CN106072756A - A kind of electronic cigarette liquid containing phenethanol glucosides - Google Patents
A kind of electronic cigarette liquid containing phenethanol glucosides Download PDFInfo
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- CN106072756A CN106072756A CN201610631475.XA CN201610631475A CN106072756A CN 106072756 A CN106072756 A CN 106072756A CN 201610631475 A CN201610631475 A CN 201610631475A CN 106072756 A CN106072756 A CN 106072756A
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- phenethanol
- glucosides
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- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
- A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
- A24B15/18—Treatment of tobacco products or tobacco substitutes
- A24B15/28—Treatment of tobacco products or tobacco substitutes by chemical substances
- A24B15/30—Treatment of tobacco products or tobacco substitutes by chemical substances by organic substances
- A24B15/36—Treatment of tobacco products or tobacco substitutes by chemical substances by organic substances containing a heterocyclic ring
- A24B15/40—Treatment of tobacco products or tobacco substitutes by chemical substances by organic substances containing a heterocyclic ring having only oxygen or sulfur as hetero atoms
- A24B15/403—Treatment of tobacco products or tobacco substitutes by chemical substances by organic substances containing a heterocyclic ring having only oxygen or sulfur as hetero atoms having only oxygen as hetero atoms
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- A24F47/008—
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07H—SUGARS; DERIVATIVES THEREOF; NUCLEOSIDES; NUCLEOTIDES; NUCLEIC ACIDS
- C07H1/00—Processes for the preparation of sugar derivatives
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07H—SUGARS; DERIVATIVES THEREOF; NUCLEOSIDES; NUCLEOTIDES; NUCLEIC ACIDS
- C07H15/00—Compounds containing hydrocarbon or substituted hydrocarbon radicals directly attached to hetero atoms of saccharide radicals
- C07H15/18—Acyclic radicals, substituted by carbocyclic rings
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Abstract
The invention discloses a kind of tobacco juice for electronic smoke containing phenethanol glucosides, being prepared from by the component of following weight portion: leaf tobacco extract 3 ~ 10%, flavouring essence for tobacco 3 ~ 8%, tobacco aromatics using 1 ~ 5%, deionized water 5 ~ 15%, glycerol 10 ~ 20%, phenethanol glucosides 3 ~ 10%, surplus is propylene glycol；Phenethanol glucosides uses the method for preferred chemosynthesis to prepare.The method environmental protection of phenethanol glucosides prepared by the present invention, rapidly and efficiently, this glucosides is possible not only to make electronic cigarette fragrance fine and smooth, reducing to be dried stimulates, and promotes suction comfort, moreover it is possible to strengthen the odor characteristic of electronic cigarette, and tobacco juice for electronic smoke is for electronic cigarette atomizing, not producing tar and CO, the harm to consumer is substantially reduced, and also will not produce second hand smoking harm.
Description
Technical field
The invention belongs to filed of daily-use chemical industry, relate to one and grow tobacco, a kind of electronics containing phenethanol glucosides
Tobacco juice.
Background technology
Along with the development of whole world Tobacco Control campaign, smoking and health, increasingly by social concerns, disappear for satisfied difference
The smoking of the person of expense and health requirements, novel tobacco goods are developed rapidly in recent years, mainly include smoke-free tobacco product,
Low temperature cigarette and electronic cigarette.Wherein, electronic cigarette does not produce the harmful substances such as tar, through the tobacco juice quilt the most rapidly of atomization
Dilution, does not has side-stream smoke, will not form second hand smoking harm, be a kind of popular cigarette substitute.
Electronic cigarette external form is similar to regular-size cigarette, is a kind of device that nicotine solution can be vaporized into fog, passes through mould
Plan is smoked true, brings stimulation to smoker.Its principle is, when sucking electronic cigarette, electronic smoke atomizer is supplied by electronic cigarette battery
Electricity, nebulizer is started working, and is atomized the tobacco juice being stored at electronic cigarette for smog.Tobacco juice in electronic cigarette, also referred to as ree-oil, actual
On be a formula essence, when sucking electronic cigarette, tobacco juice is atomized into smog, glycerol that smog includes evaporating in tobacco juice,
Propylene glycol and fragrance matter etc..Tobacco juice for electronic smoke is electronic cigarette aroma source, decides the taste style of electronic cigarette, decides product
Whether product are esthetically acceptable to the consumers.Therefore, the tobacco juice formula technique of electronic cigarette, is one of the key technology of electronic cigarette.
Glucosides is the precursor substance of a lot of natural flavor composition, and fragrance precursor converts through overheating effect and zymolysis and formed
A kind of distinctive fragrance component, this composition has the potentiality of the biggest release fragrance.Owing to fragrance material in processing and stored
In journey readily volatilized, and during Medicated cigarette burns and sucks, because essence can be caused under conditions of high temperature to volatilize, to such an extent as to fragrance meeting
Scattering and disappearing, like this will have a strong impact on the effect of essence and flavoring agent perfuming, glucosides overcomes this well as fragrance precursor
A little drawbacks.And recently as " back suction cigarette " move surging, people are the most urgent to the demand of low-coke tar cigarette.But,
Tar to be reduced, the good taste of inhaling keeping Medicated cigarette again is highly difficult, and one of method of solution uses appropriate flavouring exactly
Agent, can reach to increase the purpose of cigarette fragrance, reduce the injury to human body by synthesizing this material, and this has highly important
Realistic meaning.
Georg F etc. analyzes the glucosides class material in flue gas concentrate, finds that phenethanol Glycosides Contents enriches, is glucosides
Class material important component part.Phenethanol and derivant thereof are a kind of important fragrance matter, the aroma quality to Nicotiana tabacum L. in Nicotiana tabacum L.
Amount and feature have important impact, and its content in natural baccy is extremely low, and the cracking of phenethanol glucosides can produce phenethanol, but
Phenethanol glucosides class material is to extract from plant and obtain mostly, and naturally occurring phenethanol Glycosides Contents is few, natural carries
The difficulty taking and separating is big, and cost is high, and the chemosynthesis of phenethanol glucosides has obtained paying close attention to widely.
Phenethanol glucosides is a kind of glycoside compounds, and its structure is as follows:
Summary of the invention
For above-mentioned technical problem of the prior art, the invention provides a kind of electronic cigarette liquid containing phenethanol glucosides,
It is the most true to nature that the described this electronic cigarette liquid containing phenethanol glucosides to solve tobacco juice for electronic smoke tobacco aroma of the prior art, difficult
To replace the technical problem of real cigarette.
The invention provides a kind of tobacco juice for electronic smoke containing phenethanol glucosides, the component of following weight portion be prepared from:
Leaf tobacco extract 3～10%；
Flavouring essence for tobacco 3～8%；
Tobacco aromatics using 1～5%；
Deionized water 5～15%；
Glycerol 10～20%；
Phenethanol glucosides 3～10%；
Surplus is propylene glycol.
Further, the component of following weight portion it is prepared from:
Leaf tobacco extract 5～10%；
Flavouring essence for tobacco 5%；
Tobacco aromatics using 2%；
Deionized water 15%；
Glycerol 10%；
Phenethanol glucosides 3～8%；
Surplus is propylene glycol.
Further, the component of following weight portion it is prepared from:
Leaf tobacco extract 10%；
Flavouring essence for tobacco 5%；
Tobacco aromatics using 2%；
Deionized water 15%；
Glycerol 10%；
Phenethanol glucosides 8%；
Surplus is propylene glycol.
Further, the component of following weight portion it is prepared from:
Leaf tobacco extract 8%；
Flavouring essence for tobacco 5%；
Tobacco aromatics using 2%；
Deionized water 15%；
Glycerol 10%；
Phenethanol glucosides 5%；
Surplus is propylene glycol.
Concrete, described leaf tobacco extract, flavouring essence for tobacco, tobacco aromatics using are the conventional products during Nicotiana tabacum L. makes, ability
People from territory is all known, and does not repeats them here.
Further, the preparation method of described phenethanol glucosides comprises the steps:
1) step of preparation four acetyl glucosamine phenethanol: add dichloro in equipped with the container of five acetyl glucose
Methane, stirring makes it be substantially dissolved in dichloromethane, is then added thereto to be equivalent to five acetyl glucose molar fraction 50
～200% phenethanol solution of amount, by mixture in the case of ice-water bath, it is added thereto to be equivalent to five acetyl glucose and rubs
That mark 100～the catalyst of 400% amount, after dropping, react 1～5h under conditions of reaction temperature is 10～50 DEG C,
After completion of the reaction, extract with dichloromethane, and successively with sodium bicarbonate solution, saturated nacl aqueous solution, frozen water washing, isolate
Organic facies, is dried with anhydrous sodium sulfate, removes dichloromethane and obtains crude product；Crude product is carried out gradient elution silica gel column layer
Analysis, eluant is the mixed solvent of petroleum ether and ethyl acetate, is adjusted eluting by polarity order from small to large in elution process
The ratio of agent, collects RfThe component of=0.58, is four acetyl glucosamine phenethanol；
2) in four acetyl glucosamine phenethanol of preparation, addition is equivalent to four acetyl glucosamine phenethanol 10～20 times of matter
The absolute methanol of amount, stirring makes it fully dissolve, and after dissolving, dropping is equivalent to four acetyl glucosamine phenethanol 0.1～1% times of matter
The methanol solution of the Feldalat NM of amount, under conditions of reaction temperature is 10～50 DEG C, the stirring response time is 0.5～1.5h, instead
After Ying, removing methanol by rotary evaporation, crude product ethyl acetate, as eluant, is divided by silica gel column chromatography
From, collect RfThe component of=0.51, rotary evaporation obtains white solid products benzene ethanol glucosides.
Further, described catalyst is sodium hydroxide solution or boron trifluoride ether solution.
Further, in the mixed solvent of described petroleum ether and ethyl acetate, petroleum ether and ethyl acetate volume ratio
For arbitrarily than.
Further, in the methanol solution of sodium alkoxide, the mass volume ratio of Feldalat NM and methanol is 1g:150 milliliter.
The preparation method of the phenethanol glucosides of the present invention is capable of the chemosynthesis of phenethanol glucosides, reaction condition temperature
With, environmental protection, rapidly and efficiently, post processing is simple, safe and reliable, can be used for industrialized production.This glucosides is possible not only to make electricity
Sub-cigarette fragrance is fine and smooth, and reducing to be dried stimulates, and is applied in tobacco juice for electronic smoke, it is possible to effectively discharges the characteristic chicken flavors such as phenethanol and becomes
Point, by subjective appreciation, phenethanol glucosides can be obviously improved the organoleptic quality of Nicotiana tabacum L., it is possible to improves cigarette flavor significantly
Rich, and have good perfuming stability and uniformity, the cost of production will not be increased, therefore have at tobacco business
It is widely applied prospect.
Compared with prior art, one of beneficial effects of the present invention is:
1. the tobacco juice for electronic smoke of the present invention contains phenethanol glycoside component, has both added the comfort of electronic cigarette suction, again
Enhance the characteristic perfume of electronic cigarette.
2. the tobacco juice for electronic smoke that prepared by the present invention, for electronic cigarette atomizing, does not produce tar and CO, the harm to consumer
It is substantially reduced, and the application of this product will not produce second hand smoking harm.
3. the present invention uses the method for chemosynthesis to prepare phenethanol glucosides, improves the yield of phenethanol glucosides, preparation
Method environmental protection, product purity is high.Phenethanol glucosides has good perfuming effect for tobacco juice for electronic smoke.
Tobacco juice for electronic smoke formula material containing phenethanol glucosides the most of the present invention is readily available, and meet international and
The laws and regulations that country is relevant, production technology is the most efficient.
Detailed description of the invention
In order to make the object, technical solutions and advantages of the present invention clearer, below in conjunction with embodiment, to the present invention
It is further elaborated.Should be appreciated that specific embodiment described herein is used merely to explain the present invention, be not used to
Limit the present invention.
Below in conjunction with specific embodiment, the technology in the present invention and application scheme carried out clear and be fully described by.
The synthesis of embodiment 1: four acetyl glucosamine phenethanol
In there-necked flask, add 5g five acetyl glucose and 3g phenethanol, be added thereto to 50ml dichloromethane, stirring
Make it be substantially dissolved in dichloromethane, then there-necked flask is put in ice-water bath, continue stirring 10 minutes, at ice-water bath
Under the conditions of, be slowly added dropwise a certain amount of catalyst wherein, catalyst be equivalent to five acetyl glucose molar fraction 100～
400%, after catalyst completion of dropwise addition, remove ice-water bath, reaction continues stirring 3h at ambient temperature.After completion of the reaction, will
Mixture filters, and removes solvent by rotary evaporation.Residue is dissolved in 200 milliliters of ethyl acetate, then the most logical
Cross 2 × 100 milliliters of saturated sodium bicarbonate aqueous solutions, 2 × 100 milliliters of saturated sodium-chloride water solutions and 2 × 100 milliliters of frozen water to wash
Wash.Organic substance is dried by anhydrous sodium sulfate and evaporates.Residue petroleum ether-ethyl acetate (10:1 volume ratio) is as washing
De-agent, is separated by silica gel column chromatography.By petroleum ether ethyl acetate (4:1 volume ratio) as eluant, collect Rf=0.58
Component, obtain white solid product, i.e. four acetyl glucosamine phenethanol.
Further, described catalyst is sodium hydroxide solution or boron trifluoride ether solution.
Embodiment 2: the synthesis of phenethanol glucosides
The four acetyl glucosamine phenethanol taking preparation in 1g step one add in there-necked flask, and are added thereto to 20mL first
Alcohol, is sufficiently stirred for forming unit for uniform suspension.15 milliliters of methanol solutions containing 0.1g Feldalat NM are slowly added in suspension,
And stir 60 minutes further so that it is fully react.After completion of the reaction, methanol, residue acetic acid are removed by rotary evaporation
Ethyl ester-methanol (15:1 volume ratio), as eluant, is separated by silica gel column chromatography.With acetate-methanol (8:1 volume
Than) as eluant, by thin layer chromatography (TLC), fractionating section is monitored.Fractionating section and Rf=0.51 collects together, steams
Sending out to obtain white solid product, by appropriate recrystallizing methanol, productivity is 92%.
By the NMR (Nuclear Magnetic Resonance) spectrum map analysis to embodiment 1 and the product of embodiment 2, it may be determined that synthesized product
Match with the structure of phenethanol glucosides.
Embodiment 3:
A kind of tobacco juice for electronic smoke containing phenethanol glucosides, its component includes: tobacco juice extract 5%, flavouring essence for tobacco 8%,
Tobacco aromatics using 5%, deionized water 15%, glycerol 10%, phenethanol glucosides 5%, surplus is propylene glycol, the consumption of each component with
Mass content meter.
When preparing tobacco juice for electronic smoke, getting out said components, then they mixed, stirring 30min makes respectively at normal temperatures
Component is sufficiently mixed.
Examples of implementation 4:
A kind of tobacco juice for electronic smoke containing phenethanol glucosides, its component includes: tobacco juice extract 10%, flavouring essence for tobacco 5%,
Tobacco aromatics using 2%, deionized water 15%, glycerol 20%, phenethanol glucosides 10%, surplus is propylene glycol, the consumption of each component
In terms of mass content.
When preparing tobacco juice for electronic smoke, getting out said components, then they mixed, stirring 30min makes respectively at normal temperatures
Component is sufficiently mixed.
Embodiment 5:
A kind of tobacco juice for electronic smoke containing phenethanol glucosides, its component includes: tobacco juice extract 10%, flavouring essence for tobacco 5%,
Tobacco aromatics using 2%, deionized water 15%, glycerol 10%, phenethanol glucosides 8%, surplus is propylene glycol, the consumption of each component with
Mass content meter.
When preparing tobacco juice for electronic smoke, getting out said components, then they mixed, stirring 30min makes respectively at normal temperatures
Component is sufficiently mixed.
Comparative example 5
A kind of tobacco juice for electronic smoke without phenethanol glucosides, its component includes: tobacco juice extract 10%, flavouring essence for tobacco
5%, tobacco aromatics using 2%, deionized water 15%, glycerol 10%, surplus is propylene glycol, and the consumption of each component is with mass content
Meter.
When preparing tobacco juice for electronic smoke, getting out said components, then they mixed, stirring 30min makes respectively at normal temperatures
Component is sufficiently mixed.
By embodiment 3, embodiment 4, embodiment 5, the tobacco juice for electronic smoke of comparative example 5 preparation is added in electronic cigarette carry out
Sensory quality assessment, evaluation result is shown in Table 2.
Electronic cigarette sensory quality assessment method is as follows:
Sensory quality assessment project and standard are arranged: arrange 7 projects, respectively aroma quality, perfume quantity, concentration, stimulation
Property, miscellaneous QI, strength, pleasant impression, the maximum scale of each project is 9, and each project is with 1 as scoring unit, corresponding to each project
The meaning of each scale value is shown in Table 1.
The meaning of each scale value of each project of table 1
| Score value | Aroma quality | Perfume quantity | Concentration | Zest | Miscellaneous QI | Strength | Pleasant impression |
| 9 | Very well | Sufficient | Dense | The least | The lightest | The biggest | Very well |
| 8 | Good | Foot | Dense | Little | Gently | Greatly | Good |
| 7 | Preferably | More sufficient | Denseer | Less | Lighter | Bigger | Preferably |
| 6 | The best | The most sufficient | The denseest | Slightly smaller | The lightest | Slightly larger | The best |
| 5 | In | In | In | In | In | In | In |
| 4 | Slightly worse | Slightly | Slightly weaker | Slightly larger | The heaviest | Slightly smaller | Slightly worse |
| 3 | Poor | Thin | Thin | Bigger | Heavier | Less | Poor |
| 2 | Difference | Flat | Light | Greatly | Weight | Little | Difference |
| 1 | Very poor | The lightest | The lightest | The biggest | The heaviest | The least | Very poor |
Table 2 Analyses Methods for Sensory Evaluation Results
As shown in Table 2, the present invention utilizes tobacco juice for electronic smoke prepared by phenethanol glucosides, at the tobacco extract of different proportion
In, with compared with the contrast tobacco juice for electronic smoke of phenethanol glucosides, with the addition of the fragrance of the tobacco juice for electronic smoke of phenethanol glucosides,
Zest and pleasant impression index score all have raising in various degree, and fragrance is fine and smooth, perfume quantity increases, zest reduces, and pleasant impression is more
Add comfortable.In phenethanol glucosides applying electronic cigarette tobacco juice, it is possible to effectively discharge the characteristic chicken flavor compositions such as phenethanol, pass through sense organ
Evaluation, phenethanol glucosides can be obviously improved the organoleptic quality of tobacco juice for electronic smoke, it is possible to improves the rich of fragrance significantly, and
And have good perfuming stability and uniformity.Wherein, when the addition of phenethanol glucosides is 5～10%, tobacco juice for electronic smoke
Suction comfort and fragrance reinforced effects the most obvious.
Although reference be made herein to invention has been described for the multiple explanatory embodiment of the present invention, however, it is to be understood that
Those skilled in the art can be designed that a lot of other amendments and embodiment, and these amendments and embodiment will fall in this Shen
Within spirit disclosed in please and spirit.More specifically must say, in disclosure and right, can be to theme
The building block of composite configuration and/or layout are through the multiple modification of row and improvement.Except the change that building block and/or layout are carried out
Outside type and improvement, for a person skilled in the art, other purposes also will be apparent from.
Claims (7)
1. the tobacco juice for electronic smoke containing phenethanol glucosides, it is characterised in that be prepared from by the component of following weight portion:
Leaf tobacco extract 3 ~ 10%；
Flavouring essence for tobacco 3 ~ 8%；
Tobacco aromatics using 1 ~ 5%；
Deionized water 5 ~ 15%；
Glycerol 10 ~ 20%；
Phenethanol glucosides 3 ~ 10%；
Surplus is propylene glycol.
Electronic cigarette liquid containing phenethanol glucosides the most according to claim 1, it is characterised in that by the component of following weight portion
It is prepared from:
Leaf tobacco extract 5 ~ 10%；
Flavouring essence for tobacco 5%；
Tobacco aromatics using 2%；
Deionized water 15%；
Glycerol 10%；
Phenethanol glucosides 3 ~ 8%；
Surplus is propylene glycol.
Electronic cigarette liquid containing phenethanol glucosides the most according to claim 2, it is characterised in that by the component of following weight portion
It is prepared from:
Leaf tobacco extract 10%；
Flavouring essence for tobacco 5%；
Tobacco aromatics using 2%；
Deionized water 15%；
Glycerol 10%；
Phenethanol glucosides 8%；
Surplus is propylene glycol.
Electronic cigarette liquid containing phenethanol glucosides the most according to claim 2, it is characterised in that by the component of following weight portion
It is prepared from:
Leaf tobacco extract 8%；
Flavouring essence for tobacco 5%；
Tobacco aromatics using 2%；
Deionized water 15%；
Glycerol 10%；
Phenethanol glucosides 5%；
Surplus is propylene glycol.
5. according to the electronic cigarette liquid containing phenethanol glucosides described in claim 1 ~ 4 any one, it is characterised in that described benzene
The preparation method of ethanol glucosides comprises the steps:
1) step of preparation four acetyl glucosamine phenethanol: add dichloromethane in equipped with the container of five acetyl glucose
Alkane, is then added thereto to be equivalent to the phenethanol solution of five acetyl glucose molar fraction 50 ~ 200% amount, by mixture at ice
In the case of water-bath, it is added thereto to be equivalent to the catalyst of five acetyl glucose molar fraction 100 ~ 400% amount, drips complete
After, under conditions of reaction temperature is 10 ~ 50 DEG C, reacts 1 ~ 5h, after completion of the reaction, extracts with dichloromethane, and use carbonic acid successively
Hydrogen sodium solution, saturated nacl aqueous solution, frozen water wash, and isolate organic facies, are dried with anhydrous sodium sulfate, remove dichloromethane and obtain
To crude product；Crude product is carried out gradient elution silica gel column chromatography, and eluant is the mixed solvent of petroleum ether and ethyl acetate, washes
Adjusted the ratio of eluant during Tuo by polarity order from small to large, collect RfThe component of=0.58, is four acetyl glucosamines
Phenethanol；
2) in four acetyl glucosamine phenethanol of preparation, addition is equivalent to the nothing of four 10 ~ 20 times of quality of acetyl glucosamine phenethanol
Water methanol, stirring makes it fully dissolve, and after dissolving, dropping is equivalent to the methanol of four 0.1 ~ 1% times of quality of acetyl glucosamine phenethanol
The methanol solution of sodium, under conditions of reaction temperature is 10 DEG C ~ 50 DEG C, the stirring response time is 0.5 ~ 1.5h, after completion of the reaction,
Removing methanol by rotary evaporation, crude product ethyl acetate, as eluant, is separated by silica gel column chromatography, and collection obtains
RfThe component of=0.51, rotary evaporation obtains white solid products benzene ethanol glucosides.
A kind of electronic cigarette liquid containing phenethanol glucosides the most according to claim 5, it is characterised in that: described catalyst is
Sodium hydroxide solution or boron trifluoride ether solution.
A kind of electronic cigarette liquid containing phenethanol glucosides the most according to claim 5, it is characterised in that: at described petroleum ether
With in the mixed solvent of ethyl acetate, petroleum ether and ethyl acetate volume ratio be arbitrarily than.
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| CN108516998A (en) * | 2018-03-14 | 2018-09-11 | 郑州轻工业学院 | A kind of preparation method and application of coke sweet tea fragrance emitting agent for cigarettes active ingredient |
| CN110167365A (en) * | 2017-02-03 | 2019-08-23 | 菲利普莫里斯生产公司 | The method and system of the stability of composite before steam for improving electrical steam cigarette device |
| CN114947173A (en) * | 2022-06-24 | 2022-08-30 | 湖北中烟工业有限责任公司 | Glucoside-containing electronic cigarette atomizing agent and preparation method and application thereof |
| CN115005488A (en) * | 2022-06-24 | 2022-09-06 | 湖北中烟工业有限责任公司 | Atomizing agent for cigarettes and electronic cigarette liquid |
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110167365A (en) * | 2017-02-03 | 2019-08-23 | 菲利普莫里斯生产公司 | The method and system of the stability of composite before steam for improving electrical steam cigarette device |
| CN110167365B (en) * | 2017-02-03 | 2023-01-03 | 菲利普莫里斯生产公司 | Method and system for improving stability of pre-vapor formulation of electronic vapor smoking device |
| CN106986903A (en) * | 2017-03-07 | 2017-07-28 | 上海应用技术大学 | A kind of cigarette fragrance materials and its preparation method and application |
| CN106986903B (en) * | 2017-03-07 | 2019-07-19 | 上海应用技术大学 | A kind of cigarette fragrance materials and its preparation method and application |
| CN108516998A (en) * | 2018-03-14 | 2018-09-11 | 郑州轻工业学院 | A kind of preparation method and application of coke sweet tea fragrance emitting agent for cigarettes active ingredient |
| CN108516998B (en) * | 2018-03-14 | 2020-06-02 | 郑州轻工业学院 | Preparation method and application of effective components of aroma releasing agent for burnt sweet type cigarettes |
| CN114947173A (en) * | 2022-06-24 | 2022-08-30 | 湖北中烟工业有限责任公司 | Glucoside-containing electronic cigarette atomizing agent and preparation method and application thereof |
| CN115005488A (en) * | 2022-06-24 | 2022-09-06 | 湖北中烟工业有限责任公司 | Atomizing agent for cigarettes and electronic cigarette liquid |
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