CN106085055A - A kind of environment protection solar opto-electronic conversion coating - Google Patents
A kind of environment protection solar opto-electronic conversion coating Download PDFInfo
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- CN106085055A CN106085055A CN201610588454.4A CN201610588454A CN106085055A CN 106085055 A CN106085055 A CN 106085055A CN 201610588454 A CN201610588454 A CN 201610588454A CN 106085055 A CN106085055 A CN 106085055A
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
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- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
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- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
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- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
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- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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Abstract
The invention discloses a kind of environment protection solar opto-electronic conversion coating, in units of weight, including following raw material: matrix resin 65 100 parts, 45 50 parts of graphite, color stuffing 28 35 parts, GaAs 38 56 parts, nickel oxide 5 10 parts, lanthana 5 10 parts, magnesium oxide 48 parts, zinc oxide 48 parts, titanium oxide 36 parts, glycerol 60 100 parts, addition agent 10 20 parts, 6 10 parts of firming agent, degasser 13 parts, dispersant 12 parts, wetting agent 0.5 1.2 parts, emulsifying agent 0.4 1 parts, preservative 0.2 0.5 parts, 0.2 0.4 parts of antioxidant.The environment protection solar opto-electronic conversion coating property of the present invention is excellent, and output is big, and optoelectronic transformation efficiency is high, low production cost, environmental protection, it is easy to transport and store, it is prone to industrialized production, there is great market using value, be especially applicable to solar building integrated field.
Description
Technical field
The invention belongs to technical field of new energies and coating technology of preparing neck, be specifically related to a kind of environment protection solar photoelectricity
Conversion coating.
Background technology
Paint, is the call in ancient times；Coating, is modern civilization address, comprises more science and technology composition, in modern science and technology and
Industrial circle is widely used.But paint has some habituation addresses of blurting out still to remain, such as emulsion paint, priming paint, finish paint
Deng.It is said that in general, coating is exactly can be coated in coated article part surface and can form the material of continuous film of firm attachment.It
Both can be inorganic, such as electro-coppering, electronickelling, electrogalvanizing etc..Can also be organic, such as most organic polymer material
Material, high-molecular organic material constitutes current Coating Market major part.In the modern times along with the development of coatings industry, occur
Solar energy photoelectricity conversion coatings, it can help solar energy electroplax that solar energy is preferably changed into the required energy.
But at present, existing solar energy light electrocoating paint still suffers from following deficiency: such as Application No.
201410343126.9 Chinese patent disclose a kind of building solar energy photoelectric conversion coating and preparation method thereof, this coating is deposited
Weatherability is poor and the problem such as optoelectronic transformation efficiency low (14%-18%)；China such as Application No. 201410316134.4 is special
Profit discloses a kind of solar energy photoelectric conversion coating and preparation method thereof, there is poor lack the best with mechanical property of weatherability
Point.
The most how to overcome that existing solar energy photoelectric conversion coating weatherability is poor, mechanical property is the best and optoelectronic transformation efficiency
The defect such as low, it has also become the technical barrier that this area is urgently to be resolved hurrily.
Summary of the invention
The present invention provides a kind of environment protection solar opto-electronic conversion coating, resistance to solve existing solar energy photoelectric conversion coating
The problems such as time property is poor, mechanical property is the best and optoelectronic transformation efficiency is low.The environment protection solar opto-electronic conversion coating of the present invention
Can be excellent, output is big, and optoelectronic transformation efficiency is high, low production cost, environmental protection, it is easy to transport and store, it is easy to industrialized production,
There is great market using value, be especially applicable to solar building integrated field.
For solve above technical problem, the present invention by the following technical solutions:
A kind of environment protection solar opto-electronic conversion coating, in units of weight, including following raw material: matrix resin 65-100 part,
Graphite 45-50 part, color stuffing 28-35 part, GaAs 38-56 part, nickel oxide 5-10 part, lanthana 5-10 part, magnesium oxide 4-8
Part, zinc oxide 4-8 part, titanium oxide 3-6 part, glycerol 60-100 part, addition agent 10-20 part, firming agent 6-10 part, degasser 1-
3 parts, dispersant 1-2 part, wetting agent 0.5-1.2 part, emulsifying agent 0.4-1 part, preservative 0.2-0.5 part, antioxidant 0.2-0.4
Part；
Described color stuffing is metallic pigments and extender pigment；
Described addition agent, in units of weight portion, is made up of following raw material: propellant 2-3 part, coupling agent 2-4 part, compatilizer 1-2
Part, tranquilizer 1-2 part, bridging agent 0.8-2 part, regulator 0.6-1.8 part, hardening agent 0.4-1 part, flocculation agent 0.4-1 part, toughness reinforcing
Agent 0.4-0.8 part, plasticizer 0.4-0.8 part, thickening agent 0.4-0.6 part, stabilizer 0.3-0.5 part, terminator 0.3-0.5 part；
Described propellant is aerogel generating agent, and described coupling agent is epoxy silane class coupling agent, and described compatilizer is maleic acid
Acid anhydride grafting compatilizer, described tranquilizer constituent is ardealite, fluorgypsum, copper oxide, and described bridging agent is acrylic acid type frame
Bridge agent；Described regulator is processing aids acrylic resin；Described hardening agent is 701 powder hardening agents；Described flocculation agent is polymerization
Aluminum chloride；Described toughener is silicon carbide whisker；Described plasticizer is dioctyl adipate；Described thickening agent is cellulose ethers
Thickening agent；Described stabilizer is fat acids stabilizer；Described terminator is styrene；
Described firming agent is ethyl acrylate；Described degasser is stearic acid；Described dispersant is dispersant POLYRON；Described
Wetting agent is wetting agent BYK；
The preparation method of described environment protection solar opto-electronic conversion coating, comprises the following steps:
S1: matrix resin, graphite, color stuffing, GaAs, nickel oxide, lanthana, magnesium oxide, zinc oxide, titanium oxide are mixed also
Being ground processing, the particle diameter making mixed powder mince is 2-8 μm；
S2: by step S1 prepare mixed powder mince, glycerol, addition agent, firming agent, degasser, dispersant, wetting agent, breast
Agent, preservative, antioxidant are put in microwave reaction kettle, are 100-300W at power, and temperature is 45-65 DEG C, and speed of agitator is
It is put in homogenizer after processing 10-20min under 100-200r/min, carries out dispersion process, obtain coating emulsion；
The preparation method of addition agent described in step S2, comprises the following steps:
S21: propellant, coupling agent, compatilizer, tranquilizer, bridging agent mixing are warming up to 110-120 DEG C, are 200-at rotating speed
React 40-50min under 300r/min, prepare material I；
S22: addition regulator, hardening agent, flocculation agent, toughener, plasticizer, thickening agent mix in the material I that step S21 prepares
It is warming up to 140-145 DEG C after conjunction, under rotating speed is 300-400r/min, reacts 120-150min, prepares material II；
S23: be cooled to 115-118 DEG C, at rotating speed after adding stabilizer, terminator mixing in the material II that step S22 prepares
For reacting 60-80min under 200-300r/min, prepare addition agent；
S3: the coating emulsion that step S2 prepares is carried out spray drying treatment, prepares the powder environment-friendly type of water content≤6% too
Sun can opto-electronic conversion coating.
Further, described matrix resin is acrylic resin.
Further, described metallic pigments are argentum powder.
Further, described extender pigment is silica flour.
Further, described emulsifying agent is polyoxypropylene Arrcostab.
Further, described preservative is Liquid BPF-369.
Further, described antioxidant is antioxidant 501.
The method have the advantages that
(1) the environment protection solar opto-electronic conversion coating of the present invention is water-fast, soda acid, burn into ageing properties are good, and output is
187-192W/m2, optoelectronic transformation efficiency is 56%-60%, it is seen that the environment protection solar opto-electronic conversion coating property of the present invention is excellent, defeated
Going out power big, optoelectronic transformation efficiency is high；
(2) the environment protection solar opto-electronic conversion coating material production of the present invention is with low cost, environmental protection, it is easy to transport and store, it is easy to
Industrialized production, has great market using value, is especially applicable to solar building integrated field.
Detailed description of the invention
For ease of being more fully understood that the present invention, being illustrated by following example, these embodiments belong to the present invention's
Protection domain, but it is not intended to protection scope of the present invention.
In an embodiment, described environment protection solar opto-electronic conversion coating, in units of weight, including following raw material: base
Body resin 65-100 part, graphite 45-50 part, color stuffing 28-35 part, GaAs 38-56 part, nickel oxide 5-10 part, lanthana 5-
10 parts, magnesium oxide 4-8 part, zinc oxide 4-8 part, titanium oxide 3-6 part, glycerol 60-100 part, addition agent 10-20 part, firming agent
6-10 part, degasser 1-3 part, dispersant 1-2 part, wetting agent 0.5-1.2 part, emulsifying agent 0.4-1 part, preservative 0.2-0.5 part,
Antioxidant 0.2-0.4 part；
Described matrix resin is acrylic resin；Described color stuffing is metallic pigments and extender pigment, and described metallic pigments are silver
Powder, described extender pigment is silica flour；
Described addition agent, in units of weight portion, is made up of following raw material: propellant 2-3 part, coupling agent 2-4 part, compatilizer 1-2
Part, tranquilizer 1-2 part, bridging agent 0.8-2 part, regulator 0.6-1.8 part, hardening agent 0.4-1 part, flocculation agent 0.4-1 part, toughness reinforcing
Agent 0.4-0.8 part, plasticizer 0.4-0.8 part, thickening agent 0.4-0.6 part, stabilizer 0.3-0.5 part, terminator 0.3-0.5 part；
Described propellant is aerogel generating agent, and described coupling agent is epoxy silane class coupling agent, and described compatilizer is maleic acid
Acid anhydride grafting compatilizer, described tranquilizer constituent is ardealite, fluorgypsum, copper oxide, and described bridging agent is acrylic acid type frame
Bridge agent；Described regulator is processing aids acrylic resin；Described hardening agent is 701 powder hardening agents；Described flocculation agent is polymerization
Aluminum chloride；Described toughener is silicon carbide whisker；Described plasticizer is dioctyl adipate；Described thickening agent is cellulose ethers
Thickening agent；Described stabilizer is fat acids stabilizer；Described terminator is styrene；
Described firming agent is ethyl acrylate；Described degasser is stearic acid；Described dispersant is dispersant POLYRON；Described
Wetting agent is wetting agent BYK；Described emulsifying agent is polyoxypropylene Arrcostab；Described preservative is Liquid BPF-369；Described antioxygen
Agent is antioxidant 501；
The preparation method of described environment protection solar opto-electronic conversion coating, comprises the following steps:
S1: matrix resin, graphite, color stuffing, GaAs, nickel oxide, lanthana, magnesium oxide, zinc oxide, titanium oxide are mixed also
Being ground processing, the particle diameter making mixed powder mince is 2-8 μm；
S2: by step S1 prepare mixed powder mince, glycerol, addition agent, firming agent, degasser, dispersant, wetting agent, breast
Agent, preservative, antioxidant are put in microwave reaction kettle, are 100-300W at power, and temperature is 45-65 DEG C, and speed of agitator is
It is put in homogenizer after processing 10-20min under 100-200r/min, carries out dispersion process, obtain coating emulsion；
The preparation method of addition agent described in step S2, comprises the following steps:
S21: propellant, coupling agent, compatilizer, tranquilizer, bridging agent mixing are warming up to 110-120 DEG C, are 200-at rotating speed
React 40-50min under 300r/min, prepare material I；
S22: addition regulator, hardening agent, flocculation agent, toughener, plasticizer, thickening agent mix in the material I that step S21 prepares
It is warming up to 140-145 DEG C after conjunction, under rotating speed is 300-400r/min, reacts 120-150min, prepares material II；
S23: be cooled to 115-118 DEG C, at rotating speed after adding stabilizer, terminator mixing in the material II that step S22 prepares
For reacting 60-80min under 200-300r/min, prepare addition agent；
S3: the coating emulsion that step S2 prepares is carried out spray drying treatment, prepares the powder environment-friendly type of water content≤6% too
Sun can opto-electronic conversion coating.
Embodiment 1
A kind of environment protection solar opto-electronic conversion coating, in units of weight, including following raw material: matrix resin 80 parts, graphite
45 parts, color stuffing 30 parts, GaAs 45 parts, nickel oxide 8 parts, lanthana 8 parts, magnesium oxide 6 parts, zinc oxide 6 parts, titanium oxide 5 parts,
Glycerol 80 parts, addition agent 15 parts, 8 parts of firming agent, degasser 2 parts, dispersant 1.5 parts, wetting agent 0.9 part, emulsifying agent 0.8
Part, preservative 0.4 part, 0.3 part of antioxidant；
Described matrix resin is acrylic resin；Described color stuffing is metallic pigments and extender pigment, and described metallic pigments are silver
Powder, described extender pigment is silica flour；
Described addition agent, in units of weight portion, is made up of following raw material: propellant 1.5 parts, coupling agent 3 parts, compatilizer 1.5
Part, tranquilizer 1.5 parts, bridging agent 1.4 parts, regulator 1.2 parts, hardening agent 0.7 part, flocculation agent 0.7 part, toughener 0.6 part, increasing
Mould agent 0.6 part, thickening agent 0.5 part, stabilizer 0.4 part, terminator 0.4 part；
Described propellant is aerogel generating agent, and described coupling agent is epoxy silane class coupling agent, and described compatilizer is maleic acid
Acid anhydride grafting compatilizer, described tranquilizer constituent is ardealite, fluorgypsum, copper oxide, and described bridging agent is acrylic acid type frame
Bridge agent；Described regulator is processing aids acrylic resin；Described hardening agent is 701 powder hardening agents；Described flocculation agent is polymerization
Aluminum chloride；Described toughener is silicon carbide whisker；Described plasticizer is dioctyl adipate；Described thickening agent is cellulose ethers
Thickening agent；Described stabilizer is fat acids stabilizer；Described terminator is styrene；
Described firming agent is ethyl acrylate；Described degasser is stearic acid；Described dispersant is dispersant POLYRON；Described
Wetting agent is wetting agent BYK；Described emulsifying agent is polyoxypropylene Arrcostab；Described preservative is Liquid BPF-369；Described antioxygen
Agent is antioxidant 501；
The preparation method of described environment protection solar opto-electronic conversion coating, comprises the following steps:
S1: matrix resin, graphite, color stuffing, GaAs, nickel oxide, lanthana, magnesium oxide, zinc oxide, titanium oxide are mixed also
Being ground processing, the particle diameter making mixed powder mince is 2-8 μm；
S2: by step S1 prepare mixed powder mince, glycerol, addition agent, firming agent, degasser, dispersant, wetting agent, breast
Agent, preservative, antioxidant are put in microwave reaction kettle, are 200W at power, and temperature is 55 DEG C, and speed of agitator is 200r/min
It is put in homogenizer after lower process 15min, carries out dispersion process, obtain coating emulsion；
The preparation method of addition agent described in step S2, comprises the following steps:
S21: propellant, coupling agent, compatilizer, tranquilizer, bridging agent mixing are warming up to 115 DEG C, are 250r/min at rotating speed
Lower reaction 45min, prepares material I；
S22: addition regulator, hardening agent, flocculation agent, toughener, plasticizer, thickening agent mix in the material I that step S21 prepares
It is warming up to 142 DEG C after conjunction, under rotating speed is 350r/min, reacts 135min, prepares material II；
S23: be cooled to 116 DEG C after adding stabilizer, terminator mixing in the material II that step S22 prepares, at rotating speed be
React 70min under 250r/min, prepare addition agent；
S3: by step S2 prepare coating emulsion carry out spray drying treatment, prepared water content be 6% powder environment-friendly type too
Sun can opto-electronic conversion coating.
Embodiment 2
A kind of environment protection solar opto-electronic conversion coating, in units of weight, including following raw material: matrix resin 65 parts, graphite
45 parts, color stuffing 28 parts, GaAs 38 parts, nickel oxide 5 parts, lanthana 5 parts, magnesium oxide 4 parts, zinc oxide 4 parts, titanium oxide 3 parts,
Glycerol 60 parts, addition agent 10 parts, 6 parts of firming agent, degasser 1 part, dispersant 1 part, wetting agent 0.5 part, emulsifying agent 0.4 part,
Preservative 0.2 part, 0.2 part of antioxidant；
Described matrix resin is acrylic resin；Described color stuffing is metallic pigments and extender pigment, and described metallic pigments are silver
Powder, described extender pigment is silica flour；
Described addition agent, in units of weight portion, is made up of following raw material: propellant 2 parts, coupling agent 2 parts, compatilizer 1 part, peace
Determine agent 1 part, bridging agent 0.8 part, regulator 0.6 part, hardening agent 0.4 part, flocculation agent 0.4 part, toughener 0.4 part, plasticizer 0.4
Part, thickening agent 0.4 part, stabilizer 0.3 part, terminator 0.3 part；
Described propellant is aerogel generating agent, and described coupling agent is epoxy silane class coupling agent, and described compatilizer is maleic acid
Acid anhydride grafting compatilizer, described tranquilizer constituent is ardealite, fluorgypsum, copper oxide, and described bridging agent is acrylic acid type frame
Bridge agent；Described regulator is processing aids acrylic resin；Described hardening agent is 701 powder hardening agents；Described flocculation agent is polymerization
Aluminum chloride；Described toughener is silicon carbide whisker；Described plasticizer is dioctyl adipate；Described thickening agent is cellulose ethers
Thickening agent；Described stabilizer is fat acids stabilizer；Described terminator is styrene；
Described firming agent is ethyl acrylate；Described degasser is stearic acid；Described dispersant is dispersant POLYRON；Described
Wetting agent is wetting agent BYK；Described emulsifying agent is polyoxypropylene Arrcostab；Described preservative is Liquid BPF-369；Described antioxygen
Agent is antioxidant 501；
The preparation method of described environment protection solar opto-electronic conversion coating, comprises the following steps:
S1: matrix resin, graphite, color stuffing, GaAs, nickel oxide, lanthana, magnesium oxide, zinc oxide, titanium oxide are mixed also
Being ground processing, the particle diameter making mixed powder mince is 2-8 μm；
S2: by step S1 prepare mixed powder mince, glycerol, addition agent, firming agent, degasser, dispersant, wetting agent, breast
Agent, preservative, antioxidant are put in microwave reaction kettle, are 100W at power, and temperature is 45 DEG C, and speed of agitator is 100r/min
It is put in homogenizer after lower process 20min, carries out dispersion process, obtain coating emulsion；
The preparation method of addition agent described in step S2, comprises the following steps:
S21: propellant, coupling agent, compatilizer, tranquilizer, bridging agent mixing are warming up to 110 DEG C, are 200r/min at rotating speed
Lower reaction 50min, prepares material I；
S22: addition regulator, hardening agent, flocculation agent, toughener, plasticizer, thickening agent mix in the material I that step S21 prepares
It is warming up to 140 DEG C after conjunction, under rotating speed is 300r/min, reacts 150min, prepares material II；
S23: be cooled to 115 DEG C after adding stabilizer, terminator mixing in the material II that step S22 prepares, at rotating speed be
React 80min under 200r/min, prepare addition agent；
S3: by step S2 prepare coating emulsion carry out spray drying treatment, prepared water content be 5% powder environment-friendly type too
Sun can opto-electronic conversion coating.
Embodiment 3
A kind of environment protection solar opto-electronic conversion coating, in units of weight, including following raw material: matrix resin 100 parts, graphite
50 parts, color stuffing 35 parts, GaAs 56 parts, nickel oxide 10 parts, lanthana 10 parts, magnesium oxide 8 parts, zinc oxide 8 parts, titanium oxide 6
Part, glycerol 100 parts, addition agent 20 parts, 10 parts of firming agent, degasser 3 parts, dispersant 2 parts, wetting agent 1.2 parts, emulsifying agent 1
Part, preservative 0.5 part, 0.4 part of antioxidant；
Described matrix resin is acrylic resin；Described color stuffing is metallic pigments and extender pigment, and described metallic pigments are silver
Powder, described extender pigment is silica flour；
Described addition agent, in units of weight portion, is made up of following raw material: propellant 3 parts, coupling agent 4 parts, compatilizer 2 parts, peace
Determine agent 2 parts, bridging agent 2 parts, regulator 1.8 parts, hardening agent 1 part, flocculation agent 1 part, toughener 0.8 part, plasticizer 0.8 part, increase
Thick dose 0.6 part, stabilizer 0.5 part, terminator 0.5 part；
Described propellant is aerogel generating agent, and described coupling agent is epoxy silane class coupling agent, and described compatilizer is maleic acid
Acid anhydride grafting compatilizer, described tranquilizer constituent is ardealite, fluorgypsum, copper oxide, and described bridging agent is acrylic acid type frame
Bridge agent；Described regulator is processing aids acrylic resin；Described hardening agent is 701 powder hardening agents；Described flocculation agent is polymerization
Aluminum chloride；Described toughener is silicon carbide whisker；Described plasticizer is dioctyl adipate；Described thickening agent is cellulose ethers
Thickening agent；Described stabilizer is fat acids stabilizer；Described terminator is styrene；
Described firming agent is ethyl acrylate；Described degasser is stearic acid；Described dispersant is dispersant POLYRON；Described
Wetting agent is wetting agent BYK；Described emulsifying agent is polyoxypropylene Arrcostab；Described preservative is Liquid BPF-369；Described antioxygen
Agent is antioxidant 501；
The preparation method of described environment protection solar opto-electronic conversion coating, comprises the following steps:
S1: matrix resin, graphite, color stuffing, GaAs, nickel oxide, lanthana, magnesium oxide, zinc oxide, titanium oxide are mixed also
Being ground processing, the particle diameter making mixed powder mince is 2-8 μm；
S2: by step S1 prepare mixed powder mince, glycerol, addition agent, firming agent, degasser, dispersant, wetting agent, breast
Agent, preservative, antioxidant are put in microwave reaction kettle, are 300W at power, and temperature is 65 DEG C, and speed of agitator is 200r/min
It is put in homogenizer after lower process 10min, carries out dispersion process, obtain coating emulsion；
The preparation method of addition agent described in step S2, comprises the following steps:
S21: propellant, coupling agent, compatilizer, tranquilizer, bridging agent mixing are warming up to 120 DEG C, are 300r/min at rotating speed
Lower reaction 40min, prepares material I；
S22: addition regulator, hardening agent, flocculation agent, toughener, plasticizer, thickening agent mix in the material I that step S21 prepares
It is warming up to 145 DEG C after conjunction, under rotating speed is 400r/min, reacts 120min, prepares material II；
S23: be cooled to 118 DEG C after adding stabilizer, terminator mixing in the material II that step S22 prepares, at rotating speed be
React 60min under 300r/min, prepare addition agent；
S3: by step S2 prepare coating emulsion carry out spray drying treatment, prepared water content be 4% powder environment-friendly type too
Sun can opto-electronic conversion coating.
The environment protection solar opto-electronic conversion coating correlation performance parameters of embodiment of the present invention 1-3 is as shown in the table.
As seen from the above table: the environment protection solar opto-electronic conversion coating of the present invention is water-fast, soda acid, burn into ageing properties are good,
Output is 188-193W/m2, optoelectronic transformation efficiency is 55%-61%, it is seen that the environment protection solar opto-electronic conversion of the present invention is coated with
Material performance is excellent, and output is big, and optoelectronic transformation efficiency is high.
Above content it cannot be assumed that the present invention be embodied as be confined to these explanation, technology belonging to the present invention is led
For the those of ordinary skill in territory, without departing from the inventive concept of the premise, it is also possible to make some simple deduction or replace,
All should be considered as belonging to the scope of patent protection that the present invention is determined by the claims submitted to.
Claims (7)
1. an environment protection solar opto-electronic conversion coating, it is characterised in that in units of weight, including following raw material: matrix
Resin 65-100 part, graphite 45-50 part, color stuffing 28-35 part, GaAs 38-56 part, nickel oxide 5-10 part, lanthana 5-10
Part, magnesium oxide 4-8 part, zinc oxide 4-8 part, titanium oxide 3-6 part, glycerol 60-100 part, addition agent 10-20 part, firming agent 6-
10 parts, degasser 1-3 part, dispersant 1-2 part, wetting agent 0.5-1.2 part, emulsifying agent 0.4-1 part, preservative 0.2-0.5 part, anti-
Oxygen agent 0.2-0.4 part；
Described color stuffing is metallic pigments and extender pigment；
Described addition agent, in units of weight portion, is made up of following raw material: propellant 2-3 part, coupling agent 2-4 part, compatilizer 1-2
Part, tranquilizer 1-2 part, bridging agent 0.8-2 part, regulator 0.6-1.8 part, hardening agent 0.4-1 part, flocculation agent 0.4-1 part, toughness reinforcing
Agent 0.4-0.8 part, plasticizer 0.4-0.8 part, thickening agent 0.4-0.6 part, stabilizer 0.3-0.5 part, terminator 0.3-0.5 part；
Described propellant is aerogel generating agent, and described coupling agent is epoxy silane class coupling agent, and described compatilizer is maleic acid
Acid anhydride grafting compatilizer, described tranquilizer constituent is ardealite, fluorgypsum, copper oxide, and described bridging agent is acrylic acid type frame
Bridge agent；Described regulator is processing aids acrylic resin；Described hardening agent is 701 powder hardening agents；Described flocculation agent is polymerization
Aluminum chloride；Described toughener is silicon carbide whisker；Described plasticizer is dioctyl adipate；Described thickening agent is cellulose ethers
Thickening agent；Described stabilizer is fat acids stabilizer；Described terminator is styrene；
Described firming agent is ethyl acrylate；Described degasser is stearic acid；Described dispersant is dispersant POLYRON；Described
Wetting agent is wetting agent BYK；
The preparation method of described environment protection solar opto-electronic conversion coating, comprises the following steps:
S1: matrix resin, graphite, color stuffing, GaAs, nickel oxide, lanthana, magnesium oxide, zinc oxide, titanium oxide are mixed also
Being ground processing, the particle diameter making mixed powder mince is 2-8 μm；
S2: by step S1 prepare mixed powder mince, glycerol, addition agent, firming agent, degasser, dispersant, wetting agent, breast
Agent, preservative, antioxidant are put in microwave reaction kettle, are 100-300W at power, and temperature is 45-65 DEG C, and speed of agitator is
It is put in homogenizer after processing 10-20min under 100-200r/min, carries out dispersion process, obtain coating emulsion；
The preparation method of addition agent described in step S2, comprises the following steps:
S21: propellant, coupling agent, compatilizer, tranquilizer, bridging agent mixing are warming up to 110-120 DEG C, are 200-at rotating speed
React 40-50min under 300r/min, prepare material I；
S22: addition regulator, hardening agent, flocculation agent, toughener, plasticizer, thickening agent mix in the material I that step S21 prepares
It is warming up to 140-145 DEG C after conjunction, under rotating speed is 300-400r/min, reacts 120-150min, prepares material II；
S23: be cooled to 115-118 DEG C, at rotating speed after adding stabilizer, terminator mixing in the material II that step S22 prepares
For reacting 60-80min under 200-300r/min, prepare addition agent；
S3: the coating emulsion that step S2 prepares is carried out spray drying treatment, prepares the powder environment-friendly type of water content≤6% too
Sun can opto-electronic conversion coating.
Environment protection solar opto-electronic conversion coating the most according to claim 1, it is characterised in that described matrix resin is third
Olefin(e) acid resin.
Environment protection solar opto-electronic conversion coating the most according to claim 1, it is characterised in that described metallic pigments are silver
Powder.
Environment protection solar opto-electronic conversion coating the most according to claim 1, it is characterised in that described extender pigment is stone
Ying Fen.
Environment protection solar opto-electronic conversion coating the most according to claim 1, it is characterised in that described emulsifying agent is polyoxy
Propylene Arrcostab.
Environment protection solar opto-electronic conversion coating the most according to claim 1, it is characterised in that described preservative is anticorrosion
Agent N-369.
Environment protection solar opto-electronic conversion coating the most according to claim 1, it is characterised in that described antioxidant is antioxygen
Agent 501.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201610588454.4A CN106085055A (en) | 2016-07-25 | 2016-07-25 | A kind of environment protection solar opto-electronic conversion coating |
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| CN201610588454.4A CN106085055A (en) | 2016-07-25 | 2016-07-25 | A kind of environment protection solar opto-electronic conversion coating |
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Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101143357A (en) * | 2007-07-13 | 2008-03-19 | 清华大学 | Nanocrystalline film and its low temperature preparing method |
| CN104031530A (en) * | 2014-07-04 | 2014-09-10 | 成都新柯力化工科技有限公司 | Solar photoelectricity conversion coating and preparing method thereof |
-
2016
- 2016-07-25 CN CN201610588454.4A patent/CN106085055A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101143357A (en) * | 2007-07-13 | 2008-03-19 | 清华大学 | Nanocrystalline film and its low temperature preparing method |
| CN104031530A (en) * | 2014-07-04 | 2014-09-10 | 成都新柯力化工科技有限公司 | Solar photoelectricity conversion coating and preparing method thereof |
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