CN105176346A - Heat-resistant flame-retardant anticorrosion water-based coating - Google Patents

Heat-resistant flame-retardant anticorrosion water-based coating Download PDF

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CN105176346A
CN105176346A CN201510548007.1A CN201510548007A CN105176346A CN 105176346 A CN105176346 A CN 105176346A CN 201510548007 A CN201510548007 A CN 201510548007A CN 105176346 A CN105176346 A CN 105176346A
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parts
water
weight
modified
nano
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CN201510548007.1A
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Chinese (zh)
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戴宇钧
刘懿
汪鹏程
孙巨福
祝秀凤
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天长市银狐漆业有限公司
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Publication of CN105176346A publication Critical patent/CN105176346A/en

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Abstract

The invention discloses a heat-resistant flame-retardant anticorrosion water-based coating. The coating comprises the following raw materials: composite emulsion of polyurethane and epoxy resin, acrylic emulsion, brominated epoxy resin, silica sol, boron phenolic resin, nanometer magnesium hydroxide, nanometer aluminum oxide, hexamethylenetetramine, triethylenetetramine, modified attapulgite, sepiolite, talcum powder, nanometer boron nitride, aluminum hypophosphite, nanometer zinc oxide, polytetrafluoroethylene micro-powder, 2-ethyl-4-methylimidazole, dodecyl mercaptan, sodium hexametaphosphate, zinc iron phosphate, polyacrylamide, a defoaming agent, dimethylethanolamine, propylene glycol, methanol, ethylene glycol, 2-amino-2-methyl-1-propanol, a film coalescing aid and water. The heat-resistant flame-retardant anticorrosion water-based coating provided by the invention has the advantages of excellent heat resistance and water resistance, good storage stability, corrosion resistance and flame retardancy, high bonding strength with a substrate, and long service life.

Description

A kind of heat-proof combustion-resistant protection against corrosion water-borne coatings
Technical field
The present invention relates to technical field of coatings, particularly relate to a kind of heat-proof combustion-resistant protection against corrosion water-borne coatings.
Background technology
Solvent based coating can in preparation and construction in a large number with an organic solvent, all there is very large harm, and cost be high to environment and operator.In recent years, along with improving constantly of people's environmental consciousness, the differentiation of the Water-borne modification of coating, solvent free and high solid has become the inexorable trend of paint development.
Water-borne coatings or be called water-based paint, take water as the coating that solvent or dispersion medium are made, it mainly comprises water soluble paint and water latex paint two class, its maximum feature is that whole or most of water instead of organic solvent, filmogen is dispersed or dissolved in water by different way uniformly, and paint film has the water-fast of similar solvent based coating and physicals in the dried or cured.The maximum feature of water-borne coatings is primary solvent with water, not only reduces production cost, greatly reduce environmental pollution, and have fire prevention, be easy to the features such as transport and storage, therefore has broad application prospects.
At present, along with the fast development of society, the performance requriements of people to coating is more and more higher, and its quality and quantity of existing water-borne coatings can not meet the demands, there is poor storage stability, and heat-resistance of film, non-corrosibility and flame retardant effect are not very desirable defects.
Summary of the invention
Based on the technical problem that background technology exists, the present invention proposes a kind of heat-proof combustion-resistant protection against corrosion water-borne coatings, its thermotolerance and excellent water resistance, stability in storage, protection against corrosion and good flame resistance, high with the cohesive strength of ground, long service life.
A kind of heat-proof combustion-resistant protection against corrosion water-borne coatings that the present invention proposes, its raw material comprises following component by weight: Polyurethane-Epoxy Resin Hybrid Emulsion 50-70 part, ACRYLIC EMULSION 20-40 part, brominated epoxy resin 10-25 part, silicon sol 5-15 part, boron bakelite resin 5-15 part, nano-sized magnesium hydroxide 10-20 part, nano aluminium oxide 5-15 part, hexamethylenetetramine 1-5 part, triethylene tetramine 3-10 part, attapulgite modified 5-15 part, sepiolite 2-10 part, talcum powder 2-10 part, nm-class boron nitride 2-10 part, hypo-aluminum orthophosphate 3-12 part, nano zine oxide 5-10 part, ptfe micropowder 2-10 part, 2-ethyl-4-methylimidazole 1.5-3.5 part, lauryl mercaptan 1.5-3 part, Sodium hexametaphosphate 99 1-3.5 part, tertiary iron phosphate zinc 1-3.5 part, polyacrylamide 0.5-2 part, defoamer 1-2 part, dimethylethanolamine 0.3-2 part, propylene glycol 5-10 part, methyl alcohol 3-8 part, ethylene glycol 2-8 part, 2-amino-2-methyl-1-propanol 0.5-2 part, film coalescence aid 4-13 part, water 20-40 part.
Preferably, its raw material comprises following component by weight: Polyurethane-Epoxy Resin Hybrid Emulsion 58-63 part, ACRYLIC EMULSION 29-34 part, brominated epoxy resin 16-20 part, silicon sol 8-11 part, boron bakelite resin 8-13 part, nano-sized magnesium hydroxide 14-18 part, nano aluminium oxide 9-13 part, hexamethylenetetramine 2.6-3.5 part, triethylene tetramine 6-8 part, attapulgite modified 8-12 part, sepiolite 5.5-7 part, talcum powder 5-8 part, nm-class boron nitride 6-8 part, hypo-aluminum orthophosphate 8-11 part, nano zine oxide 7-8 part, ptfe micropowder 6-9 part, 2-ethyl-4-methylimidazole 2.1-2.6 part, lauryl mercaptan 2.2-2.8 part, Sodium hexametaphosphate 99 1.9-2.4 part, tertiary iron phosphate zinc 2-2.5 part, polyacrylamide 1.1-1.6 part, defoamer 1.2-1.7 part, dimethylethanolamine 1-1.4 part, propylene glycol 7-8 part, methyl alcohol 5-7 part, ethylene glycol 6-7 part, 2-amino-2-methyl-1-propanol 1-1.6 part, film coalescence aid 9-12 part, water 30-36 part.
Preferably, its raw material comprises following component by weight: Polyurethane-Epoxy Resin Hybrid Emulsion 60 parts, ACRYLIC EMULSION 32 parts, brominated epoxy resin 18 parts, silicon sol 10 parts, boron bakelite resin 10 parts, nano-sized magnesium hydroxide 15 parts, nano aluminium oxide 10 parts, hexamethylenetetramine 3 parts, triethylene tetramine 7 parts, attapulgite modified 10 parts, sepiolite 6 parts, talcum powder 7 parts, nm-class boron nitride 6.2 parts, hypo-aluminum orthophosphate 10 parts, nano zine oxide 7.3 parts, ptfe micropowder 7 parts, 2-ethyl-4-methylimidazole 2.5 parts, lauryl mercaptan 2.4 parts, Sodium hexametaphosphate 99 2 parts, 2.3 parts, tertiary iron phosphate zinc, polyacrylamide 1.4 parts, defoamer 1.5 parts, dimethylethanolamine 1 part, propylene glycol 7.5 parts, methyl alcohol 6 parts, ethylene glycol 6.4 parts, 2-amino-2-methyl-1-propanol 1.3 parts, film coalescence aid 10 parts, 35 parts, water.
Preferably, described ACRYLIC EMULSION is modified acrylic acid emulsion; Described modified acrylic acid emulsion is prepared according to following technique: 25-40 part octamethylcyclotetrasiloxane, 20-30 part t etram-ethyltetravinylcyclotetrasiloxane are mixed with 0.1-0.5 part sodium hydroxide by weight, stir and be warming up to 90-100 DEG C, reaction 0.8-2h, adjust ph is obtain material A after 7; By weight by 5-10 part glycidyl methacrylate, 5-10 part vinyl silane triisopropoxide, 10-20 part vinylformic acid-2,4,6-tribromophenyl, 5-20 part dodecafluoroheptyl methacrylate, 2-10 part vinylformic acid, 20-35 part methyl methacrylate, 20-40 part Hydroxyethyl acrylate mix and obtain material B; By weight 0.5-1 part sodium lauryl sulphate, 0.5-1 part polyoxyethylene octylphenol ether are added in 100-150 part water, stir at 30-38 DEG C, then 13-25 part material A and 15-25 serving material B is dripped, 10-25min is stirred at 80-90 DEG C, then 0.1-0.5 part ammonium persulphate and 0.1-0.5 part sodium bisulfite is added, 0.1-0.5 part ammonium persulphate is added after stirring 20-50min, then drip 20-40 part material A and 20-40 serving material B, after stirring 50-120min, adjust ph is that alkalescence obtains described modified acrylic acid emulsion.
Preferably, described ACRYLIC EMULSION is modified acrylic acid emulsion, described modified acrylic acid emulsion is prepared according to following technique: 30 parts of octamethylcyclotetrasiloxanes, 26 parts of t etram-ethyltetravinylcyclotetrasiloxane are mixed with 0.4 part of sodium hydroxide by weight, stir and be warming up to 95 DEG C, reaction 1h, adjust ph is obtain material A after 7, by weight by 7 parts of glycidyl methacrylate, 8 parts of vinyl silane triisopropoxides, 15 parts of vinylformic acid-2,4,6-tribromophenyl, 10 parts of dodecafluoroheptyl methacrylates, 7 parts of vinylformic acid, 30 parts of methyl methacrylates, 35 parts of Hydroxyethyl acrylates mix and obtain material B, by weight 0.7 part of sodium lauryl sulphate, 0.8 part of polyoxyethylene octylphenol ether are added in 120 parts of water, stir at 35 DEG C, then 20 parts of material A and 20 serving material B are dripped, 18min is stirred at 85 DEG C, then 0.4 part of ammonium persulphate and 0.3 part of sodium bisulfite is added, add 0.3 part of ammonium persulphate after stirring 30min, then drip 30 parts of material A and 25 serving material B, after stirring 100min, adjust ph is that alkalescence obtains described modified acrylic acid emulsion, in the preparation process of modified acrylic acid emulsion, first have selected octamethylcyclotetrasiloxane and t etram-ethyltetravinylcyclotetrasiloxane carries out copolyreaction, generate copolymerization product, then with glycidyl methacrylate, vinyl silane triisopropoxide, vinylformic acid-2, 4, 6-tribromophenyl, dodecafluoroheptyl methacrylate modified synergic acrylic ester emulsion, simultaneously by silicon, fluorine, in bromine and epoxide group introducing system, the modified acrylic acid emulsion obtained on the one hand has hydrophobic shape structure, as filmogen, improve the water tolerance of coating, in addition, adding of vinyl silane triisopropoxide facilitates copolymerization product, glycidyl methacrylate, vinylformic acid-2, 4, 6-tribromophenyl, dodecafluoroheptyl methacrylate and vinylformic acid, methyl methacrylate, the copolymerization of Hydroxyethyl acrylate, improve the cross-linking density of ACRYLIC EMULSION in film process, improve the sticking power of film, water tolerance, thermotolerance and flame retardant resistance.
Preferably, described attapulgite modified used properties-correcting agent be cetyl trimethylammonium bromide, one or more mixture in sodium stearate, APTES, imidazoles.
Preferably, described attapulgite modified used properties-correcting agent be cetyl trimethylammonium bromide, the mixture of sodium stearate, APTES, imidazoles; And the weight ratio of cetyl trimethylammonium bromide, sodium stearate, APTES, imidazoles is 1-3:2-5:3-6:1-5.
Preferably, described nano zine oxide is modified nano zinc oxide; Described modified nano zinc oxide is prepared according to following technique: be dissolved in 500-1000 part water by 2-5 part zinc nitrate by weight, then 0.3-0.5 part vulkacit H is added, at 75-85 DEG C of reaction 1.5-2.5h, reaction terminates rear filtration, drying, then roasting 1-2.5h at 300-450 DEG C, and then at 550-650 DEG C roasting 0.5-2h, cooling after pulverize obtain intermediate; Add in 50-100 part water by 2-10 part intermediate by weight, add 1-3 part Silver Nitrate after stirring 50-100min, then the pH value of regulation system is 7.5-8.5, stirs 50-100min, obtains described modified nano zinc oxide through standing, filtration, drying.
Preferably, described nano zine oxide is modified nano zinc oxide; Described modified nano zinc oxide is prepared according to following technique: be dissolved in 800 parts of water by 3 parts of zinc nitrates by weight, then 0.4 part of vulkacit H is added, at 80 DEG C of reaction 2h, reaction terminates rear filtration, drying, then roasting 1.8h at 400 DEG C, and then at 600 DEG C roasting 1.5h, cooling after pulverize obtain intermediate; Add in 85 parts of water by 8 parts of intermediates by weight, add 2 parts of Silver Nitrates after stirring 80min, then the pH value of regulation system is 8, stirs 80min, obtains described modified nano zinc oxide through standing, filtration, drying; In the preparation process of modified nano zinc oxide, with the addition of Silver Nitrate is properties-correcting agent, the silver generated in preparation process has been evenly distributed in the surface of nano zine oxide, and both have very strong effect, join in system, be uniformly dispersed in system, and show Synergistic antimicrobial, while giving the germ resistance of coating excellence, further improve the erosion resistance of coating.
Preferably, described film coalescence aid is one or more the mixture in alcohol ester 12, propylene glycol phenylate, butyl glycol ether, ethylene glycol ethyl ether.
Heat-proof combustion-resistant protection against corrosion water-borne coatings of the present invention can water-borne coatings preparation technology conveniently be prepared from.
Polyurethane-Epoxy Resin Hybrid Emulsion has had the excellent snappiness of urethane concurrently, the high-modulus of sticking power and epoxy resin, the erosion resistance of low cure shrinkage and excellence, simple Polyurethane-Epoxy Resin Hybrid Emulsion is selected to there is snappiness and the not good enough defect of shock resistance as filmogen, in the present invention, have selected Polyurethane-Epoxy Resin Hybrid Emulsion is main filmogen, and cooperation with the addition of ACRYLIC EMULSION as auxiliary film forming matter, improve the low temperature flexibility of film and dynamic cracking resistance, add silicon sol simultaneously, fine and close coating can be formed, enhance water tolerance and the erosion resistance of film, brominated epoxy resin has excellent electric insulating quality and cementability, also has excellent self-extinguishing and thermotolerance in addition, and low toxicity, join in system, give the flame retardant resistance of coating excellence, improve the cohesive strength of coating simultaneously, boron bakelite resin has excellent high thermal resistance, integrate catalysis simultaneously, become charcoal and foaming, after coordinating with nano-sized magnesium hydroxide, nano aluminium oxide, hexamethylenetetramine, triethylene tetramine, form cooperative flame retardant system, consolidate the fire retardation of brominated epoxy resin, further improve the flame retardant resistance of coating, effectively prevent mechanicalness loss of energy simultaneously, attapulgite modifiedly add in system, be uniformly dispersed in system, improve the water proof of coating, barrier, give the water tolerance of coating excellence, thermotolerance and erosion resistance, in the process of coating burns, heat is not easily transferred to matrix surface, extend the combustion time of base material, add sepiolite, talcum powder, nm-class boron nitride, hypo-aluminum orthophosphate, nano zine oxide, tetrafluoroethylene is micro-, Sodium hexametaphosphate 99, tertiary iron phosphate zinc, and have adjusted the content of each material, it is made to be uniformly dispersed in system, have adjusted the foaming degree of boron bakelite resin and the relation of layer of charcoal intensity, while enhancing coating apyrous, enhance physical strength and the sticking power of film, improve the weathering resistance of film, thermotolerance and erosion resistance, extend the work-ing life of film.
Carry out Performance Detection to heat-proof combustion-resistant protection against corrosion water-borne coatings of the present invention, its surface drying time is 0.8-1.5h; 25 DEG C, water tolerance > 24h; 25 DEG C, non-foaming, the nondiscolorations in hydrochloric acid acid resistance 8-10 days of 5wt%; 25 DEG C, non-foaming, the nondiscolorations in sodium chloride solution 8-10 days of resistance to 5wt%; The non-foaming nondiscolorations in sodium hydroxide solution 8-10 days of 5wt%; Fire endurance >=130min.
Embodiment
In a specific embodiment, a kind of heat-proof combustion-resistant protection against corrosion water-borne coatings that the present invention proposes, in its raw material, the weight part of Polyurethane-Epoxy Resin Hybrid Emulsion can be 50,53,56,57,58,62,65,67,68.7,69,70 parts; The weight part of ACRYLIC EMULSION can be 20,23,25,26,27,29,32,34,35,36,37,38.6,39,39.4,40 parts; The weight part of brominated epoxy resin can be 10,12,14,15,16,17,18.6,19,21,23,23.6,24,24.5,25 parts; The weight part of silicon sol can be 5,6,7,8,9,9.3,10,12,13,14.5,15 parts; The weight part of boron bakelite resin can be 5,6,7,8,9,9.6,10,12,13,14,14.5,15 parts; The weight part of nano-sized magnesium hydroxide can be 10,12,14,15,16,17,18.6,19,20 parts; The weight part of nano aluminium oxide can be 5,6,7,8,9,9.6,10,11,12,13.4,14,15 parts; The weight part of hexamethylenetetramine can be 1,1.4,1.8,2,2.3,2.8,3,3.4,3.8,4,4.3,4.8,5 part; The weight part of triethylene tetramine can be 3,4,5,6,6.5,7,7.6,8,9,9.7,10 parts; Attapulgite modified weight part can be 5,6,7,8,9,9.6,10,12,13,13.6,14,14.5,15 parts; The weight part of sepiolite can be 2,3,4,5,6,7,7.6,8,9,9.7,10 parts; Talcous weight part can be 2,3,4,5,6,7,8,8.6,9,9.7,10 parts; The weight part of nm-class boron nitride can be 2,3,4,5,6,6.7,7,8,8.6,9,9.7,10 parts; The weight part of hypo-aluminum orthophosphate can be 3,4,5,6,6.4,7,8,8.6,9,9.5,10,11,11.6,12 parts; The weight part of nano zine oxide can be 5,5.6,6.3,7,8,8.6,9,9.2,9.8,10 parts; The weight part of ptfe micropowder can be 2,3,4,5,6,6.4,7,8,8.6,9,9.5,10 parts; The weight part of 2-ethyl-4-methylimidazole can be 1.5,1.8,1.9,2,2.3,2.6,2.8,3,3.1,3.4,3.46,3.5 parts; The weight part of lauryl mercaptan can be 1.5,1.8,1.9,2,2.4,2.8,3 parts; The weight part of Sodium hexametaphosphate 99 can be 1,1.4,1.7,1.9,2,2.4,2.7,2.9,3,3.1,3.4,3.5 part; The weight part of tertiary iron phosphate zinc can be 1,1.4,1.6,1.8,2,2.4,2.6,2.8,2.9,3,3.2,3.4,3.5 part; The weight part of polyacrylamide can be 0.5,0.7,0.9,1,1.2,1.4,1.6,1.78,1.9,2 part; The weight part of defoamer can be 1,1.2,1.4,1.6,1.7,1.86,1.9,2 part; The weight part of dimethylethanolamine can be 0.3,0.5,0.8,0.9,1,1.2,1.4,1.6,1.7,1.8,1.9,2 part; The weight part of propylene glycol can be 5,6,7,8,8.6,9,9.6,10 parts; The weight part of methyl alcohol can be 3,3.5,4,4.5,4.8,5,5.6,6,6.7,7,7.3,8 parts; The weight part of ethylene glycol can be 2,2.5,3,3.6,4,4.3,4.8,5,5.3,6,6.7,8 parts; 2-amino-2-methyl-1-propanol 0.5,0.6,0.7,0.8,1,1.3,1.5,1.7,1.8,2 part; Film coalescence aid 4,5,6,7,8,8.6,9,9.4,10,11,11.4,12,12.5,13 parts; 20,22,25,26,27,28,29,32,35,36,37,38.5,39,40 parts, water.
Below, by specific embodiment, technical scheme of the present invention is described in detail.
Embodiment 1
A kind of heat-proof combustion-resistant protection against corrosion water-borne coatings that the present invention proposes, its raw material comprises following component by weight: Polyurethane-Epoxy Resin Hybrid Emulsion 50 parts, ACRYLIC EMULSION 40 parts, brominated epoxy resin 10 parts, silicon sol 15 parts, boron bakelite resin 5 parts, nano-sized magnesium hydroxide 20 parts, nano aluminium oxide 5 parts, hexamethylenetetramine 5 parts, triethylene tetramine 3 parts, attapulgite modified 15 parts, sepiolite 2 parts, talcum powder 10 parts, nm-class boron nitride 2 parts, hypo-aluminum orthophosphate 12 parts, nano zine oxide 5 parts, ptfe micropowder 10 parts, 2-ethyl-4-methylimidazole 3.5 parts, lauryl mercaptan 1.5 parts, Sodium hexametaphosphate 99 3.5 parts, 1 part, tertiary iron phosphate zinc, polyacrylamide 2 parts, defoamer 1 part, dimethylethanolamine 2 parts, propylene glycol 10 parts, methyl alcohol 8 parts, ethylene glycol 2 parts, 2-amino-2-methyl-1-propanol 2 parts, film coalescence aid 4 parts, 20 parts, water.
Embodiment 2
A kind of heat-proof combustion-resistant protection against corrosion water-borne coatings that the present invention proposes, its raw material comprises following component by weight: Polyurethane-Epoxy Resin Hybrid Emulsion 70 parts, ACRYLIC EMULSION 20 parts, brominated epoxy resin 25 parts, silicon sol 5 parts, boron bakelite resin 15 parts, nano-sized magnesium hydroxide 10 parts, nano aluminium oxide 15 parts, hexamethylenetetramine 1 part, triethylene tetramine 10 parts, attapulgite modified 5 parts of cetyl trimethylammonium bromide, sepiolite 10 parts, talcum powder 2 parts, nm-class boron nitride 10 parts, hypo-aluminum orthophosphate 3 parts, nano zine oxide 10 parts, ptfe micropowder 2 parts, 2-ethyl-4-methylimidazole 1.5 parts, lauryl mercaptan 3 parts, Sodium hexametaphosphate 99 1 part, 3.5 parts, tertiary iron phosphate zinc, polyacrylamide 0.5 part, defoamer 2 parts, dimethylethanolamine 0.3 part, propylene glycol 5 parts, methyl alcohol 3 parts, ethylene glycol 8 parts, 2-amino-2-methyl-1-propanol 0.5 part, alcohol ester 12 parts, propylene glycol phenylate 3 parts, butyl glycol ether 1 part, ethylene glycol ethyl ether 7 parts, 40 parts, water.
Embodiment 3
A kind of heat-proof combustion-resistant protection against corrosion water-borne coatings that the present invention proposes, its raw material comprises following component by weight: Polyurethane-Epoxy Resin Hybrid Emulsion 58 parts, ACRYLIC EMULSION 34 parts, brominated epoxy resin 16 parts, silicon sol 11 parts, boron bakelite resin 8 parts, nano-sized magnesium hydroxide 18 parts, nano aluminium oxide 9 parts, hexamethylenetetramine 3.5 parts, triethylene tetramine 6 parts, attapulgite modified 12 parts, sepiolite 5.5 parts, talcum powder 8 parts, nm-class boron nitride 6 parts, hypo-aluminum orthophosphate 11 parts, nano zine oxide 7 parts, ptfe micropowder 9 parts, 2-ethyl-4-methylimidazole 2.1 parts, lauryl mercaptan 2.8 parts, Sodium hexametaphosphate 99 1.9 parts, 2.5 parts, tertiary iron phosphate zinc, polyacrylamide 1.1 parts, defoamer 1.7 parts, dimethylethanolamine 1 part, propylene glycol 8 parts, methyl alcohol 5 parts, ethylene glycol 7 parts, 2-amino-2-methyl-1-propanol 1 part, propylene glycol phenylate 4 parts, butyl glycol ether 3 parts, ethylene glycol ethyl ether 5 parts, 30 parts, water,
Wherein, described attapulgite modified used properties-correcting agent be cetyl trimethylammonium bromide, the mixture of sodium stearate, APTES, imidazoles; And the weight ratio of cetyl trimethylammonium bromide, sodium stearate, APTES, imidazoles is 3:2:6:1;
Described ACRYLIC EMULSION is modified acrylic acid emulsion; Described modified acrylic acid emulsion is prepared according to following technique: 40 parts of octamethylcyclotetrasiloxanes, 20 parts of t etram-ethyltetravinylcyclotetrasiloxane are mixed with 0.5 part of sodium hydroxide by weight, stir and be warming up to 90 DEG C, reaction 2h, adjust ph is obtain material A after 7; By weight by 5 parts of glycidyl methacrylate, 10 parts of vinyl silane triisopropoxides, 10 parts of vinylformic acid-2,4,6-tribromophenyl, 20 parts of dodecafluoroheptyl methacrylates, 2 parts of vinylformic acid, 35 parts of methyl methacrylates, 20 parts of Hydroxyethyl acrylates mix and obtain material B; By weight 1 part of sodium lauryl sulphate, 0.5 part of polyoxyethylene octylphenol ether are added in 100 parts of water, stir at 30 DEG C, then 25 parts of material A and 15 serving material B are dripped, 10min is stirred at 90 DEG C, then 0.5 part of ammonium persulphate and 0.1 part of sodium bisulfite is added, add 0.1 part of ammonium persulphate after stirring 50min, then drip 40 parts of material A and 20 serving material B, after stirring 120min, adjust ph is that alkalescence obtains described modified acrylic acid emulsion;
Described nano zine oxide is modified nano zinc oxide; Described modified nano zinc oxide is prepared according to following technique: be dissolved in 1000 parts of water by 2 parts of zinc nitrates by weight, then 0.3 part of vulkacit H is added, at 85 DEG C of reaction 1.5h, reaction terminates rear filtration, drying, then roasting 1h at 450 DEG C, and then at 650 DEG C roasting 0.5h, cooling after pulverize obtain intermediate; Add in 50 parts of water by 10 parts of intermediates by weight, add 1 part of Silver Nitrate after stirring 100min, then the pH value of regulation system is 8.5, stirs 50min, obtains described modified nano zinc oxide through standing, filtration, drying.
Embodiment 4
A kind of heat-proof combustion-resistant protection against corrosion water-borne coatings that the present invention proposes, its raw material comprises following component by weight: Polyurethane-Epoxy Resin Hybrid Emulsion 63 parts, ACRYLIC EMULSION 29 parts, brominated epoxy resin 20 parts, silicon sol 8 parts, boron bakelite resin 13 parts, nano-sized magnesium hydroxide 14 parts, nano aluminium oxide 13 parts, hexamethylenetetramine 2.6 parts, triethylene tetramine 8 parts, attapulgite modified 8 parts, sepiolite 7 parts, talcum powder 5 parts, nm-class boron nitride 8 parts, hypo-aluminum orthophosphate 8 parts, nano zine oxide 8 parts, ptfe micropowder 6 parts, 2-ethyl-4-methylimidazole 2.6 parts, lauryl mercaptan 2.2 parts, Sodium hexametaphosphate 99 2.4 parts, 2 parts, tertiary iron phosphate zinc, polyacrylamide 1.6 parts, defoamer 1.2 parts, dimethylethanolamine 1.4 parts, propylene glycol 7 parts, methyl alcohol 7 parts, ethylene glycol 6 parts, 2-amino-2-methyl-1-propanol 1.6 parts, propylene glycol phenylate 6 parts, butyl glycol ether 3 parts, 36 parts, water,
Wherein, described attapulgite modified used properties-correcting agent be cetyl trimethylammonium bromide, the mixture of sodium stearate, APTES, imidazoles; And the weight ratio of cetyl trimethylammonium bromide, sodium stearate, APTES, imidazoles is 1:5:3:5;
Described ACRYLIC EMULSION is modified acrylic acid emulsion; Described modified acrylic acid emulsion is prepared according to following technique: 25 parts of octamethylcyclotetrasiloxanes, 30 parts of t etram-ethyltetravinylcyclotetrasiloxane are mixed with 0.1 part of sodium hydroxide by weight, stir and be warming up to 100 DEG C, reaction 0.8h, adjust ph is obtain material A after 7; By weight by 10 parts of glycidyl methacrylate, 5 parts of vinyl silane triisopropoxides, 20 parts of vinylformic acid-2,4,6-tribromophenyl, 5 parts of dodecafluoroheptyl methacrylates, 10 parts of vinylformic acid, 20 parts of methyl methacrylates, 40 parts of Hydroxyethyl acrylates mix and obtain material B; By weight 0.5 part of sodium lauryl sulphate, 1 part of polyoxyethylene octylphenol ether are added in 150 parts of water, stir at 38 DEG C, then 13 parts of material A and 25 serving material B are dripped, 25min is stirred at 80 DEG C, then 0.1 part of ammonium persulphate and 0.5 part of sodium bisulfite is added, add 0.5 part of ammonium persulphate after stirring 20min, then drip 20 parts of material A and 40 serving material B, after stirring 50min, adjust ph is that alkalescence obtains described modified acrylic acid emulsion;
Described nano zine oxide is modified nano zinc oxide; Described modified nano zinc oxide is prepared according to following technique: be dissolved in 500 parts of water by 5 parts of zinc nitrates by weight, then 0.5 part of vulkacit H is added, at 75 DEG C of reaction 2.5h, reaction terminates rear filtration, drying, then roasting 2.5h at 300 DEG C, and then at 550 DEG C roasting 2h, cooling after pulverize obtain intermediate; Add in 100 parts of water by 2 parts of intermediates by weight, add 3 parts of Silver Nitrates after stirring 50min, then the pH value of regulation system is 7.5, stirs 100min, obtains described modified nano zinc oxide through standing, filtration, drying.
Embodiment 5
A kind of heat-proof combustion-resistant protection against corrosion water-borne coatings that the present invention proposes, its raw material comprises following component by weight: Polyurethane-Epoxy Resin Hybrid Emulsion 60 parts, ACRYLIC EMULSION 32 parts, brominated epoxy resin 18 parts, silicon sol 10 parts, boron bakelite resin 10 parts, nano-sized magnesium hydroxide 15 parts, nano aluminium oxide 10 parts, hexamethylenetetramine 3 parts, triethylene tetramine 7 parts, attapulgite modified 10 parts, sepiolite 6 parts, talcum powder 7 parts, nm-class boron nitride 6.2 parts, hypo-aluminum orthophosphate 10 parts, nano zine oxide 7.3 parts, ptfe micropowder 7 parts, 2-ethyl-4-methylimidazole 2.5 parts, lauryl mercaptan 2.4 parts, Sodium hexametaphosphate 99 2 parts, 2.3 parts, tertiary iron phosphate zinc, polyacrylamide 1.4 parts, defoamer 1.5 parts, dimethylethanolamine 1 part, propylene glycol 7.5 parts, methyl alcohol 6 parts, ethylene glycol 6.4 parts, 2-amino-2-methyl-1-propanol 1.3 parts, alcohol ester 12 parts, 35 parts, water,
Wherein, described attapulgite modified used properties-correcting agent be cetyl trimethylammonium bromide, the mixture of sodium stearate, APTES, imidazoles; And the weight ratio of cetyl trimethylammonium bromide, sodium stearate, APTES, imidazoles is 2:3:5:4;
Described ACRYLIC EMULSION is modified acrylic acid emulsion; Described modified acrylic acid emulsion is prepared according to following technique: 30 parts of octamethylcyclotetrasiloxanes, 26 parts of t etram-ethyltetravinylcyclotetrasiloxane are mixed with 0.4 part of sodium hydroxide by weight, stir and be warming up to 95 DEG C, reaction 1h, adjust ph is obtain material A after 7; By weight by 7 parts of glycidyl methacrylate, 8 parts of vinyl silane triisopropoxides, 15 parts of vinylformic acid-2,4,6-tribromophenyl, 10 parts of dodecafluoroheptyl methacrylates, 7 parts of vinylformic acid, 30 parts of methyl methacrylates, 35 parts of Hydroxyethyl acrylates mix and obtain material B; By weight 0.7 part of sodium lauryl sulphate, 0.8 part of polyoxyethylene octylphenol ether are added in 120 parts of water, stir at 35 DEG C, then 20 parts of material A and 20 serving material B are dripped, 18min is stirred at 85 DEG C, then 0.4 part of ammonium persulphate and 0.3 part of sodium bisulfite is added, add 0.3 part of ammonium persulphate after stirring 30min, then drip 30 parts of material A and 25 serving material B, after stirring 100min, adjust ph is that alkalescence obtains described modified acrylic acid emulsion;
Described nano zine oxide is modified nano zinc oxide; Described modified nano zinc oxide is prepared according to following technique: be dissolved in 800 parts of water by 3 parts of zinc nitrates by weight, then 0.4 part of vulkacit H is added, at 80 DEG C of reaction 2h, reaction terminates rear filtration, drying, then roasting 1.8h at 400 DEG C, and then at 600 DEG C roasting 1.5h, cooling after pulverize obtain intermediate; Add in 85 parts of water by 8 parts of intermediates by weight, add 2 parts of Silver Nitrates after stirring 80min, then the pH value of regulation system is 8, stirs 80min, obtains described modified nano zinc oxide through standing, filtration, drying.
The above; be only the present invention's preferably embodiment; but protection scope of the present invention is not limited thereto; anyly be familiar with those skilled in the art in the technical scope that the present invention discloses; be equal to according to technical scheme of the present invention and inventive concept thereof and replace or change, all should be encompassed within protection scope of the present invention.

Claims (10)

1. a heat-proof combustion-resistant protection against corrosion water-borne coatings, is characterized in that, its raw material comprises following component by weight: Polyurethane-Epoxy Resin Hybrid Emulsion 50-70 part, ACRYLIC EMULSION 20-40 part, brominated epoxy resin 10-25 part, silicon sol 5-15 part, boron bakelite resin 5-15 part, nano-sized magnesium hydroxide 10-20 part, nano aluminium oxide 5-15 part, hexamethylenetetramine 1-5 part, triethylene tetramine 3-10 part, attapulgite modified 5-15 part, sepiolite 2-10 part, talcum powder 2-10 part, nm-class boron nitride 2-10 part, hypo-aluminum orthophosphate 3-12 part, nano zine oxide 5-10 part, ptfe micropowder 2-10 part, 2-ethyl-4-methylimidazole 1.5-3.5 part, lauryl mercaptan 1.5-3 part, Sodium hexametaphosphate 99 1-3.5 part, tertiary iron phosphate zinc 1-3.5 part, polyacrylamide 0.5-2 part, defoamer 1-2 part, dimethylethanolamine 0.3-2 part, propylene glycol 5-10 part, methyl alcohol 3-8 part, ethylene glycol 2-8 part, 2-amino-2-methyl-1-propanol 0.5-2 part, film coalescence aid 4-13 part, water 20-40 part.
2. heat-proof combustion-resistant protection against corrosion water-borne coatings according to claim 1, it is characterized in that, its raw material comprises following component by weight: Polyurethane-Epoxy Resin Hybrid Emulsion 58-63 part, ACRYLIC EMULSION 29-34 part, brominated epoxy resin 16-20 part, silicon sol 8-11 part, boron bakelite resin 8-13 part, nano-sized magnesium hydroxide 14-18 part, nano aluminium oxide 9-13 part, hexamethylenetetramine 2.6-3.5 part, triethylene tetramine 6-8 part, attapulgite modified 8-12 part, sepiolite 5.5-7 part, talcum powder 5-8 part, nm-class boron nitride 6-8 part, hypo-aluminum orthophosphate 8-11 part, nano zine oxide 7-8 part, ptfe micropowder 6-9 part, 2-ethyl-4-methylimidazole 2.1-2.6 part, lauryl mercaptan 2.2-2.8 part, Sodium hexametaphosphate 99 1.9-2.4 part, tertiary iron phosphate zinc 2-2.5 part, polyacrylamide 1.1-1.6 part, defoamer 1.2-1.7 part, dimethylethanolamine 1-1.4 part, propylene glycol 7-8 part, methyl alcohol 5-7 part, ethylene glycol 6-7 part, 2-amino-2-methyl-1-propanol 1-1.6 part, film coalescence aid 9-12 part, water 30-36 part.
3. heat-proof combustion-resistant protection against corrosion water-borne coatings according to claim 1 or 2, it is characterized in that, its raw material comprises following component by weight: Polyurethane-Epoxy Resin Hybrid Emulsion 60 parts, ACRYLIC EMULSION 32 parts, brominated epoxy resin 18 parts, silicon sol 10 parts, boron bakelite resin 10 parts, nano-sized magnesium hydroxide 15 parts, nano aluminium oxide 10 parts, hexamethylenetetramine 3 parts, triethylene tetramine 7 parts, attapulgite modified 10 parts, sepiolite 6 parts, talcum powder 7 parts, nm-class boron nitride 6.2 parts, hypo-aluminum orthophosphate 10 parts, nano zine oxide 7.3 parts, ptfe micropowder 7 parts, 2-ethyl-4-methylimidazole 2.5 parts, lauryl mercaptan 2.4 parts, Sodium hexametaphosphate 99 2 parts, 2.3 parts, tertiary iron phosphate zinc, polyacrylamide 1.4 parts, defoamer 1.5 parts, dimethylethanolamine 1 part, propylene glycol 7.5 parts, methyl alcohol 6 parts, ethylene glycol 6.4 parts, 2-amino-2-methyl-1-propanol 1.3 parts, film coalescence aid 10 parts, 35 parts, water.
4. heat-proof combustion-resistant protection against corrosion water-borne coatings according to any one of claim 1-3, is characterized in that, described ACRYLIC EMULSION is modified acrylic acid emulsion; Described modified acrylic acid emulsion is prepared according to following technique: 25-40 part octamethylcyclotetrasiloxane, 20-30 part t etram-ethyltetravinylcyclotetrasiloxane are mixed with 0.1-0.5 part sodium hydroxide by weight, stir and be warming up to 90-100 DEG C, reaction 0.8-2h, adjust ph is obtain material A after 7; By weight by 5-10 part glycidyl methacrylate, 5-10 part vinyl silane triisopropoxide, 10-20 part vinylformic acid-2,4,6-tribromophenyl, 5-20 part dodecafluoroheptyl methacrylate, 2-10 part vinylformic acid, 20-35 part methyl methacrylate, 20-40 part Hydroxyethyl acrylate mix and obtain material B; By weight 0.5-1 part sodium lauryl sulphate, 0.5-1 part polyoxyethylene octylphenol ether are added in 100-150 part water, stir at 30-38 DEG C, then 13-25 part material A and 15-25 serving material B is dripped, 10-25min is stirred at 80-90 DEG C, then 0.1-0.5 part ammonium persulphate and 0.1-0.5 part sodium bisulfite is added, 0.1-0.5 part ammonium persulphate is added after stirring 20-50min, then drip 20-40 part material A and 20-40 serving material B, after stirring 50-120min, adjust ph is that alkalescence obtains described modified acrylic acid emulsion.
5. heat-proof combustion-resistant protection against corrosion water-borne coatings according to any one of claim 1-4, is characterized in that, described ACRYLIC EMULSION is modified acrylic acid emulsion; Described modified acrylic acid emulsion is prepared according to following technique: 30 parts of octamethylcyclotetrasiloxanes, 26 parts of t etram-ethyltetravinylcyclotetrasiloxane are mixed with 0.4 part of sodium hydroxide by weight, stir and be warming up to 95 DEG C, reaction 1h, adjust ph is obtain material A after 7; By weight by 7 parts of glycidyl methacrylate, 8 parts of vinyl silane triisopropoxides, 15 parts of vinylformic acid-2,4,6-tribromophenyl, 10 parts of dodecafluoroheptyl methacrylates, 7 parts of vinylformic acid, 30 parts of methyl methacrylates, 35 parts of Hydroxyethyl acrylates mix and obtain material B; By weight 0.7 part of sodium lauryl sulphate, 0.8 part of polyoxyethylene octylphenol ether are added in 120 parts of water, stir at 35 DEG C, then 20 parts of material A and 20 serving material B are dripped, 18min is stirred at 85 DEG C, then 0.4 part of ammonium persulphate and 0.3 part of sodium bisulfite is added, add 0.3 part of ammonium persulphate after stirring 30min, then drip 30 parts of material A and 25 serving material B, after stirring 100min, adjust ph is that alkalescence obtains described modified acrylic acid emulsion.
6. heat-proof combustion-resistant protection against corrosion water-borne coatings according to any one of claim 1-5, it is characterized in that, described attapulgite modified used properties-correcting agent is cetyl trimethylammonium bromide, one or more mixture in sodium stearate, APTES, imidazoles.
7. heat-proof combustion-resistant protection against corrosion water-borne coatings according to any one of claim 1-6, it is characterized in that, described attapulgite modified used properties-correcting agent is cetyl trimethylammonium bromide, the mixture of sodium stearate, APTES, imidazoles; And the weight ratio of cetyl trimethylammonium bromide, sodium stearate, APTES, imidazoles is 1-3:2-5:3-6:1-5.
8. heat-proof combustion-resistant protection against corrosion water-borne coatings according to any one of claim 1-7, is characterized in that, described nano zine oxide is modified nano zinc oxide; Described modified nano zinc oxide is prepared according to following technique: be dissolved in 500-1000 part water by 2-5 part zinc nitrate by weight, then 0.3-0.5 part vulkacit H is added, at 75-85 DEG C of reaction 1.5-2.5h, reaction terminates rear filtration, drying, then roasting 1-2.5h at 300-450 DEG C, and then at 550-650 DEG C roasting 0.5-2h, cooling after pulverize obtain intermediate; Add in 50-100 part water by 2-10 part intermediate by weight, add 1-3 part Silver Nitrate after stirring 50-100min, then the pH value of regulation system is 7.5-8.5, stirs 50-100min, obtains described modified nano zinc oxide through standing, filtration, drying.
9. heat-proof combustion-resistant protection against corrosion water-borne coatings according to any one of claim 1-8, is characterized in that, described nano zine oxide is modified nano zinc oxide; Described modified nano zinc oxide is prepared according to following technique: be dissolved in 800 parts of water by 3 parts of zinc nitrates by weight, then 0.4 part of vulkacit H is added, at 80 DEG C of reaction 2h, reaction terminates rear filtration, drying, then roasting 1.8h at 400 DEG C, and then at 600 DEG C roasting 1.5h, cooling after pulverize obtain intermediate; Add in 85 parts of water by 8 parts of intermediates by weight, add 2 parts of Silver Nitrates after stirring 80min, then the pH value of regulation system is 8, stirs 80min, obtains described modified nano zinc oxide through standing, filtration, drying.
10. heat-proof combustion-resistant protection against corrosion water-borne coatings according to any one of claim 1-9, is characterized in that, described film coalescence aid is one or more the mixture in alcohol ester 12, propylene glycol phenylate, butyl glycol ether, ethylene glycol ethyl ether.
CN201510548007.1A 2015-08-31 2015-08-31 Heat-resistant flame-retardant anticorrosion water-based coating CN105176346A (en)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106010181A (en) * 2016-06-20 2016-10-12 上海理工大学 Preparation methods of metal surface treatment agent containing nano boron nitride and corrosion-resistant coating
CN106010068A (en) * 2016-05-31 2016-10-12 刘洪建 Steel wire thread sleeve coating
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CN108913026A (en) * 2018-06-26 2018-11-30 阜南县星光工艺品有限公司 A kind of woodwork anticorrosive coating
CN108976969A (en) * 2018-07-30 2018-12-11 阜南县大喜柳编工艺品有限公司 A kind of baskets craft water paint
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CN111187551A (en) * 2020-02-21 2020-05-22 济南鸿运保温材料有限公司 Building energy-saving heat-insulating coating and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101050296A (en) * 2007-04-20 2007-10-10 佛山市华联有机硅有限公司 Acrylic resin latex modified by fire retardation type organosilicon, and preparation method
CN101165129A (en) * 2006-10-17 2008-04-23 刘炳义 Water high-temperature resistant flaming-proof anticorrosive paint
CN103342782A (en) * 2013-07-02 2013-10-09 广东海顺新材料科技有限公司 Organosilicone modified acrylate emulsion, preparation method thereof and water-based artificial stone prepared from organosilicone modified acrylate emulsion
CN103666148A (en) * 2013-11-27 2014-03-26 湖州盛基金属制品有限公司 Anticorrosive fireproof metal coating

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101165129A (en) * 2006-10-17 2008-04-23 刘炳义 Water high-temperature resistant flaming-proof anticorrosive paint
CN101050296A (en) * 2007-04-20 2007-10-10 佛山市华联有机硅有限公司 Acrylic resin latex modified by fire retardation type organosilicon, and preparation method
CN103342782A (en) * 2013-07-02 2013-10-09 广东海顺新材料科技有限公司 Organosilicone modified acrylate emulsion, preparation method thereof and water-based artificial stone prepared from organosilicone modified acrylate emulsion
CN103666148A (en) * 2013-11-27 2014-03-26 湖州盛基金属制品有限公司 Anticorrosive fireproof metal coating

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
庹度: "载银氧化锌复合纳米粒子的制备与表征", 《包装学报》 *

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CN106010181A (en) * 2016-06-20 2016-10-12 上海理工大学 Preparation methods of metal surface treatment agent containing nano boron nitride and corrosion-resistant coating
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CN107163835A (en) * 2017-06-15 2017-09-15 苏州莱特复合材料有限公司 A kind of preparation method of metal fire resistant anticorrosive paint
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