CN106116840A - A kind of refine fertilizer additive prepared by Chinese herbal medicine active substance and preparation method thereof - Google Patents

Abstract

The invention discloses and a kind of refine fertilizer additive prepared by Chinese herbal medicine active substance and preparation method thereof, it is made up of the raw material of following weight portion: acrylic acid, starch, N, N'-methylene-bisacrylamide, ribavirin, Herba Taraxaci, Pericarpium Granati, plant ash, bone meal, perlite, Calyx Seu Fructus Physalis, Folium Artemisiae Argyi, humic acid powder, pyrethrum flowers, Borax, plant source raw material and appropriate water；Carry out Chinese herbal medicine decocting and refine; obtain the active component that plant growing is useful; the most this composition is easy decomposition failure under natural environmental condition; invention utilizes resin to be well refined into Chinese herbal medicine point and active components of plants merges; slowly discharge while resin decomposition; play the effect of digital preservation; a kind of effect separated is belonged to fertilizer; the zest avoiding fertilizer affects the effect of active component; as a kind of adding ingredient; permanently effective, the stone powder of interpolation dissipates the function of agent when can play resin forming.

Description

A kind of refine fertilizer additive prepared by Chinese herbal medicine active substance and preparation method thereof

Technical field

The invention belongs to the Technology field of fertilizer, be specifically related to a kind of refine fertilizer prepared by Chinese herbal medicine active substance Feed additives and preparation method thereof.

Background technology

In nature, by known to the low-molecular-weight secondary metabolites of phytosynthesis and release just more than 100,000 kinds, its In volatile material just account for significant proportion, and there is certain " abnormal smells from the patient " mostly.This kind of material is as a kind of behavior hint Chemical signal play very important effect between plant and between plant and insecticide, anti-by chemical pesticide is cured the disease Insect pest not only breaks up environment, wastes resource, the main Drug resistance that also can improve crop pest and serious Pesticide Residue, The improvement affecting health insect simultaneously becomes more and more difficult.

The volatile material of plant belongs to the secondary metabolite of plant, typically distributes from leaf surface, plays and walks quickly and keeps away The effect of insect, is mainly derived from the fatty acid of plant, aminoacid and the metabolism of class phenylpropyl alcohol alkane, a series of by chloroplast Enzymatic reaction completes, and discharges, can be divided into 4 classes: isoprene, monoterpene, other active and secondary active substance in air, including Alkanes, alcohols, esters, phosphinylidyne class and acids, they form fatty acid derivant, aromatic compound, monoterpene and sesquialter Terpene compound, has the most antibacterial and anti-insect activity, may be directly applied to the Biological control of pest and disease damage.

The advantage that biological preparation prevents is: general disease pest is played avoidance effect, does not strangles, and does not destroy original Biological chain, so disease pest class will not produce resistance, is also a kind of protection to beneficial organism, a lot of the most this biological plant sources Active substance of plant belongs to the active substance of natural extract plant, does not have toxicity, is free from side effects human body, in soil Slowly volatilization, plays the effect of prevention, will be wholly absent after a period of time, make the agricultural product of plantation, quality more preferably, more strong Health.Easy to use, as long as adding soil with fertilizer or together with the adding ingredient of fertilizer, the larva of insect is typically all Being originated in soil, directly effect soil is best protection.

Summary of the invention

The present invention is in order to play certain prevention and control of plant diseases, pest control effect while improving crop nutrition content, and invention one has Keep away insect pest effect fertilizer additive, realize particular by the following manner:

A kind of refine fertilizer additive prepared by Chinese herbal medicine active substance, it is characterised in that be made up of the raw material of following weight portion: Acrylic acid 20 ~ 30, starch 5 ~ 8, N, N'-methylene-bisacrylamide 0.1 ~ 0.3, ribavirin 1 ~ 3, Herba Taraxaci 10 ~ 15, Pericarpium Granati 3 ~ 6, plant ash 0.5 ~ 1.0, bone meal 2 ~ 4, perlite 1 ~ 3, Calyx Seu Fructus Physalis 8 ~ 12, Folium Artemisiae Argyi 15 ~ 20, humic acid powder 3 ~ 7, remove Worm Flos Chrysanthemi 5 ~ 8, Borax 2 ~ 5, plant source raw material 30 ~ 40 and appropriate water；

Described plant source raw material be with weight (part) be the unit fresh tomato leaf 3 ~ 6 of mixing, Folium seu Cortex Nerii 6 ~ 10, Folium Cinnamomi porrecti 8 ~ 12, Fructus Gleditsia 4 ~ 6, acer monoes 2 ~ 5, Pinus tabuliformis 10 ~ 15, ailanthus altissima (mill.) swingle 10 ~ 14 and Folium Ginkgo 7 ~ 12, after preliminary pulverizing, 0 ~ 5 DEG C of cold preservation is standby.

A kind of preparation method refining fertilizer additive prepared by Chinese herbal medicine active substance, it is characterised in that include following Several steps:

(1) by plant source raw mill 40 ~ 60min uniformly slurry, ultrasonication prepares serosity, adds by material-water ratio 1:2 ~ 3 Entering distilled water diluting, employing steam reflux, extract, 2 ~ 3h must be rich in the aqueous solution of extracting solution；

(2) mixing Herba Taraxaci, Pericarpium Granati and other following residual components being not directed to, add the water of its weight portion 5 ~ 8 times, decoct Boil 80 ~ 100min and obtain active concentration extracting solution, with (1) described aqueous solution after natural cooling；

(3) perlite is put into rotary kiln roasting 2 ~ 3h under the conditions of 500 ~ 600 DEG C, obtains oxidizing roasting product, ground 120 ~ 160 mesh sieves, in mixing ribavirin, humic acid powder and Borax addition to the mixed liquor described in (2), stirring and dissolving；

(4) finally starch is added to the mixed liquor described in (2), heats up under water bath condition 75 ~ 85 DEG C and stir to starch gelatinization, All material dissipate uniformly, be sequentially added into acrylic acid and N, N'-methylene-bisacrylamide, stir 5 ~ 10min after being cooled to room temperature In 60 ~ 70 DEG C of water-baths, react 1.5 ~ 2h, be dried at 70 ~ 80 DEG C after completing, finally grind to form powder.

The material that invention is chosen has Folium seu Cortex Nerii, and its leaf contains the Cardiac glycosides materials such as folinerinum C, and toxicity is big, can kill Worm；Folium Cinnamomi porrecti, plant contains Camphora, monoterpene and sesquialter Monoterpenes, has anthelmintic paralysis effect；Semen Ginkgo, plant contains Folium illicii Lanceolati Acid, ginkegetin, sterols material, toxic, there is anthelmintic insecticidal action；Fructus Lycopersici esculenti, containing multiple Flavonoid substances and life The licopersicin etc. of alkaloids class, can cause insecticide deterrent, refusing to eat and intoxicating phenomenon；Other tree class blade has going back of this effect same There are Fructus Gleditsia, acer monoes, Pinus tabuliformis, ailanthus altissima (mill.) swingle；

Invent Fructus Lycopersici esculenti liquid as raw material, use distilled water lifting manipulation to obtain the water solublity crude extract in tomato leaf, mix chlorine cyanogen Chrysanthemum ester acts on Muskmelon Plants, and research extract, for the resistance effect of aphid, utilizes taking food of EPG instrument test aphid, Aphid and the plant that takes food thereof are accessed same circuit, and the lancet of aphid, as electrode, forms loop during very moment needle-penetration plant, Just have corresponding display, understand the situation that takes food of aphid with this, between test data sheet 1 ~ 10h aphid take food situation, send out Passage the most in time, aphid seldom or causes damage almost without to the blade of Fructus Melo at the beginning, and passage in time is sweet The blade of melon is compromised gradually, shows: the crude extract of Fructus Lycopersici esculenti can prevent the harm of aphid, crude extract anthelminthic effect to show Antifeedant upper, this active substance belongs to a kind of volatile material.

Invention is in order to be applied to reality the action time and action effect improving plant extract, it is necessary to ensure that store this Volatile active material belongs to the material of a kind of slow degraded, simultaneously because planting site is dried, rapid dehydration is likely to lead Cause volatile material lost efficacy or distributed too fast, do not have the effect of long-time protection, in the face of problem above is invented volatility Extracting solution is combined with resin-phase, uses acrylic resin, and it is the resin of a kind of high-hydroscopicity, and it connects with C-C simultaneously High molecular polymer, can be utilized by microbial degradations such as the staphylococcus in soil, streptococcus, can slowly discharge volatility and resist Worm material, is greatly prolonged protected effect.

Beneficial effects of the present invention: carry out Chinese herbal medicine decocting and refine, obtain the active component that plant growing is useful, simultaneously This composition is easy decomposition failure under natural environmental condition, and invention utilizes resin to be well refined into Chinese herbal medicine point and plant Active component merges, and slowly discharges while resin decomposition, plays the effect of digital preservation, with fertilizer belong to a kind of every The effect opened, it is to avoid the zest of fertilizer affects the effect of active component, as a kind of adding ingredient, permanently effective, interpolation Stone powder dissipates the function of agent when can play resin forming.

Detailed description of the invention

Embodiment 1:

A kind of refine fertilizer additive prepared by Chinese herbal medicine active substance, it is characterised in that by the raw material of following weight portion (Kg) Make: acrylic acid 25, starch 7, N, N'-methylene-bisacrylamide 0.2, ribavirin 2, Herba Taraxaci 12, Pericarpium Granati 5, grass Wood ash 0.8, bone meal 3, perlite 2, Calyx Seu Fructus Physalis 10, Folium Artemisiae Argyi 18, humic acid powder 5, pyrethrum flowers 6, Borax 4, plant source raw material 36 With appropriate water；

Described plant source raw material is to be the unit fresh tomato leaf 5 of mixing, Folium seu Cortex Nerii 8, Folium Cinnamomi porrecti 9, Fructus Gleditsia with weight (Kg) 5, acer monoes 4, Pinus tabuliformis 12, ailanthus altissima (mill.) swingle 13 and Folium Ginkgo 10, after preliminary pulverizing, 0 ~ 5 DEG C of cold preservation is standby.

A kind of preparation method refining fertilizer additive prepared by Chinese herbal medicine active substance, it is characterised in that include following Several steps:

(1) by plant source raw mill 40 ~ 60min uniformly slurry, ultrasonication prepares serosity, adds by material-water ratio 1:2 ~ 3 Entering distilled water diluting, employing steam reflux, extract, 2 ~ 3h must be rich in the aqueous solution of extracting solution；

(2) mixing Herba Taraxaci, Pericarpium Granati and other following residual components being not directed to, add the water of its weight portion 5 ~ 8 times, decoct Boil 80 ~ 100min and obtain active concentration extracting solution, with (1) described aqueous solution after natural cooling；

(3) perlite is put into rotary kiln roasting 2 ~ 3h under the conditions of 500 ~ 600 DEG C, obtains oxidizing roasting product, ground 120 ~ 160 mesh sieves, in mixing ribavirin, humic acid powder and Borax addition to the mixed liquor described in (2), stirring and dissolving；

(4) finally starch is added to the mixed liquor described in (2), heats up under water bath condition 75 ~ 85 DEG C and stir to starch gelatinization, All material dissipate uniformly, be sequentially added into acrylic acid and N, N'-methylene-bisacrylamide, stir 5 ~ 10min after being cooled to room temperature In 60 ~ 70 DEG C of water-baths, react 1.5 ~ 2h, be dried at 70 ~ 80 DEG C after completing, finally grind to form powder.

Select 5 mu of rice terraces as test, applying fertilizer when, the fertilizer additive of the present invention is common with Oryza sativa L. Using after the ratio mixing of fertilizer 1:10,5 mu of rice terrace fertilizer of matched group show without any composition, result: test group The soil of rice terrace is thin, and viscous force is good, has the effect of adsorption sustained-release to common fertilizer, and the pest and disease damage in rice terrace is sent out simultaneously Raw rate reduces, and the resistance of Oryza sativa L. is preferable.

Claims (2)

1. one kind is refined fertilizer additive prepared by Chinese herbal medicine active substance, it is characterised in that by the raw material system of following weight portion Become: acrylic acid 20 ~ 30, starch 5 ~ 8, N, N'-methylene-bisacrylamide 0.1 ~ 0.3, ribavirin 1 ~ 3, Herba Taraxaci 10 ~ 15, Pericarpium Granati 3 ~ 6, plant ash 0.5 ~ 1.0, bone meal 2 ~ 4, perlite 1 ~ 3, Calyx Seu Fructus Physalis 8 ~ 12, Folium Artemisiae Argyi 15 ~ 20, humic acid powder 3 ~ 7, pyrethrum flowers 5 ~ 8, Borax 2 ~ 5, plant source raw material 30 ~ 40 and appropriate water；

Described plant source raw material be with weight (part) be the unit fresh tomato leaf 3 ~ 6 of mixing, Folium seu Cortex Nerii 6 ~ 10, Folium Cinnamomi porrecti 8 ~ 12, Fructus Gleditsia 4 ~ 6, acer monoes 2 ~ 5, Pinus tabuliformis 10 ~ 15, ailanthus altissima (mill.) swingle 10 ~ 14 and Folium Ginkgo 7 ~ 12, after preliminary pulverizing, 0 ~ 5 DEG C of cold preservation is standby.

A kind of preparation method refining fertilizer additive prepared by Chinese herbal medicine active substance, it is special Levy and be, including following step:

(1) by plant source raw mill 40 ~ 60min uniformly slurry, ultrasonication prepares serosity, adds by material-water ratio 1:2 ~ 3 Entering distilled water diluting, employing steam reflux, extract, 2 ~ 3h must be rich in the aqueous solution of extracting solution；

(2) mixing Herba Taraxaci, Pericarpium Granati and other following residual components being not directed to, add the water of its weight portion 5 ~ 8 times, decoct Boil 80 ~ 100min and obtain active concentration extracting solution, with (1) described aqueous solution after natural cooling；

(3) perlite is put into rotary kiln roasting 2 ~ 3h under the conditions of 500 ~ 600 DEG C, obtains oxidizing roasting product, ground 120 ~ 160 mesh sieves, in mixing ribavirin, humic acid powder and Borax addition to the mixed liquor described in (2), stirring and dissolving；

(4) finally starch is added to the mixed liquor described in (2), heats up under water bath condition 75 ~ 85 DEG C and stir to starch gelatinization, All material dissipate uniformly, be sequentially added into acrylic acid and N, N'-methylene-bisacrylamide, stir 5 ~ 10min after being cooled to room temperature In 60 ~ 70 DEG C of water-baths, react 1.5 ~ 2h, be dried at 70 ~ 80 DEG C after completing, finally grind to form powder.