CN106140714A - The circulating micro-nano air-bubble of kinetic pump washes out the method and device of hydrology thing - Google Patents

The circulating micro-nano air-bubble of kinetic pump washes out the method and device of hydrology thing Download PDF

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CN106140714A
CN106140714A CN201610463310.6A CN201610463310A CN106140714A CN 106140714 A CN106140714 A CN 106140714A CN 201610463310 A CN201610463310 A CN 201610463310A CN 106140714 A CN106140714 A CN 106140714A
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micro
water
pump
nano
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CN106140714B (en
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杨庆峰
姜标
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Shanghai Advanced Research Institute of CAS
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B08CLEANING
    • B08BCLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
    • B08B3/00Cleaning by methods involving the use or presence of liquid or steam
    • B08B3/04Cleaning involving contact with liquid
    • B08B3/10Cleaning involving contact with liquid with additional treatment of the liquid or of the object being cleaned, e.g. by heat, by electricity or by vibration
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B08CLEANING
    • B08BCLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
    • B08B13/00Accessories or details of general applicability for machines or apparatus for cleaning
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B08CLEANING
    • B08BCLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
    • B08B3/00Cleaning by methods involving the use or presence of liquid or steam
    • B08B3/04Cleaning involving contact with liquid
    • B08B3/10Cleaning involving contact with liquid with additional treatment of the liquid or of the object being cleaned, e.g. by heat, by electricity or by vibration
    • B08B3/14Removing waste, e.g. labels, from cleaning liquid; Regenerating cleaning liquids

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Abstract

The invention discloses the circulating micro-nano air-bubble of a kind of kinetic pump and wash out the method and device of hydrology thing.Described method is: by air dissolved pump, air and water pressurization being mixed to get air-water mixture, this air-water mixture generates micro-nano air-bubble by micro-nano bubble generator again and is carried out water outlet historical relic.The present invention utilizes the efficient interfacial activity of micro-nano bubble, superpower osmosis and micro-explosion power, weakens the adhesion between historical relic and disease attachment impurity, is peeled off by the different diseases attachment on historical relic, thus complete the cleaning of water outlet historical relic.The inventive method and routine are added compared with soda acid chelating agent, the method such as ultrasonic, for pure physical cleaning method, while effectively cleaning and separating historical relic attachment concretion, to historical relic not damaged, processing procedure does not produce environmental contaminants, and efficiency is high, can be applied to the cleaning of water outlet historical relic on a large scale.

Description

The circulating micro-nano air-bubble of kinetic pump washes out the method and device of hydrology thing
Technical field
The present invention relates to water outlet historical relic cleaning technique field, be specifically related to a kind of circulating micro-nano air-bubble of kinetic pump clear Wash out the method and device of hydrology thing.
Background technology
Historical relic is non-renewable remnants, carries abundant human history cultural information.In very long historical floods, China outputs a large amount of ware to all over the world.Sea-freight is as a kind of traditional means of transportation, and the amount of having is big, safe and convenient And the advantage such as freight rate is cheap.But owing to perils of the sea shipwreck event happens occasionally, cause countless export trade ware be retained in boundless and indistinct greatly Depths, sea.Along with the development of cause of engaging in archaeological studies under water now, a large amount of ancient Chinese ceramics devices are salvaged from ocean.By right On ship, the restoration and protection research of ware historical relic, can preferably restore Historic original appearance, understands processing technology at that time, science and technology literary composition The historical informations such as change, commerce and trade.
The historical relics such as major part ocean effluent ceramic, through the length of calcareous thing such as sea water long period of soaking and marine organisms, sea mud etc. Phase acts on, the hard concretion that tight cementing formation volume is not of uniform size.The situation that these concretions change in extraneous humiture Under, the historical relic bodies such as the pottery wherein wrapped up will necessarily be produced physical property extruding and destroy, how before guaranteeing historical relic safety Putting, by these historical relics, from concretion, complete extraction is out, it has also become an extremely urgent difficult problem.Therefore, ocean water outlet is carried out Ware week body concretion cleaning research, for protection and the preservation of the ware of archaeological excavation water outlet under water, have general All over and profound significance.But so far, for the removal research of the coagulated material of cultural artifact surface attachment in shipwreck be not yet System is carried out.
Along with the unearthed water outlet of a large amount of rare cultural relics, companion's and come is heavy and the historical relic's protection of arduousness work.In order to Properly preserve historical relic, it is necessary to its restoration and protection carrying out necessity is processed.Old pottery and porcelain mending protection technological process includes: environment divides Analysis, on-site investigation, state estimation, cleaning and descaling, desalting processing, match-place be bonding, repairs defect, reinforces closure, and colour combination is done old etc. The selection of various technological means and enforcement.
Cleaning is the first step that water outlet historical relic's protection is repaired.Water outlet cultural relic diseases includes the deposition on soluble-salt, surface Thing, organic dirt etc..Wherein the biological disease on the difficulty soluble salt deposit of cultural artifact surface attachment, surface etc. are more difficult to remove, usually need Want mechanical cleaning, Chemical cleaning and ultrasonic waves for cleaning.But these methods are while taking out stains, it is also possible to porcelain Tire glaze produces corrosion, causes than more serious or potential damage.Further, these cleaning methods there is also various shortcoming, such as machine Tool method cannot meet high cleanliness cleaning requirement, and chemical cleaning method is easily caused environmental pollution, it is thus achieved that cleannes also The most limited, particularly when dirt composition complexity, it is necessary to select multiple abluent repeatedly to clean and be only possible to meet surface cleanness Requirement.Hu Dongbo of Peking University et al. have studied the impact on porcelain of the conventional chemical cleaning materials, finds generally, The abluent that cleansing power is strong, damage the strongest (Hu Dongbo, Zhang Hongyan, the conventional cleaning material impact on porcelain to porcelain Research, historical relic's protection and archaeology science, 2010,22 (1): 49-59).
Although ultrasonic cleaning process cleaning performance is pretty good, but the cleaning to submicron order dirt grain shows helpless, The size of rinse bath also limit scope and the complexity of cleaning object simultaneously, and the historical relic after cleaning needs rapid draing Also it is a great problem.And the laser cleaning technique occurred in recent years, the high accuracy being relatively suitable for little scope is cleaned, on a large scale The occasion effect of seriously corroded is limited.
Therefore, research and develop the cleaning method of the hardest concretion of different diseases on new applicable water outlet historical relic, right Historical relic carries out efficient lossless cleaning, significant for historical relic restoration and protection and recovery Historic original appearance.
Summary of the invention
It is an object of the invention to, it is provided that the circulating micro-nano air-bubble of a kind of kinetic pump wash out hydrology thing method and Device.Have developed the cleaning method of the hardest concretion of different diseases on new applicable water outlet historical relic, it is achieved to going out the hydrology The efficient lossless of thing cleans.
To achieve these goals, the technical solution used in the present invention is as follows:
The method that the circulating micro-nano air-bubble of a kind of kinetic pump washes out hydrology thing, the method is: will by air dissolved pump Air and water pressurization are mixed to get air-water mixture, and this air-water mixture generates micro-nano gas by micro-nano bubble generator again Soaked, utilize the micro-nano air-bubble generated that water outlet historical relic is carried out.
Preferably, during by air and water pressurization mixing, air mass flow is less than or equal to 10% with the ratio of discharge.
Preferably, the discharge pressure of described air dissolved pump is 0.2~0.4Mpa.
Preferably, when the micro-nano bubble electrical conductivity of water washing out hydrology thing is constant, terminate clear to water outlet historical relic Wash.
In technical scheme, by air dissolved pump by air and water pressurization mixing, the air-water mixture of generation leads to again Cross micro-nano bubble generator and generate micro-nano air-bubble, utilize the efficient interfacial activity of micro-nano bubble, superpower infiltration to make With and micro-explosion power, weaken historical relic and disease attachment impurity between adhesion, the different diseases attachment on historical relic is shelled From, thus complete the cleaning of water outlet historical relic.
The present invention also provides for the circulating micro-nano air-bubble of a kind of kinetic pump and washes out the device of hydrology thing, this device bag Include: pump priming funnel, pump priming valve, pump priming water pot, air dissolved pump, air needle valve, air flow sensor, check-valves, pressure pass Sensor, pH sensor, conductivity sensor, rinse bath, micro-nano bubble generator, accurate filter and flow control valve;
Described pump priming funnel and pump priming valve are installed on pump priming water pot, and pump priming water pot is connected with the water inlet of air dissolved pump;
Described air needle valve, air flow sensor and check-valves are installed on the air inlet of air dissolved pump, make air and water Can simultaneously enter and air dissolved pump carries out pressurization mixing;
Described pressure transducer, pH sensor and conductivity sensor are arranged in the water outlet pipeline of described air dissolved pump, use In monitoring system operational parameters;
Described micro-nano bubble generator is arranged on the end of the water outlet pipeline of air dissolved pump, and micro-nano bubble occurs Device is placed in bottom of rinse bath;
Described accurate filter is installed on the exit of described rinse bath, in order to filter out the granule produced in cleaning process Impurity;
It is connected, in order to regulate after described flow control valve is arranged on described accurate filter and with described pump priming water pot The flow of water in purging system, and make water be recycled to described pump priming water pot.
Preferably, described accurate filter is disc-type accurate filter, and filtering accuracy is 10 microns.
Preferably, in cleaning process, monitoring pH value and the electrical conductivity of micro-nano air-bubble, historical relic cleans to micro-nano bubble Till electrical conductivity of water is constant.
It is as follows that what water outlet historical relic was carried out by said apparatus is embodied as step:
The first step, at air dissolved pump water inlet, pump priming water pot, pump priming valve and pump priming funnel are installed, pacify at air dissolved pump air inlet Loaded check valve, air flow sensor and air needle valve, mix so that air and water can simultaneously enter to carry out in air dissolved pump pressurizeing Close.Air dissolved pump water outlet pipeline is installed pressure transducer, pH sensor and conductivity sensor, to monitor system operation ginseng Number.
Second step, micro-nano bubble generator is installed in the end of air dissolved pump water outlet pipeline, and is placed on cleaning Trench bottom.At rinse bath outlet, the disc-type accurate filter that filtering accuracy is 10 microns is installed, to filter out cleaning process The granule foreign of middle generation.After filter, installation flow control valve is with the flow of water in regulation purging system, and makes cleaning Water after filtering in groove is recycled to pump priming water pot.
3rd step, open pump priming valve, by pump priming funnel, tap water is filled pump priming water pot, be then shut off pump priming valve Door.In rinse bath, place water outlet historical relic to be cleaned, and in rinse bath, be filled with tap water make historical relic be immersed in water.
4th step, startup air dissolved pump, regulation air needle valve makes air mass flow at 0.05-0.1m3/ h, regulates flow simultaneously Control valve makes water circular flow be 0.5-1m3/ h, and make the ratio (volume under mode of operation of air mass flow and discharge Than) less than or equal to 10%, the discharge pressure of corresponding air dissolved pump is 0.2-0.4Mpa.After system is run 2-5 minute, in rinse bath The most transparent water gradually becomes vaporific micro-nano air-bubble.Historical relic cleans 2-70h in rinse bath, can batch cleaning, also Can continuous wash.In cleaning process, monitor pH value and the electrical conductivity of micro-nano air-bubble.Historical relic cleans to micro-nano air-bubble Till electrical conductivity is constant, now the disease attachment on historical relic is cleaned soft by micro-nano air-bubble, then carries out conventional mechanical Cleaning (as struck off with bamboo let), i.e. completes the cleaning of historical relic.
Compared with prior art, the invention have the benefit that
1, the water outlet historical relic cleaning method that the present invention uses, utilize micro-nano air-bubble to realize historical relic and deposit with difficulty soluble salt Thing, biological disease, sea mud and other metal and the separation of nonmetal poly-doped impurity.
2, the inventive method and routine are added compared with soda acid chelating agent, the method such as ultrasonic, for pure physical cleaning method, are having Effect is cleaned while separating historical relic attachment concretion, and to historical relic not damaged, processing procedure does not produce environmental contaminants, and efficiency is high. Air is dispersed in water the vaporific micro-nano air-bubble of formation with the form of micro-nano bubble by the inventive method, can be on a large scale The cleaning being applied to water outlet historical relic separates.
Accompanying drawing explanation
Fig. 1 is the structural representation that the circulating micro-nano air-bubble of kinetic pump of the present invention washes out hydrology thing device.
Fig. 2 a is water outlet historical relic picture before micro-nano bubbling-cleaning in the embodiment of the present invention 1.
Fig. 2 b is water outlet historical relic picture after micro-nano bubbling-cleaning in the embodiment of the present invention 1.
Fig. 3 is the X-ray fluorescence spectra figure of water outlet historical relic sample in the embodiment of the present invention 3.
Detailed description of the invention
With specific embodiment, technical scheme is described below in conjunction with the accompanying drawings.
Seeing Fig. 1, this figure is that the circulating micro-nano air-bubble of kinetic pump of the present invention washes out the structure of hydrology thing device and shows Being intended to, the water outlet historical relic related in following example cleans and all uses this device.As it is shown in figure 1, this device includes: pump priming funnel 1, pump priming valve 2, pump priming water pot 3, air needle valve 4, air flow sensor 5, check-valves 6, air dissolved pump 7, pressure transducer 8, pH sensor 9, conductivity sensor 10, rinse bath 11, micro-nano bubble generator 12, disc-type accurate filter 13 and flow Control valve 14.Wherein, pump priming funnel 1 and pump priming valve 2 are installed on pump priming water pot 3, pump priming water pot 3 and air dissolved pump 7 Water inlet is connected;Needle valve 4, air flow sensor 5 and check-valves 6 are installed on the air inlet of air dissolved pump 7 successively, make air and Water can simultaneously enter and carry out pressurization mixing in air dissolved pump.Pressure transducer 8, pH sensing are installed in air dissolved pump 7 water outlet pipeline Device 9 and conductivity sensor 10, in order to monitor system operational parameters.Micro-nano bubble generator 12 is placed in bottom rinse bath 11, micro- Nano-bubble generator 12 is connected with the water outlet pipeline end of air dissolved pump 7.Disc-type accurate filter 13 is installed on rinse bath The exit of 11, in order to filter out the granule foreign produced in cleaning process, the filtering accuracy of disc-type accurate filter 13 is 10 microns.Flow control valve 14 is installed after disc-type accurate filter 13, in order to regulate the flow of water in purging system, and Make water all be back to pump priming water pot 3 to be circulated.
Embodiment 1
The present embodiment is carried out for the deposit disease on water outlet high temperature sintering ware surface.
Choose No. 8 water outlet potsherds, a size of 47*31mm in the shipwreck of the South Sea 1, it has hard attachment, through Raman Spectrum analysis is mainly composed of calcium carbonate.Before potsherd cleaning as shown in Figure 2 a, it can be seen that this potsherd smooth surface, it is High temperature sintering forms.
At air dissolved pump water inlet, pump priming water pot, valve and funnel are installed, at air inlet, check-valves, air mass flow sensing are installed Device and needle valve.Pressure transducer, pH sensor and conductivity sensor are installed in air dissolved pump water outlet pipeline.Go out at air dissolved pump Mouth of a river line end installs micro-nano bubble generator, and is placed on bottom of rinse bath.Micro-nano bubble generator uses height (Ma Jun etc. are applied to the air-dissolution air-floated technology of oiliness sewage treatment, entirely to the speed micro-nano bubble generator of rotary type State's oil is economized on water and film Application meeting with energy saving of chemical industry water-saving technology exchanging meeting and chemical industry, and 2011, pp208-213).Cleaning Groove outlet installs the disc-type accurate filter that filtering accuracy is 10 microns, installs flow control valve after filter, and Water is made to be recycled to pump priming water pot.
Open pump priming valve, by pump priming funnel, tap water is filled pump priming water pot, be then shut off pump priming valve.Cleaning Groove is placed No. 8 water outlet potsherds, and is filled with tap water and makes historical relic be immersed in water.Start air dissolved pump, regulate air needle valve Make air mass flow at 0.1m3/ h, regulation flow control valve makes water circular flow be 1m simultaneously3/ h, the water outlet pressure of corresponding air dissolved pump Power is 0.4Mpa, makes air and water can simultaneously enter in air dissolved pump and carries out pressurization mixing.After system is run 2 minutes, in rinse bath The most transparent water gradually becomes vaporific micro-nano air-bubble.Historical relic is continuous wash 2h in rinse bath.In cleaning process, prison The pH value of micrometer nanobubble water is between 7-8.After historical relic cleans 2h, micro-nano bubble electrical conductivity of water is 500 μ S/cm and protects Holding constant, now the disease attachment on historical relic is cleaned soft by micro-nano air-bubble, strikes off stripping attachment gently with bamboo let Thing, completes the cleaning of historical relic, and the potsherd after cleaning is as shown in Figure 2 b.
No. 8 water outlet potsherds are after micro-nano bubble method is cleaned, according to " Movable Cultural Relics damage assessment technical regulation " literary composition Thing protection industry standard (WW/T 0056-2014, WW/T 0056-2014), uses aberration, low in glossiness and surface damage etc. to refer to Mark and the situation of historical relic before and after cleaning is carried out safety evaluation.Result shows, aberration is 3.21 (this value is just thought less than 5 without becoming Change), low in glossiness is 0.4 (this value just thinks unchanged less than 1), and microscopic analysis shows that potsherd surface glaze is without substantially in addition Change, this shows No. 8 water outlet potsherd surfaces not damaged after micro-nano air-bubble cleans.
This example demonstrates that, micro-nano bubble method for cleaning the deposit disease on water outlet high temperature sintering ware surface is Safely and effectively.
Embodiment 2
The present embodiment is carried out for the deposit disease on water outlet low-temperature sintered ceramics device surface.
Choose No. 14 water outlet potsherds, a size of 45*45mm in the shipwreck of the South Sea 1, it has hard attachment, through Raman Spectrum analysis is mainly composed of calcium carbonate.From this potsherd outward appearance it can be seen that this potsherd rough surface, be low-temperature sintering and Become.
At air dissolved pump water inlet, pump priming water pot, valve and funnel are installed, at air inlet, check-valves, air mass flow sensing are installed Device and needle valve.Pressure transducer, pH sensor and conductivity sensor are installed in air dissolved pump water outlet pipeline.Go out at air dissolved pump Mouth of a river line end installs micro-nano bubble generator, and is placed on bottom of rinse bath.Micro-nano bubble generator uses height The speed micro-nano bubble generator of rotary type.At rinse bath outlet, the disc-type secondary filter that filtering accuracy is 10 microns is installed Device, installs flow control valve, and makes water be recycled to pump priming water pot after filter.
Open pump priming valve, by pump priming funnel, tap water is filled pump priming water pot, be then shut off pump priming valve.Cleaning Groove is placed No. 14 water outlet potsherds, and is filled with tap water and makes historical relic be immersed in water.Start air dissolved pump, regulate air needle valve Make air mass flow at 0.06m3/ h, regulation flow control valve makes water circular flow be 0.7m simultaneously3/ h, going out of corresponding air dissolved pump Water pressure is 0.3Mpa, makes air and water can simultaneously enter in air dissolved pump and carries out pressurization mixing.After system is run 3 minutes, clean Water the most transparent in groove gradually becomes vaporific micro-nano air-bubble.Historical relic is continuous wash 30h in rinse bath.Cleaning process In, monitor the pH value of micro-nano air-bubble between 7-8.After historical relic cleaning 30h, micro-nano bubble electrical conductivity of water is 650 μ S/ Cm also keeps constant, and now the disease attachment on historical relic is soft by micro-nano air-bubble, strikes off stripping gently with bamboo let attached Thing, complete the cleaning of historical relic.
No. 14 water outlet potsherds are after micro-nano bubble method is cleaned, according to " Movable Cultural Relics damage assessment technical regulation " literary composition Thing protection industry standard (WW/T 0056-2014, WW/T 0056-2014), uses aberration, low in glossiness and surface damage etc. to refer to Mark and the situation of historical relic before and after cleaning is carried out safety evaluation.Result shows, aberration is 3.68 (this value is just thought less than 5 without becoming Change), low in glossiness is 0.2 (this value just thinks unchanged less than 1), and microscopic analysis shows that potsherd surface glaze is without substantially in addition Change, this shows No. 14 water outlet potsherd surfaces not damaged after micro-nano air-bubble cleans.
This example demonstrates that, micro-nano bubble method for cleaning the deposit disease on water outlet low-temperature sintered ceramics device surface is Safely and effectively.
Embodiment 3
The present embodiment has the water outlet ware of metal attack deposit disease to be carried out for surface.
Choose No. 18 water outlet potsherds, a size of 95*59mm in the shipwreck of the South Sea 1, it has metal attack thing, penetrates through X Line spectrofluorimetry, detects the ferrum element that relative amount is higher, sees Fig. 3, and this figure is the X-ray of No. 18 water outlet potsherds Fluorescence spectrum figure.
At air dissolved pump water inlet, pump priming water pot, valve and funnel are installed, at air inlet, check-valves, air mass flow sensing are installed Device and needle valve.Pressure transducer, pH sensor and conductivity sensor are installed in air dissolved pump water outlet pipeline.Go out at air dissolved pump Mouth of a river line end installs micro-nano bubble generator, and is placed on bottom of rinse bath.Micro-nano bubble generator uses height The speed micro-nano bubble generator of rotary type.At rinse bath outlet, the disc-type secondary filter that filtering accuracy is 10 microns is installed Device, installs flow control valve, and makes water be recycled to pump priming water pot after filter.
Open pump priming valve, by pump priming funnel, tap water is filled pump priming water pot, be then shut off pump priming valve.Cleaning Groove is placed No. 18 water outlet potsherds, and is filled with tap water and makes historical relic be immersed in water.Start air dissolved pump, regulate air needle valve Make air mass flow at 0.05m3/ h, regulation flow control valve makes water circular flow be 0.5m simultaneously3/ h, going out of corresponding air dissolved pump Water pressure is 0.2Mpa, makes air and water can simultaneously enter in air dissolved pump and carries out pressurization mixing.After system is run 5 minutes, clean Water the most transparent in groove gradually becomes vaporific micro-nano air-bubble.Historical relic is batch cleaning 70h in rinse bath.Cleaning process In, monitor the pH value of micro-nano air-bubble between 7-8.After historical relic cleaning 70h, micro-nano bubble electrical conductivity of water is 600 μ S/ Cm also keeps constant, and now the disease attachment on historical relic is soft by micro-nano air-bubble, strikes off stripping gently with bamboo let attached Thing, complete the cleaning of historical relic.
No. 18 water outlet potsherds are after micro-nano bubble method is cleaned, according to " Movable Cultural Relics damage assessment technical regulation " literary composition Thing protection industry standard (WW/T 0056-2014, WW/T 0056-2014), uses aberration, low in glossiness and surface damage etc. to refer to Mark and the situation of historical relic before and after cleaning is carried out safety evaluation.Result shows, aberration is 1.62 (this value is just thought less than 5 without becoming Change), low in glossiness is 0.1 (this value just thinks unchanged less than 1), and microscopic analysis shows that potsherd surface glaze is without substantially in addition Change, this shows No. 18 water outlet potsherd surfaces not damaged after micro-nano air-bubble cleans.
This example demonstrates that, micro-nano bubble method for washing out the metal attack deposit disease on ceramic water device surface is Safely and effectively.
Embodiment 4
The present embodiment is carried out with the water outlet ware of crack disease for surface.
Choose in the shipwreck of the South Sea 1 No. 2 and go out the implements that ceramic water is an incompleteness, diameter 69mm, high 37mm, it has 6 Crack different in size, fracture width is 0.074-0.076mm.This sample surfaces is with metal attack deposit disease.
At air dissolved pump water inlet, pump priming water pot, valve and funnel are installed, at air inlet, check-valves, air mass flow sensing are installed Device and needle valve.Pressure transducer, pH sensor and conductivity sensor are installed in air dissolved pump water outlet pipeline.Go out at air dissolved pump Mouth of a river line end installs micro-nano bubble generator, and is placed on bottom of rinse bath.Micro-nano bubble generator uses height The speed micro-nano bubble generator of rotary type.At rinse bath outlet, the disc-type secondary filter that filtering accuracy is 10 microns is installed Device, installs flow control valve, and makes water be recycled to pump priming water pot after filter.
Open pump priming valve, by pump priming funnel, tap water is filled pump priming water pot, be then shut off pump priming valve.Cleaning Groove is placed No. 2 water outlet potsherds, and is filled with tap water and makes historical relic be immersed in water.Start air dissolved pump, regulate air needle valve Make air mass flow at 0.1m3/ h, regulation flow control valve makes water circular flow be 1m simultaneously3/ h, the water outlet pressure of corresponding air dissolved pump Power is 0.4Mpa, makes air and water can simultaneously enter in air dissolved pump and carries out pressurization mixing.After system is run 2 minutes, in rinse bath The most transparent water gradually becomes vaporific micro-nano air-bubble.Historical relic is continuous wash 10h in rinse bath.In cleaning process, Monitor the pH value of micro-nano air-bubble between 7-8.Historical relic clean micro-nano bubble electrical conductivity of water after 10h be 680 μ S/cm also Keeping constant, now the disease attachment on historical relic is soft by micro-nano air-bubble, strikes off stripping attachment gently with bamboo let, Complete the cleaning of historical relic.
No. 2 water outlet potsherds are after micro-nano bubble method is cleaned, according to " Movable Cultural Relics damage assessment technical regulation " literary composition Thing protection industry standard (WW/T 0056-2014, WW/T 0056-2014), uses aberration, low in glossiness and surface damage etc. to refer to Mark and the situation of historical relic before and after cleaning is carried out safety evaluation.Result shows, aberration is 3.23 (this value is just thought less than 5 without becoming Change), low in glossiness is 0.4 (this value just thinks unchanged less than 1), and microscopic analysis shows that potsherd surface glaze is without substantially in addition Change, fracture width is 0.074-0.076mm, and without significant change, this shows that No. 2 water outlet potsherd surfaces are through micro-nano air-bubble Not damaged after cleaning.
This example demonstrates that, micro-nano bubble method is safe and effective for cleaning the water outlet ware with crack disease 's.
Above are only the preferred embodiments of the present invention, the present invention is not limited in the content of embodiment.For in this area Technical staff for, can have various change and change in the range of technical scheme, any change made and Change, all within scope.

Claims (7)

1. the method that the circulating micro-nano air-bubble of kinetic pump washes out hydrology thing, the method is: by air dissolved pump by sky Gas and water pressurization are mixed to get air-water mixture, and this air-water mixture generates micro-nano bubble by micro-nano bubble generator again Water, utilizes the micro-nano air-bubble generated to be carried out water outlet historical relic.
2. the method that the circulating micro-nano air-bubble of kinetic pump as claimed in claim 1 washes out hydrology thing, it is characterised in that: During by air and water pressurization mixing, air mass flow is less than or equal to 10% with the ratio of discharge.
3. the method that the circulating micro-nano air-bubble of kinetic pump as claimed in claim 1 washes out hydrology thing, it is characterised in that: The discharge pressure of described air dissolved pump is 0.2~0.4Mpa.
4. the method that the circulating micro-nano air-bubble of kinetic pump as claimed in claim 1 washes out hydrology thing, it is characterised in that: When the micro-nano bubble electrical conductivity of water washing out hydrology thing is constant, terminate the cleaning to water outlet historical relic.
5. the circulating micro-nano air-bubble of kinetic pump washes out a device for hydrology thing, and this device includes: pump priming funnel, pump priming Valve, pump priming water pot, air dissolved pump, air needle valve, air flow sensor, check-valves, pressure transducer, pH sensor, electricity Derivative sensor, rinse bath, micro-nano bubble generator, accurate filter and flow control valve;
Described pump priming funnel and pump priming valve are installed on pump priming water pot, and pump priming water pot is connected with the water inlet of air dissolved pump;
Described air needle valve, air flow sensor and check-valves are installed on the air inlet of air dissolved pump, make air and water energy same Time enter in air dissolved pump and carry out pressurization mixing;
Described pressure transducer, pH sensor and conductivity sensor are arranged in the water outlet pipeline of described air dissolved pump, are used for supervising Examining system operational factor;
Described micro-nano bubble generator is arranged on the end of the water outlet pipeline of air dissolved pump, and micro-nano bubble generator is put In bottom of rinse bath;
Described accurate filter is installed on the exit of described rinse bath, miscellaneous in order to filter out the granule produced in cleaning process Matter;
It is connected, in order to regulate cleaning after described flow control valve is arranged on described accurate filter and with described pump priming water pot The flow of water in system, and make water be recycled to described pump priming water pot.
6. the circulating micro-nano air-bubble of kinetic pump as claimed in claim 5 washes out the device of hydrology thing, it is characterised in that: Described accurate filter is disc-type accurate filter, and filtering accuracy is 10 microns.
7. the circulating micro-nano air-bubble of kinetic pump as claimed in claim 5 washes out the device of hydrology thing, it is characterised in that: In cleaning process, monitoring pH value and the electrical conductivity of micro-nano air-bubble, historical relic cleans to micro-nano bubble electrical conductivity of water constant Till.
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CN107217270A (en) * 2017-06-30 2017-09-29 天津森罗科技股份有限公司 A kind of airtight aerating device of water outlet historical relic desalination
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CN109186317A (en) * 2018-08-28 2019-01-11 王伟 A kind of condenser cleaning equipment
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CN111282904A (en) * 2020-03-28 2020-06-16 天津全诚桓金环保科技有限公司 Environment-friendly cleaning process based on micro-nano bubbles
CN115069673A (en) * 2022-08-18 2022-09-20 智程半导体设备科技(昆山)有限公司 Process strengthening system for semiconductor tank type cleaning equipment

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