CN106025414A - Crushing apparatus for waste lithium ion power battery cell - Google Patents

Crushing apparatus for waste lithium ion power battery cell Download PDF

Info

Publication number
CN106025414A
CN106025414A CN201610465314.8A CN201610465314A CN106025414A CN 106025414 A CN106025414 A CN 106025414A CN 201610465314 A CN201610465314 A CN 201610465314A CN 106025414 A CN106025414 A CN 106025414A
Authority
CN
China
Prior art keywords
particle
alkali liquor
battery core
cell
spiral blade
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201610465314.8A
Other languages
Chinese (zh)
Other versions
CN106025414B (en
Inventor
夏雄伟
薛辛
马成
殷康健
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Zhuzhou Dingduan Equipment Co Ltd
Original Assignee
Zhuzhou Dingduan Equipment Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Zhuzhou Dingduan Equipment Co Ltd filed Critical Zhuzhou Dingduan Equipment Co Ltd
Priority to CN201610465314.8A priority Critical patent/CN106025414B/en
Publication of CN106025414A publication Critical patent/CN106025414A/en
Application granted granted Critical
Publication of CN106025414B publication Critical patent/CN106025414B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09BDISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
    • B09B3/00Destroying solid waste or transforming solid waste into something useful or harmless
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/54Reclaiming serviceable parts of waste accumulators
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/84Recycling of batteries or fuel cells

Landscapes

  • Secondary Cells (AREA)
  • Engineering & Computer Science (AREA)
  • Processing Of Solid Wastes (AREA)
  • Environmental & Geological Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)

Abstract

The invention discloses a crushing apparatus for a waste lithium ion power battery cell. According to the apparatus, the to-be-processed waste lithium ion power battery cell is temporarily stored in a cell storage bed; the cell is discharged firstly on the cell storage bed; then the discharged cell is detected, and the cell which passes the detection is conveyed to cell crushing equipment through a conveyor belt; the cell crushing equipment is provided with an alkali liquid spraying opening and a helical type blade crusher; the helical type blade crusher crushes the conveyed cell; the crushed material which is processed by the helical type blade crusher is conveyed to an environment-friendly type drying furnace; the crushed material which is dried by the environment-friendly type drying furnace is sent to the crushed material conveyor belt again; and the crushed material is conveyed to a crushed material storage tank by the crushed material conveyor belt to be stored for use. By adoption of the crushing apparatus, the problems of short circuit and outbreak of fire of the cell, decomposition and volatilization of the electrolyte, low crushing efficiency and the like in the cell crushing process can be solved.

Description

A kind of applying waste lithium ionic electrical core of power battery breaker
Technical field
The present invention relates to applying waste lithium ionic electrokinetic cell recovery technology field, particularly relate to a kind of applying waste lithium ionic electrokinetic cell Battery core breaker.
Background technology
The fast development of new-energy automobile, to the process in electrokinetic cell life-span to after date with utilize and propose new problem, according in State's automotive engineering Center Prediction, to the year two thousand twenty, China's electric automobile power battery adds up learies and is up to 12~170,000 tons Scale.The hugest learies needs to carry out in advance the electrokinetic cell recycling research of business, the grinding of battery handling equipment Send out and the groping of business model.
Along with the fast development of new-energy automobile, the recycling of Vehicular dynamic battery cause all the more people concern and Pay attention to.When less than the 70% of Vehicular dynamic battery capacity attenuation to initial capacity, once charging course continuation mileage substantially subtracts Little, it is meant that the termination of the vehicle-mounted mission of Vehicular dynamic battery.If can not to electrokinetic cell system efficient recovery in addition again Utilizing, between the new-energy automobile industry development thus brought and environment, resource, contradiction will be more and more prominent, can be right Ecological environment produces serious harm with human health.
And innoxious process for treating route after waste and old electrokinetic cell reclaims is more complicated, first have to carry out pre-to useless lithium battery Process, including discharging, disassemble, crush, sorting;Plastics and ferrum shell after disassembling reclaim;Electrode material after sorting After carrying out alkali leaching, Ore Leaching, remove impurity, extract.In this series of link, waste and old electrical core of power battery Broken is a crucial technical barrier, and especially battery core short-circuit fire, electrolyte decomposition volatilization and crushing efficiency is low etc. A difficult problem annoyings the research and development of battery battery core disintegrating apparatus.
Summary of the invention
It is an object of the invention to provide a kind of applying waste lithium ionic electrical core of power battery breaker, this device can solve the problem that at electricity The battery core short-circuit fire, the electrolyte decomposition volatilization that produce in core shattering process and the problem such as crushing efficiency is low.
A kind of applying waste lithium ionic electrical core of power battery breaker, described device includes battery core storage bed, conveyer belt, battery core Disintegrating apparatus, alkali liquor mouth spray, spiral blade disintegrating machine, alkali liquor circulating tank, environment protection-type drying oven, gas treatment set Standby, particle conveyer belt, control room, electro-motor and particle holding vessel, wherein:
Pending applying waste lithium ionic electrical core of power battery is stored temporarily in described battery core storage bed, stores up in described battery core Deposit and first this battery core discharged on platform, then to electric discharge after battery core detect, and by detection by after battery core pass through Described conveyer belt is delivered to described battery core disintegrating apparatus;
It is provided with alkali liquor mouth spray and spiral blade disintegrating machine in described battery core disintegrating apparatus, described spiral blade breaks Broken machine carries out break process to transmitting the battery core come;
During described spiral blade disintegrating machine carries out break process to battery core, described alkali liquor mouth spray constantly sprays Sig water;
The alkali liquor Recycling that described alkali liquor circulating tank will spray, is provided with detector in the inside of described alkali liquor circulating tank, Utilize this detector to detect electrolyte content and alkali liquor pH value in described alkali liquor circulating tank;
Particle after described spiral blade crusher in crushing processes is delivered in described environment protection-type drying oven, described Particle after break process is dried by environment protection-type drying oven, dries alkali liquor and the electrolyte of residual, the institute on surface State environment protection-type drying oven to be connected with described gas processing device;
Particle after described environment protection-type drying oven dried enters back into described particle conveyer belt, described particle carry Particle is delivered in described particle holding vessel to carry out to store standby by band;
Wherein, described conveyer belt and described particle conveyer belt are controlled to transmit crawler belt by described control room and electro-motor Velocity of rotation.
Particle diameter control after described spiral blade disintegrating machine processes is 25~30mm, and percentage of damage reaches 100%.
Spiral blade in described spiral blade disintegrating machine uses a plurality of arranged in parallel.
Described environment protection-type drying oven uses hermetic design, and for being dried by the particle after break process, and baking temperature controls At 30~50 DEG C.
As seen from the above technical solution provided by the invention, said apparatus can solve the problem that and produces in battery core shattering process Battery core short-circuit fire, electrolyte decomposition volatilization and the problem such as crushing efficiency is low.
Accompanying drawing explanation
In order to be illustrated more clearly that the technical scheme of the embodiment of the present invention, required use in embodiment being described below Accompanying drawing is briefly described, it should be apparent that, the accompanying drawing in describing below is only some embodiments of the present invention, for From the point of view of those of ordinary skill in the art, on the premise of not paying creative work, it is also possible to obtain according to these accompanying drawings Other accompanying drawings.
Fig. 1 is the structural representation of the embodiment of the present invention provided applying waste lithium ionic electrical core of power battery breaker;
Fig. 2 is provided the internal structure schematic diagram of spiral blade disintegrating machine by the embodiment of the present invention.
Detailed description of the invention
Below in conjunction with the accompanying drawing in the embodiment of the present invention, the technical scheme in the embodiment of the present invention is carried out clearly and completely Describe, it is clear that described embodiment is only a part of embodiment of the present invention rather than whole embodiments.Based on Embodiments of the invention, it is every other that those of ordinary skill in the art are obtained under not making creative work premise Embodiment, broadly falls into protection scope of the present invention.
Below in conjunction with accompanying drawing, the embodiment of the present invention is described in further detail, is illustrated in figure 1 embodiment of the present invention institute There is provided applying waste lithium ionic electrical core of power battery breaker structural representation, described device mainly include battery core storage bed 1, Conveyer belt 2, battery core disintegrating apparatus 3, alkali liquor mouth spray 4, spiral blade disintegrating machine 5, alkali liquor circulating tank 6, environment protection-type dry Dry stove 7, gas processing device 8, particle conveyer belt 9, control room 10, electro-motor 11 and particle holding vessel 12, wherein:
First from new forms of energy power vehicle, take off applying waste lithium ionic electrokinetic cell, after disassembling, obtain cell battery core, Again pending applying waste lithium ionic electrical core of power battery is stored temporarily in described battery core storage bed 1, stores in described battery core First this battery core is discharged on platform 1, then to electric discharge after battery core detect, and by detection by after battery core through institute State conveyer belt 2 and be delivered to described battery core disintegrating apparatus 3;
Alkali liquor mouth spray 4 and spiral blade disintegrating machine 5 it is provided with, by described spiral blade in described battery core disintegrating apparatus 3 Disintegrating machine 5 carries out break process to transmitting the battery core come;
During described spiral blade disintegrating machine 5 carries out break process to battery core, described alkali liquor mouth spray 4 constantly sprays Spill sig water;Spray the high temperature produced when on the one hand sig water can reduce broken, making of protection equipment safety extension equipment With the life-span, on the other hand sig water can neutralize the electrolyte within battery battery core, prevents volatilization and the decomposition of electrolyte Produce the Fluohydric acid. (HF) of highly corrosive;
The alkali liquor Recycling that described alkali liquor circulating tank 6 will spray, is provided with detection in the inside of described alkali liquor circulating tank 6 Instrument, utilizes this detector to detect electrolyte content and alkali liquor pH value in described alkali liquor circulating tank 6;When this detector detects When alkali liquor concentration of electrolyte in described alkali liquor circulating tank 6 is too high or alkali liquor pH value is relatively low, stop Recycling, and by alkali liquor It is delivered to waste liquid treatment tank.
Particle after described spiral blade disintegrating machine 5 break process is delivered in described environment protection-type drying oven 7, in institute State in environment protection-type drying oven 7 and the particle after break process be dried, dry alkali liquor and the electrolyte of residual on surface, Described environment protection-type drying oven 7 is connected with described gas processing device 8;In implementing, this environment protection-type drying oven 7 uses airtight Design, for being dried by the particle after break process, and baking temperature controls at 30~50 DEG C, makees for low wind speed low temperature Industry.
Particle after described environment protection-type drying oven 7 dried enters back into described particle conveyer belt 9, defeated by described particle Band 9 is sent to be delivered in described particle holding vessel 12 to carry out to store standby by particle;
Wherein, described conveyer belt 2 and described particle conveyer belt 9 are controlled to transmit by described control room 10 and electro-motor 11 The velocity of rotation of crawler belt.
It addition, be illustrated in figure 2 the embodiment of the present invention to be provided the internal structure schematic diagram of spiral blade disintegrating machine, this spiral shell Rotating blade disintegrating machine mainly includes rotary shaft 13, spiral blade 14, screen cloth 15 and rotation motor 16, wherein: described Spiral blade 14 uses a plurality of arranged in parallel, and this arrangement mode can make the cutting of battery core more uniformly, and blade type cuts Also the splashing of sig water it is effectively prevented.Particle diameter control after above-mentioned spiral blade disintegrating machine processes exists 25~30mm, and percentage of damage reaches 100%, above-mentioned break process is conducive to being dried of material, and material surface alkali liquor and electrolysis The volatilization of liquid, broken after make a particle diameter be strict controlled in optimal sorting scope, the production efficiency of cracking and sorting up to 15~20t/h.
The concrete processing technological flow of the provided device of the embodiment of the present invention is:
First, waste and old new forms of energy lithium-ion-power cell group obtains battery battery core through disassembling of early stage, carries out battery core again Electric discharge and the detection of performance, guarantee after detection that battery has been discharged to completely, enter back into breaker, detect underproof To discharge again;
The spiral blade disintegrating machine that battery battery core enters in breaker carries out break process, and constantly enters when broken Row alkali liquor sprays, and produces high temperature when preventing broken, and the electrolyte in battery core can also be neutralized by alkali liquor simultaneously, prevents electrolysis The Fluohydric acid. (HF) producing highly corrosive is decomposed in the volatilization of liquid;
This alkali liquor can be with cycling and reutilization, it is impossible to it is pending that the waste liquid of recycling enters waste collecting device;
The wet particle produced after Po Sui is through entering environment protection-type drying oven through crusher screen, to wet in environment protection-type drying oven Particle carries out drying the particle obtaining being dried, and the alkali liquor dissolved with electrolyte evaporates into gas collector collection process simultaneously, Dried particle is stored in particle holding vessel, reprocesses for the later stage.
In sum, the device that the embodiment of the present invention is provided has the advantage that
1) avoid battery battery core short-circuit fire when broken, reduce potential safety hazard;
2) solve electrolyte and air separation volatilization in battery shattering process and pollute the technical barrier of environment;
3) solve and manually disassemble that crushing efficiency is low, personal safety cannot be protected and hand breaking high in cost of production is asked Topic;
4) using blade type cutting machine, the cutting of spiral blade ensures battery battery core cutting uniformly, improves crushing efficiency, profit Sorting in later stage particle;
5) use the airtight drying oven of environment protection-type, the particle after broken dried, remove particle surface electrolyte and Alkali liquor, minimizing electrolyte, to the corrosion of equipment and the volatilization in air, protects environment, safe and reliable.
The above, the only present invention preferably detailed description of the invention, but protection scope of the present invention is not limited thereto, Any those familiar with the art in the technical scope of present disclosure, the change that can readily occur in or replace Change, all should contain within protection scope of the present invention.Therefore, protection scope of the present invention should be with claims Protection domain is as the criterion.

Claims (4)

1. an applying waste lithium ionic electrical core of power battery breaker, it is characterised in that described device includes that battery core stores Platform, conveyer belt, battery core disintegrating apparatus, alkali liquor mouth spray, spiral blade disintegrating machine, alkali liquor circulating tank, environment protection-type dry Dry stove, gas processing device, particle conveyer belt, control room, electro-motor and particle holding vessel, wherein:
Pending applying waste lithium ionic electrical core of power battery is stored temporarily in described battery core storage bed, stores up in described battery core Deposit and first this battery core discharged on platform, then to electric discharge after battery core detect, and by detection by after battery core pass through Described conveyer belt is delivered to described battery core disintegrating apparatus;
It is provided with alkali liquor mouth spray and spiral blade disintegrating machine in described battery core disintegrating apparatus, described spiral blade breaks Broken machine carries out break process to transmitting the battery core come;
During described spiral blade disintegrating machine carries out break process to battery core, described alkali liquor mouth spray constantly sprays Sig water;
The alkali liquor Recycling that described alkali liquor circulating tank will spray, is provided with detector in the inside of described alkali liquor circulating tank, Utilize this detector to detect electrolyte content and the alkali liquor pH value of alkali liquor in described alkali liquor circulating tank;
Particle after described spiral blade crusher in crushing processes is delivered in described environment protection-type drying oven, described Particle after break process is dried by environment protection-type drying oven, dries alkali liquor and the electrolyte of residual, the institute on surface State environment protection-type drying oven to be connected with described gas processing device;
Particle after described environment protection-type drying oven dried enters back into described particle conveyer belt, described particle carry Particle is delivered in described particle holding vessel to carry out to store standby by band;
Wherein, described conveyer belt and described particle conveyer belt are controlled to transmit crawler belt by described control room and electro-motor Velocity of rotation.
Applying waste lithium ionic electrical core of power battery breaker the most according to claim 1, it is characterised in that through described Particle diameter control after spiral blade disintegrating machine process is 25~30mm, and percentage of damage reaches 100%.
Applying waste lithium ionic electrical core of power battery breaker the most according to claim 1, it is characterised in that described spiral Spiral blade in formula blade disintegrating machine uses a plurality of arranged in parallel.
Applying waste lithium ionic electrical core of power battery breaker the most according to claim 1, it is characterised in that
Described environment protection-type drying oven uses hermetic design, and for being dried by the particle after break process, and baking temperature controls At 30~50 DEG C.
CN201610465314.8A 2016-06-23 2016-06-23 A kind of applying waste lithium ionic electrical core of power battery breaker Active CN106025414B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610465314.8A CN106025414B (en) 2016-06-23 2016-06-23 A kind of applying waste lithium ionic electrical core of power battery breaker

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610465314.8A CN106025414B (en) 2016-06-23 2016-06-23 A kind of applying waste lithium ionic electrical core of power battery breaker

Publications (2)

Publication Number Publication Date
CN106025414A true CN106025414A (en) 2016-10-12
CN106025414B CN106025414B (en) 2018-09-11

Family

ID=57087319

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610465314.8A Active CN106025414B (en) 2016-06-23 2016-06-23 A kind of applying waste lithium ionic electrical core of power battery breaker

Country Status (1)

Country Link
CN (1) CN106025414B (en)

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106424100A (en) * 2016-11-29 2017-02-22 哈尔滨巴特瑞资源再生科技有限公司 Scraped power lithium battery nitrogen-protection crushing equipment
CN106391267B (en) * 2016-11-29 2018-04-03 哈尔滨巴特瑞资源再生科技有限公司 One kind scraps the powered broken combination unit of lithium ion power lithium battery
CN108832220A (en) * 2018-08-15 2018-11-16 中科(菏泽)清洁能源研究院有限公司 A kind of closed waste mobile phone aluminum-shell battery device for disassembling
CN109290959A (en) * 2018-10-31 2019-02-01 株洲鼎端装备股份有限公司 A kind of waste and old power battery pack high pressure waterjet equipment
CN109449524A (en) * 2018-12-19 2019-03-08 吉林铁阳盛日循环科技有限公司 A kind of lithium ion battery crushing device
CN109669127A (en) * 2019-01-25 2019-04-23 格林美(武汉)新能源汽车服务有限公司 A kind of battery pack feeding detection system and method
CN109904549A (en) * 2019-03-28 2019-06-18 费晓平 A kind of safe forcible entry device of waste lithium cell
CN113501261A (en) * 2021-07-06 2021-10-15 柳文炎 Battery recovery system of electric automobile

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5632863A (en) * 1994-11-22 1997-05-27 Meador; W. R. Battery pyrolysis process
CN201010681Y (en) * 2007-02-14 2008-01-23 张�诚 Equipment for abstracting metal from waste circuit board
CN102029283B (en) * 2010-02-05 2012-07-25 伟翔环保科技发展(上海)有限公司 Recycling separation system of lithium battery component materials

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106424100A (en) * 2016-11-29 2017-02-22 哈尔滨巴特瑞资源再生科技有限公司 Scraped power lithium battery nitrogen-protection crushing equipment
CN106391267B (en) * 2016-11-29 2018-04-03 哈尔滨巴特瑞资源再生科技有限公司 One kind scraps the powered broken combination unit of lithium ion power lithium battery
CN108832220A (en) * 2018-08-15 2018-11-16 中科(菏泽)清洁能源研究院有限公司 A kind of closed waste mobile phone aluminum-shell battery device for disassembling
CN109290959A (en) * 2018-10-31 2019-02-01 株洲鼎端装备股份有限公司 A kind of waste and old power battery pack high pressure waterjet equipment
CN109449524A (en) * 2018-12-19 2019-03-08 吉林铁阳盛日循环科技有限公司 A kind of lithium ion battery crushing device
CN109449524B (en) * 2018-12-19 2023-12-12 吉林铁阳盛日循环科技有限公司 Lithium ion battery breaker
CN109669127A (en) * 2019-01-25 2019-04-23 格林美(武汉)新能源汽车服务有限公司 A kind of battery pack feeding detection system and method
CN109904549A (en) * 2019-03-28 2019-06-18 费晓平 A kind of safe forcible entry device of waste lithium cell
CN113501261A (en) * 2021-07-06 2021-10-15 柳文炎 Battery recovery system of electric automobile
CN113501261B (en) * 2021-07-06 2022-07-01 赣州知星科技合伙企业(有限合伙) Battery recycling system of electric automobile

Also Published As

Publication number Publication date
CN106025414B (en) 2018-09-11

Similar Documents

Publication Publication Date Title
CN106025414A (en) Crushing apparatus for waste lithium ion power battery cell
CN102017276B (en) Reutilization method of waste LiFeP04 power battery
CN103943911B (en) The method of waste and old lithium ion battery comprehensive reutilization
CN110061320A (en) A method of utilizing active powder material in cracking process recycling waste power lithium battery
CN103825065B (en) A kind of waste and old lithium ionic cell electrolyte recovery and treatment method
CN102029283B (en) Recycling separation system of lithium battery component materials
CN205680756U (en) A kind of applying waste lithium ionic electrical core of power battery disintegrating machine
CN105811041B (en) A kind of applying waste lithium ionic power battery recovery and processing system
CN110534834A (en) The recovery method of electrolyte in a kind of waste and old lithium ion battery
CN105826629A (en) All-component material separation and collection device and method for waste lithium batteries
CN105428745A (en) Method for comprehensive harmless recovery and utilization of waste lithium ion power battery
CN105870529A (en) Recovery method for waste lithium ion batteries
CN205609702U (en) Old and useless lithium cell complete set divides material separation collection device
CN107511950B (en) Surplus material recovery device is used in a kind of production of waste-tyre rubber-powder
KR20120126946A (en) Pretreatment method for recycling of lithium ion batteries
CN112275765B (en) Method for treating waste lithium battery diaphragm paper
CN107890937A (en) Processing equipment and its handling process are torn up in a kind of waste lithium cell recovery
CN210058558U (en) A shredding equipment for old and useless lithium cell is retrieved
CN105958150A (en) Comprehensive utilization method for waste lithium ion batteries
CN106207299A (en) A kind of waste and old Soft Roll electrokinetic cell disassembles breaker
CN106654431A (en) Disassembling and recycling process of power battery
CN112201872B (en) Safe discharge method and wet physical sorting method for retired batteries
CN205995569U (en) A kind of waste and old Ni-MH power cell breaker
CN104134830A (en) Method and apparatus for safe recovery of negative electrode of lithium ion battery
CN108879009A (en) A kind of oxygen-impermeable crack method of scrap lithium ion battery water proof

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant