CN106169518A - A kind of laser pulse method carrying on the back passivation solaode - Google Patents

A kind of laser pulse method carrying on the back passivation solaode Download PDF

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Publication number
CN106169518A
CN106169518A CN201610683628.5A CN201610683628A CN106169518A CN 106169518 A CN106169518 A CN 106169518A CN 201610683628 A CN201610683628 A CN 201610683628A CN 106169518 A CN106169518 A CN 106169518A
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China
Prior art keywords
pulse
laser
back surface
solaode
silicon
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CN201610683628.5A
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CN106169518B (en
Inventor
黄金
李高非
王继磊
付少剑
张娟
白炎辉
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Jinneng Clean Energy Technology Ltd
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Jin Neng Clean-Tech Co Ltd
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/18Processes or apparatus specially adapted for the manufacture or treatment of these devices or of parts thereof
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/02Details
    • H01L31/0224Electrodes
    • H01L31/022408Electrodes for devices characterised by at least one potential jump barrier or surface barrier
    • H01L31/022425Electrodes for devices characterised by at least one potential jump barrier or surface barrier for solar cells
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/50Photovoltaic [PV] energy
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

Abstract

The invention discloses a kind of laser pulse method carrying on the back passivation solaode.It comprises the following steps: A, monocrystalline silicon piece carries out making herbs into wool process, forms pyramid matte;B, diffusion are for PN junction;Flash trimming knot and surface defect are gone in C, polishing;D, made by ALD, PECVD the positive back side formed passivation film;E, carrying out lbg at back surface, fluting uses pulse mode to be multiple-pulse, and umber of pulse is 25;F, silk screen printing form anelectrode, back electrode and back surface field;G, sintering make to form good Ohmic contact between metal and silicon.Its advantage is: reduce silicon substrate and the damage of film layer, and when making lbg, the requirement to film layer planarization is relaxed, and the planarization making fluting position is more preferable, thus decreases the damage to back side film layer and silicon substrate, strengthens passivation effect;The flatness at lbg position is more preferable, enables silicon substrate and aluminum back surface field to form good Ohmic contact, thus improves the conversion efficiency of solaode.

Description

A kind of laser pulse method carrying on the back passivation solaode
Technical field
The present invention relates to a kind of laser pulse method carrying on the back passivation solaode, belong to the manufacturing technology of solaode Field.
Background technology
Cannot conduct electricity owing to Al2O3 thin film and SiN thin film are insulating barrier, the effect of laser is exactly mainly by back side film layer Scratch and make silicon substrate expose, make silicon substrate can form good ohm with aluminum back surface field after completing to carry on the back electric field printing-sintering and connect Touch, so make laser output energy have the passivation effect of aluminium oxide important impact, laser output energy conference to make corruption The erosion degree of depth increases, hot injury directly affects more greatly the passivation effect of pellumina layer so that open-circuit voltage reduces, and laser exports The little meeting of energy makes corrosion depth not enough, it is impossible to punch back side silicon nitride silicon completely and pellumina layer causes between silicon substrate and aluminum back surface field Loose contact, makes series resistance be greatly increased, and reduces so that filling.
The most common laser pulse mode mostly is pulse, and it is relatively big that the most this pulse mode exports energy on year-on-year basis, Wayward, less stable, easily causes damage to film layer and silicon substrate;The most now polishing process is for adapting to PERC electricity Pond volume production demand uses acid polishing, but the planarization of this kind of polishing mode correspondence back of the body film plating layer is poor, passes through single pulse mode Lbg position pattern is bad, is mainly reflected on planarization so that silicon substrate and the loose contact of aluminum back surface field.
Summary of the invention
The technical problem to be solved is to provide a kind of damage that can reduce back side film layer and silicon substrate, increases Strong passivation effect, and the laser pulse method of the back of the body passivation solaode of the conversion efficiency of PERC battery can be improved.
In order to solve above-mentioned technical problem, the laser pulse method of the back of the body passivation solaode of the present invention, including following Step:
A, monocrystalline silicon piece is carried out making herbs into wool process, form pyramid matte;
B, diffusion are for PN junction;
Flash trimming knot and surface defect are gone in C, polishing, make back surface smooth;
D, made by ALD, PECVD the positive back side formed passivation film;
E, using laser equipment to carry out lbg at back surface, fluting uses pulse mode to be multiple-pulse, and umber of pulse is 2-5;
F, silk screen printing form anelectrode, back electrode and back surface field;
G, sintering make to form good Ohmic contact between metal and silicon.
Described step G carries out testing the electrical property of battery after completing.
In described step E, output is 10-40W, and frequency is 400-1000KHz, and frequency is corresponding with umber of pulse, frequently Rate and umber of pulse product are less than 2000.
Described passivating film is aluminium oxide, silicon nitride or silicon oxide film or the stack membrane of at least a part of which bi-material, film layer Thickness is 50-300nm.
Described laser equipment is psec, submicrosecond or nanosecond laser.
It is an advantage of the current invention that:
Owing to fluting uses pulse mode to be multiple-pulse, particularly the parameter area of laser is set, so that Under the conditions of on year-on-year basis, utilize multiple-pulse output gross energy little, reduce silicon substrate and the damage of film layer, the increasing of umber of pulse simultaneously Adding when making lbg the requirement to film layer planarization to relax, the planarization making fluting position is more preferable, thus decreases the back side Film layer and the damage of silicon substrate, strengthen passivation effect;The flatness at lbg position is more preferable simultaneously so that silicon substrate can be with Aluminum back surface field forms good Ohmic contact, thus improves the conversion efficiency of solaode.
Detailed description of the invention
Below in conjunction with detailed description of the invention, the laser pulse method that the present invention carries on the back passivation solaode is made further Describe in detail.
The laser pulse method of the back of the body passivation solaode of the present invention, comprises the following steps:
A, monocrystalline silicon piece is carried out making herbs into wool process, form pyramid matte;
B, diffusion are for PN junction;
Flash trimming knot and surface defect are gone in C, polishing, make back surface smooth;
D, made by ALD, PECVD the positive back side formed passivation film;Passivating film is aluminium oxide, silicon nitride or silicon oxide film Or the stack membrane of at least a part of which bi-material, thicknesses of layers is 50-300nm;
E, employing laser equipment carry out lbg at back surface, and fluting uses pulse mode to be multiple-pulse, and umber of pulse is 2-5;Its output is 10-40W, and frequency is 400-1000KHz, and frequency is corresponding with umber of pulse, frequency and umber of pulse product Less than 2000;Described laser equipment is psec, submicrosecond or nanosecond laser.
F, silk screen printing form anelectrode, back electrode and back surface field;
G, sintering make to form good Ohmic contact between metal and silicon.
H, carry out test battery electrical property.
Its comparative example is as follows:
Comparative example one:
A, monocrystalline silicon piece is carried out making herbs into wool process, form pyramid matte;
B, diffusion are for PN junction;
Flash trimming knot and surface defect are gone in C, polishing, make back surface smooth;
D, made by ALD, PECVD positive back surface formed passivation film, front is silicon nitride film layer, and thickness is 80nm, the back of the body Face is aluminium oxide and silicon nitride stack film, and thickness is 130nm;
E, employing picosecond laser carry out lbg at back surface, and fluting uses pulse mode to be pulse, fluting frequency Rate is 625KHz, and output is 12W.
F, silk screen printing form anelectrode, back electrode and back surface field;
G, sintering make to form good Ohmic contact between metal and silicon;
H, the electrical property of test battery.
Comparative example two:
The laser pulse method of the back of the body passivation solaode of the present embodiment, comprises the following steps:
A, monocrystalline silicon piece is carried out making herbs into wool process, form pyramid matte;
B, diffusion are for PN junction;
Flash trimming knot and surface defect are gone in C, polishing, make back surface smooth;
D, made by ALD, PECVD the positive back side formed passivation film;Front is silicon nitride film layer, and thickness is 80nm, the back side For aluminium oxide and silicon nitride stack film, thickness is 130nm;
E, carrying out lbg at picosecond laser back surface, fluting uses pulse mode to be dipulse, and fluting frequency is 625KHz, output is 12W;
F, silk screen printing form anelectrode, back electrode and back surface field;
G, sintering make to form good Ohmic contact between metal and silicon.
F, carry out test battery electrical property.
Comparative example three:
A, monocrystalline silicon piece is carried out making herbs into wool process, form pyramid matte;
B, diffusion are for PN junction;
Flash trimming knot and surface defect are gone in C, polishing, make back surface smooth;
D, made by ALD, PECVD positive back surface formed passivation film, front is silicon nitride film layer, and thickness is 80nm, the back of the body Face is aluminium oxide and silicon nitride stack film, and thickness is 130nm;
E, employing picosecond laser carry out lbg at back surface, and fluting uses pulse mode to be three pulses, fluting frequency Rate is 625KHz, and output is 12W.
F, silk screen printing form anelectrode, back electrode and back surface field;
G, sintering make to form good Ohmic contact between metal and silicon;
H, the electrical property of test battery.
The electrical property preparing PERC battery according to the method described above is shown in Table 1, it can be seen that multiple-pulse is imitated compared to pulse Rate improves 0.2-0.4%, predominantly shows as out pressure and the raising filled, and along with the increase of umber of pulse, opens pressure lifting amplitude fall Low.
Pulse mode Eta Uoc Isc FF Rs Rsh
Pulse 20.92 0.652 9.711 79.56 0.0020 170.22
Dipulse 21.26 0.654 9.725 80.55 0.0018 250.12
Three pulses 21.26 0.655 9.757 80.14 0.0019 324.81

Claims (5)

1. carry on the back a laser pulse method for passivation solaode, comprise the following steps:
A, monocrystalline silicon piece is carried out making herbs into wool process, form pyramid matte;
B, diffusion are for PN junction;
Flash trimming knot and surface defect are gone in C, polishing, make back surface smooth;
D, made by ALD, PECVD the positive back side formed passivation film;
E, using laser equipment to carry out lbg at back surface, fluting uses pulse mode to be multiple-pulse, and umber of pulse is 2-5;
F, silk screen printing form anelectrode, back electrode and back surface field;
G, sintering make to form good Ohmic contact between metal and silicon.
2. according to the laser pulse method of the back of the body passivation solaode described in claim 1, it is characterised in that: described step G Carry out testing the electrical property of battery after completing.
3. according to the laser pulse method of the back of the body passivation solaode described in claim 1 or 2, it is characterised in that: described step In rapid E, output is 10-40W, and frequency is 400-1000KHz, and frequency is corresponding with umber of pulse, frequency and umber of pulse product Less than 2000.
4. according to the laser pulse method of the back of the body passivation solaode described in claim 1, it is characterised in that: described passivating film For aluminium oxide, silicon nitride or silicon oxide film or the stack membrane of at least a part of which bi-material, thicknesses of layers is 50-300 nm.
5. according to the laser pulse method of the back of the body passivation solaode described in claim 1, it is characterised in that: described source, laser apparatus Standby for psec, submicrosecond or nanosecond laser.
CN201610683628.5A 2016-08-17 2016-08-17 A kind of laser pulse method for carrying on the back passivation solar cell Active CN106169518B (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106784164A (en) * 2017-01-22 2017-05-31 通威太阳能(成都)有限公司 A kind of solar cell preparation technology of back side coating film treatment
CN107046078A (en) * 2017-02-22 2017-08-15 广东爱康太阳能科技有限公司 It is a kind of to be provided with PERC solar cells of hollow out bar and preparation method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20060060238A1 (en) * 2004-02-05 2006-03-23 Advent Solar, Inc. Process and fabrication methods for emitter wrap through back contact solar cells
CN102006964A (en) * 2008-03-21 2011-04-06 Imra美国公司 Laser-based material processing methods and systems
CN102122685B (en) * 2011-01-27 2013-06-05 中山大学 Method for preparing crystalline silicon solar battery having emitter wrapping structure
CN103456837A (en) * 2013-08-26 2013-12-18 镇江大全太阳能有限公司 Method for manufacturing solar cell with local back surface field passivation
CN104245220A (en) * 2012-01-31 2014-12-24 太阳能公司 Laser system with multiple laser pulses for fabrication of solar cells

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20060060238A1 (en) * 2004-02-05 2006-03-23 Advent Solar, Inc. Process and fabrication methods for emitter wrap through back contact solar cells
CN102006964A (en) * 2008-03-21 2011-04-06 Imra美国公司 Laser-based material processing methods and systems
CN102122685B (en) * 2011-01-27 2013-06-05 中山大学 Method for preparing crystalline silicon solar battery having emitter wrapping structure
CN104245220A (en) * 2012-01-31 2014-12-24 太阳能公司 Laser system with multiple laser pulses for fabrication of solar cells
CN103456837A (en) * 2013-08-26 2013-12-18 镇江大全太阳能有限公司 Method for manufacturing solar cell with local back surface field passivation

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106784164A (en) * 2017-01-22 2017-05-31 通威太阳能(成都)有限公司 A kind of solar cell preparation technology of back side coating film treatment
CN106784164B (en) * 2017-01-22 2018-05-18 通威太阳能(成都)有限公司 A kind of solar cell preparation process of back side coating film processing
CN107046078A (en) * 2017-02-22 2017-08-15 广东爱康太阳能科技有限公司 It is a kind of to be provided with PERC solar cells of hollow out bar and preparation method thereof

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Address after: 033000 Wenshui County Economic Development Zone, Lvliang, Shanxi

Patentee after: Jinneng clean energy technology stock company

Address before: 033000 Wenshui County Economic Development Zone, Lvliang, Shanxi

Patentee before: Jin Neng Clean-tech Co., Ltd