CN106087586A - Sterilization Honey comb like package carton and preparation method thereof - Google Patents

Sterilization Honey comb like package carton and preparation method thereof Download PDF

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Publication number
CN106087586A
CN106087586A CN201610438246.6A CN201610438246A CN106087586A CN 106087586 A CN106087586 A CN 106087586A CN 201610438246 A CN201610438246 A CN 201610438246A CN 106087586 A CN106087586 A CN 106087586A
Authority
CN
China
Prior art keywords
preparation
consumption
honey comb
carton
package carton
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610438246.6A
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Chinese (zh)
Inventor
解和锋
沐磊
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tongling Feng Feng Color Printing Co Ltd
Original Assignee
Tongling Feng Feng Color Printing Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tongling Feng Feng Color Printing Co Ltd filed Critical Tongling Feng Feng Color Printing Co Ltd
Priority to CN201610438246.6A priority Critical patent/CN106087586A/en
Publication of CN106087586A publication Critical patent/CN106087586A/en
Pending legal-status Critical Current

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Classifications

    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
    • D21H27/10—Packing paper
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/10—Coatings without pigments
    • D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/10—Coatings without pigments
    • D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
    • D21H19/24—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/36—Biocidal agents, e.g. fungicidal, bactericidal, insecticidal agents

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses a kind of sterilization Honey comb like package carton and preparation method thereof, wherein, described preparation method includes: form varnish M after acroleic acid polyurethane, isocyanates and acetone being mixed；Nano zine oxide is added in described varnish M, after ultrasonic disperse, obtain coating N；Described coating N being coated in honeycomb carton surface, obtains described sterilization Honey comb like package carton after drying, the bacteriostasis solving common Packaging Box is poor so that the problem of the internal easy breed bacteria of article contained.

Description

Sterilization Honey comb like package carton and preparation method thereof
Technical field
The present invention relates to Packaging Box and manufacture field, in particular it relates to sterilization Honey comb like package carton and preparation method thereof.
Background technology
Packaging Box paper products manufacture, for packing the apparatus of all kinds of article, because of its low cost, be prone to encapsulation, It is suitable for adding implant, the feature such as clean, is widely used in various field.The bacteriostasis of common Packaging Box is poor, Make the easy breed bacteria of article of internal splendid attire.
Therefore it provides a kind of mechanical strength is high and bacteriostasis is high so that the internal article contained are difficult to breed bacteria Sterilization Honey comb like package carton and preparation method thereof is the problem that the present invention needs solution badly.
Summary of the invention
It is an object of the invention to provide a kind of sterilization Honey comb like package carton and preparation method thereof, solve common wrapping paper The bacteriostasis of case is poor so that the problem of the internal easy breed bacteria of article contained.
To achieve these goals, the invention provides the preparation method of a kind of Honey comb like package carton that sterilizes, wherein, described Preparation method includes:
(1) varnish M is formed after acroleic acid polyurethane, isocyanates and acetone being mixed；
(2) nano zine oxide is added in described varnish M, after ultrasonic disperse, obtain coating N；
(3) described coating N is coated in honeycomb carton surface, after drying, obtains described sterilization Honey comb like package carton；Wherein, Relative to the acroleic acid polyurethane of 100 weight portions, the consumption of described isocyanates is 20-35 weight portion, the consumption of described acetone For 45-65 weight portion, the consumption of described nano zine oxide is 10-18 weight portion.
Present invention also offers a kind of sterilization Honey comb like package carton, described sterilization Honey comb like package carton is by above-mentioned preparation side Method prepares.
By technique scheme, the invention provides a kind of sterilization Honey comb like package carton and preparation method thereof, wherein, institute State preparation method to include: after acroleic acid polyurethane, isocyanates and acetone being mixed, form varnish M；Nano zine oxide is added In described varnish M, after ultrasonic disperse, obtain coating N；Described coating N is coated in honeycomb carton surface, obtains described after drying Sterilization Honey comb like package carton, by the synergism between each raw material so that prepared Packaging Box does not the most possess excellent Mechanical strength, and the bacteriostasis of Packaging Box is strong so that and the article that inside holds are difficult to breed bacteria, meanwhile, are used for making The method of this Packaging Box standby is simple, raw material is easy to get.
Other features and advantages of the present invention will be described in detail in detailed description of the invention part subsequently.
Detailed description of the invention
Hereinafter the detailed description of the invention of the present invention is described in detail.It should be appreciated that described herein specifically Embodiment is merely to illustrate and explains the present invention, is not limited to the present invention.
The invention provides the preparation method of a kind of Honey comb like package carton that sterilizes, described preparation method includes: by acrylic acid Varnish M is formed after polyurethane, isocyanates and acetone mixing；Nano zine oxide is added in described varnish M, after ultrasonic disperse To coating N；Described coating N is coated in honeycomb carton surface, after drying, obtains described sterilization Honey comb like package carton；Wherein, phase For the acroleic acid polyurethane of 100 weight portions, the consumption of described isocyanates is 20-35 weight portion, and the consumption of described acetone is 45-65 weight portion, the consumption of described nano zine oxide is 10-18 weight portion.
So that the Packaging Box prepared possesses the most excellent sterilizing ability, a kind of in the present invention preferably implements In mode, relative to the acroleic acid polyurethane of 100 weight portions, the consumption of described isocyanates is 25-30 weight portion, described acetone Consumption be 50-60 weight portion, the consumption of described nano zine oxide is 13-15 weight portion.
Described acroleic acid polyurethane can be the conventional use of type of those skilled in the art, such as, excellent in the one of the present invention In the embodiment of choosing, in order to increase the antibacterial ability of prepared Packaging Box further, the weight average of described acroleic acid polyurethane Molecular weight is 12000-14000.
Described nano zine oxide can be the conventional use of type of those skilled in the art, such as, preferred in the one of the present invention Embodiment in, in order to increase the antibacterial ability of prepared Packaging Box further, the particle diameter of described nano zine oxide is 10- 20nm。
So that nano zine oxide can preferably be dispersed in varnish M, the frequency of described ultrasonic disperse is 15- 20KHz。
So that coating N can be the most solid, the present invention one preferred embodiment in, described dry temperature Degree is for 45-50 DEG C, and drying time is 10-20min.
Present invention also offers a kind of sterilization Honey comb like package carton, described sterilization Honey comb like package carton is by above-mentioned preparation side Method prepares.
Hereinafter will be described the present invention by embodiment.In following example, acroleic acid polyurethane, Carbimide. Ester and acetone are conventional commercial product, the commercially available product that nano zine oxide provides for Xin Ye company limited of Shijiazhuang HTC.
Embodiment 1
Varnish M is formed after 100g acroleic acid polyurethane, 25g isocyanates and 50g acetone being mixed；13g is nano oxidized Zinc adds in described varnish M, obtains coating N after ultrasonic disperse (supersonic frequency is 15KHz)；Described coating N is coated in honeycomb Carton surface, obtains, after drying (drying temperature is 45 DEG C, and the time is 10min), the Honey comb like package carton A1 that sterilizes.
Embodiment 2
Varnish M is formed after 100g acroleic acid polyurethane, 30g isocyanates and 60g acetone being mixed；15g is nano oxidized Zinc adds in described varnish M, obtains coating N after ultrasonic disperse (supersonic frequency is 20KHz)；Described coating N is coated in honeycomb Carton surface, obtains, after drying (drying temperature is 50 DEG C, and the time is 20min), the Honey comb like package carton A2 that sterilizes.
Embodiment 3
Varnish M is formed after 100g acroleic acid polyurethane, 28g isocyanates and 55g acetone being mixed；14g is nano oxidized Zinc adds in described varnish M, obtains coating N after ultrasonic disperse (supersonic frequency is 18KHz)；Described coating N is coated in honeycomb Carton surface, obtains, after drying (drying temperature is 48 DEG C, and the time is 15min), the Honey comb like package carton A3 that sterilizes.
Embodiment 4
Being prepared according to the method for embodiment 1, except for the difference that, the consumption of acroleic acid polyurethane is 100g, described isocyanide The consumption of acid esters is 20g, and the consumption of described acetone is 45g, and the consumption of described nano zine oxide is 10g, obtains the honeycomb bag that sterilizes Cartoning A4.
Embodiment 5
Being prepared according to the method for embodiment 1, except for the difference that, the consumption of acroleic acid polyurethane is 100g, described isocyanide The consumption of acid esters is 35g, and the consumption of described acetone is 65g, and the consumption of described nano zine oxide is 18g, obtains the honeycomb bag that sterilizes Cartoning A5.
Comparative example 1
Being prepared according to the method for embodiment 1, except for the difference that, the consumption of acroleic acid polyurethane is 100g, described isocyanide The consumption of acid esters is 10g, and the consumption of described acetone is 40g, and the consumption of described nano zine oxide is 5g, obtains the Honey comb like package that sterilizes Carton D1.
Comparative example 2
Being prepared according to the method for embodiment 1, except for the difference that, the consumption of acroleic acid polyurethane is 100g, described isocyanide The consumption of acid esters is 40g, and the consumption of described acetone is 70g, and the consumption of described nano zine oxide is 20g, obtains the honeycomb bag that sterilizes Cartoning D2.
Test case 1
The tear index of Packaging Box A1-A5, D1 and D2 that detection prepares, and to colibacillary bacteriostasis rate, result It is shown in Table 1.
Table 1
Embodiment is numbered Tear index (mN m<sup>2</sup>/g) Bacteriostasis rate (%)
A1 44 97
A2 43 98
A3 45 97
A4 34 90
A5 35 91
D1 21 56
D2 19 54
By above table data it can be seen that the tear index of Packaging Box A1-A5 prepared within the scope of the present invention It is higher than outside the scope of the invention, with bacteriostasis rate, Packaging Box D1 and D2 prepared, the mechanical strength of A1-A5 and antibacterial energy are described Power is better than D1 and D2, and the Packaging Box prepared in currently preferred scope possesses the most excellent performance, thus, and can High to obtain mechanical strength, and the Packaging Box that bacteriostasis is excellent.
The preferred embodiment of the present invention described in detail above, but, the present invention is not limited in above-mentioned embodiment Detail, in the technology concept of the present invention, technical scheme can be carried out multiple simple variant, this A little simple variant belong to protection scope of the present invention.
It is further to note that each the concrete technical characteristic described in above-mentioned detailed description of the invention, at not lance In the case of shield, can be combined by any suitable means, in order to avoid unnecessary repetition, the present invention to various can The compound mode of energy illustrates the most separately.
Additionally, combination in any can also be carried out between the various different embodiment of the present invention, as long as it is without prejudice to this The thought of invention, it should be considered as content disclosed in this invention equally.

Claims (7)

1. the preparation method of the Honey comb like package carton that sterilizes, it is characterised in that described preparation method includes:
(1) varnish M is formed after acroleic acid polyurethane, isocyanates and acetone being mixed；
(2) nano zine oxide is added in described varnish M, after ultrasonic disperse, obtain coating N；
(3) described coating N is coated in honeycomb carton surface, after drying, obtains described sterilization Honey comb like package carton；Wherein, relatively In the acroleic acid polyurethane of 100 weight portions, the consumption of described isocyanates is 20-35 weight portion, and the consumption of described acetone is 45- 65 weight portions, the consumption of described nano zine oxide is 10-18 weight portion.
Preparation method the most according to claim 1, wherein, relative to the acroleic acid polyurethane of 100 weight portions, described isocyanide The consumption of acid esters is 25-30 weight portion, and the consumption of described acetone is 50-60 weight portion, and the consumption of described nano zine oxide is 13- 15 weight portions.
Preparation method the most according to claim 1, wherein, the weight average molecular weight of described acroleic acid polyurethane is 12000- 14000。
Preparation method the most according to claim 1, wherein, the particle diameter of described nano zine oxide is 10-20nm.
Preparation method the most according to claim 1, wherein, the frequency of described ultrasonic disperse is 15-20KHz.
Preparation method the most according to claim 1, wherein, described drying temperature is 45-50 DEG C, and drying time is 10- 20min。
7. a sterilization Honey comb like package carton, it is characterised in that described sterilization Honey comb like package carton is by any in claim 1-6 One described preparation method prepares.
CN201610438246.6A 2016-06-16 2016-06-16 Sterilization Honey comb like package carton and preparation method thereof Pending CN106087586A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610438246.6A CN106087586A (en) 2016-06-16 2016-06-16 Sterilization Honey comb like package carton and preparation method thereof

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Application Number Priority Date Filing Date Title
CN201610438246.6A CN106087586A (en) 2016-06-16 2016-06-16 Sterilization Honey comb like package carton and preparation method thereof

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Publication Number Publication Date
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108068484A (en) * 2017-11-28 2018-05-25 蚌埠昆仑彩印包装有限公司 A kind of environmental printing technique of Packaging Box

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1446979A (en) * 2003-01-17 2003-10-08 安县纸业有限公司 Sterilization, bacteriostasis papers as well as manufacturing methods and usage
US20060008496A1 (en) * 2004-07-06 2006-01-12 Sandeep Kulkarni Insulation paper facing containing an antimicotic or fungicide and methods of making and using the same
CN102517993A (en) * 2011-12-20 2012-06-27 广东壮丽彩印股份有限公司 Packaging and printing paper substrate with antibacterial property, and preparation method thereof
CN102942821A (en) * 2012-10-30 2013-02-27 广东壮丽彩印股份有限公司 Nano-antibacterial gravure aqueous printing ink and preparation method thereof
CN104527145A (en) * 2015-01-13 2015-04-22 正业包装（中山）有限公司 High-strength and high-pressure-resistance composite paperboard

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1446979A (en) * 2003-01-17 2003-10-08 安县纸业有限公司 Sterilization, bacteriostasis papers as well as manufacturing methods and usage
US20060008496A1 (en) * 2004-07-06 2006-01-12 Sandeep Kulkarni Insulation paper facing containing an antimicotic or fungicide and methods of making and using the same
CN102517993A (en) * 2011-12-20 2012-06-27 广东壮丽彩印股份有限公司 Packaging and printing paper substrate with antibacterial property, and preparation method thereof
CN102942821A (en) * 2012-10-30 2013-02-27 广东壮丽彩印股份有限公司 Nano-antibacterial gravure aqueous printing ink and preparation method thereof
CN104527145A (en) * 2015-01-13 2015-04-22 正业包装（中山）有限公司 High-strength and high-pressure-resistance composite paperboard

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108068484A (en) * 2017-11-28 2018-05-25 蚌埠昆仑彩印包装有限公司 A kind of environmental printing technique of Packaging Box

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Application publication date: 20161109

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