CN106140714B - The circulating micro-nano air-bubble of kinetic pump washes out the method and device of hydrology object - Google Patents

The circulating micro-nano air-bubble of kinetic pump washes out the method and device of hydrology object Download PDF

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Publication number
CN106140714B
CN106140714B CN201610463310.6A CN201610463310A CN106140714B CN 106140714 B CN106140714 B CN 106140714B CN 201610463310 A CN201610463310 A CN 201610463310A CN 106140714 B CN106140714 B CN 106140714B
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air
micro
nano
bubble
pump
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CN106140714A (en
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杨庆峰
姜标
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Shanghai Advanced Research Institute of CAS
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B08CLEANING
    • B08BCLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
    • B08B3/00Cleaning by methods involving the use or presence of liquid or steam
    • B08B3/04Cleaning involving contact with liquid
    • B08B3/10Cleaning involving contact with liquid with additional treatment of the liquid or of the object being cleaned, e.g. by heat, by electricity or by vibration
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B08CLEANING
    • B08BCLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
    • B08B13/00Accessories or details of general applicability for machines or apparatus for cleaning
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B08CLEANING
    • B08BCLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
    • B08B3/00Cleaning by methods involving the use or presence of liquid or steam
    • B08B3/04Cleaning involving contact with liquid
    • B08B3/10Cleaning involving contact with liquid with additional treatment of the liquid or of the object being cleaned, e.g. by heat, by electricity or by vibration
    • B08B3/14Removing waste, e.g. labels, from cleaning liquid; Regenerating cleaning liquids

Abstract

The invention discloses the method and devices that a kind of circulating micro-nano air-bubble of kinetic pump washes out hydrology object.The method is:Air and water pressurization are mixed to get air-water mixture by air dissolved pump, which generates micro-nano air-bubble by micro-nano bubble generator again and cleaned to water outlet historical relic.The present invention utilizes efficient interfacial activity, superpower osmosis and the micro-explosion power of micro-nano bubble, weakens the binding force between historical relic and disease attachment impurity, the different diseases attachment on historical relic is removed, to complete the cleaning of water outlet historical relic.The method of the present invention is pure physical cleaning method compared with routinely the methods of addition soda acid complexing agent, ultrasound, while effective cleaning separation historical relic adheres to coagulation, it is not damaged to historical relic, processing procedure not generation environment pollutant, it is efficient, the cleaning of water outlet historical relic can be applied on a large scale.

Description

The circulating micro-nano air-bubble of kinetic pump washes out the method and device of hydrology object
Technical field
The present invention relates to water outlet historical relic cleaning technique fields, and in particular to a kind of circulating micro-nano air-bubble of kinetic pump is clear Wash out the method and device of hydrology object.
Background technology
Historical relic is non-renewable remnants, carries abundant human history cultural information.In very long historical floods, China to outputing a large amount of wares all over the world.Sea-freight has amount big, safe and convenient as a kind of traditional means of transportation And the advantages such as freight rate is cheap.But since perils of the sea shipwreck event happens occasionally, countless export trade wares are caused to be retained in boundless and indistinct big Extra large depths.With the development of current underwater archaeology cause, a large amount of ancient Chinese ceramics devices are salvaged from ocean.By right The restoration and protection research of ware historical relic, can preferably restore Historic original appearance on ship, and manufacture craft, the science and technology understood at that time is literary The historical informations such as change, commerce and trade.
The historical relics such as most of ocean effluent ceramic, the length through the calcareous object such as seawater long period of soaking and marine organisms, ooze Phase acts on, close cementing formation volume hard coagulation not of uniform size.These coagulations are the case where extraneous humiture changes Under, physical extrudings will necessarily be generated to historical relics ontologies such as the ceramics that wherein wrap up and destroyed, how before ensuring that historical relic is safe It puts, by these historical relics, complete extraction comes out from coagulation, it has also become extremely urgent problem.Therefore, carry out ocean water outlet Ware week body coagulation cleaning research, for underwater archaeological excavation be discharged ware protection and preservation, have it is general All over and profound significance.However so far, the removal of the coagulated material adhered to for cultural artifact surface in shipwreck is studied System is carried out.
With the unearthed water outlet of a large amount of rare cultural relics, accompanied by is heavy and arduous historical relic's protection work.In order to Properly preserve historical relic, it is necessary to necessary restoration and protection processing is carried out to it.Old pottery and porcelain mending protection technological process include:Environment point Analysis, on-site investigation, status assessment, cleaning and descaling, desalting processing, match-place bonding, repairing defect, reinforce closure, colour combination is done old etc. The selection and implementation of various technological means.
Cleaning is to be discharged the first step of historical relic's protection reparation.Water outlet cultural relic diseases include soluble-salt, surface deposition Object, organic dirt etc..The biological disease of indissoluble salt deposit, surface that wherein cultural artifact surface adheres to etc. is more difficult to remove, usually needs Want mechanical cleaning, chemical cleaning and ultrasonic cleaning.However these methods are while taking out stains, it is also possible to porcelain Tire glaze generates corrosion, causes than more serious or potential damage.Also, there is also various shortcomings, such as machine for these cleaning methods Tool method cannot be satisfied high cleanliness cleaning requirement, and chemical cleaning method is easy to cause environmental pollution, the cleannes of acquisition It is very limited, especially when dirt composition complexity, it is necessary to select a variety of cleaning agents to clean repeatedly and be likely to meet surface cleanness Requirement.Hu Dongbo of Peking University et al. has studied influence of the common chemical cleaning materials to porcelain, finds under normal circumstances, The strong cleaning agent of cleaning ability, also very strong to the damage of porcelain (Hu Dongbo, Zhang Hongyan commonly use influence of the cleaning material to porcelain Research, historical relic's protection and archaeology science, 2010,22 (1):49-59).
Although ultrasonic cleaning process cleaning performance is pretty good, show helpless to the cleaning of submicron order dirt grain, The size of rinse bath also limits the range and complexity of cleaning object simultaneously, and the historical relic after cleaning needs rapid draing Also it is a great problem.And the laser cleaning technique occurred in recent years, relatively it is suitble to small-scale high-precision cleaning, for a wide range of The occasion effect of seriously corroded is limited.
Therefore, the cleaning method that different diseases on new suitable water outlet historical relic are especially hard coagulation is researched and developed, it is right Historical relic carries out efficient lossless cleaning, is of great significance for historical relic restoration and protection and recovery Historic original appearance.
Invention content
The object of the present invention is to provide a kind of circulating micro-nano air-bubble of kinetic pump wash out hydrology object method and Device.The cleaning method that different diseases on new suitable water outlet historical relic are especially hard coagulation is had developed, is realized to going out the hydrology The efficient lossless of object cleans.
To achieve the goals above, the technical solution adopted by the present invention is as follows:
A kind of method that the circulating micro-nano air-bubble of kinetic pump washes out hydrology object, this method are:It will by air dissolved pump Air and water pressurization are mixed to get air-water mixture, which generates micro-nano gas by micro-nano bubble generator again It is soaked, water outlet historical relic is cleaned using the micro-nano air-bubble of generation.
When preferably, by air and water pressurization mixing, the ratio of air mass flow and water flow is less than or equal to 10%.
Preferably, the discharge pressure of the air dissolved pump is 0.2~0.4Mpa.
Preferably, when wash out the conductivity of micro-nano air-bubble of hydrology object it is constant when, terminate to water outlet historical relic it is clear It washes.
In technical scheme of the present invention, by air dissolved pump by air and water pressurization mixing, the air-water mixture of generation leads to again It crosses micro-nano bubble generator and generates micro-nano air-bubble, made using the efficient interfacial activity of micro-nano bubble, superpower infiltration With and micro-explosion power, weaken historical relic and disease attachment impurity between binding force, the different diseases attachment on historical relic is shelled From to complete the cleaning of water outlet historical relic.
The present invention also provides the device that a kind of circulating micro-nano air-bubble of kinetic pump washes out hydrology object, the device packets It includes:Pump funnel, filling pump valve, filling water pumping tank, air dissolved pump, air needle valve, air flow sensor, check-valves, pressure is filled to pass Sensor, pH sensors, conductivity sensor, rinse bath, micro-nano bubble generator, accurate filter and flow control valve;
The filling pump funnel is installed on pump valve is filled on filling water pumping tank, is filled water pumping tank and is connected with the water inlet of air dissolved pump;
The air needle valve, air flow sensor and check-valves are installed on the air inlet of air dissolved pump, make air and water It can be simultaneously into carrying out pressurization mixing in air dissolved pump;
The pressure sensor, pH sensors and conductivity sensor are mounted on the water outlet pipe road of the air dissolved pump, use In monitoring system operational parameters;
The micro-nano bubble generator is mounted on the end of the water outlet pipeline of air dissolved pump, and micro-nano bubble occurs Device is placed in bottom of rinse bath;
The accurate filter is installed on the exit of the rinse bath, to filter out the particle generated in cleaning process Impurity;
The flow control valve, which is mounted on after the accurate filter and pumps tank with the filling, to be connected, to adjust The flow of water in cleaning system, and so that water is recycled to the filling and pump tank.
Preferably, the accurate filter is disc-type accurate filter, and filtering accuracy is 10 microns.
Preferably, in cleaning process, the pH value and conductivity of micro-nano air-bubble are monitored, historical relic is cleaned to micro-nano bubble Until the conductivity of water is constant.
The specific implementation step that above-mentioned apparatus cleans water outlet historical relic is as follows:
The first step installs filling water pumping tank, fills pump valve and fills pump funnel in air dissolved pump water inlet, in air dissolved pump air inlet peace Loaded check valve, air flow sensor and air needle valve, so that air and water can be mixed into pressurization is carried out in air dissolved pump simultaneously It closes.Pressure sensor, pH sensors and conductivity sensor are installed on air dissolved pump water outlet pipe road, to monitor system operation ginseng Number.
Second step installs micro-nano bubble generator in the end of air dissolved pump water outlet pipeline, and places it in cleaning Trench bottom.The disc-type accurate filter for being 10 microns in rinse bath water outlet installation filtering accuracy, to filter out cleaning process The granule foreign of middle generation.Flow control valve is installed to adjust the flow of water in cleaning system after filter, and makes cleaning Filtered water is recycled to filling and pumps tank in slot.
Third step opens filling pump valve, fills tap water by filling pump funnel and pumps tank, is then shut off filling pump valve Door.The water outlet historical relic to be cleaned is placed in rinse bath, and being filled with tap water into rinse bath makes historical relic be immersed in water.
4th step starts air dissolved pump, and adjusting air needle valve makes air mass flow in 0.05-0.1m3/ h, while adjusting flow Control valve makes water circular flow be 0.5-1m3/ h, and make the ratio (volume under mode of operation of air mass flow and water flow Than) it is less than or equal to 10%, the discharge pressure of corresponding air dissolved pump is 0.2-0.4Mpa.After system operation 2-5 minutes, in rinse bath Originally transparent water gradually becomes misty micro-nano air-bubble.Historical relic cleans 2-70h in rinse bath, can batch cleaning, It can continuous wash.In cleaning process, the pH value and conductivity of micro-nano air-bubble are monitored.Historical relic is cleaned to micro-nano air-bubble Until conductivity is constant, the disease attachment on historical relic has been cleaned by micro-nano air-bubble soft at this time, then carries out conventional mechanical It clears up (such as being struck off with bamboo stick), that is, completes the cleaning of historical relic.
Compared with prior art, beneficial effects of the present invention are:
1, the water outlet historical relic cleaning method that the present invention uses realizes historical relic and indissoluble mineralization using micro-nano air-bubble The separation of object, biological disease, ooze and other metals and nonmetallic poly-doped impurity.
2, the method for the present invention is pure physical cleaning method, is having compared with routinely the methods of addition soda acid complexing agent, ultrasound While effect cleaning separation historical relic attachment coagulation, processing procedure not generation environment pollutant not damaged to historical relic is efficient. Air is dispersed in water to form misty micro-nano air-bubble by the method for the present invention in the form of micro-nano bubble, can be on a large scale Cleaning separation applied to water outlet historical relic.
Description of the drawings
Fig. 1 is the structural schematic diagram that the circulating micro-nano air-bubble of kinetic pump of the present invention washes out hydrology object device.
Fig. 2 a are that historical relic is discharged in the embodiment of the present invention 1 through the picture before micro-nano bubbling -cleaning.
Fig. 2 b are picture of the water outlet historical relic after micro-nano bubbling -cleaning in the embodiment of the present invention 1.
Fig. 3 is the X-ray fluorescence spectra figure that historical relic sample is discharged in the embodiment of the present invention 3.
Specific implementation mode
Illustrate technical scheme of the present invention in the following with reference to the drawings and specific embodiments.
Referring to Fig. 1, which is that the circulating micro-nano air-bubble of kinetic pump of the present invention washes out the structure of hydrology object device and shows It is intended to, the water outlet historical relic cleaning involved in following embodiment is all made of the device.As shown in Figure 1, the device includes:Fill pump funnel 1, it fills pump valve 2, fill water pumping tank 3, air needle valve 4, air flow sensor 5, check-valves 6, air dissolved pump 7, pressure sensor 8, pH sensors 9, conductivity sensor 10, rinse bath 11, micro-nano bubble generator 12, disc-type accurate filter 13 and flow Control valve 14.Wherein, filling pump funnel 1 is installed on pump valve 2 is filled on filling water pumping tank 3, fills water pumping tank 3 and air dissolved pump 7 Water inlet is connected;Needle valve 4, air flow sensor 5 and check-valves 6 are installed on the air inlet of air dissolved pump 7 successively, make air and Water can be simultaneously into carrying out pressurization mixing in air dissolved pump.Pressure sensor 8, pH sensings are installed in 7 water outlet pipeline of air dissolved pump Device 9 and conductivity sensor 10, to monitor system operational parameters.Micro-nano bubble generator 12 is placed in 11 bottom of rinse bath, micro- Nano-bubble generator 12 is connected with the water outlet pipeline end of air dissolved pump 7.Disc-type accurate filter 13 is installed on rinse bath 11 exit, to filter out the granule foreign generated in cleaning process, the filtering accuracy of disc-type accurate filter 13 is 10 microns.Flow control valve 14 is installed after disc-type accurate filter 13, to adjust the flow of water in cleaning system, and Make water all be back to filling water pumping tank 3 to be recycled.
Embodiment 1
The present embodiment is cleaned for the deposit disease on water outlet high temperature sintering ware surface.
Choose No. 8 water outlet potsherds, size 47*31mm in the shipwreck of the South Sea 1 has hard attachment, through Raman thereon Spectrum analysis main component is calcium carbonate.Before potsherd cleaning as shown in Figure 2 a, it can be seen that the potsherd surface is smooth, is High temperature sintering forms.
It installs to fill in air dissolved pump water inlet and pumps tank, valve and funnel, check-valves, air mass flow sensing are installed in air inlet Device and needle valve.Pressure sensor, pH sensors and conductivity sensor are installed in air dissolved pump water outlet pipeline.Go out in air dissolved pump Mouth of a river line end installs micro-nano bubble generator, and places it in bottom of rinse bath.Micro-nano bubble generator is using high (horse fine horse etc. is applied to the air-dissolution air-floated technology of oiliness sewage treatment, entirely to the fast micro-nano bubble generator of rotary type State's oil and energy saving of chemical industry water-saving technology exchanging meeting and chemical industry are water-saving with film Application meeting, and 2011, pp208-213).It is cleaning Slot water outlet installs the disc-type accurate filter that filtering accuracy is 10 microns, and flow control valve is installed after filter, and So that water is recycled to filling and pumps tank.
It opens and fills pump valve, pump funnel by filling fills water pumping tank by tap water, is then shut off filling pump valve.It is cleaning No. 8 water outlet potsherds are placed in slot, and being filled with tap water makes historical relic be immersed in water.Start air dissolved pump, adjusts air needle valve Make air mass flow in 0.1m3/ h, while adjusting flow control valve makes water circular flow be 1m3/ h, the water outlet pressure of corresponding air dissolved pump Power is 0.4Mpa, enables air and water simultaneously into carrying out pressurization mixing in air dissolved pump.After system operation 2 minutes, in rinse bath Originally transparent water gradually becomes misty micro-nano air-bubble.Historical relic continuous wash 2h in rinse bath.In cleaning process, prison The pH value of micrometer nanobubble water is between 7-8.The conductivity of micro-nano air-bubble is 500 μ S/cm and protects after historical relic cleaning 2h Hold it is constant, at this time the disease attachment on historical relic by micro-nano air-bubble clean it is soft, with bamboo stick gently strike off stripping attachment Object completes the cleaning of historical relic, and the potsherd after cleaning is as shown in Figure 2 b.
No. 8 are discharged potsherds after the cleaning of micro-nano bubble method, according to《Movable Cultural Relics damage assessment technical regulation》Text Object protects professional standard (WW/T 0056-2014, WW/T 0056-2014), using fingers such as aberration, low in glossiness and surface damages It marks and safety evaluation is carried out to the situation of historical relic before and after cleaning.The result shows that aberration is that 3.21 (this value just thinks no change less than 5 Change), low in glossiness is 0.4 (this value just thinks unchanged less than 1), and microscopic analysis in addition shows potsherd surface glaze without apparent Variation, this shows that No. 8 water outlet potsherd surfaces are not damaged after the cleaning of micro-nano air-bubble.
This example demonstrates that micro-nano bubble method is for the deposit disease on cleaning water outlet high temperature sintering ware surface Safely and effectively.
Embodiment 2
The present embodiment is cleaned for the deposit disease on water outlet low-temperature sintered ceramics device surface.
Choose No. 14 water outlet potsherds, size 45*45mm in the shipwreck of the South Sea 1 has hard attachment, through Raman thereon Spectrum analysis main component is calcium carbonate.Can be seen that the potsherd rough surface from the potsherd appearance, be low-temperature sintering and At.
It installs to fill in air dissolved pump water inlet and pumps tank, valve and funnel, check-valves, air mass flow sensing are installed in air inlet Device and needle valve.Pressure sensor, pH sensors and conductivity sensor are installed in air dissolved pump water outlet pipeline.Go out in air dissolved pump Mouth of a river line end installs micro-nano bubble generator, and places it in bottom of rinse bath.Micro-nano bubble generator is using high The fast micro-nano bubble generator of rotary type.The disc-type secondary filter for being 10 microns in rinse bath water outlet installation filtering accuracy Device, filter install flow control valve later, and so that water is recycled to filling and pump tank.
It opens and fills pump valve, pump funnel by filling fills water pumping tank by tap water, is then shut off filling pump valve.It is cleaning No. 14 water outlet potsherds are placed in slot, and being filled with tap water makes historical relic be immersed in water.Start air dissolved pump, adjusts air needle valve Make air mass flow in 0.06m3/ h, while adjusting flow control valve makes water circular flow be 0.7m3/ h, corresponding air dissolved pump go out Water pressure is 0.3Mpa, enables air and water simultaneously into carrying out pressurization mixing in air dissolved pump.After system operation 3 minutes, cleaning Original transparent water gradually becomes misty micro-nano air-bubble in slot.Historical relic continuous wash 30h in rinse bath.Cleaning process In, the pH value of micro-nano air-bubble is monitored between 7-8.The conductivity of micro-nano air-bubble is 650 μ S/ after historical relic cleaning 30h Cm is simultaneously remained unchanged, and the disease attachment on historical relic is soft by micro-nano air-bubble at this time, and it is attached that stripping is gently struck off with bamboo stick Object, the cleaning of historical relic is completed.
No. 14 are discharged potsherds after the cleaning of micro-nano bubble method, according to《Movable Cultural Relics damage assessment technical regulation》Text Object protects professional standard (WW/T 0056-2014, WW/T 0056-2014), using fingers such as aberration, low in glossiness and surface damages It marks and safety evaluation is carried out to the situation of historical relic before and after cleaning.The result shows that aberration is that 3.68 (this value just thinks no change less than 5 Change), low in glossiness is 0.2 (this value just thinks unchanged less than 1), and microscopic analysis in addition shows potsherd surface glaze without apparent Variation, this shows that No. 14 water outlet potsherd surfaces are not damaged after the cleaning of micro-nano air-bubble.
This example demonstrates that micro-nano bubble method is for the deposit disease on cleaning water outlet low-temperature sintered ceramics device surface Safely and effectively.
Embodiment 3
The present embodiment has the water outlet ware of metal attack deposit disease to be cleaned for surface.
Choose No. 18 water outlet potsherds, size 95*59mm in the shipwreck of the South Sea 1 has metal attack object, is penetrated through X thereon Line spectrofluorimetry detects the higher ferro element of relative amount, and referring to Fig. 3, which is the X-ray of No. 18 water outlet potsherds Fluorescence spectra.
It installs to fill in air dissolved pump water inlet and pumps tank, valve and funnel, check-valves, air mass flow sensing are installed in air inlet Device and needle valve.Pressure sensor, pH sensors and conductivity sensor are installed in air dissolved pump water outlet pipeline.Go out in air dissolved pump Mouth of a river line end installs micro-nano bubble generator, and places it in bottom of rinse bath.Micro-nano bubble generator is using high The fast micro-nano bubble generator of rotary type.The disc-type secondary filter for being 10 microns in rinse bath water outlet installation filtering accuracy Device, filter install flow control valve later, and so that water is recycled to filling and pump tank.
It opens and fills pump valve, pump funnel by filling fills water pumping tank by tap water, is then shut off filling pump valve.It is cleaning No. 18 water outlet potsherds are placed in slot, and being filled with tap water makes historical relic be immersed in water.Start air dissolved pump, adjusts air needle valve Make air mass flow in 0.05m3/ h, while adjusting flow control valve makes water circular flow be 0.5m3/ h, corresponding air dissolved pump go out Water pressure is 0.2Mpa, enables air and water simultaneously into carrying out pressurization mixing in air dissolved pump.System operation after five minutes, is cleaned Original transparent water gradually becomes misty micro-nano air-bubble in slot.Historical relic batch cleaning 70h in rinse bath.Cleaning process In, the pH value of micro-nano air-bubble is monitored between 7-8.The conductivity of micro-nano air-bubble is 600 μ S/ after historical relic cleaning 70h Cm is simultaneously remained unchanged, and the disease attachment on historical relic is soft by micro-nano air-bubble at this time, and it is attached that stripping is gently struck off with bamboo stick Object, the cleaning of historical relic is completed.
No. 18 are discharged potsherds after the cleaning of micro-nano bubble method, according to《Movable Cultural Relics damage assessment technical regulation》Text Object protects professional standard (WW/T 0056-2014, WW/T 0056-2014), using fingers such as aberration, low in glossiness and surface damages It marks and safety evaluation is carried out to the situation of historical relic before and after cleaning.The result shows that aberration is that 1.62 (this value just thinks no change less than 5 Change), low in glossiness is 0.1 (this value just thinks unchanged less than 1), and microscopic analysis in addition shows potsherd surface glaze without apparent Variation, this shows that No. 18 water outlet potsherd surfaces are not damaged after the cleaning of micro-nano air-bubble.
This example demonstrates that micro-nano bubble method is for the metal attack deposit disease for washing out ceramic water device surface Safely and effectively.
Embodiment 4
The present embodiment is cleaned for water outlet ware of the surface with crack disease.
It is an incomplete implements that No. 2, which go out ceramic water, in the selection shipwreck of the South Sea 1, and diameter 69mm, high 37mm have 6 thereon Crack different in size, fracture width 0.074-0.076mm.The sample surfaces carry metal attack deposit disease.
It installs to fill in air dissolved pump water inlet and pumps tank, valve and funnel, check-valves, air mass flow sensing are installed in air inlet Device and needle valve.Pressure sensor, pH sensors and conductivity sensor are installed in air dissolved pump water outlet pipeline.Go out in air dissolved pump Mouth of a river line end installs micro-nano bubble generator, and places it in bottom of rinse bath.Micro-nano bubble generator is using high The fast micro-nano bubble generator of rotary type.The disc-type secondary filter for being 10 microns in rinse bath water outlet installation filtering accuracy Device, filter install flow control valve later, and so that water is recycled to filling and pump tank.
It opens and fills pump valve, pump funnel by filling fills water pumping tank by tap water, is then shut off filling pump valve.It is cleaning No. 2 water outlet potsherds are placed in slot, and being filled with tap water makes historical relic be immersed in water.Start air dissolved pump, adjusts air needle valve Make air mass flow in 0.1m3/ h, while adjusting flow control valve makes water circular flow be 1m3/ h, the water outlet pressure of corresponding air dissolved pump Power is 0.4Mpa, enables air and water simultaneously into carrying out pressurization mixing in air dissolved pump.After system operation 2 minutes, in rinse bath Originally transparent water gradually becomes misty micro-nano air-bubble.Historical relic continuous wash 10h in rinse bath.In cleaning process, The pH value of micro-nano air-bubble is monitored between 7-8.Historical relic clean 10h after micro-nano air-bubble conductivity be 680 μ S/cm simultaneously It remaining unchanged, the disease attachment on historical relic is soft by micro-nano air-bubble at this time, and stripping attachment is gently struck off with bamboo stick, Complete the cleaning of historical relic.
No. 2 are discharged potsherds after the cleaning of micro-nano bubble method, according to《Movable Cultural Relics damage assessment technical regulation》Text Object protects professional standard (WW/T 0056-2014, WW/T 0056-2014), using fingers such as aberration, low in glossiness and surface damages It marks and safety evaluation is carried out to the situation of historical relic before and after cleaning.The result shows that aberration is that 3.23 (this value just thinks no change less than 5 Change), low in glossiness is 0.4 (this value just thinks unchanged less than 1), and microscopic analysis in addition shows potsherd surface glaze without apparent Variation, fracture width 0.074-0.076mm, no significant change, this shows No. 2 water outlet potsherd surfaces through micro-nano air-bubble It is not damaged after cleaning.
This example demonstrates that micro-nano bubble method is safe and effective for cleaning the water outlet ware with crack disease 's.
The preferred embodiment of the present invention is above are only, the present invention is not limited in the content of embodiment.For in this field Technical staff for, can have various change and change within the scope of technical scheme of the present invention, made by it is any variation and Change, within the scope of the present invention.

Claims (7)

1. a kind of method that the circulating micro-nano air-bubble of kinetic pump washes out hydrology object, this method are:It will be empty by air dissolved pump Gas and water pressurization are mixed to get air-water mixture, which generates micro-nano bubble by micro-nano bubble generator again Water cleans water outlet historical relic using the micro-nano air-bubble of generation;The micro-nano bubble generator uses high-speed cyclic Decline nano-bubble generating apparatus;The discharge pressure of the air dissolved pump is 0.2~0.4Mpa.
2. the method that the circulating micro-nano air-bubble of kinetic pump as described in claim 1 washes out hydrology object, it is characterised in that: When by air and water pressurization mixing, the ratio of air mass flow and water flow is less than or equal to 10%.
3. the method that the circulating micro-nano air-bubble of kinetic pump as described in claim 1 washes out hydrology object, it is characterised in that: The discharge pressure of the air dissolved pump is 0.2~0.4Mpa.
4. the method that the circulating micro-nano air-bubble of kinetic pump as described in claim 1 washes out hydrology object, it is characterised in that: When wash out the conductivity of micro-nano air-bubble of hydrology object it is constant when, terminate to be discharged historical relic cleaning.
5. a kind of circulating micro-nano air-bubble of kinetic pump washes out the device of hydrology object, which includes:It fills pump funnel, fill pump Valve fills water pumping tank, air dissolved pump, air needle valve, air flow sensor, check-valves, pressure sensor, pH sensors, electricity Derivative sensor, rinse bath, micro-nano bubble generator, accurate filter and flow control valve;
The filling pump funnel is installed on pump valve is filled on filling water pumping tank, is filled water pumping tank and is connected with the water inlet of air dissolved pump;
The air needle valve, air flow sensor and check-valves are installed on the air inlet of air dissolved pump, keep air and water same When enter and carry out pressurization mixing in air dissolved pump;
The pressure sensor, pH sensors and conductivity sensor are mounted on the water outlet pipe road of the air dissolved pump, for supervising Examining system operating parameter;
The micro-nano bubble generator is mounted on the end of the water outlet pipeline of air dissolved pump, and micro-nano bubble generator is set In bottom of rinse bath;The micro-nano bubble generator uses the micro-nano bubble generator of high speed rotary type;The air dissolved pump Discharge pressure be 0.2~0.4Mpa;
The accurate filter is installed on the exit of the rinse bath, miscellaneous to filter out the particle generated in cleaning process Matter;
The flow control valve, which is mounted on after the accurate filter and pumps tank with the filling, to be connected, to adjust cleaning The flow of water in system, and so that water is recycled to the filling and pump tank.
6. the circulating micro-nano air-bubble of kinetic pump as claimed in claim 5 washes out the device of hydrology object, it is characterised in that: The accurate filter is disc-type accurate filter, and filtering accuracy is 10 microns.
7. the circulating micro-nano air-bubble of kinetic pump as claimed in claim 5 washes out the device of hydrology object, it is characterised in that: In cleaning process, the pH value and conductivity of micro-nano air-bubble are monitored, it is constant that historical relic cleans the conductivity to micro-nano air-bubble Until.
CN201610463310.6A 2016-06-23 2016-06-23 The circulating micro-nano air-bubble of kinetic pump washes out the method and device of hydrology object Active CN106140714B (en)

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