%, deionized water supply 100%.By above-mentioned material It mixes in proportion, after high shear agitation is uniform, you can 28% Er Lv Evil bacterium azoles phenylsulfonyl ester microemulsions are made.
Embodiment 24：39% Er Lv Evil bacterium azoles fluoxastrobin microemulsions
Following substance is weight percentage：Er Lv Evil bacterium azoles 5%, fluoxastrobin 34%, trimethylbenzene (solvent) 10%, carbon Dimethyl phthalate (solvent) 5%, peaceful newborn No. 31 (emulsifiers) 10%, resorcinol (stabilizer) 2.5%, Octacide 264 (synergist) 2%, ethylene glycol (antifreezing agent) 2%, silicone oil (antifoaming agent) 0.3%, deionized water supply 100%.Above-mentioned material is mixed in proportion It closes, after high shear agitation is uniform, you can 39% Er Lv Evil bacterium azoles fluoxastrobin microemulsions are made.
Embodiment 25：46% Er Lv Evil bacterium azoles azoxystrobin microemulsions
Following substance is weight percentage：Er Lv Evil bacterium azoles 23%, Fluoxastrobin 23%, methyl naphthalene (solvent) 10%, carbon Dimethyl phthalate (solvent) 5%, peaceful newborn No. 31 (emulsifiers) 10%, epoxychloropropane (stabilizer) 3%, Octacide 264 (synergist) 2%, ethylene glycol (antifreezing agent) 2%, silicone oil (antifoaming agent) 0.3%, deionized water supply 100%.Above-mentioned material is mixed in proportion It closes, after high shear agitation is uniform, you can 46% Er Lv Evil bacterium azoles azoxystrobin microemulsions are made.
Embodiment 26：42% Er Lv Evil bacterium azoles pyraclostrobin microemulsions
Following substance is weight percentage：Er Lv Evil bacterium azoles 40%, pyraclostrobin 2%, methyl naphthalene (solvent) 10%, Disalt base ester (solvent) 5%, agriculture breast 500 (emulsifier) 10%, epoxychloropropane (stabilizer) 3%, Octacide 264 (synergist) 2%, ethylene glycol (antifreezing agent) 2%, silicone oil (antifoaming agent) 0.3%, deionized water supply 100%.Above-mentioned material is mixed in proportion It closes, after high shear agitation is uniform, you can 42% Er Lv Evil bacterium azoles pyraclostrobin microemulsions are made.
Embodiment 27：35% Er Lv Evil bacterium azoles trifloxystrobin microemulsions
Following substance is weight percentage：Er Lv Evil bacterium azoles 13%, trifloxystrobin 22%, durene (solvent) 10%, two Salt base ester (solvent) 5%, APES sulfosuccinate (emulsifier) 8%, epoxychloropropane (stabilizer) 3%, polyether-modified trisiloxanes (synergist) 1.5%, ethylene glycol (antifreezing agent) 2%, silicone oil (antifoaming agent) 0.3%, deionization Water supplies 100%.Above-mentioned material is mixed in proportion, after high shear agitation is uniform, you can 35% Er Lv Evil bacterium are made Azoles trifloxystrobin microemulsion.
Embodiment 28：50% Er Lv Evil bacterium azoles ZEN 90160 microemulsions
Following substance is weight percentage：Er Lv Evil bacterium azoles 15%, ZEN 90160 35%, durene (solvent) 10%, Fatty acid methyl ester (solvent) 5%, APES sulfosuccinate (emulsifier) 8%, resorcinol (stabilizer) 3%, polyether-modified trisiloxanes (synergist) 1.5%, ethylene glycol (antifreezing agent) 2%, silicone oil (antifoaming agent) 0.3%, deionization Water supplies 100%.Above-mentioned material is mixed in proportion, after high shear agitation is uniform, you can 50% Er Lv Evil bacterium are made Azoles ZEN 90160 microemulsion.
Embodiment 29：60% Er Lv Evil bacterium azoles benzothiostrobin water dispersible granules
Following substance is weight percentage：Er Lv Evil bacterium azoles 15%, benzothiostrobin 45%, lauryl sodium sulfate are (wet Moisten agent) 6%, polyoxyethylene polyoxypropylene block copolymer (dispersant) 7%, low-substituted hydroxypropyl cellulose (disintegrant) 5%, Polyvinyl alcohol (binder) 0.5%, attapulgite (filler) supply 100%.Above-mentioned material is mixed in proportion, through air-flow powder Broken uniformly mixed, kneading is granulated, after dry screening, you can obtained 60% 2 chlorine Evil bacterium azoles benzothiostrobin water dispersible granules.
Embodiment 30：65% Er Lv Evil bacterium azoles phenylsulfonyl ester water dispersible granules
Following substance is weight percentage：Er Lv Evil bacterium azoles 19%, phenylsulfonyl ester 46%, lauryl sodium sulfate are (wet Moisten agent) 6%, alkylnaphthalene sulfonate condensation polymer (dispersant) 5%, ammonium sulfate (disintegrant) 3%, polyvinyl alcohol (binder) 0.5%, kaolin (filler) supplies 100%.Above-mentioned material is mixed in proportion, kneading granulation uniformly mixed through air-flow crushing, After dry screening, you can 65% 2 chlorine Evil bacterium azoles phenylsulfonyl ester water dispersible granules are made.
Embodiment 31：55% Er Lv Evil bacterium azoles fluoxastrobin water dispersible granules
Following substance is weight percentage：Er Lv Evil bacterium azoles 30%, fluoxastrobin 25%, Teepol (moistening Agent) 5%, sodium methylene bis-naphthalene sulfonate formaldehyde condensation products (dispersant) 8%, ammonium sulfate (disintegrant) 3%, hydroxyethyl cellulose (binder) 0.5%, kaolin (filler) supply 100%.Above-mentioned material is mixed in proportion, be uniformly mixed through air-flow crushing, It mediates and is granulated, after dry screening, you can 55% 2 chlorine Evil bacterium azoles fluoxastrobin water dispersible granules are made.
Embodiment 32：50% Er Lv Evil bacterium azoles azoxystrobin water dispersible granules
Following substance is weight percentage：Er Lv Evil bacterium azoles 30%, Fluoxastrobin 20%, Teepol (wetting agent) 5%, sodium methylene bis-naphthalene sulfonate formaldehyde condensation products (dispersant) 8%, urea (disintegrant) 3%, hydroxyethyl cellulose (bond Agent) 0.5%, diatomite (filler) supplies 100%.Above-mentioned material is mixed in proportion, is uniformly mixed through air-flow crushing, mediated and make After grain, dry screening, you can 50% 2 chlorine Evil bacterium azoles azoxystrobin water dispersible granules are made.
Embodiment 33：62% Er Lv Evil bacterium azoles pyraclostrobin water dispersible granules
Following substance is weight percentage：Er Lv Evil bacterium azoles 31%, pyraclostrobin 31%, alkylsulfonate (moistening Agent) 5%, calcium lignosulfonate (dispersant) 5%, urea (disintegrant) 3%, hydroxyethyl cellulose (binder) 0.5%, diatom Native (filler) supplies 100%.Above-mentioned material is mixed in proportion, is uniformly mixed through air-flow crushing, mediates granulation, dry screening Afterwards, you can 62% Er Lv Evil bacterium azoles pyraclostrobin water dispersible granules are made.
Embodiment 34：58% Er Lv Evil bacterium azoles trifloxystrobin water dispersible granules
Following substance is weight percentage：Er Lv Evil bacterium azoles 50%, trifloxystrobin 8%, alkylsulfonate (wetting agent) 5%, polyoxyethylene polyoxypropylene block copolymer (dispersant) 6%, urea (disintegrant) 3%, hydroxyethyl cellulose (bond Agent) 0.5%, sepiolite (filler) supplies 100%.Above-mentioned material is mixed in proportion, is uniformly mixed through air-flow crushing, mediated and make After grain, dry screening, you can 58% 2 chlorine Evil bacterium azoles trifloxystrobin water dispersible granules are made.
Embodiment 35：45% Er Lv Evil bacterium azoles water dispersible granules
Following substance is weight percentage：Er Lv Evil bacterium azoles 20%, ZEN 90160 25%, lauryl sodium sulfate are (wet Moisten agent) 5%, polyoxyethylene polyoxypropylene block copolymer (dispersant) 6%, sodium chloride (disintegrant) 3%, soluble starch (binder) 0.8%, sepiolite (filler) supply 100%.Above-mentioned material is mixed in proportion, be uniformly mixed through air-flow crushing, It mediates and is granulated, after dry screening, you can 45% 2 chlorine Evil bacterium azoles water dispersible granules are made.
Embodiment 36：68% Er Lv Evil bacterium azoles benzothiostrobin wettable powders
Following substance is weight percentage：Er Lv Evil bacterium azoles 10%, benzothiostrobin 58%, lauryl sodium sulfate are (wet Moisten agent) 10%, alkylnaphthalene sulfonate condensation polymer (dispersant) 5%, white carbon (filler) 5%, kaolin (filler) supplies 100%.Above-mentioned material is mixed in proportion, after mechanical crushing again through air-flow crushing, after mixing, you can be made 68% dichloro Evil bacterium azoles benzothiostrobin wettable powders.
Embodiment 37：70% Er Lv Evil bacterium azoles phenylsulfonyl ester wettable powders
Following substance is weight percentage：Er Lv Evil bacterium azoles 10%, phenylsulfonyl ester 60%, Teepol (moistening Agent) 10%, alkylnaphthalene sulfonate condensation polymer (dispersant) 5%, white carbon (filler) 5%, kaolin (filler) supplies 100%. Above-mentioned material is mixed in proportion, after mechanical crushing again through air-flow crushing, after mixing, you can be made 70% Er Lv Evil bacterium Azoles phenylsulfonyl ester wettable powder.
Embodiment 38：75% Er Lv Evil bacterium azoles fluoxastrobin wettable powders
Following substance is weight percentage：Er Lv Evil bacterium azoles 10%, fluoxastrobin 65%, Teepol (moistening Agent) 10%, di-2-ethylhexylphosphine oxide naphthalene sulfonate (dispersant) 5%, white carbon (filler) 5%, diatomite (filler) supplies 100%.It will Above-mentioned material mixes in proportion, after mechanical crushing again through air-flow crushing, after mixing, you can be made 75% Er Lv Evil bacterium azoles Fluoxastrobin wettable powder.
Embodiment 39：60% Er Lv Evil bacterium azoles Fluoxastrobin wettable powders
Following substance is weight percentage：Er Lv Evil bacterium azoles 55%, Fluoxastrobin 5%, naphthalene sulfonate (wetting agent) 10%, Di-2-ethylhexylphosphine oxide naphthalene sulfonate (dispersant) 5%, white carbon (filler) 5%, diatomite (filler) supply 100%.By above-mentioned material Mix in proportion, after mechanical crushing again through air-flow crushing, after mixing, you can be made 60% Er Lv Evil bacterium azoles Fluoxastrobins can Wet powder.
Embodiment 40：72% Er Lv Evil bacterium azoles pyraclostrobin wettable powders
Following substance is weight percentage：Er Lv Evil bacterium azoles 50%, pyraclostrobin 22%, naphthalene sulfonate (wetting agent) 10%, sodium tripolyphosphate (dispersant) 5%, white carbon (filler) 5%, bentonite (filler) supply 100%.Above-mentioned material is pressed Ratio mixes, after mechanical crushing again through air-flow crushing, after mixing, you can 72% Er Lv Evil bacterium azoles pyraclostrobins are made Wettable powder.
Embodiment 41：58% Er Lv Evil bacterium azoles trifloxystrobin wettable powders
Following substance is weight percentage：Er Lv Evil bacterium azoles 29%, trifloxystrobin 29%, nonylphenol polyoxyethylene ether are (wet Moisten agent) 8%, sodium tripolyphosphate (dispersant) 5%, white carbon (filler) 5%, bentonite (filler) supplies 100%.By above-mentioned object Material mix in proportion, after mechanical crushing again through air-flow crushing, after mixing, you can be made 58% Er Lv Evil bacterium azoles trifloxystrobins Wettable powder.
Embodiment 42：50% Er Lv Evil bacterium azoles chlorfenapyr wettable powders
Following substance is weight percentage：Er Lv Evil bacterium azoles 30%, ZEN 90160 20%, nonylphenol polyoxyethylene ether (wetting agent) 8%, sodium methylene bis-naphthalene sulfonate formaldehyde condensation products (dispersant) 6%, white carbon (filler) 5%, sepiolite (is filled out Material) supply 100%.Above-mentioned material is mixed in proportion, after mechanical crushing again through air-flow crushing, after mixing, you can be made 50% Er Lv Evil bacterium azoles chlorfenapyr wettable powders.
Embodiment 43：25% Er Lv Evil bacterium azoles benzothiostrobin ultra low volume liquids
Following substance is weight percentage：Er Lv Evil bacterium azoles 15%, benzothiostrobin 10%, cyclohexanone (solvent) 5%, N, N- dimethylacetylamides (solvent) 15%, castor oil polyoxyethylene ether (emulsifier) 5%, lauryl sodium sulfate (wetting agent) 5%, brassin lactones (poisoning palliative) 0.02%, alkyl benzyl dimethyl ammonium chloride (bleeding agent) 3%, rapeseed oil complements to 100%.Above-mentioned material is mixed in proportion, after being sufficiently stirred, you can 25% Er Lv Evil bacterium azoles benzothiostrobin super-low capacities are made Measure liquor.
Embodiment 44：20% Er Lv Evil bacterium azoles phenylsulfonyl ester ultra low volume liquids
Following substance is weight percentage：Er Lv Evil bacterium azoles 19%, phenylsulfonyl ester 1%, cyclohexanone (solvent) 5%, N, N- dimethylacetylamides (solvent) 15%, aliphatic acid polyethenoxy ether (emulsifier) 5%, lauryl sodium sulfate (wetting agent) 5%, brassin lactones (poisoning palliative) 0.02%, azone (bleeding agent) 2%, rapeseed oil complements to 100%.By above-mentioned material It mixes in proportion, after being sufficiently stirred, you can 20% Er Lv Evil bacterium azoles phenylsulfonyl ester ultra low volume liquids are made.
Embodiment 45：25% Er Lv Evil bacterium azoles fluoxastrobin ultra low volume liquids
Following substance is weight percentage：Er Lv Evil bacterium azoles 10%, fluoxastrobin 15%, cyclohexanone (solvent) 5%, N- Methyl pyrrolidone (solvent) 15%, castor oil polyoxyethylene ether (emulsifier) 5%, lauryl sodium sulfate (wetting agent) 5%, Brassin lactones (poisoning palliative) 0.02%, azone (bleeding agent) 2%, soybean oil complements to 100%.By above-mentioned material press than Example mixing, after being sufficiently stirred, you can 25% Er Lv Evil bacterium azoles fluoxastrobin ultra low volume liquids are made.
Embodiment 46：18% Er Lv Evil bacterium azoles Fluoxastrobin ultra low volume liquids
Following substance is weight percentage：Er Lv Evil bacterium azoles 2%, Fluoxastrobin 16%, cyclohexanone (solvent) 5%, N- first It is base pyrrolidones (solvent) 15%, polyoxyethylene aliphatic alcohol ether (emulsifier) 5%, lauryl sodium sulfate (wetting agent) 5%, red Mould acid (poisoning palliative) 0.03%, alky pyridinium halides (bleeding agent) 3%, soybean oil complements to 100%.By above-mentioned material It mixes in proportion, after being sufficiently stirred, you can 18% Er Lv Evil bacterium azoles Fluoxastrobin ultra low volume liquids are made.
Embodiment 47：35% Er Lv Evil bacterium azoles pyraclostrobin ultra low volume liquids
Following substance is weight percentage：Er Lv Evil bacterium azoles 15%, pyraclostrobin 20%, trimethylbenzene (solvent) 8%, It is N-Methyl pyrrolidone (solvent) 15%, polyoxyethylene aliphatic alcohol ether (emulsifier) 5%, naphthalene sulfonate (wetting agent) 5%, red mould Sour (poisoning palliative) 0.03%, alky pyridinium halides (bleeding agent) 3%, methyl oleate complements to 100%.By above-mentioned material It mixes in proportion, after being sufficiently stirred, you can 35% Er Lv Evil bacterium azoles pyraclostrobin ultra low volume liquids are made.
Embodiment 48：7% Er Lv Evil bacterium azoles trifloxystrobin ultra low volume liquids
Following substance is weight percentage：Er Lv Evil bacterium azoles 5%, trifloxystrobin 2%, trimethylbenzene (solvent) 8%, N- methyl Pyrrolidones (solvent) 15%, ethoxy castor oil (emulsifier) 5%, naphthalene sulfonate (wetting agent) 5%, (poisoning subtracts gibberellic acid Light diaphoretic prescription) 0.03%, ester sodium sulfonate (bleeding agent) 2%, methyl oleate complements to 100%.Above-mentioned material is mixed in proportion, fully After stirring, you can 7% Er Lv Evil bacterium azoles trifloxystrobin ultra low volume liquids are made.
Embodiment 49：12% Er Lv Evil bacterium azoles ZEN 90160 ultra low volume liquids
Following substance is weight percentage：Er Lv Evil bacterium azoles 3%, ZEN 90160 9%, dimethylbenzene (solvent) 8%, N- first Base pyrrolidones (solvent) 15%, ethoxy castor oil (emulsifier) 5%, naphthalene sulfonate (wetting agent) 5%, compound sodium nitrophenolate (medicine Evil palliative) 0.03%, ester sodium sulfonate (bleeding agent) 2%, biodiesel complements to 100%.Above-mentioned material is mixed in proportion, After being sufficiently stirred, you can 12% Er Lv Evil bacterium azoles ZEN 90160 ultra low volume liquids are made.
(2) indoor biological determination of activity embodiment
1, Er Lv Evil bacterium azoles and benzothiostrobin compound the indoor toxicity determination test to late blight of potato pathogen
Test method：With reference to《Farm-chemical indoor determination test rule NY/T1156.13-2008》, using blade method.
It is for statistical analysis with DPS statistical analysis softwares, calculate the EC of each medicament50, and mixture is calculated according to Sun Yunpei's Method Co-toxicity coefficient (CTC values), co-toxicity coefficient (CTC) >=120 shows as synergistic effect；Co-toxicity coefficient (CTC)≤80 shows as short of money Anti- effect；80 ＜ co-toxicity coefficients (CTC) ＜ 120 show as summation action.
1 Er Lv Evil bacterium azoles of table and benzothiostrobin compound the Toxicity Determination to late blight of potato pathogen
As it can be seen from table 1 Er Lv Evil bacterium azoles and benzothiostrobin are 20:1~1:When being compounded in the range of 20 (by weight), Co-toxicity coefficient (CTC) is all higher than 120, and synergistic function is shown to late blight of potato pathogen.Inventor is further Carry out experiment find, Er Lv Evil bacterium azoles respectively with phenylsulfonyl ester, fluoxastrobin, Fluoxastrobin, pyraclostrobin, trifloxystrobin, pyridine oxygen Bacterium ester is 20:1~1:When being compounded in the range of 20 (by weight), collaboration is equally shown to late blight of potato pathogen and is increased Effect acts on, and co-toxicity coefficient (CTC) is all higher than 120.
2, Er Lv Evil bacterium azoles and phenylsulfonyl ester compound the indoor toxicity determination test to powdery mildew of strawberry pathogen
Test method：With reference to《Farm-chemical indoor determination test rule NY/T1156.11-2008》, using pot-culture method.
It is for statistical analysis with DPS statistical analysis softwares, calculate the EC of each medicament50, and mixture is calculated according to Sun Yunpei's Method Co-toxicity coefficient (CTC values), co-toxicity coefficient (CTC) >=120 shows as synergistic effect；Co-toxicity coefficient (CTC)≤80 shows as short of money Anti- effect；80 ＜ co-toxicity coefficients (CTC) ＜ 120 show as summation action.
2 Er Lv Evil bacterium azoles of table and phenylsulfonyl ester compound the Toxicity Determination to powdery mildew of strawberry pathogen
From table 2 it can be seen that Er Lv Evil bacterium azoles and phenylsulfonyl ester are 20:1~1:When being compounded in the range of 20 (by weight), Co-toxicity coefficient (CTC) is all higher than 120, and synergistic function is shown to powdery mildew of strawberry pathogen.Inventor further opens Exhibition experiment find, Er Lv Evil bacterium azoles respectively with benzothiostrobin, fluoxastrobin, Fluoxastrobin, pyraclostrobin, trifloxystrobin, pyridine oxygen bacterium Ester is 20:1~1:When being compounded in the range of 20 (by weight), synergistic work is equally shown to powdery mildew of strawberry pathogen With co-toxicity coefficient (CTC) is all higher than 120.
3, Er Lv Evil bacterium azoles and fluoxastrobin compound the indoor toxicity determination test to cucumber downy mildew pathogen
Test method：With reference to《Farm-chemical indoor determination test rule NY/T1156.3-2006》, using plate blade Method.
It is for statistical analysis with DPS statistical analysis softwares, calculate the EC of each medicament50, and mixture is calculated according to Sun Yunpei's Method Co-toxicity coefficient (CTC values), co-toxicity coefficient (CTC) >=120 shows as synergistic effect；Co-toxicity coefficient (CTC)≤80 shows as short of money Anti- effect；80 ＜ co-toxicity coefficients (CTC) ＜ 120 show as summation action.
3 Er Lv Evil bacterium azoles of table and fluoxastrobin compound the Toxicity Determination to cucumber downy mildew pathogen
From table 3 it can be seen that Er Lv Evil bacterium azoles and fluoxastrobin are 20:1~1:When being compounded in the range of 20 (by weight), Co-toxicity coefficient (CTC) is all higher than 120, and synergistic function is shown to cucumber downy mildew pathogen.Inventor further opens Exhibition experiment find, Er Lv Evil bacterium azoles respectively with benzothiostrobin, phenylsulfonyl ester, Fluoxastrobin, pyraclostrobin, trifloxystrobin, pyridine oxygen bacterium Ester is 20:1~1:When being compounded in the range of 20 (by weight), synergistic work is equally shown to cucumber downy mildew pathogen With co-toxicity coefficient (CTC) is all higher than 120.
4, the indoor toxicity determination test of Er Lv Evil bacterium azoles and azoxystrobin compound to rice sheath blight disease pathogen
Test method：With reference to《Farm-chemical indoor determination test rule NY/T1156.5-2006》, using Broad Bean Leaves Method.
It is for statistical analysis with DPS statistical analysis softwares, calculate the EC of each medicament50, and mixture is calculated according to Sun Yunpei's Method Co-toxicity coefficient (CTC values), co-toxicity coefficient (CTC) >=120 shows as synergistic effect；Co-toxicity coefficient (CTC)≤80 shows as short of money Anti- effect；80 ＜ co-toxicity coefficients (CTC) ＜ 120 show as summation action.
The Toxicity Determination of 4 Er Lv Evil bacterium azoles of table and azoxystrobin compound to rice sheath blight disease pathogen
From table 4, it can be seen that Er Lv Evil bacterium azoles and Fluoxastrobin are 20:1~1:When being compounded in the range of 20 (by weight), altogether Malicious coefficient (CTC) is all higher than 120, and synergistic function is shown to rice sheath blight disease pathogen.Inventor further carries out Experiment find, Er Lv Evil bacterium azoles respectively with benzothiostrobin, phenylsulfonyl ester, fluoxastrobin, pyraclostrobin, trifloxystrobin, pyridine oxygen bacterium Ester is 20:1~1:When being compounded in the range of 20 (by weight), synergistic work is equally shown to rice sheath blight disease pathogen With co-toxicity coefficient (CTC) is all higher than 120.
5, Er Lv Evil bacterium azoles and pyraclostrobin compound the indoor toxicity determination test to Pathogen of Botrytis cinerea on Grape bacterium
Test method：With reference to《Farm-chemical indoor determination test rule NY/T1156.10-2008》, using pot-culture method.
It is for statistical analysis with DPS statistical analysis softwares, calculate the EC of each medicament50, and mixture is calculated according to Sun Yunpei's Method Co-toxicity coefficient (CTC values), co-toxicity coefficient (CTC) >=120 shows as synergistic effect；Co-toxicity coefficient (CTC)≤80 shows as short of money Anti- effect；80 ＜ co-toxicity coefficients (CTC) ＜ 120 show as summation action.
5 Er Lv Evil bacterium azoles of table and pyraclostrobin compound the Toxicity Determination to Pathogen of Botrytis cinerea on Grape bacterium
As can be seen from Table 5, Er Lv Evil bacterium azoles and pyraclostrobin are 20:1~1:It is compounded in the range of 20 (by weight) When, co-toxicity coefficient (CTC) is all higher than 120, and synergistic function is shown to Pathogen of Botrytis cinerea on Grape bacterium.Inventor is further Carry out experiment find, Er Lv Evil bacterium azoles respectively with benzothiostrobin, phenylsulfonyl ester, fluoxastrobin, Fluoxastrobin, trifloxystrobin, pyridine oxygen bacterium Ester is 20:1~1:When being compounded in the range of 20 (by weight), synergistic work is equally shown to Pathogen of Botrytis cinerea on Grape bacterium With co-toxicity coefficient (CTC) is all higher than 120.
6, Er Lv Evil bacterium azoles and trifloxystrobin compound the indoor toxicity determination test to apple marssonina leaf spot pathogen
Test method：With reference to《Farm-chemical indoor determination test rule NY/T1156.2-2006》, using Plating.
It is for statistical analysis with DPS statistical analysis softwares, calculate the EC of each medicament50, and mixture is calculated according to Sun Yunpei's Method Co-toxicity coefficient (CTC values), co-toxicity coefficient (CTC) >=120 shows as synergistic effect；Co-toxicity coefficient (CTC)≤80 shows as short of money Anti- effect；80 ＜ co-toxicity coefficients (CTC) ＜ 120 show as summation action.
6 Er Lv Evil bacterium azoles of table and trifloxystrobin compound the Toxicity Determination to apple marssonina leaf spot pathogen
As can be seen from Table 6, Er Lv Evil bacterium azoles and trifloxystrobin are 20:1~1:When being compounded in the range of 20 (by weight), altogether Malicious coefficient (CTC) is all higher than 120, and synergistic function is shown to apple marssonina leaf spot pathogen.Inventor further carries out Experiment find, Er Lv Evil bacterium azoles respectively with benzothiostrobin, phenylsulfonyl ester, fluoxastrobin, Fluoxastrobin, pyraclostrobin, pyridine oxygen bacterium Ester is 20:1~1:When being compounded in the range of 20 (by weight), synergistic work is equally shown to apple marssonina leaf spot pathogen With co-toxicity coefficient (CTC) is all higher than 120.
7, Er Lv Evil bacterium azoles and ZEN 90160 compound the indoor toxicity determination test to watermelon anthrax pathogen
Test method：With reference to《Farm-chemical indoor determination test rule NY/T1156.14-2008》, using pot-culture method.
It is for statistical analysis with DPS statistical analysis softwares, calculate the EC of each medicament50, and mixture is calculated according to Sun Yunpei's Method Co-toxicity coefficient (CTC values), co-toxicity coefficient (CTC) >=120 shows as synergistic effect；Co-toxicity coefficient (CTC)≤80 shows as short of money Anti- effect；80 ＜ co-toxicity coefficients (CTC) ＜ 120 show as summation action.
7 Er Lv Evil bacterium azoles of table and ZEN 90160 compound the Toxicity Determination to watermelon anthrax pathogen
As can be seen from Table 7, Er Lv Evil bacterium azoles and ZEN 90160 are 20:1~1:When being compounded in the range of 20 (by weight), Co-toxicity coefficient (CTC) is all higher than 120, and synergistic function is shown to watermelon anthrax pathogen.Inventor further opens Exhibition experiment find, Er Lv Evil bacterium azoles respectively with benzothiostrobin, phenylsulfonyl ester, fluoxastrobin, Fluoxastrobin, pyraclostrobin, oxime bacterium Ester is 20:1~1:When being compounded in the range of 20 (by weight), synergistic work is equally shown to watermelon anthrax pathogen With co-toxicity coefficient (CTC) is all higher than 120.
(3) field control effectiveness test embodiment
1, the field control effectiveness test of Er Lv Evil bacterium azoles and benzothiostrobin complex composition preparation to different diseases
In the late blight of potato, powdery mildew of strawberry, cucumber downy mildew, rice sheath blight disease, grape grey mould, brown spot of apple Disease, watermelon anthrax early stage dispenser, per 7d dispensers 1 time, dispenser 2 times altogether.State of an illness radix, the 2nd dispenser are investigated before dispenser A situation arises for 14d investigation disease afterwards, counts disease index, calculates preventive effect.
The field control effectiveness test of 8 Er Lv Evil bacterium azoles of table and benzothiostrobin complex composition preparation to different diseases
As can be seen from Table 8, each Er Lv Evil bacterium azoles and benzothiostrobin complex composition preparation are to the late blight of potato, grass The diseases such as certain kind of berries powdery mildew, cucumber downy mildew, rice sheath blight disease, grape grey mould, apple marssonina leaf spot, watermelon anthrax show good Good control effect, preventive effect is 80% or more, hence it is evident that it is used alone higher than each single dose, obvious synergy, while Do not find each Er Lv Evil bacterium azoles and benzothiostrobin complex composition preparation to potato, strawberry, cucumber, water during pilot survey The crops such as rice, grape, apple, watermelon generate poisoning.
2, the field control effectiveness test of Er Lv Evil bacterium azoles and phenylsulfonyl ester complex composition preparation to different diseases
In the late blight of potato, powdery mildew of strawberry, cucumber downy mildew, rice sheath blight disease, grape grey mould, brown spot of apple Disease, watermelon anthrax early stage dispenser, per 7d dispensers 1 time, dispenser 2 times altogether.State of an illness radix, the 2nd dispenser are investigated before dispenser A situation arises for 14d investigation disease afterwards, counts disease index, calculates preventive effect.
The field control effectiveness test of 9 Er Lv Evil bacterium azoles of table and phenylsulfonyl ester complex composition preparation to different diseases
As can be seen from Table 9, each Er Lv Evil bacterium azoles and phenylsulfonyl ester complex composition preparation are to the late blight of potato, grass The diseases such as certain kind of berries powdery mildew, cucumber downy mildew, rice sheath blight disease, grape grey mould, apple marssonina leaf spot, watermelon anthrax show good Good control effect, preventive effect is 80% or more, hence it is evident that is used alone higher than each single dose, synergistic effect is notable, while testing Do not found in fact-finding process each Er Lv Evil bacterium azoles and phenylsulfonyl ester complex composition preparation to potato, strawberry, cucumber, rice, The crops such as grape, apple, watermelon generate poisoning.
3, the field control effectiveness test of Er Lv Evil bacterium azoles and fluoxastrobin complex composition preparation to different diseases
In the late blight of potato, powdery mildew of strawberry, cucumber downy mildew, rice sheath blight disease, grape grey mould, brown spot of apple Disease, watermelon anthrax early stage dispenser, per 7d dispensers 1 time, dispenser 2 times altogether.State of an illness radix, the 2nd dispenser are investigated before dispenser A situation arises for 14d investigation disease afterwards, counts disease index, calculates preventive effect.
The field control effectiveness test of 10 Er Lv Evil bacterium azoles of table and fluoxastrobin complex composition preparation to different diseases
As can be seen from Table 10, each Er Lv Evil bacterium azoles and fluoxastrobin complex composition preparation to the late blight of potato, The diseases such as powdery mildew of strawberry, cucumber downy mildew, rice sheath blight disease, grape grey mould, apple marssonina leaf spot, watermelon anthrax are shown Good control effect, preventive effect is 80% or more, hence it is evident that is used alone higher than each single dose, synergistic effect is notable, while trying It tests in fact-finding process and does not find each Er Lv Evil bacterium azoles and fluoxastrobin complex composition preparation to potato, strawberry, cucumber, water The crops such as rice, grape, apple, watermelon generate poisoning.
4, the field control effectiveness test of Er Lv Evil bacterium azoles and azoxystrobin compound composite preparation to different diseases
In the late blight of potato, powdery mildew of strawberry, cucumber downy mildew, rice sheath blight disease, grape grey mould, brown spot of apple Disease, watermelon anthrax early stage dispenser, per 7d dispensers 1 time, dispenser 2 times altogether.State of an illness radix, the 2nd dispenser are investigated before dispenser A situation arises for 14d investigation disease afterwards, counts disease index, calculates preventive effect.
The field control effectiveness test of 11 Er Lv Evil bacterium azoles of table and azoxystrobin compound composite preparation to different diseases
As can be seen from Table 11, each Er Lv Evil bacterium azoles and azoxystrobin compound composite preparation are to the late blight of potato, grass The diseases such as certain kind of berries powdery mildew, cucumber downy mildew, rice sheath blight disease, grape grey mould, apple marssonina leaf spot, watermelon anthrax show good Good control effect, preventive effect is 80% or more, hence it is evident that is used alone higher than each single dose, synergistic effect is notable, while testing Do not find each Er Lv Evil bacterium azoles and azoxystrobin compound composite preparation to potato, strawberry, cucumber, rice, Portugal in fact-finding process The crops such as grape, apple, watermelon generate poisoning.
5, the field control effectiveness test of Er Lv Evil bacterium azoles and pyraclostrobin complex composition preparation to different diseases
In the late blight of potato, powdery mildew of strawberry, cucumber downy mildew, rice sheath blight disease, grape grey mould, brown spot of apple Disease, watermelon anthrax early stage dispenser, per 7d dispensers 1 time, dispenser 2 times altogether.State of an illness radix, the 2nd dispenser are investigated before dispenser A situation arises for 14d investigation disease afterwards, counts disease index, calculates preventive effect.
The field control effectiveness test of 12 Er Lv Evil bacterium azoles of table and pyraclostrobin complex composition preparation to different diseases
As can be seen from Table 12, each Er Lv Evil bacterium azoles and pyraclostrobin complex composition preparation are to potato late blight The diseases table such as disease, powdery mildew of strawberry, cucumber downy mildew, rice sheath blight disease, grape grey mould, apple marssonina leaf spot, watermelon anthrax Reveal good control effect, preventive effect is 80% or more, hence it is evident that be used alone higher than each single dose, synergistic effect is notable, simultaneously Do not find each Er Lv Evil bacterium azoles and pyraclostrobin complex composition preparation to potato, strawberry, Huang during pilot survey The crops such as melon, rice, grape, apple, watermelon generate poisoning.
6, the field control effectiveness test of Er Lv Evil bacterium azoles and trifloxystrobin complex composition preparation to different diseases
In the late blight of potato, powdery mildew of strawberry, cucumber downy mildew, rice sheath blight disease, grape grey mould, brown spot of apple Disease, watermelon anthrax early stage dispenser, per 7d dispensers 1 time, dispenser 2 times altogether.State of an illness radix, the 2nd dispenser are investigated before dispenser A situation arises for 14d investigation disease afterwards, counts disease index, calculates preventive effect.
The field control effectiveness test of 13 Er Lv Evil bacterium azoles of table and trifloxystrobin complex composition preparation to different diseases
As can be seen from Table 13, each Er Lv Evil bacterium azoles and trifloxystrobin complex composition preparation are to the late blight of potato, grass The diseases such as certain kind of berries powdery mildew, cucumber downy mildew, rice sheath blight disease, grape grey mould, apple marssonina leaf spot, watermelon anthrax show good Good control effect, preventive effect is 80% or more, hence it is evident that is used alone higher than each single dose, synergistic effect is notable, while testing Do not find each Er Lv Evil bacterium azoles and trifloxystrobin complex composition preparation to potato, strawberry, cucumber, rice, Portugal in fact-finding process The crops such as grape, apple, watermelon generate poisoning.
7, the field control effectiveness test of Er Lv Evil bacterium azoles and ZEN 90160 complex composition preparation to different diseases
In the late blight of potato, powdery mildew of strawberry, cucumber downy mildew, rice sheath blight disease, grape grey mould, brown spot of apple Disease, watermelon anthrax early stage dispenser, per 7d dispensers 1 time, dispenser 2 times altogether.State of an illness radix, the 2nd dispenser are investigated before dispenser A situation arises for 14d investigation disease afterwards, counts disease index, calculates preventive effect.
The field control effectiveness test of 14 Er Lv Evil bacterium azoles of table and ZEN 90160 complex composition preparation to different diseases
As can be seen from Table 14, each Er Lv Evil bacterium azoles and ZEN 90160 complex composition preparation to the late blight of potato, The diseases such as powdery mildew of strawberry, cucumber downy mildew, rice sheath blight disease, grape grey mould, apple marssonina leaf spot, watermelon anthrax are shown Good control effect, preventive effect is 80% or more, hence it is evident that is used alone higher than each single dose, synergistic effect is notable, while trying It tests in fact-finding process and does not find each Er Lv Evil bacterium azoles and ZEN 90160 complex composition preparation to potato, strawberry, cucumber, water The crops such as rice, grape, apple, watermelon generate poisoning.
In conclusion a kind of sterilization containing Er Lv Evil bacterium azoles and methoxy acrylic bactericide of the present invention Composition, obvious synergy expand fungicidal spectrum compared to the exclusive use of each single dose, improve preventive effect, can effectively prevent Multiple diseases on crops, the lasting period is long, to Crop securify, is worth promoting and applying in agricultural production.

Claims (5)

1. a kind of bactericidal composition containing Er Lv Evil bacterium azoles and methoxy acrylic bactericide, it is characterised in that：By One active constituent, two chlorine Evil bacterium azoles and the second active constituent methoxy acrylic bactericide and auxiliary agent composition, methoxyl group propylene Bactericide of phosphate (phosphinium) ester is selected from benzothiostrobin, phenylsulfonyl ester, fluoxastrobin, Fluoxastrobin, pyraclostrobin, trifloxystrobin or ZEN 90160 In one kind, the weight ratio of Er Lv Evil bacterium azoles and methoxy acrylic bactericide is 20:1~1:20.
2. a kind of Bactericidal composite containing Er Lv Evil bacterium azoles and methoxy acrylic bactericide according to claim 1 Object, it is characterised in that：The weight ratio of Er Lv Evil bacterium azoles and methoxy acrylic bactericide is 15:1~1:15.
3. a kind of Bactericidal composite containing Er Lv Evil bacterium azoles and methoxy acrylic bactericide according to claim 1 Object, it is characterised in that：The weight ratio of Er Lv Evil bacterium azoles and methoxy acrylic bactericide is 7:1~1:7.
4. a kind of Bactericidal composite containing Er Lv Evil bacterium azoles and methoxy acrylic bactericide according to claim 1 Object, it is characterised in that：The dosage form of the bactericidal composition is microcapsule suspending agent, suspending agent, aqueous emulsion, microemulsion, water-dispersible grain Agent, wettable powder, ultra low volume liquids.
5. it is described in claim 1 it is a kind of contain the bactericidal composition of Er Lv Evil bacterium azoles and methoxy acrylic bactericide use Purposes in late blight, powdery mildew, downy mildew, banded sclerotial blight, gray mold, brown spot, anthracnose on prevention crops.
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CN106359420A (en) * 2016-08-31 2017-02-01 柳州市惠农化工有限公司 Pesiticidal composition comprising dichloro oxadiazole and pyraclostrobin
CN106538574A (en) * 2016-11-26 2017-03-29 佛山市普尔玛农化有限公司 A kind of composition pesticide of the Evil bacterium azoles of Lv containing Er and pyraclostrobin
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CN109717195A (en) * 2017-10-30 2019-05-07 佛山市盈辉作物科学有限公司 A kind of bactericidal composition for disliking bacterium azoles and zoxamide containing dichloro
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