CN106117941A - 一种涂料用催干剂 - Google Patents
一种涂料用催干剂 Download PDFInfo
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- CN106117941A CN106117941A CN201610464202.0A CN201610464202A CN106117941A CN 106117941 A CN106117941 A CN 106117941A CN 201610464202 A CN201610464202 A CN 201610464202A CN 106117941 A CN106117941 A CN 106117941A
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- 239000003973 paint Substances 0.000 title claims abstract description 14
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 36
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 26
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 26
- 229920002401 polyacrylamide Polymers 0.000 claims abstract description 18
- 239000011656 manganese carbonate Substances 0.000 claims abstract description 13
- 229940093474 manganese carbonate Drugs 0.000 claims abstract description 13
- 235000006748 manganese carbonate Nutrition 0.000 claims abstract description 13
- 229910000016 manganese(II) carbonate Inorganic materials 0.000 claims abstract description 13
- XMWCXZJXESXBBY-UHFFFAOYSA-L manganese(ii) carbonate Chemical compound [Mn+2].[O-]C([O-])=O XMWCXZJXESXBBY-UHFFFAOYSA-L 0.000 claims abstract description 13
- 239000011787 zinc oxide Substances 0.000 claims abstract description 13
- NKFIBMOQAPEKNZ-UHFFFAOYSA-N 5-amino-1h-indole-2-carboxylic acid Chemical compound NC1=CC=C2NC(C(O)=O)=CC2=C1 NKFIBMOQAPEKNZ-UHFFFAOYSA-N 0.000 claims abstract description 12
- 229940120693 copper naphthenate Drugs 0.000 claims abstract description 11
- SEVNKWFHTNVOLD-UHFFFAOYSA-L copper;3-(4-ethylcyclohexyl)propanoate;3-(3-ethylcyclopentyl)propanoate Chemical compound [Cu+2].CCC1CCC(CCC([O-])=O)C1.CCC1CCC(CCC([O-])=O)CC1 SEVNKWFHTNVOLD-UHFFFAOYSA-L 0.000 claims abstract description 11
- 239000002994 raw material Substances 0.000 claims abstract description 8
- 238000002360 preparation method Methods 0.000 claims abstract description 7
- 238000003756 stirring Methods 0.000 claims description 5
- 239000002253 acid Substances 0.000 claims description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 2
- 229910052802 copper Inorganic materials 0.000 claims description 2
- 239000010949 copper Substances 0.000 claims description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims 1
- 229910052791 calcium Inorganic materials 0.000 claims 1
- 239000011575 calcium Substances 0.000 claims 1
- 235000009508 confectionery Nutrition 0.000 claims 1
- 238000001035 drying Methods 0.000 abstract description 5
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- 238000000576 coating method Methods 0.000 description 5
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 4
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000013112 stability test Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/02—Organic and inorganic ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/05—Alcohols; Metal alcoholates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/05—Alcohols; Metal alcoholates
- C08K5/053—Polyhydroxylic alcohols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
- C08K5/098—Metal salts of carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09F—NATURAL RESINS; FRENCH POLISH; DRYING-OILS; OIL DRYING AGENTS, i.e. SICCATIVES; TURPENTINE
- C09F9/00—Compounds to be used as driers, i.e. siccatives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Paints Or Removers (AREA)
Abstract
本发明公开了一种涂料用催干剂，由以下重量份配比的原料组成：环烷酸钙1‑4份、环烷酸铜1‑2份、碳酸锰1‑2份、氧化锌1‑2份、聚丙烯酰胺1‑5份、乙醇5‑10份、甘油5‑10份。本发明的催干剂，制备简单，不仅催干性能好，还具有溶解性好，稳定性好等优点，适合工业化生产。
Description
技术领域
本发明涉及催干剂技术领域，具体涉及一种涂料用催干剂。
背景技术
催干剂是涂料工业的主要助剂，其作用是加速漆膜的氧化、聚合、干燥,达到快干的目的。涂料催干剂最注重是速度，快干才能保证工业生产的高效，故大多数催干剂追求的都是催干速度，而溶解性较差。
发明内容
针对上述，本发明的目的是提供一种涂料用催干剂，其溶解性好，不皂化物含量低，具有良好的催干性能。
本发明采取的技术方案是：
一种涂料用催干剂，由以下重量份配比的原料组成：环烷酸钙1-4份、环烷酸铜1-2份、碳酸锰1-2份、氧化锌1-2份、聚丙烯酰胺1-5份、乙醇5-10份、甘油5-10份。
优选地，所述的涂料用催干剂，由以下重量份配比的原料组成：环烷酸钙2.5份、环烷酸铜1.5份、碳酸锰1.5份、氧化锌1.5份、聚丙烯酰胺3份、乙醇7.5份、甘油7.5份。
上述涂料用催干剂的制备方法为：
(1)、将聚丙烯酰胺、乙醇和甘油混入容器中，加热至65-70℃；
(2)、待聚丙烯酰胺充分溶解后，再加入环烷酸钙、环烷酸铜、碳酸锰，保持60℃以上的温度，继续溶解；
(3)加入氧化锌，搅拌均匀即可。
溶解性试验：
试剂：200#溶剂油；
测定步骤：取本发明的样品20g置于50ml烧杯中，加入200#溶剂油20g(必要时可水溶加热)，混合均匀后，不分层，无冻状物和沉淀析出。
稳定性试验：
试剂：二甲苯、亚麻仁油；
测定步骤：准确称取本发明的样品10g置于100ml烧杯中，加入5g二甲苯摇匀，再加入预热后的亚麻仁油，混合均匀后，无析出物。
本发明的有益效果是：本发明的催干剂，制备简单，不仅催干性能好，还具有溶解性好，稳定性好等优点，适合工业化生产。
具体实施方式
下面对本发明的实施例进行详细阐述，以使本发明的优点和特征能更易于被本领域技术人员理解，从而对本发明的保护范围做出更为清楚明确的界定。
实施例1
一种涂料用催干剂，由以下重量份配比的原料组成：环烷酸钙1份、环烷酸铜1份、碳酸锰1份、氧化锌1份、聚丙烯酰胺1份、乙醇5份、甘油5份。
上述涂料用催干剂的制备方法为：
(1)、将聚丙烯酰胺、乙醇和甘油混入容器中，加热至65-70℃；
(2)、待聚丙烯酰胺充分溶解后，再加入环烷酸钙、环烷酸铜、碳酸锰，保持60℃以上的温度，继续溶解；
(3)加入氧化锌，搅拌均匀即可。
实施例2
一种涂料用催干剂，由以下重量份配比的原料组成：环烷酸钙2.5份、环烷酸铜1.5份、碳酸锰1.5份、氧化锌1.5份、聚丙烯酰胺3份、乙醇7.5份、甘油7.5份。
上述涂料用催干剂的制备方法为：
(1)、将聚丙烯酰胺、乙醇和甘油混入容器中，加热至65-70℃；
(2)、待聚丙烯酰胺充分溶解后，再加入环烷酸钙、环烷酸铜、碳酸锰，保持60℃以上的温度，继续溶解；
(3)加入氧化锌，搅拌均匀即可。
实施例3
一种涂料用催干剂，由以下重量份配比的原料组成：环烷酸钙4份、环烷酸铜2份、碳酸锰2份、氧化锌2份、聚丙烯酰胺5份、乙醇10份、甘油10份。
上述涂料用催干剂的制备方法为：
(1)、将聚丙烯酰胺、乙醇和甘油混入容器中，加热至65-70℃；
(2)、待聚丙烯酰胺充分溶解后，再加入环烷酸钙、环烷酸铜、碳酸锰，保持60℃以上的温度，继续溶解；
(3)加入氧化锌，搅拌均匀即可。
Claims (3)
1.一种涂料用催干剂，其特征在于由以下重量份配比的原料组成：环烷酸钙1-4份、环烷酸铜1-2份、碳酸锰1-2份、氧化锌1-2份、聚丙烯酰胺1-5份、乙醇5-10份、甘油5-10份。
2.根据权利要求1所述的涂料用催干剂，其特征在于由以下重量份配比的原料组成：环烷酸钙2.5份、环烷酸铜1.5份、碳酸锰1.5份、氧化锌1.5份、聚丙烯酰胺3份、乙醇7.5份、甘油7.5份。
3.根据权利要求1或2所述的涂料用催干剂，其特征在于制备方法为：
(1)、将聚丙烯酰胺、乙醇和甘油混入容器中，加热至65-70℃；
(2)、待聚丙烯酰胺充分溶解后，再加入环烷酸钙、环烷酸铜、碳酸锰，保持60℃以上的温度，继续溶解；
(3)加入氧化锌，搅拌均匀即可。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610464202.0A CN106117941A (zh) | 2016-06-23 | 2016-06-23 | 一种涂料用催干剂 |
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| CN201610464202.0A CN106117941A (zh) | 2016-06-23 | 2016-06-23 | 一种涂料用催干剂 |
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| CN106117941A true CN106117941A (zh) | 2016-11-16 |
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| CN201610464202.0A Pending CN106117941A (zh) | 2016-06-23 | 2016-06-23 | 一种涂料用催干剂 |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB339922A (zh) * | 1929-02-23 | |||
| GB364863A (en) * | 1931-01-21 | 1932-01-14 | Ig Farbenindustrie Ag | Process for preventing the sedimentation and gelatinisation of solutions of driers in volatile organic solvents |
| US3705852A (en) * | 1970-12-01 | 1972-12-12 | Tenneco Chem | Stable solutions of calcium salts |
| CN105567093A (zh) * | 2014-10-14 | 2016-05-11 | 武汉鸿信通科技有限公司 | 一种工业涂料用催干剂的制备方法 |
-
2016
- 2016-06-23 CN CN201610464202.0A patent/CN106117941A/zh active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB339922A (zh) * | 1929-02-23 | |||
| GB364863A (en) * | 1931-01-21 | 1932-01-14 | Ig Farbenindustrie Ag | Process for preventing the sedimentation and gelatinisation of solutions of driers in volatile organic solvents |
| US3705852A (en) * | 1970-12-01 | 1972-12-12 | Tenneco Chem | Stable solutions of calcium salts |
| CN105567093A (zh) * | 2014-10-14 | 2016-05-11 | 武汉鸿信通科技有限公司 | 一种工业涂料用催干剂的制备方法 |
Non-Patent Citations (2)
| Title |
|---|
| 吴世敏 等: "《简明精细化工大辞典》", 30 June 1999 * |
| 常有宏 等: "《设施蔬菜安全用药》", 31 May 2013 * |
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