CN106146002A - A kind of preparation method of ceramic water-permeable brick - Google Patents
A kind of preparation method of ceramic water-permeable brick Download PDFInfo
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- CN106146002A CN106146002A CN201610653991.2A CN201610653991A CN106146002A CN 106146002 A CN106146002 A CN 106146002A CN 201610653991 A CN201610653991 A CN 201610653991A CN 106146002 A CN106146002 A CN 106146002A
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- permeable brick
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B38/00—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
- C04B38/0038—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof by superficial sintering or bonding of particulate matter
- C04B38/0041—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof by superficial sintering or bonding of particulate matter the particulate matter having preselected particle sizes
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
- C04B33/132—Waste materials; Refuse; Residues
- C04B33/1324—Recycled material, e.g. tile dust, stone waste, spent refractory material
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00241—Physical properties of the materials not provided for elsewhere in C04B2111/00
- C04B2111/00284—Materials permeable to liquids
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3427—Silicates other than clay, e.g. water glass
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/44—Metal salt constituents or additives chosen for the nature of the anions, e.g. hydrides or acetylacetonate
- C04B2235/447—Phosphates or phosphites, e.g. orthophosphate, hypophosphite
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/44—Metal salt constituents or additives chosen for the nature of the anions, e.g. hydrides or acetylacetonate
- C04B2235/448—Sulphates or sulphites
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/50—Constituents or additives of the starting mixture chosen for their shape or used because of their shape or their physical appearance
- C04B2235/54—Particle size related information
- C04B2235/5418—Particle size related information expressed by the size of the particles or aggregates thereof
- C04B2235/5427—Particle size related information expressed by the size of the particles or aggregates thereof millimeter or submillimeter sized, i.e. larger than 0,1 mm
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/60—Aspects relating to the preparation, properties or mechanical treatment of green bodies or pre-forms
- C04B2235/604—Pressing at temperatures other than sintering temperatures
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P40/00—Technologies relating to the processing of minerals
- Y02P40/60—Production of ceramic materials or ceramic elements, e.g. substitution of clay or shale by alternative raw materials, e.g. ashes
Abstract
The invention discloses the preparation method of a kind of ceramic water-permeable brick, comprise the steps: that (1) crushes, Jian Tao factory waste solid floor tile pulverizer is crushed to 0 10mm;(2) screening, screens out the 30 above granules of mesh in step (1) pulverized particles stand-by, and 30 mesh 1mm are as surface layer, and 1 3mm is as main part;(3) batch mixing, adds the close material formula of following mass percent by the raw material that filters out: aluminum phosphate solution 10% 20%, aluminum sulfate solution 15% 25%, carbamide 4 10%, clay 15 25%, sodium silicate 8 16%, binding agent 4 6%, sodium sulfate 4 6%;(4) stirring, fully stirs evenly with blender;(5) molding, adds mixture paste in mould, compressing with press;(6) high temperature sintering, kiln discharge chooses to install.It is short that the present invention has the firing time, and process is simple, and production cost is relatively low, and product water-permeable and air permeable performance is good, intensity is high, rough surface, and wearability is strong, and snow defence is anti-skidding, and salvage value is high, protection environment, saving natural resources.
Description
Technical field
The present invention relates to a kind of ceramic wall and floor bricks technical field, particularly relate to the preparation method of a kind of ceramic water-permeable brick.
Background technology
Be commonly used at present the road base cement concretes to be used of public place such as square, park, road, stone material,
The fluid-tight material such as Ceramic Tiles is laid and is formed, but this hard surface has been not suitable with the requirement keeping good ecological environment:
As when raining in torrents, rainwater flows away from sewer via the drainage outlet on hard surface, but due to the residual leaf on road, rubbish punching
It is frequently occluded scupper to drainage outlet, causes low-lying place hydrops serious, it is impossible to be current;On the other hand, owing to hard surface is to rain
Water does not absorbs, and rainwater is wasted, and subsoil water also can not get supplementing of necessity, causes level of ground water to decline;When after rainy season,
The problem of drought hydropenia again, makes city heat island phenomenon occur.Accordingly, it would be desirable to use the various field of dank material making in a large number
Ground and road surface, to keep the good ecological environment in city.
Along with the fast development of ceramic industry, ceramic industry waste material is increasing, exerts heavy pressures on urban environment, also
Limit the sustainable development of ceramic industry;At present, the process of China's ceramic industry waste material is relatively low with producing level, causes a large amount of
Waste material ties up arable land, makes water and air be contaminated.How to process and to utilize shraff, turning waste into wealth, it has also become society is altogether
With the problem paid close attention to.
As the Chinese patent of Patent No. CN99104294 discloses a kind of floor tile manufacturer with water permeability
Method, including: (1) aggregate is broken, screening;(2) binding agent is dried, crushes, sieves;(3) raw material adds water mixing;(4) compressing;
(5) burn till at 1150~1250 DEG C, it is characterised in that: aggregate is brick grain, and proportioning is 85~94%;Binding agent is that low temperature height glues
Property clay, proportioning is 6~15%.The water-permeable brick paving ground using the present invention to manufacture, can get rid of rapidly excess surface water, improve ring
Border, and the intensity of water-permeable brick can meet or exceed the standard of existing square brick.The present invention brick that can give up is primary raw material, for having
Effect utilizes pottery waste product to open new approach.
The Chinese patent of Patent No. CN01127813 discloses a kind of ceramic water-permeable brick and production method, its technology solution
Certainly scheme is: useless Wall or floor tile grain 70-90, feldspar powder 8-20, cellulose 1-5, wood flour 1-5, size-reduced mixing of sieving, and adds appropriate
Water stirs, then base, be dried, under conditions of firing temperature is 1100-1300 DEG C calcine 100-140 minute, cooling
Discharging becomes ceramic water-permeable brick.Utilize its high water-permeability, high respiratory and anti-wear performance, ceramic water-permeable brick will become most ecological and
The functional paving material of environmental protection mode.
The Chinese patent of Patent No. CNO2151782 discloses a kind of novel environment friendly ecology relating to refuse reclamation and builds
Build the production technology of material, quickly fire the production technology of environment friendly pervious air brick especially with roller kilns, it is characterised in that:
(1) with the industrial residues such as waste ceramic, refractory material, clay, slag, self-igniting coal gangue, refuse incineration slag, municipal sewage system dirt
Mud, waste plastics, wood flour, bamboo bits and the special low temperature adhesive being made up of mixture Organic substance and inorganic matter are that raw material is put into broken
Crusher machine is to the granule of 6~100 mesh;(2) the above-mentioned granule crushed is put into blender or ball mill batch mixing;(3) with laggard
Enter harder compacting or with vacuum pugging extruder extrusion molding;(4) roller kilns it are finally putting into through 30 minutes~6 hours high temperature
Sinter the microporous cellular infrastructure product of capillary tube through hole into.
The Chinese patent of Patent No. CN200310105410 discloses one graphite tailing and manufactures enviroment protective ceramic ecology
Brick, belongs to solid waste and utilizes and field of novel.This product utilization graphite tailing particle packing forms Environment-friendlyecological ecological brick, brick
Internal hole, utilizes plasticity bonding agent to improve the intensity of its processability and green compact, promotes enviroment protective ceramic by sintering aid
Burning till of ecological brick, increases its intensity and coefficient of permeability, reduces firing temperature.It is characterized in that having following formula (component and
Its percentage by weight %): graphite tailing (8-3mm) 10-40, (3-1mm) 10-40, (< 1mm) 0-20;Plasticity bonding agent 0.5-
1;Sintering aid (Anhydrite, incinerator ash, glass) 5-40;Water adds to 100.
It is saturating that the Chinese patent of Patent No. CN200310115100 discloses a kind of slag with network-like pore structure
Water route face brick.It is characterized in that adding in steel slag pavement brick slag, steel slag pavement brick divides upper and lower two-layer, slag
Grain particle diameter is 2.5~10mm, and in bottom raw material, steel slag particle accounts for 75~78wt%, and No. 42.5 cement account for 13~15wt%, slag
Pulverized powder accounts for 3~5wt%, and water reducer accounts for 0.5~0.8wt%, and water accounts for 3.5~6.0wt%;In the raw material of upper strata, steel slag particle accounts for
71~74wt%, No. 42.5 cement account for 15~18wt%, and slag mill fine powder accounts for 3.5~5.5wt%, water reducer account for 0.7~
0.9wt%, water accounts for 3.5~6.0wt%.Compared with ceramic water-permeable brick, the present invention can be greatly lowered the production of road surface water-permeable brick
Cost, is not required to calcining simultaneously, can save the energy, protects environment.Compared with current existing common cement-base water-permeable brick, it is to avoid
The shortcoming of freeze-thaw resistance difference.
The Chinese patent of Patent No. CN200410039203 discloses a kind of environmental protection water permeable brick structure and preparation method thereof, and this is saturating
Water brick includes the upper brick layer integrally fired and lower brick layer, and the thickness of this lower brick layer accounts for the 75~95% of water-permeable brick gross thickness,
On this, brick layer and lower brick layer are formed by the ceramic fine particle and coarse grain being mixed with additive and bonding agent respectively, and composition after saturating
The comprcssive strength of water brick is more than specification value 300kgf/cm2, and rupture strength is at more than 50kgf/cm2, and permeability rate is more than
0.035ml·cm/mm2/sec.Above-mentioned water-permeable brick according to setting procedure by waste ceramic processed, through high temperature sintering molding, can
Make the increase of water-permeable brick intensity, easy coloring, can back washing and may filter that impurity and tool breathability;Be applicable to pavement, ramp, from
Runway and the water-permeable brick of edge of pool.
The Chinese patent of Patent No. CN200610159648 discloses the production method of a kind of composite ceramic water-permeable brick, should
Method with include combustible industrial residue for bottom aggregate, with waste ceramic particle for surface layer aggregate, its grain composition is all: cross 10~
The material of 20 mesh sieves accounts for 55~65, and the material crossing 20~30 mesh sieves accounts for 35~45;By additional appropriate high-temperature agglomerant and organic viscous
Knot agent CMC, through dispensing, old, molding, be dried, calcining process and obtain product.Said method is mainly by optimizing grain composition
Utilizing combustible that industrial residue itself contains as pore former dexterously, and two-layer uses different the most former up and down
Material, makes that the product not only water penetration that obtained by the method is strong, good water-retaining property, intensity are high, but also simplifies the technique mistake of brickmaking
Journey, reduces production cost.This product is a kind of reason for laying the public places such as footpath, parking lot, airport, square
Think product.
The Chinese patent of Patent No. CN03222998.4 discloses a kind of molding pressure producing ultra-thin large size ceramic tile
Machine, can produce thickness 3~5 millimeters, width 1 meter, the Ceramic Tiles of length 3 meters, is ceramic machinery field.It includes main frame frame
Frame, decompressor and Belt Conveying distribution device, main machine frame hollow forming has the punching press chamber running through overall, and decompressor is located at
Punching press intracavity, decompressor includes top board, the oil cylinder of a plurality of band piston, dynamic beam and base plate, and top board is located at bottom punching press chamber, dynamic
Beam is positioned at above top board, and oil cylinder and piston are between dynamic beam and top board, and base plate is fixed on punching press top of chamber and is positioned on dynamic beam
Side, Belt Conveying distribution device includes carrying club and belt, passes between the driven beam of belt and base plate.This utility model structure
Advantages of simple, does not use mould, can produce super large-scale ornament materials easily, saves ceramic powder and the energy.
The Chinese patent of Patent No. CN200510020723.9 discloses a kind of process producing ultrathin ceramic bricks,
Including: use ultra-fine equipment to carry out micronization process the raw material producing Ceramic Tiles;It is dried the powder body after micronization;Will be dry
Burn till after pressed by powder molding after dry, polish and obtain finished product.Superfine powder machine is taked in useful the having the technical effect that of the present invention
Ceramic Material is processed by tool, replaces original ball mill and technique thereof, can fundamentally solve ceramic industry powder
High energy consumption problem in terms of preparation, meanwhile, superfine powder raw material will bring revolution for subsequent technique and final ceramic product quality
The progress of property.
But prior art disclosed above exists: raw material is complicated, cost is high, and properties of product have to be hoisted.
Summary of the invention
The deficiencies in the prior art in view of the above, it is an object of the invention to provide a kind of ceramic water-permeable brick
Preparation method.
For solving above-mentioned technical problem, the technical solution used in the present invention is: the preparation method of a kind of ceramic water-permeable brick, its
It is characterised by: comprise the steps: that (1) crushes, Jian Tao factory waste solid floor tile pulverizer is pulverized;(2) screening, screening
Going out the 30 above granules of mesh in step (1) pulverized particles stand-by, 30 mesh-1mm are as surface layer, and 1-3mm is as main part;(3) mixed
Material, adds the close material formula of following mass percent by the raw material that filters out: aluminum phosphate solution 10%-20%, aluminum sulfate solution
15%-25%, carbamide 4-10%, clay 15-25%, sodium silicate 8-16%, binding agent 4-6%, sodium sulfate 4-6%;(4) stir
Mix, fully stir evenly with blender;(5) molding, adds mixture paste in mould, compressing with press;(6) high temperature burns
Knot, kiln discharge chooses to install.
Preferably, in described step (1), waste solid floor tile pulverizer is crushed to 0-10mm.
Preferably, the press selected in described step (5) is hydraulic press or friction press.
Preferably, in described step (6), the temperature of high temperature sintering is 1200 DEG C-1300 DEG C
Preferably, in described step (5), the ceramic water-permeable brick specification of compacting is 200 × 100mm, and thickness is 40mm-60mm.
The invention has the beneficial effects as follows: the inventive method can be produced porosity plus close material formula in the present invention and reach
The ceramic water-permeable brick of 20%, has good water permeability, and water-permeable brick is that micropore instigates shape capillary tube through hole structure, can absorb and makes an uproar
Sound, serves the effect of noise reduction, and this structure class to a certain extent absorbs vehicle exhaust, serves the effect purifying air, subtracts
Lack the vehicle exhaust pollution to urban air;Water-permeable brick compressive property prepared by the inventive method is good, anti-skidding, high intensity.
Detailed description of the invention
The invention provides the preparation method of a kind of ceramic water-permeable brick, comprise the steps: that (1) crushes, Jian Tao factory is given up
Abandon solid floor tile pulverizer and be crushed to 0-10mm;(2) screening, screens out the 30 above granule of mesh in step (1) pulverized particles
Stand-by, 30 mesh-1mm are as surface layer, and 1-3mm is as main part;(3) batch mixing, adds following quality hundred by the raw material filtered out
The close material formula of proportion by subtraction: aluminum phosphate solution 10%-20%, aluminum sulfate solution 15%-25%, carbamide 4-10%, clay 15-
25%, sodium silicate 8-16%, binding agent 4-6%, sodium sulfate 4-6%;(4) stirring, fully stirs evenly with blender;(5) molding, will
Mixture paste adds in mould, compressing with hydraulic press or friction press, and the specification of compacting water-permeable brick is 200 ×
100mm, thickness is 40mm-60mm;(6) high temperature sintering, sintering temperature is 1200 DEG C-1300 DEG C, and kiln discharge chooses to install.
The foregoing is only the preferred embodiments of the present invention, be not limited to the present invention, although with reference to aforementioned reality
Executing example to be described in detail the present invention, for a person skilled in the art, it still can be to aforementioned each enforcement
Technical scheme described in example is modified, or wherein portion of techniques feature is carried out equivalent.All essences in the present invention
Within god and principle, any modification, equivalent substitution and improvement etc. made, should be included within the scope of the present invention.
Claims (5)
1. the preparation method of a ceramic water-permeable brick, it is characterised in that: comprise the steps:
(1) broken, Jian Tao factory waste solid floor tile pulverizer is pulverized;
(2) screening, screens out the 30 above granules of mesh in step (1) pulverized particles stand-by, and 30 mesh-1mm make as surface layer, 1-3mm
For main part;
(3) batch mixing, adds the close material formula of following mass percent by the raw material that filters out: aluminum phosphate solution 10%-20%, sulfur
Acid aluminum solutions 15%-25%, carbamide 4-10%, clay 15-25%, sodium silicate 8-16%, binding agent 4-6%, sodium sulfate 4-
6%;
(4) stirring, fully stirs evenly with blender;
(5) molding, adds mixture paste in mould, compressing with press;
(6) high temperature sintering, kiln discharge chooses to install.
The preparation method of ceramic water-permeable brick the most according to claim 1, it is characterised in that: discarded solid in described step (1)
Body floor tile pulverizer is crushed to 0-10mm.
The preparation method of ceramic water-permeable brick the most according to claim 1, it is characterised in that: described step (5) is selected
Press is hydraulic press or friction press.
The preparation method of ceramic water-permeable brick the most according to claim 1, it is characterised in that: in described step (6), high temperature burns
The temperature of knot is 1200 DEG C-1300 DEG C.
The preparation method of ceramic water-permeable brick the most according to claim 1, it is characterised in that: compacting in described step (5)
Ceramic water-permeable brick specification is 200 × 100mm, and thickness is 40mm-60mm.
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106518032A (en) * | 2016-11-25 | 2017-03-22 | 贵州欧玛陶瓷有限责任公司 | Water-permeable brick and preparation method thereof |
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CN101182185A (en) * | 2007-12-06 | 2008-05-21 | 福建省晋江协隆陶瓷有限公司 | Outdoor ceramic permeable brick and preparation method thereof |
CN102070343A (en) * | 2010-10-12 | 2011-05-25 | 厦门三荣陶瓷开发有限公司 | Permeable brick and production method thereof |
CN104276800A (en) * | 2014-09-10 | 2015-01-14 | 李勇 | Preparation method of water filter brick |
CN105753504A (en) * | 2016-01-28 | 2016-07-13 | 广东省建筑科学研究院集团股份有限公司 | Ceramic water permeable brick produced by utilizing ceramic waste material and straw and preparation method for ceramic water permeable brick |
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2016
- 2016-08-11 CN CN201610653991.2A patent/CN106146002A/en active Pending
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CN101182185A (en) * | 2007-12-06 | 2008-05-21 | 福建省晋江协隆陶瓷有限公司 | Outdoor ceramic permeable brick and preparation method thereof |
CN102070343A (en) * | 2010-10-12 | 2011-05-25 | 厦门三荣陶瓷开发有限公司 | Permeable brick and production method thereof |
CN104276800A (en) * | 2014-09-10 | 2015-01-14 | 李勇 | Preparation method of water filter brick |
CN105753504A (en) * | 2016-01-28 | 2016-07-13 | 广东省建筑科学研究院集团股份有限公司 | Ceramic water permeable brick produced by utilizing ceramic waste material and straw and preparation method for ceramic water permeable brick |
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许晓海等: "《耐火材料技术手册》", 31 January 2000, 冶金工业出版社 * |
Cited By (1)
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---|---|---|---|---|
CN106518032A (en) * | 2016-11-25 | 2017-03-22 | 贵州欧玛陶瓷有限责任公司 | Water-permeable brick and preparation method thereof |
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