CN106113534B - 一种pert保温管道一步法成型工艺 - Google Patents

一种pert保温管道一步法成型工艺 Download PDF

Info

Publication number
CN106113534B
CN106113534B CN201610457361.8A CN201610457361A CN106113534B CN 106113534 B CN106113534 B CN 106113534B CN 201610457361 A CN201610457361 A CN 201610457361A CN 106113534 B CN106113534 B CN 106113534B
Authority
CN
China
Prior art keywords
foaming
inner tube
outer jacket
baffle
utilidor
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201610457361.8A
Other languages
English (en)
Other versions
CN106113534A (zh
Inventor
马金
李永峰
田军伍
李华
张红梅
邱林
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
NINGXIA QINGLONG PIPES INDUSTRY Co Ltd
Original Assignee
NINGXIA QINGLONG PIPES INDUSTRY Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by NINGXIA QINGLONG PIPES INDUSTRY Co Ltd filed Critical NINGXIA QINGLONG PIPES INDUSTRY Co Ltd
Priority to CN201610457361.8A priority Critical patent/CN106113534B/zh
Publication of CN106113534A publication Critical patent/CN106113534A/zh
Application granted granted Critical
Publication of CN106113534B publication Critical patent/CN106113534B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/001Combinations of extrusion moulding with other shaping operations
    • B29C48/0012Combinations of extrusion moulding with other shaping operations combined with shaping by internal pressure generated in the material, e.g. foaming
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C44/00Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
    • B29C44/34Auxiliary operations
    • B29C44/35Component parts; Details or accessories
    • B29C44/351Means for preventing foam to leak out from the foaming device during foaming
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C44/00Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
    • B29C44/34Auxiliary operations
    • B29C44/36Feeding the material to be shaped
    • B29C44/38Feeding the material to be shaped into a closed space, i.e. to make articles of definite length
    • B29C44/42Feeding the material to be shaped into a closed space, i.e. to make articles of definite length using pressure difference, e.g. by injection or by vacuum
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C44/00Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
    • B29C44/34Auxiliary operations
    • B29C44/36Feeding the material to be shaped
    • B29C44/38Feeding the material to be shaped into a closed space, i.e. to make articles of definite length
    • B29C44/42Feeding the material to be shaped into a closed space, i.e. to make articles of definite length using pressure difference, e.g. by injection or by vacuum
    • B29C44/424Details of machines
    • B29C44/425Valve or nozzle constructions; Details of injection devices
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/001Combinations of extrusion moulding with other shaping operations
    • B29C48/0013Extrusion moulding in several steps, i.e. components merging outside the die
    • B29C48/0015Extrusion moulding in several steps, i.e. components merging outside the die producing hollow articles having components brought in contact outside the extrusion die
    • B29C48/0016Extrusion moulding in several steps, i.e. components merging outside the die producing hollow articles having components brought in contact outside the extrusion die using a plurality of extrusion dies
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/001Combinations of extrusion moulding with other shaping operations
    • B29C48/0021Combinations of extrusion moulding with other shaping operations combined with joining, lining or laminating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/001Combinations of extrusion moulding with other shaping operations
    • B29C48/0022Combinations of extrusion moulding with other shaping operations combined with cutting
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/03Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
    • B29C48/09Articles with cross-sections having partially or fully enclosed cavities, e.g. pipes or channels
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29LINDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2009/00Layered products
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29LINDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2023/00Tubular articles
    • B29L2023/22Tubes or pipes, i.e. rigid

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Extrusion Moulding Of Plastics Or The Like (AREA)
  • Molding Of Porous Articles (AREA)

Abstract

一种PERT保温管道一次法成型工艺,属于保温管生产领域。其步骤是:首先对挤出工作内管;随后工作内管在输送装置的作用下进入外护层挤出机的机头处的中心孔,当工作内管从中心孔的另一侧伸出外护层挤出机的距离达到设计长度后,外护层挤出机挤出外护层,外护层与工作内管同轴布置,通过钢丝绳牵引通过发泡挡板环孔;外护层通过发泡挡板环孔后与工作内管同步匀速向前运动,在发泡平台对外护管进行开注射孔,高压发泡机的枪管通过注射孔向外护层与工作内管之间的空腔注入发泡原液,发泡原液随即发泡形成保温层;发泡后管材通过牵引机后进行定长切割。本发明解决了保温管道无法在线发泡的难题,具有生产工艺简单、效率高、成本低的优点。

Description

一种PERT保温管道一步法成型工艺
技术领域
本发明属于聚乙烯保温管的生产技术领域, 特别涉及一种生产PERT保温管的一步法成型工艺。
背景技术
聚乙烯保温管是绝热管道的简称,用于液体、气体及其他介质的输送,在石油、化工、航天、军事、 集中供热、中央空调、市政等管道的绝热保温工程均有广泛应用。PERT保温管道具有耐高温、承压高、使用寿命长,输送流量大、易安装、敷设无需补偿等诸多优异性能。
PERT保温管道从内向外分为三层结构,第一层:工作内管,使用耐热聚乙烯(PE-RT)挤出成型。第二层:聚氨酯保温层,简称保温层。保温层包覆在工作内管的外表面,生产中由高压发泡机发泡制成。第三层 :高密度聚乙烯保护层,简称外护层或外护管。通常是具有一定壁厚的黑色或黄色聚乙烯塑料管材。其作用一是保护保温层免遭机械硬物破坏,二是防腐、防水。
现有PERT保温管道生产多采用二步法成型工艺。分别挤出工作内管和外护管,在发泡平台将工作内管和外护管组装后进行发泡。这种生产工艺存在工艺繁琐、生产效率低和材料浪大的问题。
发明内容
本发明目的是针对现有生产PERT保温管道采用二步法成型工艺存在的不足之处,提供一种生产PERT保温管道一步法成型工艺。
为解决上述问题,本发明所采用的技术方案是:
一种PERT保温管道一步法成型工艺,所述保温管包括由内向外逐层设置的工作内管、保温层、外护层。改进后,所述一步法成型工艺包括以下步骤 :
步骤1:工作内管经挤出机挤出,定型后,通过外护层挤出机头中心孔,当工作内管通过外护层挤出机中心孔设计长度后,外护层挤出机的出料端挤出外护层,外护层环绕工作内管,并与工作内管同步匀速向前运动。
步骤2:工作内管和外护层同时运动通过发泡挡板后,进入发泡平台。
步骤3:工作内管和外护层一端通过发泡平台一段距离后,发泡平台开孔装置对外护层进行开注射孔,高压发泡机的枪管向注射孔注入发泡原液,发泡原液随即发泡形成保温层。
步骤4:发泡后管材通过牵引机进行定长切割。
上述PERT保温管道一步法成型工艺中,所述外护层挤出模具具有和工作内管外径相适配的圆形通孔。
上述PERT保温管道一步法成型工艺,所述发泡挡板为两个环形装置构成。
上述PERT保温管道一步法成型工艺,所述发泡挡板内环形结构一侧具有(DIN:1.2738)718S型号钢材制作环形发泡挡板,发泡挡板端面粗糙度为Ra0.01-0.05。
上述PERT保温管道一步法成型工艺,所述发泡挡板上均布锥形结构,每个锥形结构长度15mm。
上述PERT保温管道一步法成型工艺,所述注射孔开孔装置为圆盘锯,孔径25mm。
上述PERT保温管道一步法成型工艺,所述发泡机枪管可随管道同轴往复运动,运动周期与牵引速度相适应。
上述PERT保温管道一步法成型工艺,所述发泡机通过定时开关控制器控制发泡原液的注入和停止。
上述PERT保温管道一步法成型工艺,所述注射孔注射发泡原液后加盖堵头,堵头中心具有排气针孔。
上述PERT保温管道一步法成型工艺,所述管线切割机具有三个刀头,直接加工出管材熔接预留长度。
本发明具有如下显著效果:
1.本发明在一步法成型制作PERT保温管道的过程中,巧妙设计在工作内管和外护管之间设置发泡挡板,解决了PERT保温管道无法在线发泡的难题。
2.本发明在一步法成型制作PERT保温管道的过程中,将发泡机注射枪管设计为可往复运动,解决了PERT保温管道无法在线发泡的难题。
3.本发明在一步法成型制作PERT保温管道的过程中,将注射孔堵头设计为中间带有排气针孔,避免发泡过程产生的气压对设备和模具的影响。
4.本发明在一步法成型制作PERT保温管道的过程中,将发泡挡板端面设计为粗糙度Ra0.01-0.05,均布锥形结构,增加两次发泡连接面接触面积,使保温层粘接强度达到要求。
5.本发明具有生产工艺简单、效率高、成本低的优点。
附图说明
图1为本发明工艺所经工序设备结构示意图。
图2是本发明发泡挡板结构示意图。
图中:1-工作内管挤出机,2-工作内管,3-工作内管定径箱,4-外护层挤出机,5-外护层,6-外护管定径箱,7-发泡平台,8-发泡挡板,9-开孔装置,10-高压发泡机,11-牵引机,12-切割机,13-发泡层,801-发泡挡板中心孔,802-发泡挡板环孔,803-固定螺栓孔,804-锥形结构,805-挡板内圈,806-挡板外圈。
具体实施方式
本发明的具体实施方式结合附图及实施例做进一步详细说明。
实施例:
如图1所示:PERT保温管道由内向外包括工作内管2,保温层13,外护层5。
PERT保温管道一步法成型工艺为:
步骤A、工作内管挤出机1挤出工作内管2,工作内管牵引通过工作内管定径箱3。
步骤B、工作内管2通过牵引机11牵引从外护层挤出机4一侧进入外护层挤出机4中心孔,并从中心孔的另一侧(即外护层挤出机4的出料端)伸出外护层挤出机4。当工作内管2通过外护层挤出机4出料端、外护管定径箱6和发泡挡板8的中心孔801后达到一定长度后,外护层挤出机4内的塑料原料从出料端挤出形成外护层5。挤出的外护层5与工作内管同轴布置,外护层5通过钢丝绳牵引,并与工作内管同轴、同速运动。
步骤C、外护层5通过外护层定径箱6后,牵引进入发泡挡板环孔802。当外护管通过发泡平台7一定距离后,使用卡箍将外护层5固定于工作内管外侧,同时取掉外护管5牵引绳。
步骤D、开孔装置9对外护管进行开注射孔,高压发泡机10枪管通过注射孔向工作内管2和外护层5之间注入发泡原液,随即将堵头塞入外护层5上的注射孔,发泡原液随即发泡形成保温层。
步骤E、发泡后的工作内管2、保温层、外护管5同轴运动至切割机12,从切割机一侧中心孔通过设计长度后,切割机对保温管道进行定长切割。
如图2所示,801-发泡挡板中心孔,802-发泡挡板环孔,803-固定螺栓孔,804-锥形结构,805-挡板内圈,806-挡板外圈。发泡挡板(8)为两个环形结构,其中挡板内圈805中心为与工作内管2外径相匹配的发泡挡板中心孔801,挡板外圈806与挡板内圈805中间形成发泡挡板环孔802。挡板内圈805上均匀布置有锥形结构(804)。挡板内圈805,挡板外圈806,锥形结构804为18S型号钢材制作,其表面粗糙度为Ra0.01-0.05。发泡挡板上均布的锥形结构,可增加两次发泡间发泡层的接触面积。

Claims (4)

1.一种PERT保温管道一步法成型工艺,所述保温管由内向外逐层布置为工作内管(2)、保温层(13)、外护层 (5),其特征在于所述的一步法成型工艺包括以下步骤 :
步骤A.工作内管挤出机(1)挤出工作内管(2),工作内管在输送装置的作用下通过外护管挤出机中心孔,当工作内管通过中心孔一定距离后,外护管挤出机(4)挤出外护层(5),外护层(5)与工作内管(2)同轴匀速向前运动;
步骤B.工作内管(2)与外护层(5)同轴向前运动,通过固定在发泡平台(7)的发泡挡板(8),通过发泡挡板后使用卡箍将外护层固定在工作内管上;
步骤C.当工作内管(2)和外护层(5)通过发泡挡板(8)一定距离后,发泡平台(7)开孔装置(9)在外护层进行开注射孔,高压发泡机(10)枪管通过注射孔向工作内管(2)和外护层(5)之间注入发泡原液,随即将堵头塞入外护层(5)上的注射孔,发泡原液随即发泡形成保温层;
步骤D.发泡后的工作内管(2)、保温层、外护层(5)同轴运动至切割机(12),从切割机一侧中心孔通过设计长度后,切割机对保温管道进行定长切割;
所述步骤B中,发泡挡板(8)为两个环形结构,其中挡板内圈(805)中心为与工作内管(2)外径相匹配的发泡挡板中心孔(801),挡板外圈(806)与挡板内圈(805)中间形成的环孔为发泡挡板环孔(802)。
2.根据权利要求1所述的一种PERT保温管道一步法成型工艺,其特征在于:所述的挡板内圈(805)上均匀布置有锥形结构(804)。
3.根据权利要求1所述的一种PERT保温管道一步法成型工艺,其特征在于:挡板内圈(805),挡板外圈(806),锥形结构(804)为718S型号钢材制作,其表面粗糙度为Ra0.01-0.05。
4.根据权利要求1所述的一种PERT保温管道一步法成型工艺,其特征在于:发泡平台开孔装置(9)、高压发泡机(10)与牵引机(11)通过控制器同步工作。
CN201610457361.8A 2016-06-20 2016-06-20 一种pert保温管道一步法成型工艺 Active CN106113534B (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610457361.8A CN106113534B (zh) 2016-06-20 2016-06-20 一种pert保温管道一步法成型工艺

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610457361.8A CN106113534B (zh) 2016-06-20 2016-06-20 一种pert保温管道一步法成型工艺

Publications (2)

Publication Number Publication Date
CN106113534A CN106113534A (zh) 2016-11-16
CN106113534B true CN106113534B (zh) 2019-03-26

Family

ID=57269267

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610457361.8A Active CN106113534B (zh) 2016-06-20 2016-06-20 一种pert保温管道一步法成型工艺

Country Status (1)

Country Link
CN (1) CN106113534B (zh)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107116816A (zh) * 2017-06-22 2017-09-01 广州骊阳能源科技有限公司 一种新型塑料复合管的生产方法
CN113580624B (zh) * 2021-07-22 2023-03-31 京华派克邯郸机械科技有限公司 一种复合保温管连续生产工艺
CN114347523B (zh) * 2021-12-22 2024-07-02 荥阳市坛山热力保温管道有限公司 一种保温管生产线

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2611687Y (zh) * 2003-04-04 2004-04-14 机科发展科技股份有限公司 供热管发泡封口密封环
CN104149355A (zh) * 2014-08-18 2014-11-19 唐山兴邦管道工程设备有限公司 一种保温管一步法成型工艺
CN105623038A (zh) * 2014-11-03 2016-06-01 青岛鼎益塑料机械有限公司 一种聚乙烯发泡保温管及其制备方法

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2564375B1 (fr) * 1984-05-18 1987-03-06 Eternit Financiere Procede de fabrication de tubes alleges, rigides en matiere thermoplastique
CN85102477B (zh) * 1985-04-01 1988-03-16 胜利油田油田建设第一指挥部油田建设机具研究所 钢管道绝热防腐层“一步法”成型方法
CN202943821U (zh) * 2012-12-10 2013-05-22 孟扬 保温管均匀发泡装置
CN105299334B (zh) * 2015-12-08 2018-01-26 朗格斯特哈尔滨环保节能产品制造有限公司 含有高密度聚乙烯增强支架的保温管道及制作方法

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2611687Y (zh) * 2003-04-04 2004-04-14 机科发展科技股份有限公司 供热管发泡封口密封环
CN104149355A (zh) * 2014-08-18 2014-11-19 唐山兴邦管道工程设备有限公司 一种保温管一步法成型工艺
CN105623038A (zh) * 2014-11-03 2016-06-01 青岛鼎益塑料机械有限公司 一种聚乙烯发泡保温管及其制备方法

Also Published As

Publication number Publication date
CN106113534A (zh) 2016-11-16

Similar Documents

Publication Publication Date Title
CN106113534B (zh) 一种pert保温管道一步法成型工艺
CN102359668A (zh) 矿用阻燃抗静电钢丝网骨架聚乙烯复合管及其制备方法
CN103574187A (zh) 柔性超高分子量聚乙烯复合管及其制备方法与生产系统
CN105946192A (zh) 一种复合保温管连续生产方法及其设备
CN209309492U (zh) 一种发泡聚苯乙烯直埋保温塑料复合管道
CN105835386B (zh) 卷制薄壁金属套管与喷涂聚氨酯泡沫同步连续生产保温管的方法
WO2023103108A1 (zh) 一种连续纤维增强复合管的成型设备
CN110328822A (zh) 一种保温管及其挤出模具和制造方法
CN203948806U (zh) 一种冷热水保温管
CN101881356B (zh) 钢丝增强型承插口复合塑料管及其制作工艺
CN205048007U (zh) 一种连续纤维方管加强筋大口径压力管道
CN109099224B (zh) 连续纤维增强热塑性管件管及其制造方法
CN101788084B (zh) 一种承口增强复合型塑料管及其制作工艺
CN210362355U (zh) 一种保温管及其挤出模具
WO2023103109A1 (zh) 一种纤维增强复合管的生产设备
CN201715118U (zh) 钢丝增强型承插口复合塑料管
CN105965813A (zh) 柔性预制保温塑料管道外护层连续贴合装置及外护层连续贴合方法
WO2017024746A1 (zh) 一种聚合物管道喷流堆砌成型方法及装置
CN102059799A (zh) 多层复合塑料管材生产方法及其生产线
CN208774020U (zh) 厚壁管坯和棒材一体生产设备
CN104455790A (zh) 玻璃钢pe复合管及连续缠绕生产工艺
CN107152567A (zh) 一种柔性聚氨酯保温管及其生产工艺
CN210484855U (zh) 柔性复合管
CN201836547U (zh) 承口增强复合型塑料管
CN201827529U (zh) 钢板增强型承插口复合塑料管

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant