CN106010068A - Steel wire thread sleeve coating - Google Patents
Steel wire thread sleeve coating Download PDFInfo
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- CN106010068A CN106010068A CN201610376038.8A CN201610376038A CN106010068A CN 106010068 A CN106010068 A CN 106010068A CN 201610376038 A CN201610376038 A CN 201610376038A CN 106010068 A CN106010068 A CN 106010068A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D151/00—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
- C09D151/08—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/83—Chemically modified polymers
- C08G18/831—Chemically modified polymers by oxygen-containing compounds inclusive of carbonic acid halogenides, carboxylic acid halogenides and epoxy halides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention discloses a steel wire thread sleeve coating. The steel wire thread sleeve coating is prepared from, by weight, methyl methacrylate, polyethylene glycol, abietate, an emulsifier, aqueous epoxy resin, modified aqueous polyurethane, primary amine, ethyl titanate, nanometer diatomite, an active diluent, an antifoaming agent and a functional assistant. A coating layer formed by using the coating has the advantages of excellent corrosion resistance, excellent pollution resistance, good adhesion, good lubricity, high hardness, scratch resistance, salt mist resistance, acid and alkali resistance, high glossiness, realization of one-shot finishing paint spraying without using a priming paint, fast solidification speed, low cost, good adhesion, and realization of no wastes due to cycle use realization. The coating has the advantages of greenness, no pollution, excellent working performances and technological performances, high surface strength, good thermal stability at a low temperature, and excellent water and solvent resistance, and all above performances of the coating can be realized through a reasonable formula and a correct preparation technology.
Description
Technical field
The present invention relates to chemical field, particularly relate to a kind of steel-wire screw-socket coating.
Background technology
Steel-wire screw-socket is a kind of novel threaded female fastener, it be with high intensity, in high precision, a kind of concentric body of spring-like internal and external threads of accurately processing of the cold rolling rhombus stainless steel silk of any surface finish.It is mainly used in strengthening and the female thread of protection low-intensity material.Its principle is to form elasticity between screw and matrix female thread to connect, and eliminates screw thread foozle, improves bonding strength.Steel-wire screw-socket is divided into again plain edition and lock type two kinds, and lock type is to increase by circle or an a few circle clamp ring on the basis of medium-sized, and rigging screw is played the locking effect of fastening.The coating of existing steel-wire screw-socket, adhesive force is low, and coating is uneven, and coating life is low, and then affects the life-span of steel-wire screw-socket.
Summary of the invention
It is an object of the invention to provide a kind of steel-wire screw-socket coating, be achieved through the following technical solutions:
A kind of steel-wire screw-socket coating, is made up of following component: methyl methacrylate 26, Polyethylene Glycol 27, rosin ester 7, emulsifying agent 1.8, aqueous epoxy resins 28, modified aqueous polyurethane 24, primary amine 0.5, tetraethyl titanate 1, nano diatomite 0.5, reactive diluent 13, defoamer 0.8, functional aid 0.65 by weight；
Described reactive diluent is made up of following component by weight: tert-butyl phenol glycidyl ether 15, acrylic acid 10, vinyl ethers 12, suberic acid 3, nano-attapulgite 1, hydroquinone 0.3；Its preparation method is by after tert-butyl phenol glycidyl ether, acrylic acid, vinyl ethers, suberic acid mixing, add in reactor, temperature is set to 68 DEG C, and mixing speed is 300r/min, after keeping 30 minutes, add nano-attapulgite, hydroquinone, temperature is set to 98 DEG C, and mixing speed is 500r/min, after keeping 40 minutes, naturally cool to room temperature,；
Described emulsifying agent is made up of following component by weight: sorbitan oleate 4, sorbitol anhydride laurate 3, Oleum Gossypii semen 6, sodium hydroxide 1, polyvinyl alcohol 12, dodecyl sodium sulfate 1, phosphoglyceride 2, water 80；Its preparation method is: after sorbitan oleate, sorbitol anhydride laurate, Oleum Gossypii semen, sodium hydroxide, polyvinyl alcohol, dodecyl sodium sulfate, phosphoglyceride, water mixing, add in reactor, then temperature is adjusted to 42 DEG C, pressure is 0.5MPa, stirs 20 minutes with 300r/min speed, then temperature is adjusted to 53 DEG C, pressure is 0.8MPa, after stirring 30 minutes with 600r/min speed, stand 1 hour,；
Described defoamer is organic silicon defoamer；Described functional aid is: Oleum Verniciae fordii, maleic acid, alkyd resin are mixed by the mass ratio of 3:1:8；
Described methyl methacrylate, aqueous epoxy resins, primary amine, tetraethyl titanate process through being blended, and blending temperature is 156 DEG C, and time 18min, rotating speed 100r/min are blended；
Described modified aqueous polyurethane is made up of following component by weight: aqueous polyurethane 40, acrylic acid 5, pentaerythritol triacrylate 1, epoxy soybean oil 2, glycerol 2；Its preparation method is: aqueous polyurethane, acrylic acid, pentaerythritol triacrylate, epoxy soybean oil, glycerol is added in reactor successively and stirs with 120r/min speed, temperature controls between 45-48 DEG C, it is separated by 5 minutes between adding every time, after all adding, mixing speed is increased to 240r/min, and temperature is adjusted to 54-56 DEG C, keeps 30 minutes, naturally cool to room temperature,.
A kind of manufacture method of steel-wire screw-socket coating, including:
1) methyl methacrylate of blended for process process, aqueous epoxy resins, primary amine, tetraethyl titanate are mixed with modified aqueous polyurethane, Polyethylene Glycol, after mix homogeneously, add emulsifying agent and carry out composite emulsifying, and when being heated to 98 DEG C, add after rosin ester, mix homogeneously, carry out stirring 30 minutes with 400r/min speed, then, 10 minutes are stood；
2) in rapid dispersion machine add 1) in gained raw material, after 10 minutes, then add nano diatomite, reactive diluent, stir with 100r/min rotating speed, after 10 minutes, add through defoamer, stir with 200r/min rotating speed, after 10 minutes, add functional aid, stir 10 minutes with 400r/min rotating speed, then stir after 20 minutes with 1000r/min speed, stand.
Coating of the present invention uses 1000W high-pressure lamp to irradiate solidification, and irradiation distance is 16.4cm.
The reactive diluent that the present invention is prepared by lot of experiments, there is photosensition, the viscosity of coating can be effectively reduced, improve the curing rate of coating, there is good storage stability, by the reactive diluent using the present invention to prepare, the coating top layer enabling to the coating top layer relatively common coating hardening time formation that coating of the present invention is formed shortens half hardening time, and, the shrinkage factor of the coating that coating of the present invention is formed is reduced to 1/3rd that common coating forms the shrinkage factor of coating, and, adhesive force and the toughness of the coating that coating of the present invention is formed are splendid.
The emulsifying agent that the present invention is prepared by lot of experiments, the multimolecular adsorption film of some strength can be defined with other molecule, chemical stability, mechanical stability, freeze-thaw stability and the bin stability of coating all had lifting greatly, coating is preserved down for a long time, will not precipitate, affect the serviceability of coating, and film forming speed and its stability of coating can be improved.
By the functional aid of preparation, promoting coating further and form the adhesive force of coating, coating has the most excellent processability and outdoor durable.
By methyl methacrylate, aqueous epoxy resins, primary amine, tetraethyl titanate are processed through being blended, the film layer that coating can be made to be formed has the best tack, lubricity and corrosion resistance, and the heat resistance of coating can be improved, improve angle degeneration and the ageing resistance of coating；
By the pretreatment to nano diatomite, the heat stability under the curing rate of coating, coating hardness, adhesive force and low temperature can be improved.
The modified aqueous polyurethane that the present invention is prepared by numerous studies, the coating performance formed by coating aqueous polyurethane, acrylic acid, pentaerythritol triacrylate, epoxy soybean oil, glycerol blending and modifying prepared is significantly improved than common water borne polyaminoester emulsion coating performance, hardness and the hot strength of coating are greatly improved, elongation at break then has and improves by a small margin, hardness of film reaches glass hard (HRC65Yi Shang) 0.87, coating machine performance enhancement, storage is stable to be raised.
The invention has the beneficial effects as follows: the coating that coating of the present invention is formed has excellent corrosion resistance, excellent anti-fouling performance and good tack, lubricity, hardness height, damage resistant, salt spray resistance, acid and alkali-resistance, glossiness are high, only need to spray a finish paint, being not required to do priming paint, curing rate is fast, low cost, good attachment, can be recycled and do not waste.Coating green non-pollution of the present invention, there is excellent service behaviour and processing performance, having the Heat stability is good under surface strength high and low temperature, resistance to water and excellent solvent resistance, these performances are mainly obtained by rational formula in the present invention and correct preparation technology.Using under the same conditions, the life-span of the coating that coating of the present invention is formed is higher than the life-span that general coating is formed by 70%.
Detailed description of the invention
A kind of steel-wire screw-socket coating, is made up of following component: methyl methacrylate 26, Polyethylene Glycol 27, rosin ester 7, emulsifying agent 1.8, aqueous epoxy resins 28, modified aqueous polyurethane 24, primary amine 0.5, tetraethyl titanate 1, nano diatomite 0.5, reactive diluent 13, defoamer 0.8, functional aid 0.65 by weight；
Described reactive diluent is made up of following component by weight: tert-butyl phenol glycidyl ether 15, acrylic acid 10, vinyl ethers 12, suberic acid 3, nano-attapulgite 1, hydroquinone 0.3；Its preparation method is by after tert-butyl phenol glycidyl ether, acrylic acid, vinyl ethers, suberic acid mixing, add in reactor, temperature is set to 68 DEG C, and mixing speed is 300r/min, after keeping 30 minutes, add nano-attapulgite, hydroquinone, temperature is set to 98 DEG C, and mixing speed is 500r/min, after keeping 40 minutes, naturally cool to room temperature,；
Described emulsifying agent is made up of following component by weight: sorbitan oleate 4, sorbitol anhydride laurate 3, Oleum Gossypii semen 6, sodium hydroxide 1, polyvinyl alcohol 12, dodecyl sodium sulfate 1, phosphoglyceride 2, water 80；Its preparation method is: after sorbitan oleate, sorbitol anhydride laurate, Oleum Gossypii semen, sodium hydroxide, polyvinyl alcohol, dodecyl sodium sulfate, phosphoglyceride, water mixing, add in reactor, then temperature is adjusted to 42 DEG C, pressure is 0.5MPa, stirs 20 minutes with 300r/min speed, then temperature is adjusted to 53 DEG C, pressure is 0.8MPa, after stirring 30 minutes with 600r/min speed, stand 1 hour,；
Described defoamer is organic silicon defoamer；Described functional aid is: Oleum Verniciae fordii, maleic acid, alkyd resin are mixed by the mass ratio of 3:1:8；
Described methyl methacrylate, aqueous epoxy resins, primary amine, tetraethyl titanate process through being blended, and blending temperature is 156 DEG C, and time 18min, rotating speed 100r/min are blended；
Described modified aqueous polyurethane is made up of following component by weight: aqueous polyurethane 40, acrylic acid 5, pentaerythritol triacrylate 1, epoxy soybean oil 2, glycerol 2；Its preparation method is: aqueous polyurethane, acrylic acid, pentaerythritol triacrylate, epoxy soybean oil, glycerol is added in reactor successively and stirs with 120r/min speed, temperature controls between 45-48 DEG C, it is separated by 5 minutes between adding every time, after all adding, mixing speed is increased to 240r/min, and temperature is adjusted to 54-56 DEG C, keeps 30 minutes, naturally cool to room temperature,.
A kind of manufacture method of steel-wire screw-socket coating, including:
1) methyl methacrylate of blended for process process, aqueous epoxy resins, primary amine, tetraethyl titanate are mixed with modified aqueous polyurethane, Polyethylene Glycol, after mix homogeneously, add emulsifying agent and carry out composite emulsifying, and when being heated to 98 DEG C, add after rosin ester, mix homogeneously, carry out stirring 30 minutes with 400r/min speed, then, 10 minutes are stood；
2) in rapid dispersion machine add 1) in gained raw material, after 10 minutes, then add nano diatomite, reactive diluent, stir with 100r/min rotating speed, after 10 minutes, add through defoamer, stir with 200r/min rotating speed, after 10 minutes, add functional aid, stir 10 minutes with 400r/min rotating speed, then stir after 20 minutes with 1000r/min speed, stand.
Coating of the present invention uses 1000W high-pressure lamp to irradiate solidification, and irradiation distance is 16.4cm.
The reactive diluent that the present invention is prepared by lot of experiments, there is photosensition, the viscosity of coating can be effectively reduced, improve the curing rate of coating, there is good storage stability, by the reactive diluent using the present invention to prepare, the coating top layer enabling to the coating top layer relatively common coating hardening time formation that coating of the present invention is formed shortens half hardening time, and, the shrinkage factor of the coating that coating of the present invention is formed is reduced to 1/3rd that common coating forms the shrinkage factor of coating, and, adhesive force and the toughness of the coating that coating of the present invention is formed are splendid.
The emulsifying agent that the present invention is prepared by lot of experiments, the multimolecular adsorption film of some strength can be defined with other molecule, chemical stability, mechanical stability, freeze-thaw stability and the bin stability of coating all had lifting greatly, coating is preserved down for a long time, will not precipitate, affect the serviceability of coating, and film forming speed and its stability of coating can be improved.
By the functional aid of preparation, promoting coating further and form the adhesive force of coating, coating has the most excellent processability and outdoor durable.
By methyl methacrylate, aqueous epoxy resins, primary amine, tetraethyl titanate are processed through being blended, the film layer that coating can be made to be formed has the best tack, lubricity and corrosion resistance, and the heat resistance of coating can be improved, improve angle degeneration and the ageing resistance of coating；
By the pretreatment to nano diatomite, the heat stability under the curing rate of coating, coating hardness, adhesive force and low temperature can be improved.
The modified aqueous polyurethane that the present invention is prepared by numerous studies, the coating performance formed by coating aqueous polyurethane, acrylic acid, pentaerythritol triacrylate, epoxy soybean oil, glycerol blending and modifying prepared is significantly improved than common water borne polyaminoester emulsion coating performance, hardness and the hot strength of coating are greatly improved, elongation at break then has and improves by a small margin, hardness of film reaches glass hard (HRC65Yi Shang) 0.87, coating machine performance enhancement, storage is stable to be raised.
Coating property index of the present invention:
1, paint film appearance: flat smooth
2, viscosity (23 ± 1 DEG C of viscometers, S): 82
3, fineness≤33 μm
4, high temperature resistant (130 DEG C) >=510h
5, hardness >=2H
6, salt spray resistance (120h level) >=2
7, resistance to water (29 ± 1 DEG C of 240h): non-foaming, does not falls off
8, oil resistant (90# gasoline, 56h): non-foaming, does not falls off
9, alkali resistance (GB/T9755-2001): more than 60 hours
10, artificial weathering ageing resistance (GB/T9755-2001): more than 1220 hours.
Claims (2)
1. a steel-wire screw-socket coating, it is characterized in that, be made up of following component by weight: methyl methacrylate 26, Polyethylene Glycol 27, rosin ester 7, emulsifying agent 1.8, aqueous epoxy resins 28, modified aqueous polyurethane 24, primary amine 0.5, tetraethyl titanate 1, Ethylene glycol dimethacrylate 4, nano diatomite 0.5, reactive diluent 13, defoamer 0.8, functional aid 0.65；
Described reactive diluent is made up of following component by weight: tert-butyl phenol glycidyl ether 15, acrylic acid 10, vinyl ethers 12, suberic acid 3, nano-attapulgite 1, hydroquinone 0.3；Its preparation method is by after tert-butyl phenol glycidyl ether, acrylic acid, vinyl ethers, suberic acid mixing, add in reactor, temperature is set to 68 DEG C, and mixing speed is 300r/min, after keeping 30 minutes, add nano-attapulgite, hydroquinone, temperature is set to 98 DEG C, and mixing speed is 500r/min, after keeping 40 minutes, naturally cool to room temperature,；
Described emulsifying agent is made up of following component by weight: sorbitan oleate 4, sorbitol anhydride laurate 3, Oleum Gossypii semen 6, sodium hydroxide 1, polyvinyl alcohol 12, dodecyl sodium sulfate 1, phosphoglyceride 2, water 80；Its preparation method is: after sorbitan oleate, sorbitol anhydride laurate, Oleum Gossypii semen, sodium hydroxide, polyvinyl alcohol, dodecyl sodium sulfate, phosphoglyceride, water mixing, add in reactor, then temperature is adjusted to 42 DEG C, pressure is 0.5MPa, stirs 20 minutes with 300r/min speed, then temperature is adjusted to 53 DEG C, pressure is 0.8MPa, after stirring 30 minutes with 600r/min speed, stand 1 hour,；
Described defoamer is organic silicon defoamer；Described functional aid is: Oleum Verniciae fordii, maleic acid, alkyd resin are mixed by the mass ratio of 3:1:8；
Described methyl methacrylate, aqueous epoxy resins, primary amine, tetraethyl titanate process through being blended, and blending temperature is 156 DEG C, and time 18min, rotating speed 100r/min are blended；
Described nano diatomite is through pretreatment: add the titanium dioxide of its quality 2% in nano diatomite, after mix homogeneously, then adds the sad solution of mixture quality 20%, the mass concentration of octanoic acid solution is 9.8%, then is stirred, and is then ground 30 minutes, filter, be dried,；
Described modified aqueous polyurethane is made up of following component by weight: aqueous polyurethane 40, acrylic acid 5, pentaerythritol triacrylate 1, epoxy soybean oil 2, glycerol 2；Its preparation method is: aqueous polyurethane, acrylic acid, pentaerythritol triacrylate, epoxy soybean oil, glycerol is added in reactor successively and stirs with 120r/min speed, temperature controls between 45-48 DEG C, it is separated by 5 minutes between adding every time, after all adding, mixing speed is increased to 240r/min, and temperature is adjusted to 54-56 DEG C, keeps 30 minutes, naturally cool to room temperature,.
The manufacture method of a kind of steel-wire screw-socket coating the most according to claim 1, it is characterised in that including:
1) methyl methacrylate of blended for process process, aqueous epoxy resins, primary amine, tetraethyl titanate are mixed with modified aqueous polyurethane, Polyethylene Glycol, after mix homogeneously, add emulsifying agent and carry out composite emulsifying, and when being heated to 98 DEG C, add after rosin ester, mix homogeneously, carry out stirring 30 minutes with 400r/min speed, then, 10 minutes are stood；
2) in rapid dispersion machine add 1) in gained raw material, after 10 minutes, then add nano diatomite, reactive diluent, stir with 100r/min rotating speed, after 10 minutes, add through defoamer, stir with 200r/min rotating speed, after 10 minutes, add functional aid, stir 10 minutes with 400r/min rotating speed, then stir after 20 minutes with 1000r/min speed, stand.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610376038.8A CN106010068A (en) | 2016-05-31 | 2016-05-31 | Steel wire thread sleeve coating |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610376038.8A CN106010068A (en) | 2016-05-31 | 2016-05-31 | Steel wire thread sleeve coating |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106010068A true CN106010068A (en) | 2016-10-12 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610376038.8A Pending CN106010068A (en) | 2016-05-31 | 2016-05-31 | Steel wire thread sleeve coating |
Country Status (1)
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| CN (1) | CN106010068A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108753166A (en) * | 2018-05-09 | 2018-11-06 | 阜南县勤艺工艺品有限公司 | A kind of surface has the bamboo clappers of good anti-pollution characteristic |
| CN113460532A (en) * | 2021-05-31 | 2021-10-01 | 常州市第一人民医院 | Automatic compression and garbage bin of taking disinfection function |
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| CN101215438A (en) * | 2008-01-03 | 2008-07-09 | 海门市森达装饰材料有限公司 | Anti-soiling aging-resisting stainless steel paint and preparation method thereof |
| CN101747594A (en) * | 2009-12-11 | 2010-06-23 | 上海新天和树脂有限公司 | Epoxy acrylate prepolymer resin and preparation method thereof and application in photocurable coating |
| CN104017478A (en) * | 2014-06-13 | 2014-09-03 | 长沙恒大环保科技有限公司 | Water soluble anticorrosive paint for iron-based materials as well as preparation method and application thereof |
| CN104962176A (en) * | 2015-08-03 | 2015-10-07 | 何肖凤 | Water-based epoxy resin paint and preparation method thereof |
| CN105176346A (en) * | 2015-08-31 | 2015-12-23 | 天长市银狐漆业有限公司 | Heat-resistant flame-retardant anticorrosion water-based coating |
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2016
- 2016-05-31 CN CN201610376038.8A patent/CN106010068A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101215438A (en) * | 2008-01-03 | 2008-07-09 | 海门市森达装饰材料有限公司 | Anti-soiling aging-resisting stainless steel paint and preparation method thereof |
| CN101747594A (en) * | 2009-12-11 | 2010-06-23 | 上海新天和树脂有限公司 | Epoxy acrylate prepolymer resin and preparation method thereof and application in photocurable coating |
| CN104017478A (en) * | 2014-06-13 | 2014-09-03 | 长沙恒大环保科技有限公司 | Water soluble anticorrosive paint for iron-based materials as well as preparation method and application thereof |
| CN104962176A (en) * | 2015-08-03 | 2015-10-07 | 何肖凤 | Water-based epoxy resin paint and preparation method thereof |
| CN105176346A (en) * | 2015-08-31 | 2015-12-23 | 天长市银狐漆业有限公司 | Heat-resistant flame-retardant anticorrosion water-based coating |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108753166A (en) * | 2018-05-09 | 2018-11-06 | 阜南县勤艺工艺品有限公司 | A kind of surface has the bamboo clappers of good anti-pollution characteristic |
| CN113460532A (en) * | 2021-05-31 | 2021-10-01 | 常州市第一人民医院 | Automatic compression and garbage bin of taking disinfection function |
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Application publication date: 20161012 |