CN106133202A - There is the anodized system that the medicine utilizing electrolyte to automatically analyze puts into the metal of function - Google Patents
There is the anodized system that the medicine utilizing electrolyte to automatically analyze puts into the metal of function Download PDFInfo
- Publication number
- CN106133202A CN106133202A CN201480077535.7A CN201480077535A CN106133202A CN 106133202 A CN106133202 A CN 106133202A CN 201480077535 A CN201480077535 A CN 201480077535A CN 106133202 A CN106133202 A CN 106133202A
- Authority
- CN
- China
- Prior art keywords
- electrolyte
- metal
- determinator
- current value
- medicine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D21/00—Processes for servicing or operating cells for electrolytic coating
- C25D21/12—Process control or regulation
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D11/00—Electrolytic coating by surface reaction, i.e. forming conversion layers
- C25D11/005—Apparatus specially adapted for electrolytic conversion coating
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D21/00—Processes for servicing or operating cells for electrolytic coating
- C25D21/12—Process control or regulation
- C25D21/14—Controlled addition of electrolyte components
Abstract
The present invention relates to the anodized system of metal, in the electrolyte determinator in the space having and contain outside the electrolysis bath of electrolyte, measure magnitude of voltage and current value, can the drug concentration such as Accurate Determining sulphuric acid, can accurately regulate the amount of medicament added to electrolysis bath.
Description
Technical field
The present invention relates to automatically engage the anodized system of the metal of medicine, specifically, at the anode of metal
In oxidation treatment device, in order to metallic surface processes, analyze a certain amount of electrolyte contained in a cell, and to electrolysis
Groove is automatically added to sulphuric acid (sulfuric acid:H2SO4) etc. medicine, make the magnitude of voltage of electrolyte and current value keep certain
Value.
Background technology
In general, anodic oxidation (Anodizing) processing means of metal is that metal or parts etc. are hung over anode,
The electrolyte of dilute acid is electrolysed, and utilizes the oxygen produced at anode, formation to have super large with base metal and be close to
Oxide film (aluminium oxide: the Al of power2O3).Anodic oxidation is anode (Anode) and the synthesis language (Ano-of oxidation (Oxidizing)
dizing).It addition, carry out being electroplate with difference with metal parts hangs in plating negative electrode.The most representative anodised material
Material is aluminum (Al), is also used in addition with metal materials such as magnesium (Mg), zinc (Zn), titanium (Ti), tantalum (Ta), hafnium (Hf), niobiums (Nb)
Anodized.Recently, the anodized of magnesium and titanium material also has the trend gradually expanding its purposes.
Generally, anodic oxidation (the Anodizing on Aluminum of oxide film process is carried out on the surface of aluminum
Alloys) being that, by aluminum when anode electrolysis, the half on aluminum surface is to be etched, second half is to form aluminum oxide film.Aluminium anodes
Oxidation (anodic oxidation) is, according to composition and concentration, additive, the temperature of electrolyte, voltage, the electricity of multiple electrolysis (process) liquid
Stream etc., can form thin film of different nature.
The characteristic of above-mentioned anodic oxidation film is, thin film is the corrosion resistance that close oxide has excellence, can improve
Decorative appearance, anode film is fairly hard, has the wearability of excellence, can improve application adhesive force, improves bonding
(Bonding) performance, improves lubricity, plays the peculiar color as decorative purpose, can carry out the pre-treatment electroplated, can check
Surface damage.
Particularly, the feature of anode hardening oxidation (Hard Anodizing) is, utilize the alloy characteristic of aluminum low temperature (or
Person's room temperature) it is electrolysed as at sulphuric acid (H2SO4) method of low-temperature electrolytic in solution, so comparing common anode oxide film, it is to have
Corrosion resistance, wearability, the harder thin film of insulating properties, can be called hard time more than at least 30 μm.By aluminum metal surface profit
Electricity consumption, chemical method are changed to the process of aluminium oxide ceramics.When using this process, aluminum metal self will aoxidize,
Being changed to aluminium oxide ceramics, the character on aluminum surface is harder than iron and steel, has the wearability more excellent than the chromium plating of hard.Unlike
Plating or application (coating, coating) are peeled off like that, have been changed to alumina ceramic face and have had the electrical insulating property of excellence
(1500V), but it is energized well inside it.Currently develop and use and utilize hard anodizing in such aluminum metal
(Hard-Anodizing) sophisticated technology of surface treatment process method.
In order to carry out the anodized of hard in such aluminum metal, equipped with acid solution, particularly dissolve
Have sulphuric acid electrolyte electrolysis bath in immerse after aluminum metal, be passed through certain voltage and electric current, form oxide-film in metal surface,
Now basis is passed through the voltage and current of electrolysis bath, and the thickness of oxide-film is different.Especially, electrolyte needs to keep certain value
Magnitude of voltage and current value, according to the sulfuric acid concentration dissolved in the electrolytic solution, magnitude of voltage can be different with current value.Therefore, electrolyte
In need to add a certain amount of sulphuric acid.
In the past, general plating was the process covering certain thickness thin film at metallic surface, and operating personnel utilizes letter
Single skilled work or the data specified, can realize required plating, and plating performed as described above can ensure a certain degree of quality, but
Be metal anodized surface process can separate out tens of kinds of alloys by the precipitation oxidation technology method of metal surface.Now,
Silicon, ferrum or the lead etc. that hinder the anodized surface of metal to process are dissolved the most together.Therefore, in the anodized surface of metal
During process, in order to remove foreign body or the aluminum of dissolving of residual in electrolyte, add certain density sulphuric acid in the electrolytic solution, according to
The thickness of sulfuric acid concentration uniform treatment thin film and color.It is, generally need to be dissolved with about 200 in the electrolyte of 1 liter
Gram sulphuric acid.But, in the anodized surface processing procedure of metal, the concentration of sulphuric acid can reduce, it is therefore desirable to electrolysis
Liquid supplies a certain amount of sulphuric acid.Electrolyte should keep magnitude of voltage and the current value of certain value, needs for this to add sulphuric acid.
Therefore, the hard anodizing surface of aluminum metal processes is that the long-term skilled operation by operating personnel realizes metal
Oxide film thickness or color.It addition, skilled operating personnel is also required to the defect rate born to a certain degree.Therefore, not
The anodized surface of the oxide film of the metal that skilled or first operation personnel are carried out processes and arises that what defect rate increased
Shortcoming and inefficient productivity.
It addition, process to implement the uniform anodized surface of metal, need the magnitude of voltage of electrolyte and current value
Keep certain, so needing the concentration being dissolved in the sulphuric acid of electrolyte also to keep certain.Therefore, the real time measure is dissolved in electrolysis
The sulfuric acid concentration of liquid, and add a certain amount of sulphuric acid to electrolysis bath, the most complicated, and it is difficult to add the sulphuric acid of correct amount.
To this end, be the film thickness increasing metal, required time will be elongated, the manpower that the anodized surface for aluminum metal processes
Will increase with expense.
Certainly, in order to solve these problems, the applicant is it is proposed that cross registered patent the 10-1048041st.This relates to
The sulphuric acid automatically adding device of the anodic oxidation treatment device of metal, is immersion plating object in the electrolysis bath containing electrolyte
Thing, imports power supply in the electrolytic solution, and plating object thing carries out the anodic oxidation treatment device of the metal of anodized, should
Device includes: detection device, this detection device is immersed in above-mentioned electrolyte, and detects magnitude of voltage and the current value of electrolyte；Control
Device processed, this controller control to above-mentioned detection device import power supply, by from detection device input magnitude of voltage and current value with
The standard voltage value and the current value that have set compare, and export control signal；Electromagnetic valve, this electromagnetic valve is arranged on and contains sulphuric acid
Accumulator tank below, utilize the control signal of controller noted above to carry out opening and closing accumulator tank, by pipe arrangement to electrolysis bath add and block
Sulphuric acid.In order to make the electrolyte stored in electrolysis bath keep certain magnitude of voltage and current value, add a certain amount of sulphuric acid, thus
Improve quality and productivity, the convenience of operation, the anodic oxidation of metal of the product of the anodic oxidation electroplating processes of metal
The working performance of processing means.
But, the detection device of composition as described above is that the state being immersed in electrolyte arranges and measures electrolyte
The structure of electrical conductivity, owing to being the electrical conductivity measuring electrolyte in the anodic oxidation electroplating processes process of metal, so existing
Problem be can not accurately to measure sulfuric acid concentration, there is the biggest error.
Particularly, for further Accurate Determining, need the state of the anodized of metal in stopping electrolysis bath
Lower mensuration electrical conductivity, so in the mensuration of electrical conductivity with utilize its sulphuric acid to add operation can not carry out the anodic oxidation of metal
Processing, therefore, it is difficult to realize persistently carrying out anodized operation, major part situation is to carry out in dangerous operation field
The addition of monitored conductivity and sulphuric acid controls, and is the most also difficult to the shape at local remote monitoring electrolyte such as control rooms
State.
Summary of the invention
In order to solve above-mentioned conventional technical problem, it is an object of the invention to provide to have and utilize electrolyte to automatically analyze
Medicine put into the anodized system of metal of function, for containing a certain amount of electrolyte in electrolysis bath, in electrolysis
In independent electrolyte determinator outside groove, the electrical conductivity of Accurate Determining electrolyte.
There is the medicine utilizing the electrolyte to automatically analyze put into the metal of function it addition, it is an object of the invention to provide
Anodized system, when persistently carrying out the anodized of metal in electrolysis bath, it is also possible to the real time measure
The concentration of medicine, and can be in the electrolyte state of the remote monitoring electrolysis baths such as control room.
For solving above-mentioned technical task, the present invention provides the gold with the medicine input function utilizing electrolyte to automatically analyze
The anodized system belonged to, it is characterised in that this device includes: electrolyte determinator, is soaked with and needs at anodic oxidation
The electrolyte of the plating object thing of reason is stored in electrolysis bath, and by the driving of pump, the electrolyte of storage flows into electrolyte and measures
During device, electrolyte determinator by sun (+) electrode and cloudy (-) electrode, measure magnitude of voltage and the current value of electrolyte；Control
Device processed, this controller controls the power supply imported to above-mentioned electrolyte determinator, the voltage that will input from electrolyte determinator
Value and current value compare with the normal voltage set and current value, export control signal；Electromagnetic valve, this electromagnetic valve utilizes
The control signal of controller noted above is carried out opening and closing and is contained the drug stock control groove of medicine, is added and blocking agent to electrolysis bath by pipe arrangement
Product.
Now, it is characterised in that described electrolyte determinator includes: container, this containers store electrolyte, this electrolyte
The electrolyte being previously stored in electrolysis bath is come through oral siphon inflow by the driving of pump；Sun (+) electrode and cloudy (-) electrode,
This sun (+) electrode (120) and the moon (-) electrode (130) is arranged on inside said vesse, measures electrical conductivity.
Additionally, it is characterised in that the opposite side of said vesse connects drain pipe, this drain pipe is for by the electricity in container
Solve liquid to discharge to above-mentioned electrolysis bath.
And, it is characterised in that controller noted above includes: calculating control portion, this calculating control portion will measure from electrolyte
Magnitude of voltage and the current value of device input compare with the standard voltage value set and current value, export control signal；Deposit
Storage portion, this storage part store driver.
Now, it is characterised in that controller noted above also includes USB joint portion, this USB joint portion has from electricity for combination
Solve magnitude of voltage and the USB storage of current value of the input of liquid determinator.
Additionally, it is characterised in that controller noted above also includes communication unit, this communication unit and the control computer in control room
Connect, send data in real time.
In addition, it is characterised in that the side of above-mentioned electrolysis bath is additionally provided with degreasing plant, this degreasing plant includes: defat
Groove；Drainage screen, this drainage screen is arranged in degreasing bath, for segregating foreign objects from the electrolyte of the separates walls crossing electrolysis bath；
Pump, this pump is for sending water by the electrolyte implementing defat in degreasing bath by flow pipe.
And, it is characterised in that the opposite side of above-mentioned electrolysis bath is additionally provided with metallicity impurities removing unit, this metallicity
Impurities removing unit includes: filter tank；Metallicity impurity absorption filter, this metallicity impurity absorption filter is arranged on
In filter tank, the metallicity impurity dissolved in the electrolyte adsorbing the separates walls crossing electrolysis bath；Pump, this pump for incited somebody to action
The electrolyte removing metallicity impurity in filter pocket send water by flow pipe.
According to the present invention, in the electrolyte determinator in the space having and contain outside the electrolysis bath of electrolyte, survey
Determine magnitude of voltage and current value, can the drug concentration such as Accurate Determining sulphuric acid, can accurately regulate the amount of medicament added to electrolysis bath.
It addition, in the present invention, in the electrolyte determinator in the space having and contain outside the electrolysis bath of electrolyte,
Measure magnitude of voltage and current value, so with the state estimating of electrolyte independently, the sustainable anodic oxygen carrying out plating object thing
Change processes operation.And, it is possible to add state in the remote states confirming electrolyte such as control room and medicine.
Accompanying drawing explanation
Fig. 1 is the anodic oxidation of the metal with the medicine input function utilizing electrolyte to automatically analyze that the present invention relates to
The axonometric chart of the electrolysis bath processed.
Fig. 2 is the anodic oxidation of the metal with the medicine input function utilizing electrolyte to automatically analyze that the present invention relates to
The electrolysis bath processed and the sectional view of electrolyte determinator.
Fig. 3 is the anodic oxidation of the metal with the medicine input function utilizing electrolyte to automatically analyze that the present invention relates to
The structure chart of processing system.
Fig. 4 is the circuit diagram of the DC source importing rectification in the controller that the present invention relates to electrolyte determinator.
Fig. 5 to Fig. 7 is the schematic diagram of other embodiments of the present invention.
Detailed description of the invention
With reference to the accompanying drawings, by the embodiment of narration in detail, it will be appreciated that having of the present invention relates to utilizes electrolyte certainly
The dynamic medicine analyzed puts into the anodized system of the metal of function.
The present invention can implement multiple change, can have multiple form, describe in detail in this article and realize example (embodiment party
Formula, aspect) (or embodiment).But, the present invention is not limited to specifically disclosed form, it is thus understood that be included in the present invention's
All changes, equipollent and substitute in thought and technical scope.
In the drawings, identical reference, particularly tens and one digit number or tens, one digit number and
The identical reference of letter refers to the parts with same or like function, in addition to special instruction, and each attached in accompanying drawing
The parts that figure labelling is pointed out can determine whether as the parts with this standard.
It addition, structural element (particularly, each layer thickness of laminated film) is in view of the facility on understanding in each accompanying drawing, its
Size and thickness processing and amplifying (or blocked up) (or the thinnest), although illustrate simply, but can not be limited for this
Explain protection scope of the present invention.
In this specification use term simply to illustrate that particular implementation (or embodiment) and use, not
It is to limit the present invention.The performance of odd number is the most substantially to point out outside difference on context, including the performance of plural number.At this
In application, " including " or " composition " etc., term simply pointed out that feature that description records, numeral, step, action, structure are wanted
Element, section components or the existence of these combinations, be not get rid of in advance other features one or more, numeral, step,
Action, structural element, section components or the existence of these combinations or additional probability.
Outside in addition to additional definitions, all terms being used herein including technology and scientific words are in institute of the present invention
The personnel in genus technical field with usual knowledge are the most accessible.The term etc. of the dictionary definition generally used can be explained
For consistent with the meaning having on the context of correlation technique, outside explicitly defining in this application, it is impossible to extremely or exceedingly solve
It is interpreted as the pro forma meaning.
Referring to figs. 1 through Fig. 3, in the anodic oxidation treatment device of the metal of the present invention, real-time Accurate Determining and detection exist
The electrical conductivity of the electrolyte that electrolysis bath 1 contains, is automatically added to medicines such as a certain amount of sulphuric acid in electrolysis bath 1, makes magnitude of voltage
Keep certain value with current value, therefore in the electrolysis bath 1 of the anodic oxidation treatment device of metal, contain a certain amount of electrolyte.
Now, plating object thing 1a is immersed in electrolysis bath 1, imports the power supply of certain value in electrolyte, carries out the sun of plating object thing
Pole oxidation processes.
On the other hand, in order to the electrical conductivity of electrolyte contained in measuring above-mentioned electrolysis bath 1, i.e. certain value magnitude of voltage and
Current value, is provided with electrolyte determinator 100 in the side of above-mentioned electrolysis bath 1.
Above-mentioned electrolyte determinator 100 includes: container 110, and this container 110 stores electrolyte, and this electrolyte is to store
Electrolyte in electrolysis bath 1 is come through oral siphon 102 inflow by the driving of pump P1；Sun (+) electrode 120 and cloudy (-) electricity
Pole 130, this sun (+) electrode 120 and cloudy (-) to be arranged on said vesse 110 internal for electrode 130, measures electrical conductivity.
Certainly, the side of said vesse 110 connects above-mentioned oral siphon 102, and the connection of the opposite side of said vesse 110 has
Drain pipe 104, this drain pipe 104 is for discharging the electrolyte in container 110 to above-mentioned electrolysis bath 1.
Now, above-mentioned sun (+) electrode 120 and cloudy (-) electrode 130 keeps being positioned apart from, can be formed as shown in the figure
Shaft-like.But can also be arranged to, cloudy (-) electrode 130 it may be that drum the moon (-) electrode 130 is integrally attached to
On insulator (not diagram) inwall, the moon of being connected with insulator one (-) it is formed with multiple through hole on electrode 130, make electricity
Solve liquid free flow；Above-mentioned sun (+) electrode 120 it may be that drum the moon (-) central part of electrode 130 with cloudy (-)
Electrode 130 is arranged with keeping certain intervals.
Now, above-mentioned insulator can use synthetic resin, particularly can use PVC (polrvinyl chloride) pipe etc., cloudy (-) electricity
Pole 130 and sun (+) electrode 120 can use metal, particularly lead, but be preferably used in surface and carry out the metal material of platinum process
Material, prevents foreign body from adhere to, it is possible to the correct electrical conductivity detecting electrolyte, and cloudy (-) electrode 130 with (+) the consolidating of electrode 120
Limiting-members 122,132 is preferably non-conductor or the synthetic resin of insulant or metal, and support member 122,132 is preferably closes
Resin or rubber etc..
Certainly, above-mentioned sun (+) electrode 120 and cloudy (-) electrode 130 is fixed on terminal 124,134, with electric wire 125,135
Connect, sun (+) electrode 120 and cloudy (-) electrode 130 power supply, i.e. magnitude of voltage and the current value that measure be input to controller 200,
Controller noted above 200, for controlling the power supply imported to electrolyte determinator 100, will input from electrolyte determinator 100
Power supply, i.e. magnitude of voltage and current value compare with the standard voltage value set and current value, export control signal.
On the one hand, controller noted above 200 includes: calculating control portion 210, this calculating control portion 210 will measure from electrolyte
Magnitude of voltage and the current value of device 100 input compare with the standard voltage value set and current value, export control signal；
Storage part 220, this storage part 220 store driver, storage part 220 stores all data to controller 200 input, storage
Temperature, magnitude of voltage and the normal data of the adding amount of medicines such as current value, sulphuric acid.It addition, be stored in the input of above-mentioned storage part 220
Data can be set as the normal data of the anodized of metal, or can be used as standardized data base or data.
Controller noted above 200 controls the driving of said pump P1, the electrolyte in electrolysis bath 1 is flowed into above-mentioned electrolyte and surveys
Determine in the container 110 of device 100.Now, controller noted above 200 is not persistent loop electrolyte, but drives within the setting time
Dynamic, thus after being full of electrolyte in container 110, stopping action, within the time of setting (such as, 3-5 minute), measure electrolysis
The magnitude of voltage of liquid and current value, and compare with the standard voltage value set and current value.
Afterwards, the driving of pump is repeated as a unit (such as, 1 hour or 30 minutes being a unit) setting the time
Move and the mensuration process of electrolyte, while keeping above-mentioned standard voltage value and current value in electrolysis bath 1, it is also possible to hold
The continuous anodized carrying out metal.
On the one hand, controller noted above 200 also includes USB joint portion 250 and communication unit 260.
Now, above-mentioned USB joint portion 250 combines USB storage 252, by above-mentioned sun (+) electrode 120 and cloudy (-) electrode
130 magnitudes of voltage measured and current value quantize, and are stored in USB storage 252.So numeric data of accumulation storage
The anodized normal data into metal can be reset, or can be used as standardized data base or data in the future.
It addition, above-mentioned communication unit 260 be runed by wire and wireless mode or the wireless near field communication means such as bluetooth or
Telecommunication means are constituted, and connect with the control computer 300 in control room (such as, office), real-time tranception data, can
The remote controlled state confirming pump P1 and the magnitude of voltage of electrolyte and current value.It is of course also possible to used by above-mentioned control
Computer 300 controls the driving of controller noted above 200.
Particularly, permissible value or not enough permission are exceeded when the controlled state of pump and the magnitude of voltage of electrolyte and current value
During value, buzzer or microphone that above-mentioned control computer 300 will be possessed by control computer export warning tones, make management
Person takes measures rapidly.
On the other hand, store the medicines such as sulphuric acid drug stock control groove 400 electromagnetic valve 410 be provided below, utilize
The control signal of controller 200 carrys out opening and closing drug stock control groove 400, is added by pipe arrangement 412 or block medicine in electrolysis bath 1.
It addition, controller noted above 200 sets by detecting the thermometer 430 of electrolyte temperature by being immersed in above-mentioned electrolyte
Put in drug stock control groove 400, it is possible to detect the temperature of the medicine added to electrolysis bath 1.
Additionally, controller noted above 200 also includes display part 230, this display part 230 visually shows that above-mentioned electrolyte measures
Magnitude of voltage that device 100 measures and detects and current value and the adding amount of medicines added to electrolyte through electromagnetic valve 410 and
Time etc..
Now, above-mentioned display part 230 include respectively voltage display meter 231, electric current display meter 232, time showing meter 233 with
And temperature display meter 234.
It addition, display part 230 also includes that operating personnel can select the deflector rod switch T/S of power supply.
Additionally, referring to the drawings 4, controller noted above 200 possesses toggle switch T/S, optional importing electrolyte determinator
The power supply of 100.It is, by the operation of toggle switch T/S, the alternating current power supply (AC) of R end and S end will be imported at transducer T
Primary side may select 1 grade or 2 grades, transducer T secondary side import power supply.It addition, the electricity that the secondary side of transducer T imports
Source through diode D1, D2 rectification, thus import just (+) DC source.It addition, negative (-) DC source possesses timer (T/
S), it is possible to set time importing DC source.
Now, in the present invention, it is dissolved in the medicine of electrolyte, such as sulphuric acid, it is preferable that concentration is every liter of 200 ± 50g,
The electric current of detection is 10 ± 2A, and the temperature of detection is 20 ± 1 DEG C, and the voltage of detection is 15 ± 2V, the anodized of metal
Time is 30 ± 2 minutes.In particular it is preferred that ground, containing biosurfactant in sulphuric acid, thus promote that the bubble of electrolyte is lived
Property.
Additionally, in the present invention, according to importing the magnitude of voltage of electrolysis bath 1 and current value and anodized time, really
The thickness of fixed plating and color.Utilize controller 200, in electrolyte determinator 100 by electric wire 125,135 to sun (+)
Electrode 120 and cloudy (-) electrode 130 imports the voltage and current of certain value.Sun (+) electrode 120 and cloudy (-) electrode 130 it
Between by electrolyte circulation electric current within container.Now, according to the drug concentration dissolved in electrolyte, current value is different.And
And magnitude of voltage between sun (+) electrode 120 and the moon (-) electrode 130 is the most different.Therefore, controller 200 detect sun (+) electrode
120 and cloudy (-) magnitude of voltage between electrode 130 and current value, measure and detect the drug concentration that dissolves in electrolyte.It addition,
Controller 200, by measuring the thermometer 240 of electrolyte temperature in being arranged on electrolysis bath 1, receives the temperature of electrolyte simultaneously
Value.The data of reception are stored in storage part 220 and USB storage 252 by controller 200, and be stored in storage part 220 and
The normal data of USB storage 252 compares, it is determined whether from the drug stock control groove 400 containing medicine add medicine and
Addition.
In order to keep certain voltage value and the current value of electrolyte, when the drug concentration dissolved in electrolyte is established standards
Within time, do not open electromagnetic valve 410, and when the drug concentration dissolved in electrolyte is less than established standards, the most open electromagnetic valve
410.Now, the amount of medicament added from electromagnetic valve 410, the Xining point of monitoring electromagnetic valve 410 are measured.Especially, controller
The temperature of 200 detection electrolyte, preheats drug stock control groove 400.This is to reduce to greatest extent at the anodic oxidation of metal
The defect rate of reason, during because the medicine lower than electrolyte temperature joins electrolyte, may produce gold when electrolyte temperature reduces
The defect rate of the anodized belonged to.
It addition, during in controller 200, all data of input and output are stored in storage part 220 and USB storage 252, can
Normal data as the anodized of metal.Especially, table, operating personnel is become only to pass through standardized data creating
Monitor the display part 230 of controller 200, it becomes possible to carry out the anodized of more effective metal.
Therefore, it is possible to the drug concentration making to be stored in the electrolyte in electrolysis bath 1 keeps certain, not only practician and also just
Plating defect rate when phase worker also can reduce anodized to greatest extent, and also can be accurate in anodized
Really measuring drug concentration, the data that thus can realize having reliability guarantee and medicine addition, improve productivity.
Additionally, Fig. 5 and Fig. 6 is the schematic diagram of the additional embodiment of the present invention.
As it is shown in figure 5, the side of electrolysis bath 1 is additionally provided with degreasing plant 10.Now, above-mentioned degreasing plant 10 includes: de-
Fat groove 11；Drainage screen 12, this drainage screen 12 is arranged in degreasing bath 11, for from the electrolyte of the separates walls 4 crossing electrolysis bath 1
Middle segregating foreign objects；Pump P2, this pump P2 are for sending water by the electrolyte of defat from degreasing bath 10 by flow pipe 14.By above-mentioned
Structure, the electrolyte of the separates walls 4 crossing electrolysis bath 1 passes through drainage screen 12 segregating foreign objects, is then added in electrolysis bath 1.
It addition, as shown in Figure 6, the opposite side of electrolysis bath 1 is additionally provided with the electricity of the anodized for adsorbing metal
Solving the metallicity impurities removing unit 20 of the metallicity impurity dissolved in the electrolyte of groove, this metallicity impurities removing unit 20 is wrapped
Include: filter tank 21；Metallicity impurity absorption filter 22, this metallicity impurity absorption filter 22 is arranged on filter tank 21
In, the metallicity impurity dissolved in the electrolyte adsorbing the separates walls 5 crossing electrolysis bath 1；Pump P3, this pump P3 for incited somebody to action
The electrolyte removing metallicity impurity in filter pocket 21 send water by flow pipe 24.By said structure, cross the separation of electrolysis bath 1
The electrolyte of wall 5 removes metallicity impurity by metallicity impurity absorption filter 22, is then added in electrolysis bath 1.Now,
Metallicity impurity absorption is preferably with filter 22 and directly uses the applicant to propose in registered patent the 10-1244166th
Metallicity impurity absorption filter.
Certainly, said pump P2, P3 pass through controller 200 and control, as shown in Figure 7, it is also possible to arrange degreasing plant continuously
10 and metallicity impurities removing unit 20, electrolyte is after degreasing plant 10 once crosses the impurity such as oil strain, miscellaneous through metallicity
Matter removing device 20 secondary filter metallicity impurity.
By arranging above-mentioned degreasing plant 10 and metallicity impurities removing unit 20, the oil that is dissolved in removed in electrolyte becomes
Divide the metallicity impurity such as the lead in electrolyte, ferrum, make electrolyte keep finite concentration for a long time, uniform anodic oxidation can be realized
Process.
Be explained above the preferred embodiments of the present invention, but the interest field of the present invention do not limit here, with this
The scope of bright embodiment substantially equalization is also included within the interest field of the present invention, without departing from the scope of the inventive concept
In, numerous variations can be implemented the personnel in the technical field of the invention with usual knowledge.
Probability is utilized in industry
The present invention provides the anodized system with the metal that the medicine utilizing electrolyte to automatically analyze puts into function
System, it is characterised in that including: electrolyte determinator, is soaked with the electrolyte storage of the plating object thing needing anodized
Existing in electrolysis bath, by the driving of pump, when the electrolyte of storage flows into electrolyte determinator, electrolyte determinator passes through
Sun (+) electrode and cloudy (-) electrode, measure magnitude of voltage and the current value of electrolyte；Controller, this controller controls to above-mentioned electricity
Solve the power supply that liquid determinator imports, by magnitude of voltage input from electrolyte determinator and current value and the standard electric set
Pressure and current value compare, and export control signal；Electromagnetic valve, this electromagnetic valve utilizes the control signal of controller noted above to carry out opening and closing
Contain the drug stock control groove of medicine, added and blocking-up medicine to electrolysis bath by pipe arrangement.
Claims (7)
1. there is the anodized system that the medicine utilizing electrolyte to automatically analyze puts into the metal of function, its feature
It is, including:
Electrolyte determinator (100), the electrolyte being soaked with the plating object thing (1a) needing anodized is stored in electricity
Solve in groove (1), by the driving of pump (P1), when the electrolyte of storage flows into described electrolyte determinator (100), described electrolysis
Liquid determinator (100) is by sun (+) electrode (120) and the moon (-) electrode (130), the magnitude of voltage of mensuration electrolyte and electric current
Value；
Controller (200), this controller (200) controls the power supply imported to described electrolyte determinator (100), will be from electrolysis
Magnitude of voltage and current value that liquid determinator (100) inputs compare with the normal voltage set and current value, output control
Signal processed；
Electromagnetic valve (410), this electromagnetic valve (410) utilizes the control signal of described controller (200) to carry out opening and closing and contains the medicine of medicine
Product accumulator tank (400), is added by pipe arrangement (412) to electrolysis bath (1) and blocks medicine,
Described electrolyte determinator (100) including:
Container (110), this container (110) stores electrolyte, and the electrolyte that this electrolyte is previously stored in electrolysis bath (1) passes through pump
(P1) driving flows into through oral siphon (102)；
Sun (+) electrode (120) and the moon (-) electrode (130), described sun (+) electrode (120) and described the moon (-) electrode (130) sets
Put at described container (110) internal, measure electrical conductivity.
The most according to claim 1 have the anodic oxidation that the medicine utilizing electrolyte to automatically analyze puts into the metal of function
Processing system, it is characterised in that the opposite side of described container (110) connects has drain pipe (104), this drain pipe (104) to be used for
Electrolyte in container (110) is discharged to described electrolysis bath (1).
The most according to claim 1 have the anodic oxidation that the medicine utilizing electrolyte to automatically analyze puts into the metal of function
Processing system, it is characterised in that described controller (200) including:
Calculate control portion (210), the magnitude of voltage that this calculating control portion (210) will input from described electrolyte determinator (100)
Compare with the standard voltage value set and current value with current value, export control signal；
Storage part (220), this storage part (220) store driver.
The most according to claim 3 have the anodic oxidation that the medicine utilizing electrolyte to automatically analyze puts into the metal of function
Processing system, it is characterised in that described controller (200) also includes USB joint portion (250), this USB joint portion (250) is used for
In conjunction with the USB storage (252) having magnitude of voltage and the current value inputted from described electrolyte determinator (100).
The most according to claim 3 have the anodic oxidation that the medicine utilizing electrolyte to automatically analyze puts into the metal of function
Processing system, it is characterised in that in described controller (200) also includes communication unit (260), this communication unit (260) and control room
Control with computer (300) connect, send data in real time.
The most according to claim 1 have the anodic oxidation that the medicine utilizing electrolyte to automatically analyze puts into the metal of function
Processing system, it is characterised in that the side of described electrolysis bath (1) is additionally provided with degreasing plant (10), this degreasing plant (10) wraps
Include:
Degreasing bath (11)；
Drainage screen (12), this drainage screen (12) is arranged in described degreasing bath (11), for from crossing dividing of described electrolysis bath (1)
Segregating foreign objects in the electrolyte of wall (4)；
Pump (P2), this pump (P2) is for sending water by the electrolyte of defat from described degreasing bath (10) by flow pipe (14).
The most according to claim 1 have the anodic oxidation that the medicine utilizing electrolyte to automatically analyze puts into the metal of function
Processing system, it is characterised in that the opposite side of described electrolysis bath (1) is additionally provided with metallicity impurities removing unit (20), this gold
Attribute impurities removing unit (20) including:
Filter tank (21)；
Metallicity impurity absorption filter (22), this metallicity impurity absorption filter (22) are arranged on filter tank (21)
In, the metallicity impurity dissolved in the electrolyte of the separates walls (5) crossing electrolysis bath (1) for absorption；
Pump (P3), this pump (P3) is for sending the electrolyte removing metallicity impurity in filter tank (21) by flow pipe (24)
Water.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR10-2014-0035211 | 2014-03-26 | ||
| KR1020140035211A KR101423024B1 (en) | 2014-03-26 | 2014-03-26 | Anodizing Treatment System of Metal through Automatic Analysis of An Electrolyte |
| PCT/KR2014/009600 WO2015147395A1 (en) | 2014-03-26 | 2014-10-14 | Metal anodizing treatment system having chemical injection function through automatic electrolyte analysis |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106133202A true CN106133202A (en) | 2016-11-16 |
Family
ID=51742965
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201480077535.7A Pending CN106133202A (en) | 2014-03-26 | 2014-10-14 | There is the anodized system that the medicine utilizing electrolyte to automatically analyze puts into the metal of function |
Country Status (4)
| Country | Link |
|---|---|
| JP (1) | JP2017514999A (en) |
| KR (1) | KR101423024B1 (en) |
| CN (1) | CN106133202A (en) |
| WO (1) | WO2015147395A1 (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110195247A (en) * | 2019-06-27 | 2019-09-03 | 东莞智富五金制品有限公司 | A kind of anodic oxidation filming equipment of automatic electrolyte |
| CN110618172A (en) * | 2018-06-20 | 2019-12-27 | 深圳市裕展精密科技有限公司 | Analysis method and analysis system for anodic oxidation electrolyte of titanium or titanium alloy |
| CN114351231A (en) * | 2022-01-04 | 2022-04-15 | 深圳技术大学 | Apparatus and method for measuring and monitoring the concentration of metal ions in an electrolyte |
| US11340205B2 (en) | 2019-01-24 | 2022-05-24 | Hong Kong Applied Science And Technology Research Institute Co., Ltd. | Systems and methods for determining concentrations of materials in solutions |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114540933B (en) * | 2022-03-03 | 2023-04-25 | 常熟市新达模塑成型有限公司 | Electrolytic cell capable of continuously controlling electrolyte depth without measuring device and adjusting method thereof |
| WO2024069257A1 (en) * | 2022-09-26 | 2024-04-04 | Casanova Luca | System and method for coloring metal objects |
| CN117305940A (en) * | 2023-11-29 | 2023-12-29 | 威海德旭船舶有限公司 | Aluminum product anodic oxidation system |
Citations (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4055751A (en) * | 1975-05-13 | 1977-10-25 | Siemens Aktiengesellschaft | Process control system for the automatic analysis and regeneration of galvanic baths |
| JPS59116400A (en) * | 1982-12-23 | 1984-07-05 | Nippon Steel Corp | Automatic controlling method of concentration in plating bath |
| JPH0379794A (en) * | 1989-08-19 | 1991-04-04 | Fujitsu Ltd | Method for controlling plating solution |
| JP2002167698A (en) * | 2000-11-28 | 2002-06-11 | Nec Kansai Ltd | Plating equipment |
| JP2002235194A (en) * | 2001-02-05 | 2002-08-23 | Fuji Denka Kk | Method for controlling treatment solution in anodic oxidation treatment for aluminum or aluminum alloy |
| KR100945725B1 (en) * | 2009-10-14 | 2010-03-05 | 주식회사 삼원알텍 | Anodizing treatment method of metal having grease removing apparatus and apparatus thereof |
| KR101048041B1 (en) * | 2011-02-22 | 2011-07-13 | 주식회사 삼원알텍 | Apparatus for auto input of sulfuric acid for anodizing treatment apparatus of metal |
| KR20120005714A (en) * | 2010-07-09 | 2012-01-17 | 한국생산기술연구원 | Method for treating a surface of a magnesium alloy and magnesium alloy having a surface treated by the same |
| CN202175734U (en) * | 2011-08-22 | 2012-03-28 | 胜宏科技（惠州）有限公司 | Automatic adding device for electroplating solution |
| CN202465940U (en) * | 2012-01-04 | 2012-10-03 | 江阴三知工控机械有限公司 | Device for monitoring concentration in phosphoric acid tank on line and adding phosphoric acid automatically |
| CN102703947A (en) * | 2012-05-23 | 2012-10-03 | 上海飞机制造有限公司 | Bath solution supplementing method for microarc oxidation ion exchange membrane electrolytic bath |
| CN202465937U (en) * | 2012-01-04 | 2012-10-03 | 江阴三知工控机械有限公司 | On-line concentration monitoring and automatic feeding device for soap immersion trough |
| KR101244166B1 (en) * | 2012-07-30 | 2013-04-02 | 주식회사 삼원알텍 | Metalic impurity eleminating filter for anodizing treatment of metal |
| CN103266316A (en) * | 2013-05-09 | 2013-08-28 | 东风汽车紧固件有限公司 | Phosphating solution online-monitoring and automatic-supplementing apparatus |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5110139A (en) * | 1974-07-15 | 1976-01-27 | Fuji Photo Film Co Ltd | KINZOKUHYOMENSHORIEKINODONO SEIGYOHOHO |
| JPS5844759B2 (en) * | 1981-02-26 | 1983-10-05 | 勝川工業株式会社 | Electrolysis method and device using electrodes with fluid permeation function |
| JP2944999B1 (en) * | 1998-08-21 | 1999-09-06 | 日本ニユクリア・フユエル株式会社 | Cladding tube surface treatment equipment |
| JP2003019876A (en) * | 2001-07-06 | 2003-01-21 | Fuji Photo Film Co Ltd | Device for manufacturing lithographic printing plate and method for detecting insulation failure spot in the device |
| JP2005060781A (en) * | 2003-08-14 | 2005-03-10 | Fuji Photo Film Co Ltd | Method and apparatus for surface treatment of aluminum support |
| JP4869183B2 (en) * | 2007-08-28 | 2012-02-08 | 中国電力株式会社 | Portable recording medium management system, portable recording medium management method, and program |
-
2014
- 2014-03-26 KR KR1020140035211A patent/KR101423024B1/en active IP Right Grant
- 2014-10-14 WO PCT/KR2014/009600 patent/WO2015147395A1/en active Application Filing
- 2014-10-14 JP JP2017502546A patent/JP2017514999A/en active Pending
- 2014-10-14 CN CN201480077535.7A patent/CN106133202A/en active Pending
Patent Citations (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4055751A (en) * | 1975-05-13 | 1977-10-25 | Siemens Aktiengesellschaft | Process control system for the automatic analysis and regeneration of galvanic baths |
| JPS59116400A (en) * | 1982-12-23 | 1984-07-05 | Nippon Steel Corp | Automatic controlling method of concentration in plating bath |
| JPH0379794A (en) * | 1989-08-19 | 1991-04-04 | Fujitsu Ltd | Method for controlling plating solution |
| JP2002167698A (en) * | 2000-11-28 | 2002-06-11 | Nec Kansai Ltd | Plating equipment |
| JP2002235194A (en) * | 2001-02-05 | 2002-08-23 | Fuji Denka Kk | Method for controlling treatment solution in anodic oxidation treatment for aluminum or aluminum alloy |
| KR100945725B1 (en) * | 2009-10-14 | 2010-03-05 | 주식회사 삼원알텍 | Anodizing treatment method of metal having grease removing apparatus and apparatus thereof |
| KR20120005714A (en) * | 2010-07-09 | 2012-01-17 | 한국생산기술연구원 | Method for treating a surface of a magnesium alloy and magnesium alloy having a surface treated by the same |
| KR101048041B1 (en) * | 2011-02-22 | 2011-07-13 | 주식회사 삼원알텍 | Apparatus for auto input of sulfuric acid for anodizing treatment apparatus of metal |
| CN202175734U (en) * | 2011-08-22 | 2012-03-28 | 胜宏科技（惠州）有限公司 | Automatic adding device for electroplating solution |
| CN202465940U (en) * | 2012-01-04 | 2012-10-03 | 江阴三知工控机械有限公司 | Device for monitoring concentration in phosphoric acid tank on line and adding phosphoric acid automatically |
| CN202465937U (en) * | 2012-01-04 | 2012-10-03 | 江阴三知工控机械有限公司 | On-line concentration monitoring and automatic feeding device for soap immersion trough |
| CN102703947A (en) * | 2012-05-23 | 2012-10-03 | 上海飞机制造有限公司 | Bath solution supplementing method for microarc oxidation ion exchange membrane electrolytic bath |
| KR101244166B1 (en) * | 2012-07-30 | 2013-04-02 | 주식회사 삼원알텍 | Metalic impurity eleminating filter for anodizing treatment of metal |
| CN103266316A (en) * | 2013-05-09 | 2013-08-28 | 东风汽车紧固件有限公司 | Phosphating solution online-monitoring and automatic-supplementing apparatus |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110618172A (en) * | 2018-06-20 | 2019-12-27 | 深圳市裕展精密科技有限公司 | Analysis method and analysis system for anodic oxidation electrolyte of titanium or titanium alloy |
| CN110618172B (en) * | 2018-06-20 | 2022-05-24 | 深圳市裕展精密科技有限公司 | Analysis method and analysis system for anodic oxidation electrolyte of titanium or titanium alloy |
| US11340205B2 (en) | 2019-01-24 | 2022-05-24 | Hong Kong Applied Science And Technology Research Institute Co., Ltd. | Systems and methods for determining concentrations of materials in solutions |
| CN110195247A (en) * | 2019-06-27 | 2019-09-03 | 东莞智富五金制品有限公司 | A kind of anodic oxidation filming equipment of automatic electrolyte |
| CN114351231A (en) * | 2022-01-04 | 2022-04-15 | 深圳技术大学 | Apparatus and method for measuring and monitoring the concentration of metal ions in an electrolyte |
| CN114351231B (en) * | 2022-01-04 | 2022-11-25 | 深圳技术大学 | Apparatus and method for measuring and monitoring the concentration of metal ions in an electrolyte |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2015147395A1 (en) | 2015-10-01 |
| KR101423024B1 (en) | 2014-07-29 |
| JP2017514999A (en) | 2017-06-08 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106133202A (en) | There is the anodized system that the medicine utilizing electrolyte to automatically analyze puts into the metal of function | |
| Zhang et al. | Electrodeposition of high corrosion resistance Cu/Ni–P coating on AZ91D magnesium alloy | |
| Zarebidaki et al. | Microstructure and corrosion behavior of electrodeposited nano-crystalline nickel coating on AZ91 Mg alloy | |
| CN102747393B (en) | Composite multi-layer nickel electrolytic coating and electro-plating method thereof | |
| TW201325905A (en) | Surface treatment for aluminum or aluminum alloy and product manufactured by the same | |
| Poroch-Seritan et al. | Experimental design for modelling and multi-response optimization of Fe–Ni electroplating process | |
| CN104502196A (en) | Device and method for detecting hydrogen embrittlement sensibility in high-strength steel surface treatment process | |
| KR101557050B1 (en) | Rack for Anodizing Treatment | |
| Yogesha et al. | Optimization of deposition conditions for development of high corrosion resistant Zn–Fe multilayer coatings | |
| Razaghi et al. | Electrochemical noise and impedance study on the corrosion of electroplated Ni-Cr coatings in HBF4 aqueous solution | |
| KR101925748B1 (en) | An Electrolyte current analysis And Automatic Sulfuric Acid Supply System for Metal Anodizing Treatment Apparatus | |
| US8512541B2 (en) | Electrolytic dissolution of chromium from chromium electrodes | |
| Neuróhr et al. | Near-substrate composition depth profile of direct current-plated and pulse-plated Fe–Ni alloys | |
| KR101048041B1 (en) | Apparatus for auto input of sulfuric acid for anodizing treatment apparatus of metal | |
| Moradi et al. | Pulse electrodeposition as a new approach in electrowinning of high purity cobalt from WC–Co scraps. Part I: The effect of frequency and duty cycle | |
| Liu et al. | The effect of pulse reversal on morphology of cobalt hard gold | |
| Liu et al. | Modeling of galvanostatic pulse and pulsed reverse electroplating of gold | |
| CN101603197A (en) | Electropolishing is with electrolyte prescription and electrolysis process | |
| CN103911649A (en) | Preparation method of zinc-based composite coating | |
| CN103088380A (en) | Methods for preparing super-hydrophobic coatings on surfaces of magnesium and magnesium alloy | |
| Ivanov et al. | Corrosion resistance of compositionally modulated Zn–Ni multilayers electrodeposited from dual baths | |
| Sulyma et al. | Analysis of current transients for voltage pulse-modulated surface processing: Application to anodic electro-dissolution of copper for electrochemical mechanical planarization | |
| TWI690624B (en) | Method for electrolytically depositing a zinc-nickel alloy layer on at least a substrate to be treated | |
| CN204314149U (en) | A kind of device detecting plow-steel process of surface treatment Hydrogen Embrittlement | |
| Bhat et al. | Corrosion stability of electrodeposited cyclic multilayer Zn–Ni alloy coatings |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20161116 |