CN106119892A - The overflow mechanism of electrolyte - Google Patents
The overflow mechanism of electrolyte Download PDFInfo
- Publication number
- CN106119892A CN106119892A CN201610796339.6A CN201610796339A CN106119892A CN 106119892 A CN106119892 A CN 106119892A CN 201610796339 A CN201610796339 A CN 201610796339A CN 106119892 A CN106119892 A CN 106119892A
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- CN
- China
- Prior art keywords
- electrolyte
- siphon
- chamber
- overflow
- pipe
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C1/00—Electrolytic production, recovery or refining of metals by electrolysis of solutions
- C25C1/12—Electrolytic production, recovery or refining of metals by electrolysis of solutions of copper
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C7/00—Constructional parts, or assemblies thereof, of cells; Servicing or operating of cells
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Electrolytic Production Of Metals (AREA)
Abstract
The invention discloses the overflow mechanism of a kind of electrolyte, including overflow pipe and the collector tube collecting overflow electrolyte, in the overflowing liquid entrance of overflow pipe upper end is arranged in each electrolysis bath and highly it is identical with liquid level of electrolyte, it is characterised in that: it is connected between lower end electrolyte outlet and the collector tube of overflow pipe and has siphon unit.Layout by siphon unit, just can siphon enter in collector tube when so making to accumulate during the electrolyte in overflow pipe certain altitude, so electrolyte in the electrolyte waited during siphon in overflow pipe with collector tube is in partition state, that is the loop of electric leakage is cut off, so can efficiently reduce electric leakage, thus reduce power consumption, extend the service life of pipeline.
Description
Technical field
The present invention relates to technical field of smelting, be specifically related to the overflow mechanism of a kind of electrolyte.
Background technology
In prior art, copper mine enterprise is usually to be placed in electrolysis bath the blister copper prepared and uses electro deposition pure
Copper, but in actual production, the impurity such as arsenic in blister copper, antimony, bismuth can synchronize electrolytically generated arsenic ion, antimony ion with copper
Deng impurity, these ionic impurities can form the least flocculent substance of dissolubility in copper electrolyte and adhere to negative electrode and electricity
Solve the surface of copper, greatly reduce the quality of the cathode copper of generation.To this end, during actual arrangement at the electrolyte in meeting electrolysis bath
In continuous circulation state, i.e. as it is shown in figure 1, reality can constantly have new electrolyte to add to electrolysis by pipeline
In groove 1, also can arrange an overflow pipe 2 in electrolysis bath 1, the upper end mouth of pipe of overflow pipe 2 is upward and mouth of pipe height is less than electrolysis simultaneously
The notch height of groove 1, the electrolyte of the upper end mouth of pipe so exceeding overflow pipe 2 the upper end mouth of pipe of overflow pipe 2 will overflow into and lead to
Piping is delivered to cleaning system and utilizes with Posterior circle to be clean,.
But, there is problems in that as it is shown in figure 1, due to the electrolysis in the overflow pipe 2 of each electrolysis bath 1 time actually used
Liquid can be pooled in a collector tube 3 concentrate and be delivered to cleaning system, and each electrolysis bath 1 is connected in series energising, as long as this results in
When having the state that two electrolysis baths 1,1a are in simultaneously overflow electrolyte, the two electrolysis bath 1,1a overflow pipe 2 in electrolysis
Liquid will form a current loop with the electrolyte in collector tube 3, and this current loop is the equal of and described two electrolysis
Circuit in parallel between groove 1,1a, the phenomenon that so will result in electric leakage occurs.Moreover, the overflow pipe that current loop is corresponding
2 and collector tube 3 pipeline section in will electrode separate out copper, not only can damage pipeline, and the service life of pipeline can be substantially reduced.
Therefore, how to solve the problems such as electrolyte overflow electric leakage, this is the problem that relevant enterprise have to consider.
Summary of the invention
It is an object of the invention to provide a kind of simple in construction, the overflow mechanism of the electrolyte that stability in use is good.
For achieving the above object, the technical solution used in the present invention is: the overflow mechanism of a kind of electrolyte, including overflow pipe
With collect the collector tube of overflow electrolyte, in the overflowing liquid entrance of overflow pipe upper end is arranged in each electrolysis bath and height and electrolyte
Liquid level coincide, it is characterised in that: it is connected between lower end electrolyte outlet and the collector tube of overflow pipe and has siphon unit.
Use having the beneficial effects that of technique scheme generation: by the layout of siphon unit, so make overflow pipe
In electrolyte time just can siphon enter in collector tube when accumulating certain altitude, so overflow during wait siphon
Electrolyte in pipe and the electrolyte in collector tube are in partition state, that is the loop of electric leakage is cut off, and so can have
Effect ground reduces electric leakage, thus reduces power consumption, extends the service life of pipeline.
Accompanying drawing explanation
Fig. 1 is the distribution schematic diagram of anolyte return in prior art；
Fig. 2 is the structural representation of the present invention.
Detailed description of the invention
The overflow mechanism of a kind of electrolyte, as in figure 2 it is shown, it includes overflow pipe 10 and collects the collector tube of overflow electrolyte
70, the overflowing liquid entrance of overflow pipe 10 upper end is arranged in each electrolysis bath and height is identical with liquid level of electrolyte, overflow pipe
It is connected between the lower end electrolyte outlet of 10 and collector tube 70 and has siphon unit.By the layout of siphon unit, so make to overflow
Just can siphon enter in collector tube 70 when accumulating certain altitude during electrolyte in flow tube 10, so in the mistake waiting siphon
In journey, the electrolyte in overflow pipe 10 and the electrolyte in collector tube 70 are in partition state, that is the loop of electric leakage is cut
Disconnected, so compared with the continuous flow of prior art, use technique scheme disclosed by the invention can efficiently reduce leakage
Electricity, thus reduce power consumption, extend the service life of pipeline.
Further, described siphon unit the most at least arranged in series two, concrete, described siphon unit
Including first and second two siphons 20,30 going to upper and lower layout.By the layout of multiple siphon unit, rainbow so can be avoided
Electrolyte is occurred to form current loop continuously during suction.
For the concrete structure of two siphon unit, as in figure 2 it is shown, the tube chamber of overflow pipe 10 includes first from top to bottom,
Second chamber 11,12, the high and low end of the first siphon 20 inserts from the top tube wall of first, second chamber 11,12 respectively
One, in the second chamber 11,12, the high-end top tube wall from the second chamber 11 of the second siphon 20 is inserted in the second chamber 11,
The low side of the second siphon 20 leads to the collector tube 70 collecting overflow electrolyte.Time the most actually used, first, second chamber
11, it is to be communicated by the first siphon 20 between the liquid in 12, and specifically only has the overflow electrolyte in the first chamber 11 to arrive
When reaching certain liquid level, just can be through the first siphon 20 siphon to the according to the electrolyte in siphon principle the first chamber 11
In two chambers 12, the electrolyte in the second chamber 12 is same, is also through the most just siphon leading to collector tube 70
In, effectively the electrolyte in overflow pipe 10 is cut off thus by siphonal layout, make electrolyte enter with batch (-type) overflow
Enter in collector tube 70.Present configuration is simple, practical, and using effect is good.
As further preferred version, as in figure 2 it is shown, the tube chamber of described overflow pipe 10 is by two spaced apart dividing plates
50 separate first, second, third chamber 11,12,13 that composition is arranged up and down, and described siphon unit also includes the 3rd siphon
40, the high and low end of the second siphon 20 inserts second, third chamber from the top tube wall of second, third chamber 12,13 respectively
12, in 13, the high-end top tube wall from the 3rd chamber 13 of the 3rd siphon 40 is inserted in the 3rd chamber 13, the 3rd siphon 40
The low side mouth of pipe lead in the collector tube collecting overflow electrolyte.So when actually used, when the first siphon 20 is just at rainbow
During suction, it is possible to cause the second siphon 30 to start to occur siphon, the electrolyte in such first, second chamber 11,12
Will occur continuously, but be caused by the second siphon 30 siphon fluid infusion when the 3rd siphon 40 starts siphon, and when the
Two, when the 3rd siphon 30,40 starts simultaneously at siphon, the first siphon 20 is just essentially 0 in the probability of siphon, thus by
Multiple chambers interval carries out siphon overflowing liquid, may further ensure that overflowing liquid stops in short route, and then improves elimination leakage
The reliability of electricity, thus be prevented effectively from the formation of existing current loop and leak electricity.
Preferably, the upper end mouth of pipe of overflow pipe 10 is disposed with cover plate 14, the plate face of cover plate 14 is disposed with for feed tube 60
The perforate that plant connects, offers the V-notch 61 that electrolysis hydrorrhea enters, individually arranges feed liquor at the upper end mouth of pipe of feed tube 60
Pipe 60, so can control electrolyte and overflow to the flow in overflow pipe 10, be arranged to by the upper end mouth of pipe of feed tube 60 meanwhile
V-notch 61, so can allow electrolyte slowly flow into overflow pipe from V-notch 61.Certainly, actual add man-hour can be into
The upper end mouth of pipe of liquid pipe 60 directly offers V-notch 61, for convenience of processing, it is also possible to the end sheathed connecting tube of the mouth of pipe thereon,
The upper end mouth of pipe of connecting tube offers V-notch 61, as shown in Figure 2.
Concrete, as in figure 2 it is shown, the high-end mouth of pipe of first, second, third siphon 20,30,40 extends to separately down
Near at the bottom of the chamber of first, second, third chamber 11,12,13, first, second, third siphon 20,30,40 so can be improved
Electrolyte content in siphon first, second, third chamber 11,12,13, so may insure that substantial amounts of electrolyte is by once
Siphon is fallen, and makes the electrolyte added in each chamber have little time the electrolyte with siphon and occurs continuously.
Further, as it is shown in figure 1, first, second siphon 20,30 is once drawn in first, second chamber 11,12
Liquid height is respectively h1, h3, and when second, third siphon 30,40 siphon, second, third chamber 12,13 needs the liquid met
Position height is h2, h4, and described h1 > h2 > h3 > h4, time the most actually used, the first siphon 20 is by the electrolysis in the first chamber 11
When liquid is once drawn into the second chamber 12, the second siphon 30 will directly meet siphon requirement and electrolyte directly sucks the
In three chambers 13, similarly, electrolyte also correspondingly can be siphoned away and enter in collector tube by the 3rd siphon 40, so can be true
Protect the electrolyte accumulated in overflow pipe 10 quickly to be drained, thus avoid lower chamber to treat the second siphon of its upper chamber
When liquid enters and siphon occurs, upper chamber siphon liquid is too much and siphonage time is long, so can use up and reduce overflow possibly greatly
Electrolyte in pipe 10 flows continuously.
Concrete, described overflow mechanism is to use PVC material or acidproof, alkaline-resisting process for un-metal material to make,
It is to say, described overflow pipe 10, dividing plate 50 and each siphon are all to use the process for un-metal material such as PVC to make, from
And guarantee the safe and reliable property that overflow mechanism uses.
Claims (8)
1. an overflow mechanism for electrolyte, including overflow pipe (10) and the collector tube (70) that collects overflow electrolyte, overflow pipe
(10) in the overflowing liquid entrance of upper end is arranged in each electrolysis bath and highly it is identical with liquid level of electrolyte, it is characterised in that: overflow
It is connected between the lower end electrolyte outlet of flow tube (10) with collector tube (70) and has siphon unit.
The overflow mechanism of the electrolyte described in 1 the most as requested, it is characterised in that: described siphon unit is the most at least gone here and there
Connection arranges two.
The overflow mechanism of the electrolyte described in 2 the most as requested, it is characterised in that: described siphon unit includes going to upper and lower cloth
First and second two siphons (20,30) put, the tube chamber of overflow pipe (10) include from top to bottom first, second chamber (11,
12), the high and low end of the first siphon (20) inserts first, second from the top tube wall of first, second chamber (11,12) respectively
In chamber (11,12), the high-end top tube wall from the second chamber (11) of the second siphon (20) is inserted in the second chamber (11),
The low side of the second siphon (20) leads to the collector tube (70) collecting overflow electrolyte.
The overflow mechanism of electrolyte the most according to claim 3, it is characterised in that: the tube chamber of described overflow pipe (10) passes through
Two spaced apart dividing plates (50) separate first, second, third chamber (11,12,13) that composition is arranged up and down, described siphon list
Unit also includes the 3rd siphon (40), upper from second, third chamber (12,13) respectively of the high and low end of the second siphon (20)
Portion's tube wall is inserted in second, third chamber (12,13), the high-end top tube wall from the 3rd chamber (13) of the 3rd siphon (40)
Inserting in the 3rd chamber (13), the low side mouth of pipe of the 3rd siphon (40) leads in the collector tube (70) collecting overflow electrolyte.
The overflow mechanism of electrolyte the most according to claim 4, it is characterised in that: the upper end mouth of pipe of overflow pipe (10) is arranged
There is cover plate (14), the plate face of cover plate (14) is disposed with the perforate of connection of planting for feed tube (60), the upper end of feed tube (60)
The V-notch (61) that electrolysis hydrorrhea enters is offered at the mouth of pipe.
The overflow mechanism of electrolyte the most according to claim 5, it is characterised in that: first, second, third siphon (20,
30,40) the high-end mouth of pipe extends close at the bottom of the chamber of first, second, third chamber (11,12,13) separately down.
The overflow mechanism of electrolyte the most according to claim 6, it is characterised in that: first, second siphon (20,30)
Liquid height in secondary absorption first, second chamber (11,12) is respectively h1, h3, second, third siphon (30,40) siphon
Time second, third chamber (12,13) need meet liquid level be h2, h4, described h1 > h2 > h3 > h4.
The overflow mechanism of electrolyte the most according to claim 7, it is characterised in that: described overflow mechanism is to use PVC material
Material or acidproof, alkaline-resisting process for un-metal material are made.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610796339.6A CN106119892B (en) | 2016-08-31 | 2016-08-31 | The overflow mechanism of electrolyte |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610796339.6A CN106119892B (en) | 2016-08-31 | 2016-08-31 | The overflow mechanism of electrolyte |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106119892A true CN106119892A (en) | 2016-11-16 |
| CN106119892B CN106119892B (en) | 2018-07-13 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610796339.6A Active CN106119892B (en) | 2016-08-31 | 2016-08-31 | The overflow mechanism of electrolyte |
Country Status (1)
| Country | Link |
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| CN (1) | CN106119892B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114122463A (en) * | 2020-11-30 | 2022-03-01 | 海川太风水储能科技(无锡)有限公司 | Flow battery electrolyte storage tank |
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| RU2081946C1 (en) * | 1994-12-26 | 1997-06-20 | Акционерное общество "Союзцветметавтоматика" | Device for interrupting electrolyte jet |
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| Publication number | Publication date |
|---|---|
| CN106119892B (en) | 2018-07-13 |
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Effective date of registration: 20190412 Address after: 244100 West Building of Changjiang West Road Nonferrous Courtyard, Tongling City, Anhui Province Patentee after: Tongling Nonferrous Metals Group Co., Ltd. Address before: 244100 Jinguan Copper Branch of Tongling Nonferrous Circular Economy Industrial Park, Anhui Province Patentee before: JINGUAN COPPER INDUSTRY BRANCH OF TONGLING NONFERROUS METALS GROUP HOLDING CO., LTD. |
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