CN106065178B - A kind of compression mold device of desulfurization flyash energy-conserving and environment-protective construction wall packing material and its preparation method of packing material - Google Patents

A kind of compression mold device of desulfurization flyash energy-conserving and environment-protective construction wall packing material and its preparation method of packing material Download PDF

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CN106065178B
CN106065178B CN201610389705.6A CN201610389705A CN106065178B CN 106065178 B CN106065178 B CN 106065178B CN 201610389705 A CN201610389705 A CN 201610389705A CN 106065178 B CN106065178 B CN 106065178B
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pressing mold
conserving
packing material
environment
parts
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CN106065178A (en
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项玮
李莹
郭莉
郭婷婷
仇宝进
邹吕熙
梁峙
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Xuzhou University of Technology
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Xuzhou University of Technology
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/02Organic and inorganic ingredients
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C43/00Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
    • B29C43/02Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor of articles of definite length, i.e. discrete articles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C43/00Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
    • B29C43/32Component parts, details or accessories; Auxiliary operations
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/16Nitrogen-containing compounds
    • C08K5/17Amines; Quaternary ammonium compounds
    • C08K5/18Amines; Quaternary ammonium compounds with aromatically bound amino groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/16Nitrogen-containing compounds
    • C08K5/20Carboxylic acid amides
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/16Nitrogen-containing compounds
    • C08K5/315Compounds containing carbon-to-nitrogen triple bonds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/16Nitrogen-containing compounds
    • C08K5/32Compounds containing nitrogen bound to oxygen
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/36Sulfur-, selenium-, or tellurium-containing compounds
    • C08K5/41Compounds containing sulfur bound to oxygen
    • C08K5/42Sulfonic acids; Derivatives thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C43/00Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
    • B29C43/32Component parts, details or accessories; Auxiliary operations
    • B29C2043/3272Component parts, details or accessories; Auxiliary operations driving means
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/10Process efficiency

Abstract

The invention discloses the preparation method of a kind of compression mold device of desulfurization flyash energy-conserving and environment-protective construction wall packing material and its packing material, it is made up of pressing mold transmission device, housing, shell holder, central control system;The filling materials for wall body of required pressing mold is launched into the equipment above housing, press central control system face button and start pressing mold transmission device, pressing mold transmission device carries out pressing mold processing to the filling materials for wall body in housing, and the filling materials for wall body block after pressing mold is discharged from the discharging opening of housing side.A kind of compression mold device of desulfurization flyash energy-conserving and environment-protective construction wall packing material of the present invention and its preparation method novel and reasonable structure of packing material, manipulation is convenient and swift, and automaticity is high, pressing mold high efficiency, and the scope of application is wide.

Description

A kind of compression mold device of desulfurization flyash energy-conserving and environment-protective construction wall packing material and its The preparation method of packing material
Technical field
The invention belongs to filling materials for wall body processing unit field, and in particular to a kind of desulfurization flyash energy-conserving and environment-protective building The compression mold device of filling materials for wall body and its preparation method of packing material.
Background technology
In traditional building trade, completed in building after blank is built, it is necessary to be detected to the structure of building, often The situation of the wall pit caused by a variety of causes, wall local collapse can often be found, it is necessary to repaired accordingly, and It is not readily portable due to the particularity of concrete mortar, and the wall position repaired is also different so that repairing is got up more numb It is tired.
It is cumbersome and time consuming in whole building course and existing wall has largely continued to use brick, cement and reinforcing bar masonry construction, It is particularly very inconvenient when building higher wall.In addition in order to improve the heat insulation effect of wall, often in wall construction When, benzene plate is accompanied in brick wall or benzene plate is pasted on the outside of brick wall, although the wall of this structure can improve heat insulation effect, brick Wall builds that consumption is substantial amounts of artificial, and patch folder benzene plate material cost is very high by laying bricks or stones.
Existing cooling-heating room construction wall, usually by rock wool, glass silk flosssilk wadding with clinker pressing mold, special firing Into compact material, there is many weak points in this wall:
(1) because equipment factor of production, the maximum limit of composite material of mineral wool can only produce the plate that thickness is 200mm Material, its thickness do not reach the warming requirement of northern area;
(2) factor of composite material of mineral wool plate deadweight, which exceedes certain length, causes construction and installation difficulty to increase, and cost is inclined Certain gap be present in height, two plate junctions;
(3) existing glass silk flosssilk wadding die mould composite, the deadweight of its glass silk flosssilk wadding is sagging or the involvement of sleet water will wherein cause Glass silk flosssilk wadding is accumulated downwards, final to influence wall warming effect so as to construction wall top occur in various degree without glass silk flosssilk wadding.
Filling wall for cooling-heating room construction wall, it has been mainly to go along with sb. to guard him and compartmentation that it, which is acted on, and weight is by beam column Undertake, fill wall not load-bearing.The raw material that existing high water filling material product uses are glass silk flosssilk wadding, composite material of mineral wool exists Under 62.5MPa pressure, clinker pressing mold, special firing with sulphate aluminium cement turn into finished product, and such material feedstock is more expensive, carries The high cost of building, while the anti-flammability such as sound-proofing and quality can not meet use demand, therefore people well A kind of extensive packing material and compression mold device are intentionally got, while can be good at the use needs for meeting people.
Under prior art conditions, the increase of filling materials for wall body compression mold device construction cost and operating cost will turn into must So, existing traditional handicraft, processing method have technological process length, and control is complicated, and pressing mold efficiency is low, and processing cost height etc. lacks Point.
The content of the invention
In order to solve the above-mentioned technical problem, the present invention provides a kind of desulfurization flyash energy-conserving and environment-protective construction wall packing material Compression mold device, including:
Pressing mold transmission device 1, housing 2, shell holder 3, central control system 4;The upper surface of shell holder 3 is provided with shell Body 2, the pressing mold transmission device 1 are located at the side of shell holder 3, and ground, the pressure are fixed in the bottom of pressing mold transmission device 1 The side of mould transmission device 1 is provided with central control system 4.
Further, the pressing mold transmission device 1 includes:Y-shaped fixed mount 1-1, driving motor 1-2, transmission main shaft 1- 3, active runner 1-4, driving belt 1-5, driven runner 1-6, driven roller centre rotating shaft 1-7, big trochal disc 1-8, star-like fixation Frame 1-9, moving block 1-10, swing pole 1-11, sliding mandril 1-12, pressuring template 1-13, horizontal concrete chute 1-14, and big trochal disc rotates Failure sensor 1-15;The driving motor 1-2 is arranged at ground level, driving motor 1-2 and the polygon control survey of central control system 4 Connection;Driving motor 1-2 output one end is fixed in described transmission main shaft 1-3 one end, and the transmission main shaft 1-3 other ends are fixed with master Turn wheel 1-4;The active runner 1-4 and transmission main shaft 1-3 interference fits connect, in active runner 1-4 and transmission main shaft 1-3 Mandrel line overlaps;Described driving belt 1-5 one end is sheathed on active runner 1-4 external diameter surfaces, and the driving belt 1-5 other ends are arranged In driven runner 1-6 external diameter surfaces;The driven runner 1-6 centre bores are fixed with driven roller centre rotating shaft 1-7, described driven Roller centre rotating shaft 1-7 and driven runner 1-6 interference fits connect, driven roller centre rotating shaft 1-7 and driven runner 1-6 centers Axis overlaps;The Y-shaped fixed mount 1-1 profiles are in capitalization " Y " shape of upper end closed, and Y-shaped fixed mount 1-1 is put down bottom Face is fixed on the ground, and Y-shaped fixed mount 1-1 intermediate throughholes are fixed on driven roller centre rotating shaft 1-7, Y-shaped fixed mount 1-1 and driven roller centre rotating shaft 1-7 interference fits connect, Y-shaped fixed mount 1-1 and driven roller centre rotating shaft 1-7 centers Axis overlaps;The big trochal disc 1-8 is located at Y-shaped fixed mount 1-1 sides, and big trochal disc 1-8 is with Y-shaped fixed mount 1-1 spacing 10mm~20mm, big trochal disc 1-8 are fixed on driven roller centre rotating shaft 1-7, big trochal disc 1-8 and driven roller centre rotating shaft 1- 7 interference fit connections, big trochal disc 1-8 overlap with driven roller centre rotating shaft 1-7 central axis, and big trochal disc 1-8 profiles are in automobile Direction plate-like, big trochal disc 1-8 inner wall surfaces are welded with star-like fixed mount 1-9, and the star-like fixed mount 1-9 surfaces pass through pin Axle is rotatablely connected with moving block 1-10;The Y-shaped fixed mount 1-1 bottom sidewalls are connected with by bearing pin and swing pole 1-11, Be provided with chute among the swing pole 1-11, the moving block 1-10 is connected with slide, swing pole 1-11 one end and Y-shaped fixed mount 1-1 bottom sidewall hinge connections, swing the pole 1-11 other ends and rotated by fixing axle and sliding mandril 1-12 Connection, the horizontal concrete chute 1-14 that the sliding mandril 1-12 and Y-shaped fixed mount 1-1 tops are set are slidably connected, sliding mandril 1-12 end faces are provided with pressuring template 1-13, the pressuring template 1-13 and sliding mandril 1-12 end faces seamless welding, and pressuring template 1-13 is Rectangular configuration, pressuring template 1-13 sizes are 200cm~400cm (length) × 100cm~180cm (width) × 15cm~30cm (thickness); The big trochal disc rotates failure sensor 1-15 and be located at star-like fixed mount 1-9 surfaces, big trochal disc rotate failure sensor 1-15 and The polygon control survey of central control system 4 connects.
Further, the housing 2 includes:Feeding warehouse 2-1, pressing mold storehouse 2-2, discharging bin 2-3, telescopic oil cylinder 2-4, stretch Baffle plate 2-5, charging conduit 2-6, discharging opening 2-7;The feeding warehouse 2-1 profiles are the bucket-shaped structures of rectangular cross-section, feeding warehouse 2-1 The narrow upper width in section bottom, feeding warehouse 2-1 tops are in open-like shape, and feeding warehouse 2-1 inclined-planes are shown as α, the α value ranges with horizontal plane angle For 15 °~50 °, feeding warehouse 2-1 lower sections are provided with pressing mold storehouse 2-2, and the pressing mold storehouse 2-2 is in rectangular parallelepiped structure, and pressing mold storehouse 2-2 is with entering Feed bin 2-1 is welded and fixed, and is mutually communicated inside pressing mold storehouse 2-2 and feeding warehouse 2-1, and discharging bin 2-3 is provided with below the 2-2 of pressing mold storehouse, The discharging bin 2-3 is welded and fixed with pressing mold storehouse 2-2, is penetrated, gone out by charging conduit 2-6 inside discharging bin 2-3 and pressing mold storehouse 2-2 Feed bin 2-3 profiles are italic shape, and discharging bin 2-3 inclined-planes are shown as β with horizontal plane angle, and the β value ranges are 10 °~70 °;It is described Telescopic oil cylinder 2-4 is located inside the 2-2 of pressing mold storehouse, and telescopic oil cylinder 2-4 knock-pins one end is welded with telescopic baffle 2-5, described Telescopic baffle 2-5 is located at below pressuring template 1-13, and telescopic baffle 2-5 and pressuring template 1-13 vertical interval is 3mm~6mm, is stretched Contracting baffle plate 2-5 surfaces are provided with substantial amounts of leak through hole, and leak number of openings is no less than 500, and pore diameter range value is 1mm~5mm; The discharging opening 2-7 is located at discharging bin 2-3 sidewall bottoms, and discharging opening 2-7 sizes are not less than pressuring template 1-13 sizes.
Further, the invention also discloses a kind of making side of desulfurization flyash energy-conserving and environment-protective construction wall packing material Method, the desulfurization flyash energy-conserving and environment-protective construction wall packing material are molded by high polymer material pressing mold and are made, desulfurization fine coal The constituent and manufacturing process of grey energy-conserving and environment-protective construction wall packing material are as follows:
First, desulfurization flyash energy-conserving and environment-protective construction wall packing material constituent:
Count in parts by weight, 39~99 parts of desulfurization flyash, 29~79 parts of p-Nitrophenyl sulfonyl acetate, to acetyl ammonia 59~99 parts of base-methyl o-anisate, 139~269 parts of 3- (to methanesulfonylphenYl) serine ethyl ester, 3- oxo fourths Sour 119~279 parts of ethyl ester of 2- (methyl (phenyl methyl) amino), 4- { [double (β-chloroethyl) amino] phenyl } methyl butyrate 39~ 109 parts, concentration be 29ppm~69ppm 79~119 parts of 4-tert-Butylphenylacetic acid methyl esters, gavaculine ethyl ester 69~129 Part, 139~289 parts of m-dibutylamino benzoic acid, 29~109 parts, N of crosslinking agent, (dimethyl between N- dimethyl carbamic acids Amino) 29~99 parts of phenyl ester, 39~139 parts of the N- pi-allyl-N- m-aminophenyl Methyl-carbamic acids tert-butyl ester, 5- amino isophthalic 59~109 parts of dicarboxylic acid dimethyl ester, [(2,4,5- trimethoxy-benzene) is sub- by poly- [α, β-(N-2- ethoxys)-DL- asparagines] 2- Amino] 139~249 parts of diethyl succinate;
The crosslinking agent between the chloro- 2- butynyls-N- of 4- meta-chlorocarbanilate, 3,4- dichlorophenyls carbamic acid- 2- [3- butyl -4- (2,2- dicyanoethenyls) -3- toluidinos] ethyl ester, N- (the chloro- 2- nitrobenzophenones of 4-)-o-amino benzoyl Any one in acid;
2nd, the manufacturing process of desulfurization flyash energy-conserving and environment-protective construction wall packing material, is comprised the steps of:
1st step:359~1159 parts of the ultra-pure water that electrical conductivity is the μ S/cm of 1.9 μ S/cm~2.9 is added in a kettle, is opened Agitator in dynamic reactor, rotating speed is 109rpm~219rpm, starts heat pump, reactor temperature is risen to 39 DEG C~59 ℃;Desulfurization flyash, p-Nitrophenyl sulfonyl acetate, acetparaminosalol-methyl o-anisate are sequentially added, is stirred To being completely dissolved, regulation pH value is 3.9~9.9, agitator speed is adjusted into 149rpm~219rpm, temperature is 79 DEG C~149 DEG C, esterification 19~29 hours;
2nd step:Take 3- (to methanesulfonylphenYl) serine ethyl ester, 3- ketobutyric acids 2- (methyl (phenyl methyl) amino) Ethyl ester is crushed, and powder diameter is 119~329 mesh;Add the mixing of 4- { [double (β-chloroethyl) amino] phenyl } methyl butyrate Uniformly, be laid in pallet, tiling thickness is 49mm~69mm, use dosage for 5.9kGy~8.9kGy, energy be 19MeV~ 29MeV alpha ray irradiates 49~89 minutes, and the β x ray irradiation xs 59~119 minutes of Isodose;
3rd step:The mixed-powder handled through the 2nd step is dissolved in the 4-tert-Butylphenylacetic acid methyl esters that concentration is 29ppm~69ppm In, reactor is added, agitator speed is 89rpm~159rpm, and temperature is 79 DEG C~169 DEG C, and starting vavuum pump makes reactor Vacuum reach -0.49MPa~-1.69MPa, keep this state response 19~29 hours;Pressure release is simultaneously passed through nitrogen, makes reaction Pressure is 0.90MPa~1.90MPa in kettle, and insulation stands 19~29 hours;Agitator speed is promoted to 119rpm~269rpm, The pressure release of simultaneous reactions kettle is to 0MPa;Sequentially add gavaculine ethyl ester, after m-dibutylamino benzoic acid is completely dissolved, Add crosslinking agent to be stirred so that the hydrophilic lipophilic balance of reactor solution is 4.9~9.9, and it is small that insulation stands 19~29 When;
4th step:When agitator speed is 109rpm~229rpm, N is sequentially added, (two between N- dimethyl carbamic acids Methylamino) phenyl ester, the N- pi-allyl-N- m-aminophenyl Methyl-carbamic acids tert-butyl ester, 5- amino isophthalic acids dimethyl ester, Poly- [α, β-(N-2- ethoxys)-DL- asparagines] 2- [(2,4,5- trimethoxy-benzene) imino group] diethyl succinate, lifting Reactor pressure, 0.90MPa~1.90MPa is reached, temperature is 119 DEG C~239 DEG C, polymerisation 19~39 hours;Instead Reacting kettle inner pressure is down to 0MPa after the completion of answering, 29 DEG C~49 DEG C is cooled to, discharging, enters compression mold device and can be prepared by desulfurized powder Coal ash energy-conserving and environment-protective construction wall packing material.
Further, the invention also discloses a kind of pressing mold of desulfurization flyash energy-conserving and environment-protective construction wall packing material to set Standby method of work, this method include following steps:
1st step:The desulfurization flyash energy-conserving and environment-protective construction wall packing material of required pressing mold is thrown above feeding warehouse 2-1 The telescopic baffle 2-5 surfaces being put into inside the 2-2 of pressing mold storehouse, press the start button on the surface of central control system 4, center control system System 4 starts driving motor 1-2, and driving motor 1-2 transmission main shaft 1-3 drives active runner 1-4 to do circle rotation motion, actively Runner 1-4 imparts power to driven runner 1-6 by driving belt 1-5, and then driven runner 1-6 also does circle rotation fortune Dynamic, driven runner 1-6 imparts power to big trochal disc 1-8 by driven roller centre rotating shaft 1-7, drive big trochal disc 1-8 with from Turn wheel central rotating shaft 1-7 is that center of circle line moves in a circle, and big trochal disc 1-8 rotated by rotation block 1-10 is swinging pole 1- Slided in chute among 11, moving block 1-10 slip band movable pendulum moves pole 1-11 and does circumference roll motion, swings branch Swinging for bar 1-11 drives sliding mandril 1-12 to be slidably reciprocated in horizontal concrete chute 1-14, and then drives 1-13 pairs of pressuring template Desulfurization flyash energy-conserving and environment-protective construction wall packing material does pressing mold processing;In the process, big trochal disc rotates failure sensor 1-15 is monitored in real time to big trochal disc 1-8 rotation situation, and big trochal disc is sensed when big trochal disc rotates failure sensor 1-15 1-8 is stuck when not turning, and big trochal disc rotates failure sensor 1-15 and sends feedback signal and the 55s that alarms to central control system 4, in Control system 4 is entreated to cut off device power supply (DPS), staff repairs to equipment;
2nd step:Treat that desulfurization flyash energy-conserving and environment-protective construction wall packing material is pressed into block by pressing mold transmission device 1 Afterwards, central control system 4 starts telescopic oil cylinder 2-4, and telescopic oil cylinder 2-4 knock-pin drives telescopic baffle 2-5 back to move, this When desulfurization flyash energy-conserving and environment-protective construction wall packing material die block dropped into by charging conduit 2-6 in discharging bin 2-3, desulfurized powder Inclined-plane of the coal ash energy-conserving and environment-protective construction wall packing material die block along discharging bin 2-3 slides to discharging opening 2-7, and then by going out Material mouth 2-7 is discharged.
A kind of compression mold device of desulfurization flyash energy-conserving and environment-protective construction wall packing material disclosed by the invention and its filling The preparation method of material, the advantage is that:
(1) the device pressing mold transmission structures are reasonable in design, and motion is more flexible;
(2) apparatus structure is reasonable in design compact, and integrated level is high;
(3) the device pressuring template is prepared using high polymer material, and intensity is more preferable.
A kind of compression mold device of desulfurization flyash energy-conserving and environment-protective construction wall packing material of the present invention and its filling The preparation method novel and reasonable structure of material, manipulation is convenient and swift, and automaticity is high, and pressing mold high efficiency is applied widely It is wealthy.
Brief description of the drawings
Fig. 1 is that a kind of compression mold device of heretofore described desulfurization flyash energy-conserving and environment-protective construction wall packing material shows It is intended to.
Fig. 2 is heretofore described pressing mold transmission device forward sight structural representation.
Fig. 3 is heretofore described pressing mold transmission device backsight structural representation.
Fig. 4 is heretofore described housing interior structure schematic diagram.
Fig. 5 is desulfurization flyash energy-conserving and environment-protective construction wall packing material of the present invention and reference examples in pressing mold consolidation Spend the relation comparison diagram of enhancing rate.
In figure 1 above~Fig. 4, pressing mold transmission device 1, Y-shaped fixed mount 1-1, driving motor 1-2, transmission main shaft 1-3, Active runner 1-4, driving belt 1-5, driven runner 1-6, driven roller centre rotating shaft 1-7, big trochal disc 1-8, star-like fixed mount 1-9, moving block 1-10, swing pole 1-11, sliding mandril 1-12, pressuring template 1-13, horizontal concrete chute 1-14, and big trochal disc rotates event Hinder sensor 1-15, housing 2, feeding warehouse 2-1, pressing mold storehouse 2-2, discharging bin 2-3, telescopic oil cylinder 2-4, telescopic baffle 2-5, blanking Groove 2-6, discharging opening 2-7, shell holder 3, central control system 4.
Embodiment
A kind of desulfurization flyash energy-conserving and environment-protective construction wall provided by the invention is filled with reference to the accompanying drawings and examples The compression mold device of material is further described.
As shown in figure 1, it is a kind of pressing mold of desulfurization flyash energy-conserving and environment-protective construction wall packing material provided by the invention The schematic diagram of equipment.Find out in figure, including:Pressing mold transmission device 1, housing 2, shell holder 3, central control system 4;Its feature It is, the upper surface of shell holder 3 is provided with housing 2, and the pressing mold transmission device 1 is located at the side of shell holder 3, the pressing mold Ground is fixed in the bottom of transmission device 1, and the side of pressing mold transmission device 1 is provided with central control system 4.
As shown in Figure 2 and Figure 3, it is heretofore described pressing mold transmission device forward sight structural representation and pressing mold transmission dress Put backsight structural representation.Find out from Fig. 2, Fig. 3 or Fig. 1, the pressing mold transmission device 1 includes:Y-shaped fixed mount 1-1, pass Dynamic motor 1-2, transmission main shaft 1-3, active runner 1-4, driving belt 1-5, driven runner 1-6, driven roller centre rotating shaft 1- 7, big trochal disc 1-8, star-like fixed mount 1-9, moving block 1-10, swing pole 1-11, sliding mandril 1-12, pressuring template 1-13, water Smooth groove 1-14, big trochal disc rotate failure sensor 1-15;The driving motor 1-2 is arranged at ground level, driving motor 1-2 with The polygon control survey of central control system 4 connects;Driving motor 1-2 output one end is fixed in described transmission main shaft 1-3 one end, transmission The main shaft 1-3 other ends are fixed with active runner 1-4;The active runner 1-4 and transmission main shaft 1-3 interference fits connect, actively Runner 1-4 overlaps with transmission main shaft 1-3 central axis;Described driving belt 1-5 one end is sheathed on active runner 1-4 external diameter tables Face, the driving belt 1-5 other ends are sheathed on driven runner 1-6 external diameter surfaces;The driven runner 1-6 centre bores are fixed with driven Roller centre rotating shaft 1-7, the driven roller centre rotating shaft 1-7 and driven runner 1-6 interference fit connection, driven roller centre Rotating shaft 1-7 overlaps with driven runner 1-6 central axis;The Y-shaped fixed mount 1-1 profiles are in the capitalization of upper end closed " Y " shape, Y-shaped fixed mount 1-1 bottoms plane fix on the ground, and Y-shaped fixed mount 1-1 intermediate throughholes are fixed on driven runner On central rotating shaft 1-7, Y-shaped fixed mount 1-1 and driven roller centre rotating shaft 1-7 interference fits connect, Y-shaped fixed mount 1-1 Overlapped with driven roller centre rotating shaft 1-7 central axis;The big trochal disc 1-8 is located at Y-shaped fixed mount 1-1 sides, big trochal disc 1-8 and Y-shaped fixed mount 1-1 spacing are 10mm~20mm, and big trochal disc 1-8 is fixed on driven roller centre rotating shaft 1-7, bull wheel Disk 1-8 and driven roller centre rotating shaft 1-7 interference fits connect, big trochal disc 1-8 and driven roller centre rotating shaft 1-7 central axis Overlap, big trochal disc 1-8 profiles are in automobile steering plate-like, and big trochal disc 1-8 inner wall surfaces are welded with star-like fixed mount 1-9, institute Star-like fixed mount 1-9 surfaces are stated to be rotatablely connected by bearing pin and moving block 1-10;The Y-shaped fixed mount 1-1 bottom sidewalls are led to Cross bearing pin and be connected with swing pole 1-11, the swing pole 1-11 centres are provided with chute, and the moving block 1-10 is slided with chute Dynamic connection, swings pole 1-11 one end and Y-shaped fixed mount 1-1 bottom sidewall hinge connections, swings the pole 1-11 other ends and leads to Cross fixing axle to be rotatablely connected with sliding mandril 1-12, the level set at the top of the sliding mandril 1-12 and Y-shaped fixed mount 1-1 Chute 1-14 is slidably connected, and sliding mandril 1-12 end faces are provided with pressuring template 1-13, the pressuring template 1-13 and sliding mandril 1-12 End face seamless welding, pressuring template 1-13 are rectangular configuration, pressuring template 1-13 sizes be 200cm~400cm (length) × 100cm~ 180cm (width) × 15cm~30cm (thickness);The big trochal disc rotates failure sensor 1-15 and is located at star-like fixed mount 1-9 surfaces, Big trochal disc rotates failure sensor 1-15 and is connected with the polygon control survey of central control system 4.
As shown in figure 4, it is heretofore described housing interior structure schematic diagram.Find out from Fig. 4, Fig. 3 or Fig. 2, institute Stating housing 2 includes:Feeding warehouse 2-1, pressing mold storehouse 2-2, discharging bin 2-3, telescopic oil cylinder 2-4, telescopic baffle 2-5, charging conduit 2-6, Discharging opening 2-7;The feeding warehouse 2-1 profiles are the bucket-shaped structures of rectangular cross-section, the narrow upper width in feeding warehouse 2-1 sections bottom, are fed It is in open-like shape above the 2-1 of storehouse, feeding warehouse 2-1 inclined-planes are shown as α with horizontal plane angle, and the α value ranges are 15 °~50 °, feeding warehouse Pressing mold storehouse 2-2 is provided with below 2-1, the pressing mold storehouse 2-2 is in rectangular parallelepiped structure, and pressing mold storehouse 2-2 is welded and fixed with feeding warehouse 2-1, It is mutually communicated inside pressing mold storehouse 2-2 and feeding warehouse 2-1, discharging bin 2-3, the discharging bin 2-3 and pressure is provided with below the 2-2 of pressing mold storehouse Mould storehouse 2-2 is welded and fixed, and is penetrated inside discharging bin 2-3 and pressing mold storehouse 2-2 by charging conduit 2-6, and discharging bin 2-3 profiles are italic Shape, discharging bin 2-3 inclined-planes are shown as β with horizontal plane angle, and the β value ranges are 10 °~70 °;The telescopic oil cylinder 2-4 is positioned at pressure Inside the 2-2 of mould storehouse, telescopic oil cylinder 2-4 knock-pins one end is welded with telescopic baffle 2-5, the telescopic baffle 2-5 positioned at pressure Below template 1-13, telescopic baffle 2-5 and pressuring template 1-13 vertical interval is 3mm~6mm, and telescopic baffle 2-5 surfaces are provided with Substantial amounts of leak through hole, leak number of openings are no less than 500, and pore diameter range value is 1mm~5mm;The discharging opening 2-7 is located at Discharging bin 2-3 sidewall bottoms, discharging opening 2-7 sizes are not less than pressuring template 1-13 sizes.
A kind of pressing mold mistake of the compression mold device of desulfurization flyash energy-conserving and environment-protective construction wall packing material of the present invention Cheng Shi:1st step:The desulfurization flyash energy-conserving and environment-protective construction wall packing material of required pressing mold is launched above feeding warehouse 2-1 Telescopic baffle 2-5 surfaces inside to pressing mold storehouse 2-2, press the start button on the surface of central control system 4, central control system 4 start driving motor 1-2, and driving motor 1-2 transmission main shaft 1-3 drives active runner 1-4 to do circle rotation motion, actively turned Wheel 1-4 imparts power to driven runner 1-6 by driving belt 1-5, and then driven runner 1-6 also does circle rotation motion, Driven runner 1-6 imparts power to big trochal disc 1-8 by driven roller centre rotating shaft 1-7, drives big trochal disc 1-8 with from turn Wheel central rotating shaft 1-7 is that center of circle line moves in a circle, and big trochal disc 1-8 rotated by rotation block 1-10 is in pole 1-11 is swung Between chute in slide, moving block 1-10 slip band movable pendulum moves pole 1-11 and does circumference roll motion, swings pole 1- 11 swing drives sliding mandril 1-12 to be slidably reciprocated in horizontal concrete chute 1-14, and then drives pressuring template 1-13 to desulfurization Flyash energy-conserving and environment-protective construction wall packing material does pressing mold processing;In the process, big trochal disc rotates failure sensor 1-15 Big trochal disc 1-8 rotation situation is monitored in real time, big trochal disc 1-8 cards are sensed when big trochal disc rotates failure sensor 1-15 When stubbornly refusing to turn, big trochal disc rotates failure sensor 1-15 and sends feedback signal and the 55s that alarms, center control to central control system 4 System 4 processed cuts off device power supply (DPS), and staff repairs to equipment;
2nd step:Treat that desulfurization flyash energy-conserving and environment-protective construction wall packing material is pressed into block by pressing mold transmission device 1 Afterwards, central control system 4 starts telescopic oil cylinder 2-4, and telescopic oil cylinder 2-4 knock-pin drives telescopic baffle 2-5 back to move, this When desulfurization flyash energy-conserving and environment-protective construction wall packing material block dropped into by charging conduit 2-6 in discharging bin 2-3, desulfurization flyash Inclined-plane of the energy-conserving and environment-protective construction wall packing material die block along discharging bin 2-3 slides to discharging opening 2-7, and then passes through discharging opening 2-7 is discharged.
A kind of compression mold device structure of desulfurization flyash energy-conserving and environment-protective construction wall packing material of the present invention is novel Rationally, manipulation is convenient and swift, and automaticity is high, pressing mold high efficiency, and the scope of application is wide.
It is the embodiment of the manufacturing process of desulfurization flyash energy-conserving and environment-protective construction wall packing material of the present invention below, Embodiment is to further illustrate present disclosure, but be should not be construed as limiting the invention.Without departing substantially from the present invention In the case of spirit and essence, the modification and replacement made to the inventive method, step or condition, model of the invention is belonged to Enclose.
Unless otherwise specified, the conventional meanses that technological means used in embodiment is well known to those skilled in the art.
Embodiment 1
Desulfurization flyash energy-conserving and environment-protective construction wall packing material of the present invention is manufactured according to following steps, and by weight Fraction meter:
1st step:359 parts of the ultra-pure water that electrical conductivity is 1.9 μ S/cm is added in a kettle, starts agitator in reactor, Rotating speed is 109rpm, starts heat pump, reactor temperature is risen to 39 DEG C;Sequentially add 39 parts of desulfurization flyash, to nitre 29~79 parts of base benzenesulfonyl acetic acid esters, 59 parts of acetparaminosalol-methyl o-anisate, stirring are adjusted to being completely dissolved It is 3.9 to save pH value, agitator speed is adjusted into 149rpm, temperature is 79 DEG C, esterification 19 hours;
2nd step:Take 139 parts of 3- (to methanesulfonylphenYl) serine ethyl ester, 3- ketobutyric acids 2- (methyl (phenyl methyl) Amino) 119 parts of ethyl ester crushed, and powder diameter is 119 mesh;Add 4- { [double (β-chloroethyl) amino] phenyl } methyl butyrate 39 parts well mixed, is laid in pallet, tiling thickness is 49mm, uses the alpha ray that dosage is 19MeV for 5.9kGy, energy Irradiation 49 minutes, and the β x ray irradiation xs 59 minutes of Isodose;
3rd step:The mixed-powder handled through the 2nd step is dissolved in 79 parts of the 4-tert-Butylphenylacetic acid methyl esters that concentration is 29ppm, Add reactor, agitator speed 89rpm, temperature be 79 DEG C, start vavuum pump make the vacuum of reactor reach- 0.49MPa, keeps this state response 19 hours;Pressure release is simultaneously passed through nitrogen, and it is 0.90MPa to make reacting kettle inner pressure, and insulation is stood 19 hours;Agitator speed is promoted to 119rpm, simultaneous reactions kettle pressure release to 0MPa;Sequentially add gavaculine ethyl ester 69 After part, 139 parts of m-dibutylamino benzoic acid are completely dissolved, add 29 parts of crosslinking agent and be stirred so that reactor solution Hydrophilic lipophilic balance be 4.9, insulation stand 1 hour;
4th step:When agitator speed is 109rpm, N is sequentially added, between N- dimethyl carbamic acids (dimethylamino) 29 parts of phenyl ester, 39 parts of the N- pi-allyl-N- m-aminophenyl Methyl-carbamic acids tert-butyl ester, 5- amino isophthalic acids dimethyl ester 59 Part, poly- [α, β-(N-2- ethoxys)-DL- asparagines] 2- [(2,4,5- trimethoxy-benzenes) imino group] diethyl succinate 139 parts, reactor pressure is lifted, reaches 0.90MPa, temperature is 119 DEG C, polymerisation 19 hours;Will after the completion of reaction Reacting kettle inner pressure is down to 0MPa, is cooled to 29 DEG C, discharging, enters compression mold device and can be prepared by desulfurization flyash energy-conserving and environment-protective building Filling materials for wall body;
Crosslinking agent meta-chlorocarbanilate between the chloro- 2- butynyls-N- of 4-.
Embodiment 2
Desulfurization flyash energy-conserving and environment-protective construction wall packing material of the present invention is manufactured according to following steps, and by weight Fraction meter:
1st step:1159 parts of the ultra-pure water that electrical conductivity is 2.9 μ S/cm is added in a kettle, is started in reactor and is stirred Device, rotating speed 219rpm, start heat pump, reactor temperature is risen to 59 DEG C;Sequentially add 99 parts of desulfurization flyash, right 79 parts of nitrobenzene sulphonyl yl acetate, 99 parts of acetparaminosalol-methyl o-anisate, stirring are adjusted to being completely dissolved PH value 9.9, agitator speed is adjusted to 219rpm, temperature is 149 DEG C, esterification 29 hours;
2nd step:Take 269 parts of 3- (to methanesulfonylphenYl) serine ethyl ester, 3- ketobutyric acids 2- (methyl (phenyl methyl) Amino) 279 parts of ethyl ester crushed, and powder diameter is 329 mesh;Add 4- { [double (β-chloroethyl) amino] phenyl } methyl butyrate 109 parts well mixed, is laid in pallet, tiling thickness is 69mm, uses the alpha ray that dosage is 29MeV for 8.9kGy, energy Irradiation 89 minutes, and the β x ray irradiation xs 119 minutes of Isodose;
3rd step:The mixed-powder handled through the 2nd step is dissolved in 119 parts of the 4-tert-Butylphenylacetic acid methyl esters that concentration is 69ppm In, add reactor, agitator speed 159rpm, temperature be 169 DEG C, start vavuum pump make the vacuum of reactor reach- 1.69MPa, keeps this state response 29 hours;Pressure release is simultaneously passed through nitrogen, and it is 1.90MPa to make reacting kettle inner pressure, and insulation is stood 29 hours;Agitator speed is promoted to 269rpm, simultaneous reactions kettle pressure release to 0MPa;Sequentially add gavaculine ethyl ester 129 parts, after 289 parts of m-dibutylamino benzoic acid is completely dissolved, adds 109 parts of crosslinking agent and be stirred so that reactor The hydrophilic lipophilic balance of solution is 9.9, and insulation stands 29 hours;
4th step:When agitator speed is 229rpm, N is sequentially added, between N- dimethyl carbamic acids (dimethylamino) 99 parts of phenyl ester, 139 parts of the N- pi-allyl-N- m-aminophenyl Methyl-carbamic acids tert-butyl ester, 5- amino isophthalic acid dimethyl esters 109 parts, poly- [α, β-(N-2- ethoxys)-DL- asparagines] 2- [(2,4,5- trimethoxy-benzenes) imino group] succinic acid diethyl 249 parts of ester, reactor pressure is lifted, reach 1.90MPa, temperature is 239 DEG C, polymerisation 39 hours;After the completion of reaction Reacting kettle inner pressure is down to 0MPa, is cooled to 49 DEG C, discharging, enters compression mold device and can be prepared by desulfurization flyash energy-conserving and environment-protective to build Build filling materials for wall body;
The crosslinking agent is N- (the chloro- 2- nitrobenzophenones of 4-)-ortho-aminobenzoic acid.
Embodiment 3
Lifting rope desulfurization flyash energy-conserving and environment-protective construction wall packing material of the present invention is manufactured according to following steps, and is pressed Weight fraction meter:1st step:759 parts of the ultra-pure water that electrical conductivity is 2.4 μ S/cm is added in a kettle, is started in reactor and is stirred Device, rotating speed 159rpm, start heat pump, reactor temperature is risen to 49 DEG C;Sequentially add 59 parts of desulfurization flyash, right 49 parts of nitrobenzene sulphonyl yl acetate, 69 parts of acetparaminosalol-methyl o-anisate, stirring are adjusted to being completely dissolved PH value is 5.9, agitator speed is adjusted into 179rpm, temperature is 119 DEG C, esterification 24 hours;
2nd step:Take 169 parts of 3- (to methanesulfonylphenYl) serine ethyl ester, 3- ketobutyric acids 2- (methyl (phenyl methyl) Amino) 179 parts of ethyl ester crushed, and powder diameter is 229 mesh;Add 4- { [double (β-chloroethyl) amino] phenyl } methyl butyrate 89 parts well mixed, is laid in pallet, tiling thickness is 59mm, uses the alpha ray that dosage is 25MeV for 7.9kGy, energy Irradiation 69 minutes, and the β x ray irradiation xs 89 minutes of Isodose;
3rd step:The mixed-powder handled through the 2nd step is dissolved in 89 parts of the 4-tert-Butylphenylacetic acid methyl esters that concentration is 49ppm, Add reactor, agitator speed 119rpm, temperature be 119 DEG C, start vavuum pump make the vacuum of reactor reach- 1.29MPa, keeps this state response 22 hours;Pressure release is simultaneously passed through nitrogen, and it is 1.30MPa to make reacting kettle inner pressure, and insulation is stood 23 hours;Agitator speed is promoted to 169rpm, simultaneous reactions kettle pressure release to 0MPa;Sequentially add gavaculine ethyl ester 99 After part, 189 parts of m-dibutylamino benzoic acid are completely dissolved, add 79 parts of crosslinking agent and be stirred so that reactor solution Hydrophilic lipophilic balance be 7.9, insulation stand 22 hours;
4th step:When agitator speed is 189rpm, N is sequentially added, between N- dimethyl carbamic acids (dimethylamino) 69 parts of phenyl ester, 59 parts of the N- pi-allyl-N- m-aminophenyl Methyl-carbamic acids tert-butyl ester, 5- amino isophthalic acids dimethyl ester 79 Part, poly- [α, β-(N-2- ethoxys)-DL- asparagines] 2- [(2,4,5- trimethoxy-benzenes) imino group] diethyl succinate 189 parts, reactor pressure is lifted, reaches 1.40MPa, temperature is 179 DEG C, polymerisation 29 hours;Will after the completion of reaction Reacting kettle inner pressure is down to 0MPa, is cooled to 39 DEG C, discharging, enters compression mold device and can be prepared by desulfurization flyash energy-conserving and environment-protective building Filling materials for wall body;
The crosslinking agent is 3,4- dichlorophenyl carbamic acids -2- [3- butyl -4- (2,2- dicyanoethenyls) -3- first Phenylamino] ethyl ester.
Reference examples
Reference examples are the filling materials for wall body of certain commercially available brand, the use experiment for construction wall filling pressing mold process.
Embodiment 4
Described in the desulfurization flyash energy-conserving and environment-protective construction wall packing material and reference examples that embodiment 1~3 is prepared Filling materials for wall body, for wall filling pressing mold process service condition contrasted.Pressing mold is filled out to wall respectively after terminating The parameters for filling material pressing mold process are detected, as a result as shown in table 1.
Table 1 is used for every ginseng of wall filling pressing mold process for the filling materials for wall body described in embodiment 1~3 and reference examples Several comparing results, as seen from Table 1, desulfurization flyash energy-conserving and environment-protective construction wall packing material of the present invention, its hardness Enhancing rate, strength enhancing rate, corrosion resistant erosion degree enhancing rate, pressing mold degree of packing enhancing rate are above the product of prior art production.
In addition, as shown in figure 5, it is desulfurization flyash energy-conserving and environment-protective construction wall packing material of the present invention with compareing Relation comparison diagram of the example in pressing mold degree of packing enhancing rate.Find out in figure, the desulfurization flyash energy-saving ring manufactured by high polymer material Protect construction wall packing material material to be evenly distributed, hardness, intensity and rigidity, compared with the filling materials for wall body parameter described in reference examples Value is high;It is equal using desulfurization flyash energy-conserving and environment-protective construction wall packing material of the present invention, its pressing mold degree of packing enhancing rate Better than existing product.

Claims (3)

1. a kind of compression mold device of desulfurization flyash energy-conserving and environment-protective construction wall packing material, including:Pressing mold transmission device(1), Housing(2), shell holder(3), central control system(4);Characterized in that, the shell holder(3)Upper surface is provided with housing (2), housing(2)For stainless steel;The pressing mold transmission device(1)Positioned at shell holder(3)Side, the pressing mold transmission dress Put(1)Ground, the pressing mold transmission device are fixed in bottom(1)Side is provided with central control system(4);
The pressing mold transmission device(1)Including:Y-shaped fixed mount(1-1), driving motor(1-2), transmission main shaft(1-3), actively Runner(1-4), driving belt(1-5), driven runner(1-6), driven roller centre rotating shaft(1-7), big trochal disc(1-8), it is star-like Fixed mount(1-9), moving block(1-10), swing pole(1-11), sliding mandril(1-12), pressuring template(1-13), horizontal concrete chute (1-14), big trochal disc rotation failure sensor(1-15);Wherein described driving motor(1-2)It is arranged at ground level, driving motor (1-2)With central control system(4)Polygon control survey connects;The transmission main shaft(1-3)Driving motor is fixed in one end(1-2)'s Export one end, transmission main shaft(1-3)The other end is fixed with active runner(1-4);The active runner(1-4)With transmission main shaft (1-3)Interference fit connection, active runner(1-4)With transmission main shaft(1-3)Central axis overlaps;The driving belt(1-5) One end is sheathed on active runner(1-4)External diameter surface, driving belt(1-5)The other end is sheathed on driven runner(1-6)External diameter table Face;The driven runner(1-6)Centre bore is fixed with driven roller centre rotating shaft(1-7), the driven roller centre rotating shaft(1- 7)With driven runner(1-6)Interference fit connection, driven roller centre rotating shaft(1-7)With driven runner(1-6)Central axis weight Close;The Y-shaped fixed mount(1-1)Profile is in capitalization " Y " shape of upper end closed, Y-shaped fixed mount(1-1)Bottom plane Fix on the ground, Y-shaped fixed mount(1-1)Intermediate throughholes are fixed on driven roller centre rotating shaft(1-7)On, Y-shaped is fixed Frame(1-1)With driven roller centre rotating shaft(1-7)Interference fit connection, Y-shaped fixed mount(1-1)With driven roller centre rotating shaft (1-7)Central axis overlaps;The big trochal disc(1-8)Located at Y-shaped fixed mount(1-1)Side, big trochal disc(1-8)With Y-shaped Fixed mount(1-1)Spacing is the mm of 10 mm~20, big trochal disc(1-8)It is fixed on driven roller centre rotating shaft(1-7)On, big trochal disc (1-8)With driven roller centre rotating shaft(1-7)Interference fit connection, big trochal disc(1-8)With driven roller centre rotating shaft(1-7)In Mandrel line overlaps, big trochal disc(1-8)Profile is in automobile steering plate-like, big trochal disc(1-8)Inner wall surface is welded with star-like solid Determine frame(1-9), the star-like fixed mount(1-9)Surface passes through bearing pin and moving block(1-10)Rotation connection;The Y-shaped is fixed Frame(1-1)Bottom sidewall is connected with by bearing pin and swings pole(1-11), the swing pole(1-11)Centre is provided with chute, institute State moving block(1-10)It is connected with slide, swings pole(1-11)One end and Y-shaped fixed mount(1-1)Bottom sidewall hinge Connection, swing pole(1-11)The other end passes through fixing axle and sliding mandril(1-12)Rotation connection, the sliding mandril(1- 12)With Y-shaped fixed mount(1-1)The horizontal concrete chute that top is set(1-14)It is slidably connected, sliding mandril(1-12)End face is provided with Pressuring template(1-13), the pressuring template(1-13)With sliding mandril(1-12)End face seamless welding, pressuring template(1-13)For rectangle Structure, pressuring template(1-13)Size length × width x thickness is cm~30 of the cm of the cm of the cm of 200 cm~400 × 100~180 × 15 cm;The big trochal disc rotates failure sensor(1-15)Positioned at star-like fixed mount(1-9)Surface, big trochal disc rotate failure sensor (1-15)With central control system(4)Polygon control survey connects;
The housing(2)Including:Feeding warehouse(2-1), pressing mold storehouse(2-2), discharging bin(2-3), telescopic oil cylinder(2-4), stretch gear Plate(2-5), charging conduit(2-6), discharging opening(2-7);Wherein described feeding warehouse(2-1)Profile is the bucket-shaped knot of rectangular cross-section Structure, feeding warehouse(2-1)The narrow upper width in section bottom, feeding warehouse(2-1)Top is in open-like shape, feeding warehouse(2-1)Inclined-plane presss from both sides with horizontal plane Angle is shown as α, and the α value ranges are 15 °~50 °, feeding warehouse(2-1)Lower section is provided with pressing mold storehouse(2-2), the pressing mold storehouse(2- 2)In rectangular parallelepiped structure, pressing mold storehouse(2-2)With feeding warehouse(2-1)It is welded and fixed, pressing mold storehouse(2-2)With feeding warehouse(2-1)It is internal It is mutually communicated, pressing mold storehouse(2-2)Lower section is provided with discharging bin(2-3), the discharging bin(2-3)With pressing mold storehouse(2-2)It is welded and fixed, Discharging bin(2-3)With pressing mold storehouse(2-2)Inside passes through charging conduit(2-6)Insertion, discharging bin(2-3)Profile is italic shape, discharging Storehouse(2-3)Inclined-plane is shown as β with horizontal plane angle, and the β value ranges are 10 °~70 °;The telescopic oil cylinder(2-4)Positioned at pressure Mould storehouse(2-2)Inside, telescopic oil cylinder(2-4)Knock-pin one end is welded with telescopic baffle(2-5), the telescopic baffle(2- 5)Positioned at pressuring template(1-13)Lower section, telescopic baffle(2-5)With pressuring template(1-13)Vertical interval be the mm of 3 mm~6, stretch Baffle plate(2-5)Surface is provided with substantial amounts of leak through hole, and leak number of openings is no less than 500, and pore diameter range value is 1 mm~5 mm;The discharging opening(2-7)Positioned at discharging bin(2-3)Sidewall bottom, discharging opening(2-7)Size is not less than pressuring template(1-13)Greatly It is small.
2. a kind of compression mold device of desulfurization flyash energy-conserving and environment-protective construction wall packing material according to claim 1, its It is characterised by, a kind of preparation method of desulfurization flyash energy-conserving and environment-protective construction wall packing material, the desulfurization flyash energy-conservation Environment protection architecture filling materials for wall body is molded by high polymer material pressing mold and is made, the filling of desulfurization flyash energy-conserving and environment-protective construction wall The constituent and manufacturing process of material are as follows:
First, desulfurization flyash energy-conserving and environment-protective construction wall packing material constituent:
Count in parts by weight, 39~99 parts of desulfurization flyash, 29~79 parts of p-Nitrophenyl sulfonyl acetate, acetparaminosalol- 59~99 parts of methyl o-anisate, 139~269 parts of 3- (to methanesulfonylphenYl) serine ethyl ester, 3- ketobutyric acids 2- (methyl (phenyl methyl) amino) 119~279 parts of ethyl ester, 4- { [double (β-chloroethyl) amino] phenyl } methyl butyrate 39~ 109 parts, concentration is the ppm of 29 ppm~69 79~119 parts of 4-tert-Butylphenylacetic acid methyl esters, gavaculine ethyl ester 69~ 129 parts, 139~289 parts of m-dibutylamino benzoic acid, 29~109 parts, N of crosslinking agent, (two between N- dimethyl carbamic acids Methylamino) 29~99 parts of phenyl ester, 39~139 parts of the N- pi-allyl-N- m-aminophenyl Methyl-carbamic acids tert-butyl ester, 5- amino 59~109 parts of DMIP, poly- [α, β-(N-2- ethoxys)-DL- asparagines] 2- [(2,4,5- trimethoxies Benzene) imino group] 139~249 parts of diethyl succinate;
The crosslinking agent meta-chlorocarbanilate, 3,4- dichlorophenyl carbamic acid -2- [3- between the chloro- 2- butynyls-N- of 4- Butyl -4- (2,2- dicyanoethenyls) -3- toluidinos] ethyl ester, in N- (the chloro- 2- nitrobenzophenones of 4-)-ortho-aminobenzoic acid Any one;
2nd, the manufacturing process of desulfurization flyash energy-conserving and environment-protective construction wall packing material, is comprised the steps of:
1st step:359~1159 parts of the ultra-pure water that electrical conductivity is the μ S/cm of 1.9 μ S/cm~2.9 is added in a kettle, is started Agitator in reactor, rotating speed are the rpm of 109 rpm~219, start heat pump, make reactor temperature rise to 39 DEG C~ 59 ℃;Desulfurization flyash, p-Nitrophenyl sulfonyl acetate, acetparaminosalol-methyl o-anisate are sequentially added, To being completely dissolved, regulation pH value is 3.9~9.9 for stirring, and agitator speed is adjusted into the rpm of 149 rpm~219, temperature 79 DEG C~149 DEG C, esterification 19~29 hours;
2nd step:Take 3- (to methanesulfonylphenYl) serine ethyl ester, 3- ketobutyric acids 2- (methyl (phenyl methyl) amino) ethyl ester Crushed, powder diameter is 119~329 mesh;4- { [double (β-chloroethyl) amino] phenyl } methyl butyrate is added to be well mixed, Be laid in pallet, tiling thickness is the mm of 49 mm~69, use dosage for the kGy of 5.9 kGy~8.9, energy be 19 MeV~ 29 MeV alpha ray irradiates 49~89 minutes, and the β x ray irradiation xs 59~119 minutes of Isodose;
3rd step:The mixed-powder handled through the 2nd step is dissolved in 4-tert-Butylphenylacetic acid methyl esters of the concentration for the ppm of 29 ppm~69 In, reactor is added, agitator speed is the rpm of 89 rpm~159, and temperature is 79 DEG C~169 DEG C, and starting vavuum pump makes instead Answer the vacuum of kettle to reach the MPa of -0.49 MPa~-1.69, keep this state response 19~29 hours;Pressure release is simultaneously passed through nitrogen, Making reacting kettle inner pressure, insulation stands 19~29 hours for the MPa of 0.90 MPa~1.90;Agitator speed is promoted to 119 rpm ~269 rpm, simultaneous reactions kettle pressure release to 0MPa;Sequentially add gavaculine ethyl ester, m-dibutylamino benzoic acid After being completely dissolved, add crosslinking agent and be stirred so that the hydrophilic lipophilic balance of reactor solution is 4.9~9.9, and insulation is quiet Put 19~29 hours;
4th step:When agitator speed is 109 rpm~229 rpm, N is sequentially added, (diformazan between N- dimethyl carbamic acids Base amino) it is phenyl ester, the N- pi-allyl-N- m-aminophenyl Methyl-carbamic acids tert-butyl ester, 5- amino isophthalic acids dimethyl ester, poly- [α, β-(N-2- ethoxys)-DL- asparagines] 2- [(2,4,5- trimethoxy-benzene) imino group] diethyl succinate, lifting are anti- Kettle pressure is answered, reaches the MPa of 0.90 MPa~1.90, temperature is 119 DEG C~239 DEG C, polymerisation 19~39 hours; Reacting kettle inner pressure is down to 0 MPa after the completion of reaction, 29 DEG C~49 DEG C is cooled to, discharging, enters compression mold device and can be prepared by Desulfurization flyash energy-conserving and environment-protective construction wall packing material.
A kind of a kind of 3. compression mold device work of desulfurization flyash energy-conserving and environment-protective construction wall packing material as claimed in claim 1 Make method, it is characterised in that this method includes following steps:
1st step:By the desulfurization flyash energy-conserving and environment-protective construction wall packing material of required pressing mold from feeding warehouse(2-1)Launch top To pressing mold storehouse(2-2)Internal telescopic baffle(2-5)Surface, press central control system(4)The start button on surface, center control System processed(4)Start driving motor(1-2), driving motor(1-2)Transmission main shaft(1-3)Drive active runner(1-4)Do circle All rotary motions, active runner(1-4)Pass through driving belt(1-5)Impart power to driven runner(1-6), and then from turn Wheel(1-6)Also circle rotation motion, driven runner are done(1-6)Pass through driven roller centre rotating shaft(1-7)Impart power to big Wheel disc(1-8), drive big trochal disc(1-8)With driven roller centre rotating shaft(1-7)Moved in a circle for center of circle line, big trochal disc(1- 8)Rotated by rotation block(1-10)Swinging pole(1-11)Slided in middle chute, moving block(1-10)Slip band Movable pendulum moves pole(1-11)Circumference roll motion is done, swings pole(1-11)Swing drive sliding mandril(1-12) In horizontal concrete chute(1-14)Inside slidably reciprocate, and then drive pressuring template(1-13)Desulfurization flyash energy-conserving and environment-protective construction wall is filled out Fill material and do pressing mold processing;In the process, big trochal disc rotates failure sensor(1-15)To big trochal disc(1-8)Rotation situation Monitored in real time, when big trochal disc rotates failure sensor(1-15)Sense big trochal disc(1-8)Stuck when not turning, big trochal disc turns Dynamic failure sensor(1-15)To central control system(4)Send feedback signal and 55 s of alarm, central control system(4)Cut-out Device power supply (DPS), staff repair to equipment;
2nd step:Treat pressing mold transmission device(1)After desulfurization flyash energy-conserving and environment-protective construction wall packing material is pressed into block, Central control system(4)Start telescopic oil cylinder(2-4), telescopic oil cylinder(2-4)Knock-pin drive telescopic baffle(2-5)It is past to backhaul Dynamic, now desulfurization flyash energy-conserving and environment-protective construction wall packing material die block passes through charging conduit(2-6)Drop into discharging bin(2-3) In, desulfurization flyash energy-conserving and environment-protective construction wall packing material die block is along discharging bin(2-3)Inclined-plane to discharging opening(2-7)It is sliding OK, and then discharging opening is passed through(2-7)Discharge.
CN201610389705.6A 2016-06-03 2016-06-03 A kind of compression mold device of desulfurization flyash energy-conserving and environment-protective construction wall packing material and its preparation method of packing material Active CN106065178B (en)

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CN2556001Y (en) * 2002-08-01 2003-06-18 孙义田 Hydraulic vibration type multipurpose brick making machine without firing
CN2778522Y (en) * 2005-01-28 2006-05-10 广西金瓯建材机械有限公司 Automatic forming machine for hollow bearing brick
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Publication number Priority date Publication date Assignee Title
CN2556001Y (en) * 2002-08-01 2003-06-18 孙义田 Hydraulic vibration type multipurpose brick making machine without firing
CN2778522Y (en) * 2005-01-28 2006-05-10 广西金瓯建材机械有限公司 Automatic forming machine for hollow bearing brick
CN201380533Y (en) * 2009-03-02 2010-01-13 宁波职业技术学院 Energy-saving type hydraulic system of concrete block forming machine

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