CN109453671A - It is a kind of to slow down the stifled process of reverse osmosis membrane dirt - Google Patents

It is a kind of to slow down the stifled process of reverse osmosis membrane dirt Download PDF

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Publication number
CN109453671A
CN109453671A CN201811423611.1A CN201811423611A CN109453671A CN 109453671 A CN109453671 A CN 109453671A CN 201811423611 A CN201811423611 A CN 201811423611A CN 109453671 A CN109453671 A CN 109453671A
Authority
CN
China
Prior art keywords
reverse osmosis
cleaning
osmosis membrane
dirt
cartridge filter
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201811423611.1A
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Chinese (zh)
Inventor
李开光
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Qianxi Guizhou Coal Chemical Investment Co Ltd
Original Assignee
Qianxi Guizhou Coal Chemical Investment Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Qianxi Guizhou Coal Chemical Investment Co Ltd filed Critical Qianxi Guizhou Coal Chemical Investment Co Ltd
Priority to CN201811423611.1A priority Critical patent/CN109453671A/en
Publication of CN109453671A publication Critical patent/CN109453671A/en
Withdrawn legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D61/00Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/02Reverse osmosis; Hyperfiltration ; Nanofiltration
    • B01D61/08Apparatus therefor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D65/00Accessories or auxiliary operations, in general, for separation processes or apparatus using semi-permeable membranes
    • B01D65/02Membrane cleaning or sterilisation ; Membrane regeneration
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D65/00Accessories or auxiliary operations, in general, for separation processes or apparatus using semi-permeable membranes
    • B01D65/08Prevention of membrane fouling or of concentration polarisation

Abstract

Slow down the stifled process of reverse osmosis membrane dirt the invention discloses a kind of, before the reverse osmosis host water inlet of cartridge filter, chemical cleaning is carried out to cartridge filter reverse osmosis membrane and water rinses, comprising the following steps: (1) clean, the reverse osmosis product water without free chlorine is squeezed into pressure vessel with pump and discharges a few minutes;(2) cleaning solution is prepared in cleaning case with clean product water;(3) cleaning solution is recycled 1 hour in pressure vessel;(4) it empties cleaning case and is rinsed;(5) step (1) operation is repeated;(6) the reverse osmosis host of cartridge filter is run under product water discharging valve opening state.The present invention is before the water inlet of reverse osmosis host, and using the effective treatment process of synthesis, emphasis improves the removal rate of hardness, basicity;Carbonate scale pollution and microbial contamination are reduced, reverse osmosis membrane dirt is reduced and blocks up, propose the high yield water rate of recovery;And whole set equipment is compact-sized, easy to operate, operating cost economy.

Description

It is a kind of to slow down the stifled process of reverse osmosis membrane dirt
Technical field
It is specifically a kind of to slow down the stifled process of reverse osmosis membrane dirt the present invention relates to reverse osmosis membrane group cleaning method.
Background technique
Hyperfiltration is a kind of membrane separation technique, it has also become a kind of chemical engineering unit operation of maturation.Reverse osmosis technology due to Low energy consumption for separation process, without phase-change, without other chemicals, without secondary environmental pollution, equipment is simple, operating cost is low and dimension It repairs conveniently, therefore, it is widely used for people.Currently, anti-penetration wastewater disposal has been widely used for various industries, can both mention For industrial waters such as chemical industry, medicine, electronics, light industry and food, and brackish water desalination can be used for and produce domestic water.
Its surface will appear dirt when reverse osmosis membrane is used for a long time, it is therefore desirable to carry out to the dirt on reverse osmosis membrane It is stifled to place reverse osmosis membrane dirt for cleaning.
Summary of the invention
Slow down the stifled process of reverse osmosis membrane dirt the purpose of the present invention is to provide a kind of, to solve above-mentioned background technique The problem of middle proposition.
To achieve the above object, the invention provides the following technical scheme:
It is a kind of to slow down the stifled process of reverse osmosis membrane dirt, before the reverse osmosis host water inlet of cartridge filter, to cartridge filter Reverse osmosis membrane carries out chemical cleaning and water and rinses, and when cleaning recycles cleaning solution with low pressure and mass flow in the high-pressure side of film, protects Pacify filter reverse-osmosis membrane element cleaning the following steps are included:
(1) clean, the reverse osmosis product water without free chlorine is squeezed into pressure vessel side by side from cleaning case or corresponding water source with pump Put a few minutes;
(2) cleaning solution is prepared in cleaning case with clean product water;
(3) cleaning solution is recycled to 1 hour or preset time in pressure vessel;
(4) it after cleaning is completed, empties cleaning case and is rinsed, clean product water is then full of into cleaning case in case of under One step is rinsed;
(5) step (1) operation is repeated, the clean, product water without free chlorine is squeezed into pressure from cleaning case or corresponding water source with pump In container and discharge a few minutes;
(6) after rinsing cartridge filter reverse osmosis membrane, it is reverse osmosis that cartridge filter is run under product water discharging valve opening state Host, until product water cleaning, non-foam or without cleaning agent.
As a further solution of the present invention: the scavenging period of the cartridge filter reverse osmosis membrane is 15-30 minutes.
As a further solution of the present invention: in step (3), when for 8 inches or 8.5 inches of pressure vessels, flow velocity It is 35-40 gallon per minute, i.e., 133-151 liters/min, when for 6 inches of pressure vessels, flow velocity is 15-20 gallon per minute, i.e., 57-76 liters/min, when for 4 inches of pressure vessels, flow velocity is 9-10 gallon per minute, i.e., 34-38 liters/min.
As a further solution of the present invention: the dirt on the cartridge filter reverse-osmosis membrane element includes calcium carbonate Dirt, calcium sulfate scale, metal oxide dirt, silicon dirt and organic sediment.
As the present invention further scheme: maximum temperature is 40 DEG C when cleaning, required articles in every 100 gallons plus Enter meter, solution is prepared using the reverse osmosis product water without free chlorine when preparing cleaning solution and is uniformly mixed.
Compared with prior art, the beneficial effects of the present invention are:
The present invention is before the water inlet of reverse osmosis host, and using the effective treatment process of synthesis, emphasis improves the removal of hardness, basicity Rate;Carbonate scale pollution and microbial contamination are reduced, reverse osmosis membrane dirt is reduced and blocks up, propose the high yield water rate of recovery;And whole set equipment knot Structure is compact, easy to operate, operating cost economy.
Specific embodiment
The technical solution of the patent is explained in further detail With reference to embodiment.
Embodiment 1
It is a kind of to slow down the stifled process of reverse osmosis membrane dirt, before the reverse osmosis host water inlet of cartridge filter, to cartridge filter Reverse osmosis membrane carries out chemical cleaning and water and rinses, and when cleaning recycles cleaning solution with low pressure and mass flow in the high-pressure side of film, institute Stating the dirt on cartridge filter reverse-osmosis membrane element includes calcium carbonate scale, calcium sulfate scale, metal oxide dirt, silicon dirt and organic Deposit, the scavenging period of the cartridge filter reverse osmosis membrane are 15 minutes, the cleaning of cartridge filter reverse-osmosis membrane element Hold the following steps are included: clean, the reverse osmosis product water without free chlorine is squeezed into pressure from cleaning case or corresponding water source with pump by (1) In device and discharge a few minutes;(2) cleaning solution is prepared in cleaning case with clean product water;(3) by cleaning solution in pressure vessel 1 hour or the preset time of middle circulation, when for 8 inches or 8.5 inches of pressure vessels, flow velocity is 35 gallon per minute, I.e. 133 liters/min, when for 6 inches of pressure vessels, flow velocity be 15 gallon per minute, i.e., 57 liters/min, for 4 inches of pressure When container, flow velocity is 9 gallon per minute, i.e., 34 liters/min;(4) it after cleaning is completed, empties cleaning case and is rinsed, then Into cleaning case full of clean product water in case rinsing in next step;(5) repetition step (1) operation, with pump by clean, nothing is free The product water of chlorine is squeezed into pressure vessel from cleaning case or corresponding water source and discharges a few minutes;(6) cartridge filter reverse osmosis is rinsed After permeable membrane, the reverse osmosis host of cartridge filter is run under product water discharging valve opening state, until product water cleaning, non-foam Or without cleaning agent;Maximum temperature is 40 DEG C when cleaning, and required articles are adopted when preparing cleaning solution so that meter is added in every 100 gallons Solution is prepared with the reverse osmosis product water without free chlorine and is uniformly mixed.
Embodiment 3
It is a kind of to slow down the stifled process of reverse osmosis membrane dirt, before the reverse osmosis host water inlet of cartridge filter, to cartridge filter Reverse osmosis membrane carries out chemical cleaning and water and rinses, and when cleaning recycles cleaning solution with low pressure and mass flow in the high-pressure side of film, institute Stating the dirt on cartridge filter reverse-osmosis membrane element includes calcium carbonate scale, calcium sulfate scale, metal oxide dirt, silicon dirt and organic Deposit, the scavenging period of the cartridge filter reverse osmosis membrane are 20 minutes, the cleaning of cartridge filter reverse-osmosis membrane element Hold the following steps are included: clean, the reverse osmosis product water without free chlorine is squeezed into pressure from cleaning case or corresponding water source with pump by (1) In device and discharge a few minutes;(2) cleaning solution is prepared in cleaning case with clean product water;(3) by cleaning solution in pressure vessel 1 hour or the preset time of middle circulation, when for 8 inches or 8.5 inches of pressure vessels, flow velocity is 32 gallon per minute, I.e. 140 liters/min, when for 6 inches of pressure vessels, flow velocity be 18 gallon per minute, i.e., 67 liters/min, for 4 inches of pressure When container, flow velocity is 9 gallon per minute, i.e., 34 liters/min;(4) it after cleaning is completed, empties cleaning case and is rinsed, then Into cleaning case full of clean product water in case rinsing in next step;(5) repetition step (1) operation, with pump by clean, nothing is free The product water of chlorine is squeezed into pressure vessel from cleaning case or corresponding water source and discharges a few minutes;(6) cartridge filter reverse osmosis is rinsed After permeable membrane, the reverse osmosis host of cartridge filter is run under product water discharging valve opening state, until product water cleaning, non-foam Or without cleaning agent;Maximum temperature is 40 DEG C when cleaning, and required articles are adopted when preparing cleaning solution so that meter is added in every 100 gallons Solution is prepared with the reverse osmosis product water without free chlorine and is uniformly mixed.
Embodiment 3
It is a kind of to slow down the stifled process of reverse osmosis membrane dirt, before the reverse osmosis host water inlet of cartridge filter, to cartridge filter Reverse osmosis membrane carries out chemical cleaning and water and rinses, and when cleaning recycles cleaning solution with low pressure and mass flow in the high-pressure side of film, institute Stating the dirt on cartridge filter reverse-osmosis membrane element includes calcium carbonate scale, calcium sulfate scale, metal oxide dirt, silicon dirt and organic Deposit, the scavenging period of the cartridge filter reverse osmosis membrane are 30 minutes, the cleaning of cartridge filter reverse-osmosis membrane element Hold the following steps are included: clean, the reverse osmosis product water without free chlorine is squeezed into pressure from cleaning case or corresponding water source with pump by (1) In device and discharge a few minutes;(2) cleaning solution is prepared in cleaning case with clean product water;(3) by cleaning solution in pressure vessel 1 hour or the preset time of middle circulation, when for 8 inches or 8.5 inches of pressure vessels, flow velocity is 40 gallon per minute, I.e. 151 liters/min, when for 6 inches of pressure vessels, flow velocity be 20 gallon per minute, i.e., 76 liters/min, for 4 inches of pressure When container, flow velocity is 10 gallon per minute, i.e., 38 liters/min;(4) it after cleaning is completed, empties cleaning case and is rinsed, so Full of clean product water in case rinsing in next step in backward cleaning case;(5) repeat step (1) operation, with pump will it is clean, without trip It is squeezed into pressure vessel from the product water of chlorine from cleaning case or corresponding water source and discharges a few minutes;(6) it is anti-to rinse cartridge filter After permeable membrane, under product water discharging valve opening state run the reverse osmosis host of cartridge filter, until product water cleaning, it is still Foam or without cleaning agent;Maximum temperature is 40 DEG C when cleaning, and required articles are meter to be added in every 100 gallons, when preparing cleaning solution Solution is prepared using the reverse osmosis product water without free chlorine and is uniformly mixed.
The preferred embodiment of the patent is described in detail above, but this patent is not limited to above-mentioned embodiment party Formula within the knowledge of one of ordinary skill in the art can also be under the premise of not departing from this patent objective It makes a variety of changes.

Claims (5)

1. a kind of slow down the stifled process of reverse osmosis membrane dirt, before the reverse osmosis host water inlet of cartridge filter, security personnel are filtered Device reverse osmosis membrane carries out chemical cleaning and water and rinses, and when cleaning recycles cleaning solution with low pressure and mass flow in the high-pressure side of film, It is characterized in that, the cleaning of cartridge filter reverse-osmosis membrane element the following steps are included:
Clean, the reverse osmosis product water without free chlorine is squeezed into pressure vessel and discharged several from cleaning case or corresponding water source with pump Minute;
Cleaning solution is prepared in cleaning case with clean product water;
Cleaning solution is recycled to 1 hour or preset time in pressure vessel;
It after cleaning is completed, empties cleaning case and is rinsed, be then full of clean product water into cleaning case in case next Step is rinsed;
Step (1) operation is repeated, the clean, product water without free chlorine is squeezed into pressure vessel from cleaning case or corresponding water source with pump In and discharge a few minutes;
After rinsing cartridge filter reverse osmosis membrane, the reverse osmosis master of cartridge filter is run under product water discharging valve opening state Machine, until product water cleaning, non-foam or without cleaning agent.
2. according to claim 1 slow down the stifled process of reverse osmosis membrane dirt, which is characterized in that the cartridge filter The scavenging period of reverse osmosis membrane is 15-30 minutes.
3. according to claim 1 slow down the stifled process of reverse osmosis membrane dirt, which is characterized in that in step (3), for 8 inches or when 8.5 inches of pressure vessels, flow velocity is 35-40 gallon per minute, i.e., 133-151 liters/min, for 6 inches of pressure When container, flow velocity is 15-20 gallon per minute, i.e., 57-76 liters/min, when for 4 inches of pressure vessels, flow velocity adds for 9-10 Logical sequence/minute, i.e., 34-38 liters/min.
4. according to claim 1 slow down the stifled process of reverse osmosis membrane dirt, which is characterized in that the cartridge filter Dirt on reverse-osmosis membrane element includes calcium carbonate scale, calcium sulfate scale, metal oxide dirt, silicon dirt and organic sediment.
5. according to claim 1 slow down the stifled process of reverse osmosis membrane dirt, which is characterized in that maximum temperature when cleaning It is 40 DEG C, required articles are meter to be added in every 100 gallons, using the reverse osmosis product water for being free of free chlorine when preparing cleaning solution It prepares solution and is uniformly mixed.
CN201811423611.1A 2018-11-27 2018-11-27 It is a kind of to slow down the stifled process of reverse osmosis membrane dirt Withdrawn CN109453671A (en)

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CN201811423611.1A CN109453671A (en) 2018-11-27 2018-11-27 It is a kind of to slow down the stifled process of reverse osmosis membrane dirt

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201811423611.1A CN109453671A (en) 2018-11-27 2018-11-27 It is a kind of to slow down the stifled process of reverse osmosis membrane dirt

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112657340A (en) * 2020-12-11 2021-04-16 山东誉盛化工有限公司 Cleaning method of reverse osmosis membrane

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112657340A (en) * 2020-12-11 2021-04-16 山东誉盛化工有限公司 Cleaning method of reverse osmosis membrane

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Application publication date: 20190312