CN106281110A - A kind of packing box super glue - Google Patents
A kind of packing box super glue Download PDFInfo
- Publication number
- CN106281110A CN106281110A CN201610743177.XA CN201610743177A CN106281110A CN 106281110 A CN106281110 A CN 106281110A CN 201610743177 A CN201610743177 A CN 201610743177A CN 106281110 A CN106281110 A CN 106281110A
- Authority
- CN
- China
- Prior art keywords
- parts
- packing box
- super glue
- box super
- raw material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J103/00—Adhesives based on starch, amylose or amylopectin or on their derivatives or degradation products
- C09J103/02—Starch; Degradation products thereof, e.g. dextrin
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention discloses a kind of packing box super glue, by forming according to the raw material of weight portion as follows: starch 20 ~ 45 parts, Polyamide Yarns 12 ~ 26 parts, lignin 8 ~ 19 parts, Mel 5 ~ 12 parts, modified polyvinylalcohol 16 ~ 26 parts, polyurethane 21 ~ 35 parts, epoxy resin 6 ~ 10 parts, 1 ~ 5 part of carbon fiber, collagen fiber 1 ~ 6 part, organosilicon 4 ~ 15 parts, 3 ~ 8 parts of acetone, dispersant 2 ~ 8 parts and stabilizer 2 ~ 6 parts.This kind of packing box super glue stable components, corrosivity is relatively low, is difficult to hardening, and it is fast to bind speed, and cohesive is strong, Heat stability is good, and raw material sources are extensive, safety non-toxic, effectively reduces and mounts glue foamings, degumming, the false generation phenomenon such as gluing.
Description
Technical field
The present invention relates to chemical products field, be specifically related to a kind of packing box super glue.
Background technology
Glue effect in commercial production and daily life is very big, suffers from widely in every field
Application.Being indispensable in glue packaging field, it is mainly used in the compound working procedure of wrapping paper or corrugated board.Existing glue
Water has certain corrosivity to binding itself, is easily generated hardening phenomenon, and the most difficult in terms of bonding force and heat stability
To meet the use requirement of people.
Summary of the invention
Present invention aim at solving the problems referred to above, it is provided that a kind of packing box super glue.
For achieving the above object, the invention provides a kind of packing box super glue, by following former according to weight portion
Material composition: starch 20 ~ 45 parts, Polyamide Yarns 12 ~ 26 parts, lignin 8 ~ 19 parts, Mel 5 ~ 12 parts, modified polyvinylalcohol 16 ~ 26 parts,
Polyurethane 21 ~ 35 parts, epoxy resin 6 ~ 10 parts, 1 ~ 5 part of carbon fiber, collagen fiber 1 ~ 6 part, organosilicon 4 ~ 15 parts, acetone 3 ~ 8
Part, dispersant 2 ~ 8 parts and stabilizer 2 ~ 6 parts.
Described packing box super glue, forms according to the raw material of weight portion: starch 22 ~ 41 parts, Polyamide Yarns 15 ~ 20 as follows
Part, lignin 10 ~ 15 parts, Mel 7 ~ 10 parts, modified polyvinylalcohol 18 ~ 21 parts, polyurethane 24 ~ 28 parts, epoxy resin 7 ~ 9 parts,
2 ~ 4 parts of carbon fiber, collagen fiber 3 ~ 5 parts, organosilicon 6 ~ 12 parts, 5 ~ 7 parts of acetone, dispersant 3 ~ 6 parts and stabilizer 3 ~ 5 parts.
Described packing box super glue, forms according to the raw material of weight portion as follows: starch 35 parts, Polyamide Yarns 16 parts, wood
Quality 12 parts, Mel 8 parts, modified polyvinylalcohol 19 parts, polyurethane 25 parts, epoxy resin 8 parts, 3 parts of carbon fiber, collagen fiber 4
Part, organosilicon 8 parts, 6 parts of acetone, dispersant 5 parts and stabilizer 4 parts.
The preparation method of described modified polyvinylalcohol comprises the steps of
1) do at argon in the environment of protection gas, polyvinyl alcohol is added to the water, is heated to 100 DEG C, is slowly stirred, obtain solution
A。
2) in solution A, add graphite, at a temperature of 100 DEG C, stand 30min, then, filter graphite, obtain solution B.
3) solution B is cooled to rapidly room temperature, separates out pulverulent solids C, filter, C is dried, obtains modified poly ethylene
Alcohol.
Described packing box super glue also includes additive.
The additive of described packing box super glue comprises following raw material: 10 ~ 20 parts of water of oxidation, anion add
Add agent 1 ~ 5 part, 0.6 ~ 1.5 part of carbamide, binding agent 1.4 ~ 2.9 parts.
Beneficial effects of the present invention: this kind of packing box super glue stable components, corrosivity is relatively low, is difficult to hardening, glutinous
Sum velocity is fast, and cohesive is strong, Heat stability is good, and raw material sources are extensive, and safety non-toxic effectively reduces and mounts glue foaming, degumming, vacation
The generation of the phenomenon such as viscous.
Detailed description of the invention
Embodiment 1
In the embodiment of the present invention, a kind of packing box super glue, by forming according to the raw material of weight portion as follows: starch 20 parts,
Polyamide Yarns 12 parts, lignin 8 parts, Mel 5 parts, modified polyvinylalcohol 16 parts, polyurethane 21 parts, epoxy resin 6 parts, carbon fiber 1
Part, collagen fiber 1 part, organosilicon 4 parts, 3 parts of acetone, dispersant 2 parts and stabilizer 2 parts.
Embodiment 2
In the embodiment of the present invention, a kind of packing box super glue, by forming according to the raw material of weight portion as follows: starch 45 parts,
Polyamide Yarns 26 parts, lignin 19 parts, Mel 12 parts, modified polyvinylalcohol 26 parts, polyurethane 35 parts, epoxy resin 10 parts, carbon are fine
Tie up 5 parts, collagen fiber 6 parts, organosilicon 15 parts, 8 parts of acetone, dispersant 8 parts and stabilizer 6 parts.
Embodiment 3
In the embodiment of the present invention, a kind of packing box super glue, by forming according to the raw material of weight portion as follows: starch 35 parts,
Polyamide Yarns 16 parts, lignin 12 parts, Mel 8 parts, modified polyvinylalcohol 19 parts, polyurethane 25 parts, epoxy resin 8 parts, carbon fiber 3
Part, collagen fiber 4 parts, organosilicon 8 parts, 6 parts of acetone, dispersant 5 parts and stabilizer 4 parts.
Embodiment 4
In the embodiment of the present invention, it is with embodiment 3 difference, also includes aoxidizing 10 parts of water, anionic additive 1 part, carbamide 0.6
Part, binding agent 1.4 parts.
Embodiment 5
In the embodiment of the present invention, it is with embodiment 3 difference, also includes aoxidizing 15 parts of water, anionic additive 3 parts, carbamide 1.1
Part, binding agent 2.1 parts.
Embodiment 6
In the embodiment of the present invention, it is with embodiment 3 difference, also includes aoxidizing 20 parts of water, anionic additive 5 parts, carbamide 1.5
Part, binding agent 2.9 parts.
The glue of embodiment 1 ~ 6, the bonding time at different ambient temperatures is as shown in the table.
Tack time under table 1 different temperatures
Embodiment 1 ~ 3 group tack time difference at different temperatures is little as can be seen from the table, and embodiment 4 groups is when 0 DEG C
Tack time is significantly lower than other groups, and the embodiment 5 groups tack time when 20 DEG C is relatively low, embodiment 6 groups gluing when 40 DEG C
The knot time is relatively low.
This kind of packing box super glue stable components, corrosivity is relatively low, is difficult to hardening, binds speed soon, and cohesive is strong,
Heat stability is good, raw material sources are extensive, safety non-toxic, effectively reduce and mount glue foamings, degumming, the false generation phenomenon such as gluing.
The preferred embodiment of the present invention described in detail above.Should be appreciated that those of ordinary skill in the art without
Need creative work just can make many modifications and variations according to the design of the present invention.Therefore, all technology in the art
Personnel are available by logical analysis, reasoning, or a limited experiment the most on the basis of existing technology
Technical scheme, all should be in the protection domain being defined in the patent claims.
Claims (6)
1. a packing box super glue, it is characterised in that by forming according to the raw material of weight portion as follows: starch 20 ~ 45 parts,
Polyamide Yarns 12 ~ 26 parts, lignin 8 ~ 19 parts, Mel 5 ~ 12 parts, modified polyvinylalcohol 16 ~ 26 parts, polyurethane 21 ~ 35 parts, epoxy
Resin 6 ~ 10 parts, 1 ~ 5 part of carbon fiber, collagen fiber 1 ~ 6 part, organosilicon 4 ~ 15 parts, 3 ~ 8 parts of acetone, dispersant 2 ~ 8 parts are with stable
Agent 2 ~ 6 parts.
Packing box super glue the most according to claim 1, it is characterised in that as follows according to the raw material group of weight portion
Become: starch 22 ~ 41 parts, Polyamide Yarns 15 ~ 20 parts, lignin 10 ~ 15 parts, Mel 7 ~ 10 parts, modified polyvinylalcohol 18 ~ 21 parts, poly-
Urethane 24 ~ 28 parts, epoxy resin 7 ~ 9 parts, 2 ~ 4 parts of carbon fiber, collagen fiber 3 ~ 5 parts, organosilicon 6 ~ 12 parts, acetone 5 ~ 7 part, point
Powder 3 ~ 6 parts and stabilizer 3 ~ 5 parts.
Packing box super glue the most according to claim 1, it is characterised in that as follows according to the raw material group of weight portion
Become: starch 35 parts, Polyamide Yarns 16 parts, lignin 12 parts, Mel 8 parts, modified polyvinylalcohol 19 parts, polyurethane 25 parts, asphalt mixtures modified by epoxy resin
8 parts of fat, 3 parts of carbon fiber, collagen fiber 4 parts, organosilicon 8 parts, 6 parts of acetone, dispersant 5 parts and stabilizer 4 parts.
Packing box super glue the most according to claim 1, it is characterised in that the preparation side of described modified polyvinylalcohol
Method comprises the steps of
1) do at argon in the environment of protection gas, polyvinyl alcohol is added to the water, is heated to 100 DEG C, is slowly stirred, obtain solution
A；
2) in solution A, add graphite, at a temperature of 100 DEG C, stand 30min, then, filter graphite, obtain solution B；
3) solution B is cooled to rapidly room temperature, separates out pulverulent solids C, filter, C is dried, obtains modified polyvinylalcohol.
Packing box super glue the most according to claim 1, it is characterised in that also include additive.
Packing box super glue the most according to claim 5, it is characterised in that it is former that additive comprises following weight portion
Material: oxidation 10 ~ 20 parts of water, anionic additive 1 ~ 5 part, 0.6 ~ 1.5 part of carbamide, binding agent 1.4 ~ 2.9 parts.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610743177.XA CN106281110A (en) | 2016-08-29 | 2016-08-29 | A kind of packing box super glue |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610743177.XA CN106281110A (en) | 2016-08-29 | 2016-08-29 | A kind of packing box super glue |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106281110A true CN106281110A (en) | 2017-01-04 |
Family
ID=57677953
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610743177.XA Pending CN106281110A (en) | 2016-08-29 | 2016-08-29 | A kind of packing box super glue |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106281110A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108018000A (en) * | 2017-12-13 | 2018-05-11 | 定远县嘉恒木业有限公司 | A kind of high intensity sawdust adhesive |
| CN108284640A (en) * | 2017-12-18 | 2018-07-17 | 星光印刷（苏州）有限公司 | A kind of book flask production method |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104178066A (en) * | 2014-06-30 | 2014-12-03 | 安徽神舟飞船胶业有限公司 | Formula and preparation process of acrylic starch-modified sulfur copolymerization adhesive |
| CN104327787A (en) * | 2014-11-11 | 2015-02-04 | 句容市茂源织造厂 | Carton processing adhesive |
| CN104327760A (en) * | 2014-10-17 | 2015-02-04 | 龙利得包装印刷股份有限公司 | Fold-resistant environmentally-friendly adhesive and preparation method thereof |
| CN105647451A (en) * | 2016-01-15 | 2016-06-08 | 上海齐驭实业有限公司 | Novel waterproof wood material adhesive and preparation method thereof |
-
2016
- 2016-08-29 CN CN201610743177.XA patent/CN106281110A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104178066A (en) * | 2014-06-30 | 2014-12-03 | 安徽神舟飞船胶业有限公司 | Formula and preparation process of acrylic starch-modified sulfur copolymerization adhesive |
| CN104327760A (en) * | 2014-10-17 | 2015-02-04 | 龙利得包装印刷股份有限公司 | Fold-resistant environmentally-friendly adhesive and preparation method thereof |
| CN104327787A (en) * | 2014-11-11 | 2015-02-04 | 句容市茂源织造厂 | Carton processing adhesive |
| CN105647451A (en) * | 2016-01-15 | 2016-06-08 | 上海齐驭实业有限公司 | Novel waterproof wood material adhesive and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108018000A (en) * | 2017-12-13 | 2018-05-11 | 定远县嘉恒木业有限公司 | A kind of high intensity sawdust adhesive |
| CN108284640A (en) * | 2017-12-18 | 2018-07-17 | 星光印刷（苏州）有限公司 | A kind of book flask production method |
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| C06 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
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| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20170104 |