CN106087530A - Environment-protective honeycomb Packaging Box and preparation method thereof - Google Patents

Environment-protective honeycomb Packaging Box and preparation method thereof Download PDF

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Publication number
CN106087530A
CN106087530A CN201610436499.XA CN201610436499A CN106087530A CN 106087530 A CN106087530 A CN 106087530A CN 201610436499 A CN201610436499 A CN 201610436499A CN 106087530 A CN106087530 A CN 106087530A
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CN
China
Prior art keywords
consumption
preparation
pulp
weight portion
packaging box
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610436499.XA
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Chinese (zh)
Inventor
解和锋
沐磊
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tongling Feng Feng Color Printing Co Ltd
Original Assignee
Tongling Feng Feng Color Printing Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tongling Feng Feng Color Printing Co Ltd filed Critical Tongling Feng Feng Color Printing Co Ltd
Priority to CN201610436499.XA priority Critical patent/CN106087530A/en
Publication of CN106087530A publication Critical patent/CN106087530A/en
Pending legal-status Critical Current

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Classifications

    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H13/00—Pulp or paper, comprising synthetic cellulose or non-cellulose fibres or web-forming material
    • D21H13/36—Inorganic fibres or flakes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B31—MAKING ARTICLES OF PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER; WORKING PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER
    • B31D—MAKING ARTICLES OF PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER, NOT PROVIDED FOR IN SUBCLASSES B31B OR B31C
    • B31D3/00—Making articles of cellular structure, e.g. insulating board
    • B31D3/04—Making articles of cellular structure, e.g. insulating board cellular packaging articles, e.g. for bottles
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/33—Synthetic macromolecular compounds
    • D21H17/34—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H17/36—Polyalkenyalcohols; Polyalkenylethers; Polyalkenylesters
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/33—Synthetic macromolecular compounds
    • D21H17/34—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H17/37—Polymers of unsaturated acids or derivatives thereof, e.g. polyacrylates
    • D21H17/375—Poly(meth)acrylamide
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/33—Synthetic macromolecular compounds
    • D21H17/46—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H17/54—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen
    • D21H17/56—Polyamines; Polyimines; Polyester-imides
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/63—Inorganic compounds
    • D21H17/67—Water-insoluble compounds, e.g. fillers, pigments
    • D21H17/675—Oxides, hydroxides or carbonates
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/63—Inorganic compounds
    • D21H17/67—Water-insoluble compounds, e.g. fillers, pigments
    • D21H17/68—Water-insoluble compounds, e.g. fillers, pigments siliceous, e.g. clays

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Paper (AREA)

Abstract

The invention discloses a kind of environment-protective honeycomb Packaging Box and preparation method thereof, wherein, described preparation method includes: by the stirring mixing of wood pulp, reed pulp, zeolite, ceramic fibre, polyacrylamide and retention agent, form pulp suspension M；In pulp suspension M, add nano titanium oxide heated and stirred, obtain pulp suspension N；Through copy paper technique, pulp suspension N is obtained described environment-protective honeycomb Packaging Box, and the seal solving common Packaging Box is poor, the problem being not suitable for inside it holding some volatile chemical noxious materials.

Description

Environment-protective honeycomb Packaging Box and preparation method thereof
Technical field
The present invention relates to Packaging Box and manufacture field, in particular it relates to environment-protective honeycomb Packaging Box and preparation method thereof.
Background technology
Packaging Box paper products manufacture, for packing the apparatus of all kinds of article, because of its low cost, be prone to encapsulation, It is suitable for adding implant, the feature such as clean, is widely used in various field.The seal of common Packaging Box is poor, in it Portion is not suitable for holding some volatile chemical noxious materials.
Therefore it provides a kind of good leak tightness, high adsorption capacity, it is suitable for holding the honeybee of some volatile chemical noxious materials Nest Packaging Box is the problem that the present invention needs solution badly.
Summary of the invention
It is an object of the invention to provide a kind of environment-protective honeycomb Packaging Box and preparation method thereof, solve common wrapping paper The seal of case is poor, the problem being not suitable for inside it holding some volatile chemical noxious materials.
To achieve these goals, the invention provides the preparation method of a kind of environment-protective honeycomb Packaging Box, wherein, described Preparation method includes:
(1) by the stirring mixing of wood pulp, reed pulp, zeolite, ceramic fibre, polyacrylamide and retention agent, form paper pulp and hang Supernatant liquid M；
(2) in pulp suspension M, add nano titanium oxide and heated and stirred, obtain pulp suspension N；
(3) pulp suspension N is obtained described environment-protective honeycomb Packaging Box through copy paper technique；Wherein, relative to 100 weight The wood pulp of part, the consumption of described reed pulp is 50-70 weight portion, and the consumption of described zeolite is 5-15 weight portion, and described pottery is fine The consumption of dimension is 1-10 weight portion, and the consumption of described polyacrylamide is 2-10 weight portion, and the consumption of described retention agent is 2-4 weight Amount part, the consumption of described nano titanium oxide is 20-40 weight portion.
The invention provides a kind of environment-protective honeycomb Packaging Box, wherein, described environment-protective honeycomb Packaging Box is by above-mentioned system Preparation Method prepares.
By technique scheme, the invention provides a kind of environment-protective honeycomb Packaging Box and preparation method thereof, wherein, institute State preparation method to include: by the stirring mixing of wood pulp, reed pulp, zeolite, ceramic fibre, polyacrylamide and retention agent, form paper Mass suspension M；In pulp suspension M, add nano titanium oxide heated and stirred, obtain pulp suspension N；Paper pulp is hanged Supernatant liquid N obtains described environment-protective honeycomb Packaging Box through copy paper technique, by the synergism between each raw material so that prepared bag Cartoning possesses good sealing, high adsorption capacity, is difficult to when inside holds some volatile chemical noxious materials expand Dissipating, the method being simultaneously used for preparing this Packaging Box is simple, raw material is easy to get.
Other features and advantages of the present invention will be described in detail in detailed description of the invention part subsequently.
Detailed description of the invention
Hereinafter the detailed description of the invention of the present invention is described in detail.It should be appreciated that described herein specifically Embodiment is merely to illustrate and explains the present invention, is not limited to the present invention.
The invention provides the preparation method of a kind of environment-protective honeycomb Packaging Box, wherein, described preparation method includes: by wood Slurry, reed pulp, zeolite, ceramic fibre, polyacrylamide and retention agent stirring mixing, form pulp suspension M；At pulp suspension Liquid M adds nano titanium oxide heated and stirred, obtains pulp suspension N；Pulp suspension N is obtained institute through copy paper technique State environment-protective honeycomb Packaging Box；Wherein, relative to the wood pulp of 100 weight portions, the consumption of described reed pulp is 50-70 weight portion, The consumption of described zeolite is 5-15 weight portion, and the consumption of described ceramic fibre is 1-10 weight portion, the use of described polyacrylamide Amount is 2-10 weight portion, and the consumption of described retention agent is 2-4 weight portion, and the consumption of described nano titanium oxide is 20-40 weight Part.
So that the Packaging Box prepared possesses the most excellent sealing and absorbability, relative to 100 weight portions Wood pulp, the consumption of described reed pulp is 55-65 weight portion, and the consumption of described zeolite is 8-12 weight portion, described ceramic fibre Consumption be 3-7 weight portion, the consumption of described polyacrylamide is 4-6 weight portion, the consumption of described retention agent be 2.5-3.5 weight Amount part, the consumption of described nano titanium oxide is 25-35 weight portion.
In order to improve adjuvant retention in wood pulp and reed pulp, the machinery improving the Packaging Box prepared further is strong Degree, described retention agent is made up of polymine and polyvinyl alcohol, and described polymine and the quality of described polyvinyl alcohol Ratio is 1:1-2.
Described nano titanium oxide can be type commonly used in the art, such as, in order to improve prepared wrapping paper The mechanical strength of case and absorbability, the particle diameter of described nano titanium oxide is 20-40nm.
So that can be sufficiently mixed between adjuvant, wood pulp and reed pulp, a kind of preferably embodiment party of the present invention In formula, described mixing speed is 240-300r/min, and the temperature of described heated and stirred is 45-65 DEG C.
The present invention one preferred embodiment in, the weight average molecular weight of described polyacrylamide is 6000-9000.
The invention provides a kind of environment-protective honeycomb Packaging Box, wherein, described environment-protective honeycomb Packaging Box is by above-mentioned system Preparation Method prepares.
Hereinafter will be described the present invention by embodiment.In following example, ceramic fibre and polyacrylamide The commercially available product that amine provides for Shanghai brightness industry chemical industry, nano titanium oxide for Beijing Deco Dao Jin Science and Technology Ltd. provide commercially available Product.
Embodiment 1
By 100g wood pulp, 55g reed pulp, 8g zeolite, 3g ceramic fibre, 4g polyacrylamide and 2.5g retention agent (poly-second Alkene imines and polyvinyl alcohol form, and the mass ratio of described polymine and described polyvinyl alcohol is 1:1) stirring mixing, shape Become pulp suspension M；In pulp suspension M, (mixing speed is 240r/ for addition 25g nano titanium oxide heated and stirred Min, temperature is 45 DEG C), obtain pulp suspension N；Pulp suspension N is obtained environment-protective honeycomb Packaging Box through copy paper technique A1。
Embodiment 2
By 100g wood pulp, 65g reed pulp, 12g zeolite, 7g ceramic fibre, 6g polyacrylamide and 3.5g retention agent (poly-second Alkene imines and polyvinyl alcohol form, and the mass ratio of described polymine and described polyvinyl alcohol is 1:2) stirring mixing, shape Become pulp suspension M；In pulp suspension M, (mixing speed is 300r/ for addition 35g nano titanium oxide heated and stirred Min, temperature is 65 DEG C), obtain pulp suspension N；Pulp suspension N is obtained environment-protective honeycomb Packaging Box through copy paper technique A2。
Embodiment 3
By 100g wood pulp, 60g reed pulp, 10g zeolite, 5g ceramic fibre, 5g polyacrylamide and 3g retention agent (polyethylene Imines and polyvinyl alcohol form, and the mass ratio of described polymine and described polyvinyl alcohol is 2:3) stirring mixing, formed Pulp suspension M；Pulp suspension M adds 30g nano titanium oxide heated and stirred (mixing speed is 280r/min, Temperature is 55 DEG C), obtain pulp suspension N；Pulp suspension N is obtained environment-protective honeycomb Packaging Box A3 through copy paper technique.
Embodiment 4
Being prepared according to the method for embodiment 1, except for the difference that, the consumption of wood pulp is 100g, the consumption of described reed pulp For 50g, the consumption of described zeolite is 5g, and the consumption of described ceramic fibre is 1g, and the consumption of described polyacrylamide is 2g, described The consumption of retention agent is 2g, and the consumption of described nano titanium oxide is 20g, obtains environment-protective honeycomb Packaging Box A4.
Embodiment 5
Being prepared according to the method for embodiment 1, except for the difference that, the consumption of wood pulp is 100g, the consumption of described reed pulp For 70g, the consumption of described zeolite is 15g, and the consumption of described ceramic fibre is 10g, and the consumption of described polyacrylamide is 10g, The consumption of described retention agent is 4g, and the consumption of described nano titanium oxide is 40g, obtains environment-protective honeycomb Packaging Box A5.
Comparative example 1
Being prepared according to the method for embodiment 1, except for the difference that, the consumption of wood pulp is 100g, the consumption of described reed pulp For 40g, the consumption of described zeolite is 3g, and the consumption of described ceramic fibre is 0.5g, and the consumption of described polyacrylamide is 1g, institute The consumption stating retention agent is 1g, and the consumption of described nano titanium oxide is 15g, obtains environment-protective honeycomb Packaging Box D1.
Comparative example 2
Being prepared according to the method for embodiment 1, except for the difference that, the consumption of wood pulp is 100g, the consumption of described reed pulp For 75g, the consumption of described zeolite is 20g, and the consumption of described ceramic fibre is 15g, and the consumption of described polyacrylamide is 15g, The consumption of described retention agent is 8g, and the consumption of described nano titanium oxide is 45g, obtains environment-protective honeycomb Packaging Box D2.
Table 1
Embodiment is numbered Tear index (mN m<sup>2</sup>/g) The adsorption rate (%) of PARA FORMALDEHYDE PRILLS(91,95)
A1 42 65
A2 41 62
A3 41 70
A4 35 55
A5 35 58
D1 21 20
D2 19 15
By above table data it can be seen that within the scope of the invention prepare environment-protective honeycomb Packaging Box A1-A5, Its tear index is higher than outside the scope of the invention environment-protective honeycomb Packaging Box D1 and D2 prepared, and illustrates that the machinery of A1-A5 is strong Degree is better than D1 and D2, and the adsorption rate of A1-A5 PARA FORMALDEHYDE PRILLS(91,95) is higher than D1 and D2, illustrates that the absorption property of A1-A5 is more excellent, at this The performance of the environment-protective honeycomb Packaging Box A1-A3 prepared in the range of invention preferably is more excellent, it is hereby achieved that mechanical strength is high, And the environment-protective honeycomb Packaging Box that absorbability is stronger.
The preferred embodiment of the present invention described in detail above, but, the present invention is not limited in above-mentioned embodiment Detail, in the technology concept of the present invention, technical scheme can be carried out multiple simple variant, this A little simple variant belong to protection scope of the present invention.
It is further to note that each the concrete technical characteristic described in above-mentioned detailed description of the invention, at not lance In the case of shield, can be combined by any suitable means, in order to avoid unnecessary repetition, the present invention to various can The compound mode of energy illustrates the most separately.
Additionally, combination in any can also be carried out between the various different embodiment of the present invention, as long as it is without prejudice to this The thought of invention, it should be considered as content disclosed in this invention equally.

Claims (8)

1. the preparation method of an environment-protective honeycomb Packaging Box, it is characterised in that described preparation method includes:
(1) by the stirring mixing of wood pulp, reed pulp, zeolite, ceramic fibre, polyacrylamide and retention agent, pulp suspension is formed M；
(2) in pulp suspension M, add nano titanium oxide and heated and stirred, obtain pulp suspension N；
(3) pulp suspension N is obtained described environment-protective honeycomb Packaging Box through copy paper technique；Wherein, relative to 100 weight portions Wood pulp, the consumption of described reed pulp is 50-70 weight portion, and the consumption of described zeolite is 5-15 weight portion, described ceramic fibre Consumption is 1-10 weight portion, and the consumption of described polyacrylamide is 2-10 weight portion, and the consumption of described retention agent is 2-4 weight Part, the consumption of described nano titanium oxide is 20-40 weight portion.
Preparation method the most according to claim 1, wherein, relative to the wood pulp of 100 weight portions, the consumption of described reed pulp For 55-65 weight portion, the consumption of described zeolite is 8-12 weight portion, and the consumption of described ceramic fibre is 3-7 weight portion, described poly- The consumption of acrylamide is 4-6 weight portion, and the consumption of described retention agent is 2.5-3.5 weight portion, described nano titanium oxide Consumption is 25-35 weight portion.
Preparation method the most according to claim 1, wherein, described retention agent is made up of polymine and polyvinyl alcohol, And the mass ratio of described polymine and described polyvinyl alcohol is 1:1-2.
Preparation method the most according to claim 1, wherein, the particle diameter of described nano titanium oxide is 20-40nm.
Preparation method the most according to claim 1, wherein, described mixing speed is 240-300r/min.
Preparation method the most according to claim 1, wherein, the temperature of described heated and stirred is 45-65 DEG C.
Preparation method the most according to claim 1, wherein, the weight average molecular weight of described polyacrylamide is 6000-9000.
8. an environment-protective honeycomb Packaging Box, it is characterised in that described environment-protective honeycomb Packaging Box is by any in claim 1-7 One described preparation method prepares.
CN201610436499.XA 2016-06-16 2016-06-16 Environment-protective honeycomb Packaging Box and preparation method thereof Pending CN106087530A (en)

Priority Applications (1)

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Application Number Priority Date Filing Date Title
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108329708A (en) * 2018-01-10 2018-07-27 合肥盛鼎包装材料有限公司 A kind of heat safe Packaging Box

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1308098A (en) * 2000-01-29 2001-08-15 柳长甫 Disposable degradable packing material and its preparation
CN101319478A (en) * 2008-07-02 2008-12-10 福建师范大学 Preparation method and application of composite paper based material with organic matter adsorption and degradation function
CN103103892A (en) * 2012-12-27 2013-05-15 山东轻工业学院 Preparation method of nanometer titanium dioxide (TiO2) sound absorption paper board
WO2013069788A1 (en) * 2011-11-10 2013-05-16 日本製紙株式会社 Barrier paper packaging material

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1308098A (en) * 2000-01-29 2001-08-15 柳长甫 Disposable degradable packing material and its preparation
CN101319478A (en) * 2008-07-02 2008-12-10 福建师范大学 Preparation method and application of composite paper based material with organic matter adsorption and degradation function
WO2013069788A1 (en) * 2011-11-10 2013-05-16 日本製紙株式会社 Barrier paper packaging material
CN103103892A (en) * 2012-12-27 2013-05-15 山东轻工业学院 Preparation method of nanometer titanium dioxide (TiO2) sound absorption paper board

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108329708A (en) * 2018-01-10 2018-07-27 合肥盛鼎包装材料有限公司 A kind of heat safe Packaging Box

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Application publication date: 20161109