CN106614656A - Pesticide composition containing dichlorooxazole and ametoctradin - Google Patents
Pesticide composition containing dichlorooxazole and ametoctradin Download PDFInfo
- Publication number
- CN106614656A CN106614656A CN201611171188.1A CN201611171188A CN106614656A CN 106614656 A CN106614656 A CN 106614656A CN 201611171188 A CN201611171188 A CN 201611171188A CN 106614656 A CN106614656 A CN 106614656A
- Authority
- CN
- China
- Prior art keywords
- azoles
- pesticide
- synergistic composition
- composition according
- evil bacterium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/82—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with three ring hetero atoms
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a bactericidal composition containing dichlorooxazole and ametoctradin. The bactericidal composition has an obvious synergistic effect on a plurality of types of crop diseases in a range from (1 to 30) to (30 to 1). The pesticide composition disclosed by the invention is especially suitable for prevention and treatment of potato late blight and cucumber downy mildew; the use amount of active components of pesticides can be reduced, the pesticide cost is reduced, and the prevention and treatment effects are improved; and the pesticide composition disclosed by the invention is safe to crops and is worthy of being popularized and applied in production.
Description
Technical field
The invention belongs to technical field of pesticide combination, and in particular to be a kind of containing Er Lv Evil bacterium azoles and azoles mepanipyrim
Composition pesticide and its for epidemic disease, the application of downy mildew.
Background technology
The late blight of potato is a kind of destructive disease in Rhizoma Solani tuber osi production, and the whole world generally occurs, typically results in
Rhizoma Solani tuber osi underproduction 20-80%, severe one can have no harvest.The eighties in 20th century, late blight starts frequently to occur all over the world, 20th century
After the nineties, late blight generally occurs in China Rhizoma Solani tuber osi main producing region, endangers in rising trend.The late blight of potato is made to production
Into massive losses cause the very big concern of international community, International Potato Center was classified as the late blight of potato in 1992
CIP priority research targets, and found a state border Research of Potato Late Blight coorporative network in 1996 year's harvest, to Rhizoma Solani tuber osi evening can be reduced
The loss that epidemic disease is brought.
Cucumber downy mildew is the infectivity aeroborne disease caused by Cuba artificial downy mildew, and to cucumber production huge prestige is brought
The side of body, the main method for preventing and treating cucumber downy mildew is chemical pesticide.Either downy mildew or late blight, exist in chemical prevention
Drug resistance and to people, the problem of environmental pollution.
In the real process of agricultural production, it is to delay pathogen Drug resistance to produce that different pesticide activity components carry out compounding
Very common method.Different pesticide activity components are compounded to judge that certain compounding is potentiation, adds and or antagonism work
With.In most cases, the compounding effect of pesticide is all additive effect, and the compounding of real potentiation is little, in fact later
The compounding that potentiation is apparent, synergy ratio is very high is just less.
Er Lv Evil bacterium azoles is the Yi Zhong oxazole sulfone series bactericidal agents found by Guizhou University.Sulfone compound is because with wide spectrum life
Thing activity and cause concern of the people to it, especially sulfone group is incorporated in a variety of compound structures, by knot
Structure modification can produce a series of compounds with broad-spectrum biological activity so that it has given play in novel super-high effect pesticides discovery
More and more important effect.
Azoles mepanipyrim is triazolo pyrimidine series bactericidal agent, is systemic fungicide, with excellent protection, therapeutic activity, is held
Effect activity and resistance of rainwater washing against activity, to have suppress well and make to Oomycete pathogens such as downy mildew, pythiaceae, white phytophthora sections
With, it is adaptable to prevent and treat downy mildew, the epidemic disease of the crops such as melon, solanaceous vegetables, Fructus Vitis viniferae.
Present inventor has found through substantial amounts of indoor virulence test and field control effectiveness test, by Er Lv Evil bacterium azoles and
After azoles mepanipyrim is mutually compounded, there is good potentiation to the preventing and treating of various crop disease in certain scope, pass through
Further research completes the present invention.At present, there is no the relevant report with regard to Er Lv Evil bacterium azoles and azoles mepanipyrim compounding.
The content of the invention
Present invention aims to the deficiencies in the prior art, there is provided one kind has obvious synergistic function, preventing and treating
Effect is good, the composition pesticide that dosage is reduced.
Another object of the present invention is to provide the offer composition pesticide to be used to prevent and treat multiple kinds of crops disease,
In particular for preventing and treating downy mildew, the epidemic disease of the crops such as Rhizoma Solani tuber osi, melon, solanaceous vegetables, Fructus Vitis viniferae.
Further, composition pesticide of the invention is particularly suited for preventing and treating the late blight of potato, cucumber downy mildew.
To reach above-mentioned purpose, the present invention is adopted the following technical scheme that：
A kind of composition pesticide, it is characterised in that active component includes Er Lv Evil bacterium azoles and azoles mepanipyrim, wherein, Er Lv Evil bacterium
The weight ratio of azoles and azoles mepanipyrim is 1:30-30:1.
Further, the weight ratio preferably 1 of Er Lv Evil bacterium azoles and azoles mepanipyrim:15-10:1.
Further, in the composition pesticide active component weight percentage be 1-80%, preferably 10-60%,
Remaining is auxiliary agent and/or carrier conventional in pesticidal preparations.According to different type of dosage form and controlling object, active component contains
Amount is different.
Further, the conventional active ingredients during composition pesticide of the invention is by being aided with Pesticide formulation are prepared into
Any one dosage form, for example can be cream, water dispersible granules, wettable powder, suspending agent, microemulsion, aqueous emulsion, microcapsule hang
In floating agent any one.
Further, the method for application of the Pesticidal combination flexibly, both can be poured and be dripped with foliar spray with soil
Fill, it can also be used to seed treatment.
Further, Pesticidal combination of the invention such as insecticide, attractant, can kill line with other active component
Worm agent, antifungal, plant growth regulator, herbicide, fertilizer etc. are used in mixed way.
Compared with prior art, of the invention composition pesticide has the beneficial effect that：
（1）Between the composition pesticide active component Er Lv Evil bacterium azoles and azoles mepanipyrim of the present invention in certain proportion
Compounding has obvious potentiation, can reduce the usage amount of pesticide activity component, reduces production cost and use cost；
（2）The active component mechanism of action is different in the composition pesticide of the present invention, can overcome and/or delay pathogen
Drug-fast generation, can be with diseases such as the various epidemic diseases of effectively preventing, downy mildew；
（3）The composition pesticide preparation process is simple of the present invention, to crop safety.
Specific embodiment
In order that the objects, technical solutions and advantages of the present invention become more apparent, present invention specific examples below
Illustrate, but the present invention is limited to absolutely not these examples.Described below is only the present invention preferably embodiment, is used only for explaining
The present invention, but can not be therefore understands that being the restriction to the scope of the claims of the present invention.It should be pointed out that it is all the present invention spirit and
Any modification, equivalent or improvement for being made within principle etc., should be included within the scope of the present invention, therefore,
The protection domain of patent of the present invention should be defined by claims.
First, example of formulations
1st, embodiment 1:31% Er Lv Evil bacterium azoles azoles mepanipyrim wettable powders（1:30）
Er Lv Evil bacterium azoles 1%
Azoles mepanipyrim 30%
Sodium lignin sulfonate 4%
Sodium lauryl sulphate 5%
Naphthalenesulfonate formaldehyde condensation compound 3%
Precipitated calcium carbonate surplus
The preparation method of the wettable powder is：Er Lv Evil bacterium azoles and azoles mepanipyrim are counted into precipitated calcium carbonate by above-mentioned formula
In, it is uniform to be subsequently adding wetting agent and dispersant, adds appropriate water Jing after comminution by gas stream, Jing kneadings, pelletize, drying,
Screening is obtained wettable powder of the present invention.
2nd, embodiment 2:12% Er Lv Evil bacterium azoles azoles mepanipyrim aqueous emulsions（5:7）
Er Lv Evil bacterium azoles 5%
Azoles mepanipyrim 7%
Ketohexamethylene 9%
Styryl phenol polyethenoxy ether 5%
Fatty alcohol-polyoxyethylene ether 2%
Glycerol 2%
Organic silicone 1.2%
Deionized water surplus
The preparation method of the aqueous emulsion is：Pesticide activity component, solvent, emulsifying agent are mixed into stirring by above-mentioned formula
It is uniformly set to be dissolved as homogeneous oil phase；Deionized water, antifreeze, defoamer are mixed, homogeneous water phase is stirred into.
Under the conditions of high-speed stirred, water is added to into oil phase, aqueous emulsion of the present invention is obtained.
3rd, embodiment 4：40% Er Lv Evil bacterium azoles azoles mepanipyrim water dispersible granules（1：1）
Er Lv Evil bacterium azoles 20%
Azoles mepanipyrim 20%
Alkylbenzenesulfonate 4%
Alkylphenol polyoxyethylene sulfate 3%
Alkyl sulfo succinate 5%
Ammonium sulfate 4%
Arabic gum 4%
Kaolin surplus
The preparation method of the water dispersible granules is：Er Lv Evil bacterium azoles and azoles mepanipyrim are added in carrier by above-mentioned formula, and
Add wetting agent, dispersant and disintegrating agent, mixing that appropriate water, Jing kneadings, pelletize, drying, screening are added Jing after comminution by gas stream
Water dispersible granules of the present invention are obtained afterwards.
4th, embodiment 4:36% Er Lv Evil bacterium azoles azoles mepanipyrim suspending agents（1:5）
Er Lv Evil bacterium azoles 6%
Azoles mepanipyrim 30%
Fatty alcohol-polyoxyethylene ether 5%
EO-PO block copolymers 4%
Dispersant MF -5 4%
Aluminium-magnesium silicate 2%
Bronopol 1%
Ethylene glycol 1.5%
Deionized water surplus
The preparation method of the suspending agent is：After dispersant, wetting agent, thickening agent, preservative, antifreeze nitrile high speed shear
Mix homogeneously, adds Er Lv Evil bacterium azoles and azoles mepanipyrim, deionized water to supply surplus, and ball milling 2-3 hours, make in ball mill
Diameter of particle is obtained below 5 microns, suspending agent of the present invention is obtained.
5th, embodiment 5:31% Er Lv Evil bacterium azoles azoles mepanipyrim water dispersible granules（30:1）
Er Lv Evil bacterium azoles 30%
Azoles mepanipyrim 1%
Dialkyl group Succinate sodium sulfonate salt 3%
Alkylphenol polyoxyethylene sulfate 3%
Lignosulfonates 4%
Carbamide 4%
Arabic gum 4%
Kieselguhr surplus
The preparation method of the water dispersible granules is：Er Lv Evil bacterium azoles and azoles mepanipyrim are added in carrier by above-mentioned formula, and
Add wetting agent, dispersant and disintegrating agent, mixing that appropriate water, Jing kneadings, pelletize, drying, screening are added Jing after comminution by gas stream
Water dispersible granules of the present invention are obtained afterwards.
2nd, Toxicity Determination
1st, the Toxicity Determination of Er Lv Evil bacterium azoles and azoles mepanipyrim compounding to the late blight of potato
Test target：Late blight of potato pathogenic bacterium phytophthora infestans
Test method：By Er Lv Evil bacterium azoles and azoles mepanipyrim active compound respectively with after a small amount of acetone solution, with containing 0.1% Tween 80
Deionized water dilution be configured to the mother solution of 1000 ug/mL, it is stand-by in 4 DEG C of preservations.
Test reference《Farm-chemical indoor determination test rule NY/T1156.2-2006》Using mycelial growth rate method.
On ultra-clean operating board, by the medicinal liquid for preparing with the rye agar culture medium melted with 1:9 volume ratio mix homogeneously,
Enter in the glass culture dish of the cm of preparation 9, per the mL of ware 10, make pastille culture medium, be with the sterilized water containing 0.1% Tween 80
Control, per concentration 3 repetitions are set.The bacterium that cut-off meets 5 mm is beaten from the growth examination phytophthora infestans strain colony edge that supplies of 10 days
Handle, face down is connected on the pastille culture medium flat board for preparing, and is placed under 18 DEG C of dark condition and is cultivated about 12 days.When right
When according to colony diameter being approximately the 2/3 of culture dish diameter, colony diameter is measured using crossing method, calculate suppression ratio.United with DPS
Meter analysis software carries out statistical analysiss, calculates the EC of each medicament50, and the co-toxicity coefficient CTC of mixture is calculated according to the abundant methods of Sun Yun.Examination
Test result as indicated with 1：
As shown in table 1 to the Toxicity Determination result of the late blight of potato after Er Lv Evil bacterium azoles and azoles mepanipyrim compounding, table 1 can
To find out, Er Lv Evil bacterium azoles and azoles mepanipyrim are 1:30-30：In the range of 1 to the preventing and treating of the late blight of potato show collaboration
Potentiation；Wherein, when both compound proportions are 1:15-10:When 1, more than 180, synergistic function is more for co-toxicity coefficient
Substantially.Additionally, when both compound proportions are 5:When 7, synergistic function is most notable, and co-toxicity coefficient is up to 278.61.
2nd, Er Lv Evil bacterium azoles and azoles mepanipyrim are to cucumber downy mildew Toxicity Determination
Test target：Cucumber downy mildew
Test method：By Er Lv Evil bacterium azoles and azoles mepanipyrim active compound respectively with after a small amount of acetone solution, with containing 0.1% Tween 80
Deionized water dilution be configured to the mother solution of 1000 ug/mL, it is stand-by in 4 DEG C of preservations.
Test reference《Farm-chemical indoor determination test rule NY/T1156.2-2006》Using mycelial growth rate method.
On ultra-clean operating board, by the medicinal liquid for preparing with the PDA culture medium melted with 1:9 volume ratio mix homogeneously, pours into
In the glass culture dish of the cm of preparation 9, per the mL of ware 10, pastille culture medium is made, be right with the sterilized water containing 0.1% Tween 80
According to every concentration sets 3 repetitions.The bacterium that cut-off meets 5 mm is beaten from the growth examination cucumber downy mildew pathogenic bacteria bacterial strain colony edge that supplies of 10 days
Handle, face down is connected on the pastille culture medium flat board for preparing, and is placed under 18 DEG C of dark condition and is cultivated about 12 days.When right
When according to colony diameter being approximately the 2/3 of culture dish diameter, colony diameter is measured using crossing method, calculate suppression ratio.United with DPS
Meter analysis software carries out statistical analysiss, calculates the EC of each medicament50, and the co-toxicity coefficient CTC of mixture is calculated according to the abundant methods of Sun Yun.Examination
Test result as indicated with 2：
It is as shown in table 2 to the Toxicity Determination result of cucumber downy mildew after Er Lv Evil bacterium azoles and azoles mepanipyrim compounding, can by table 2
Know, to the preventing and treating of cucumber downy mildew 1 after Er Lv Evil bacterium azoles and azoles mepanipyrim compounding:30-30：Collaboration is shown in the range of 1
Potentiation.Especially when both compound proportions are 1:15-10:When 1, more than 170, synergistic function is more for co-toxicity coefficient
Substantially.
3rd, field control effectiveness test
In order to further verify the practical application effect of the composition pesticide of the present invention, carry out using the composition pesticide of the present invention
The late blight of potato, cucumber downy mildew field control effectiveness test are prevented and treated, disease indexs is investigated within 7,14 days after medicine and is calculated anti-
Effect, result of the test is as shown in table 3, table 4.
As shown in Table 3, preventing and treating of the pesticidal preparations of embodiment 1-5 to the late blight of potato shows preferable prevention effect, and two
Person's compounding is 120 g a.i./hm in consumption2Spraying, to the preventive effects of 14 days after late blight of potato medicine more than 80%, hence it is evident that
It is better than the preventive effect of control single dose.It is especially 5 when both compound:When 7, to the preventive effect of the late blight of potato more than 90%.
As shown in Table 4, preventing and treating of the pesticidal preparations of embodiment 1-4 to cucumber downy mildew shows preferable prevention effect, both
Compounding is 120 g a.i./hm in consumption2Spraying, to the preventive effects of 14 days after cucumber downy mildew medicine more than 80%, hence it is evident that be better than
The preventive effect of control single dose.In addition, in scope of medication, not finding the composition pesticide of the present invention has poisoning to produce cucumber crop
It is raw, show that the composition pesticide of the present invention, to crop safety, is worth the popularization and application in production.
Claims (8)
1. a kind of pesticide sterilizing synergistic composition, it is characterised in that active component includes Er Lv Evil bacterium azoles and azoles mepanipyrim.
2. pesticide sterilizing synergistic composition according to claim 1, it is characterised in that the Er Lv Evil bacterium azoles and the phonetic bacterium of azoles
The weight ratio of amine is 1:30-30:1.
3. pesticide sterilizing synergistic composition according to claim 2, it is characterised in that the Er Lv Evil bacterium azoles and the phonetic bacterium of azoles
The weight ratio of amine is 1:15-10:1.
4. the pesticide sterilizing synergistic composition according to any one of claim 1-3 claim, it is characterised in that described
The weight percentage of active component is 1-80%, preferably 10-60% in sterilization synergetic pesticide composition.
5. pesticide sterilizing synergistic composition according to claim 4, it is characterised in that its dosage form is to be cream, moisture
In shot agent, wettable powder, suspending agent, microemulsion, aqueous emulsion, microcapsule suspending agent any one.
6. pesticide sterilizing synergistic composition according to claim 4, it is characterised in that it also includes other active component,
One or more in insecticide, attractant, nematicide, antifungal, plant growth regulator, herbicide, fertilizer.
7. the pesticide sterilizing synergistic composition according to claim 1-6 is used to prevent and treat the purposes of corps diseases.
8. purposes according to claim 7, it is characterised in that the corps diseases are preferably the late blight of potato and Huang
Melon downy mildew.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611171188.1A CN106614656A (en) | 2016-12-17 | 2016-12-17 | Pesticide composition containing dichlorooxazole and ametoctradin |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611171188.1A CN106614656A (en) | 2016-12-17 | 2016-12-17 | Pesticide composition containing dichlorooxazole and ametoctradin |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106614656A true CN106614656A (en) | 2017-05-10 |
Family
ID=58823075
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611171188.1A Pending CN106614656A (en) | 2016-12-17 | 2016-12-17 | Pesticide composition containing dichlorooxazole and ametoctradin |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106614656A (en) |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1188394A (en) * | 1995-06-20 | 1998-07-22 | 纳幕尔杜邦公司 | Arthropodicidal and fungicidal cyclic amides |
| CN101812034B (en) * | 2010-05-11 | 2011-12-14 | 贵州大学 | 2-substituent-5-(2,4-dichlorophenyl)-1,3,4-oxadiazole derivative, synthetic method and application thereof |
| CN102757400B (en) * | 2012-07-18 | 2014-08-06 | 贵州大学 | 2, 5-substituent group oxazole derivative and applications thereof |
| CN104045605A (en) * | 2014-07-08 | 2014-09-17 | 贵州大学 | Phenoxymethyl sulfone derivatives as well as synthesis method and application of phenoxymethyl sulfone derivatives |
| CN106070241A (en) * | 2016-06-21 | 2016-11-09 | 广东中迅农科股份有限公司 | A kind of containing dichloro evil bacterium azoles and the bactericidal composition of fluorine thiazole pyrrole ethyl ketone |
| CN106106470A (en) * | 2016-06-21 | 2016-11-16 | 广东中迅农科股份有限公司 | A kind of containing dichloro evil bacterium azoles and the bactericidal composition of amisulbrom |
| CN106172438A (en) * | 2016-07-19 | 2016-12-07 | 广东中迅农科股份有限公司 | bactericidal composition |
-
2016
- 2016-12-17 CN CN201611171188.1A patent/CN106614656A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1188394A (en) * | 1995-06-20 | 1998-07-22 | 纳幕尔杜邦公司 | Arthropodicidal and fungicidal cyclic amides |
| CN101812034B (en) * | 2010-05-11 | 2011-12-14 | 贵州大学 | 2-substituent-5-(2,4-dichlorophenyl)-1,3,4-oxadiazole derivative, synthetic method and application thereof |
| CN102757400B (en) * | 2012-07-18 | 2014-08-06 | 贵州大学 | 2, 5-substituent group oxazole derivative and applications thereof |
| CN104045605A (en) * | 2014-07-08 | 2014-09-17 | 贵州大学 | Phenoxymethyl sulfone derivatives as well as synthesis method and application of phenoxymethyl sulfone derivatives |
| CN106070241A (en) * | 2016-06-21 | 2016-11-09 | 广东中迅农科股份有限公司 | A kind of containing dichloro evil bacterium azoles and the bactericidal composition of fluorine thiazole pyrrole ethyl ketone |
| CN106106470A (en) * | 2016-06-21 | 2016-11-16 | 广东中迅农科股份有限公司 | A kind of containing dichloro evil bacterium azoles and the bactericidal composition of amisulbrom |
| CN106172438A (en) * | 2016-07-19 | 2016-12-07 | 广东中迅农科股份有限公司 | bactericidal composition |
Non-Patent Citations (2)
| Title |
|---|
| 朱国仁等: "《新编蔬菜病虫害防治手册》", 31 October 1990, 金盾出版社 * |
| 柴宝山等: "辛唑嘧菌胺的合成与生物活性", 《农药》 * |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103766353B (en) | Sterilization composition containing fluopyram | |
| CN105010358A (en) | Bactericidal composition and application thereof | |
| CN106234388B (en) | A kind of composition pesticide of alkene containing benzo fluorine bacterium azoles and jamaicin | |
| CN106172429A (en) | A kind of containing benzothiostrobin with the bactericidal composition of acid amide fungicides | |
| CN109463384A (en) | A kind of bactericidal composition containing Thymol and Boscalid | |
| CN105941426B (en) | A kind of composition pesticide of fluorine-containing thiazole pyrrole ethyl ketone and tiger glue adipic acid copper | |
| CN102217638B (en) | Pesticide composition for preventing and treating plant virus diseases | |
| CN106234389B (en) | A kind of composition pesticide of fluorine-containing thiazole pyrrole ethyl ketone and jamaicin | |
| CN106561677A (en) | Pesticide composition containing 2-methyl sufone-5-(2,4-dichlorophenyl)-1,2,3-oxadiazole and amino-oligosaccharin and application of pesticide composition | |
| CN107318865A (en) | The composition pesticide of captan and furametpyr compounding | |
| CN106614656A (en) | Pesticide composition containing dichlorooxazole and ametoctradin | |
| CN106417313A (en) | Bactericidal composition containing amisulbrom and fluopicolide | |
| CN105123746B (en) | A kind of complex composition and bactericide containing toxic fluoride phosphate and bromothalonil | |
| CN102017949A (en) | Synergistic pesticidal composition containing nitenpyram and ethofenprox and application thereof | |
| CN109769819A (en) | Ternary weeding composition and application thereof | |
| CN104970021A (en) | Sterilization composition containing oxine-copper and xinjunan acetate | |
| CN107318868A (en) | Bactericidal composition comprising folpet and benzene metsulfovax | |
| CN106508920A (en) | Bactericidal composition comprising C4H7Cl2O4P and difenoconazole | |
| CN107047577A (en) | A kind of bactericidal composition containing fluoxastrobin and triazolone | |
| CN103081931B (en) | The bactericidal composition of benzene metsulfovax and dimethomorph | |
| CN106417334A (en) | Bactericide composition containing 2-methylsulfuryl-5-(2, 4-dichlorophenyl)-1, 3, 4-oxadiazole and benthiavalicarb-isopropyl | |
| CN105994291A (en) | Bactericidal composition containing benzovindiflupyr | |
| CN106508911A (en) | Sterilizing composition comprising cyprodinil and oligochitosan | |
| CN106212483A (en) | A kind of containing fluoxastrobin with the bactericidal composition of fluorine azoles Acibenzolar | |
| CN107864966A (en) | A kind of bactericidal composition containing benzene metsulfovax Yu azoles mepanipyrim |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170510 |