CN107890937A - Processing equipment and its handling process are torn up in a kind of waste lithium cell recovery - Google Patents

Processing equipment and its handling process are torn up in a kind of waste lithium cell recovery Download PDF

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Publication number
CN107890937A
CN107890937A CN201711132986.8A CN201711132986A CN107890937A CN 107890937 A CN107890937 A CN 107890937A CN 201711132986 A CN201711132986 A CN 201711132986A CN 107890937 A CN107890937 A CN 107890937A
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CN
China
Prior art keywords
tunnel
transfer mechanism
discharging opening
hot air
baking oven
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201711132986.8A
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Chinese (zh)
Inventor
李艳艳
陈建清
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Guangzhou Bin Plastic Machinery Equipment Co Ltd
Original Assignee
Guangzhou Bin Plastic Machinery Equipment Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Guangzhou Bin Plastic Machinery Equipment Co Ltd filed Critical Guangzhou Bin Plastic Machinery Equipment Co Ltd
Publication of CN107890937A publication Critical patent/CN107890937A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B02CRUSHING, PULVERISING, OR DISINTEGRATING; PREPARATORY TREATMENT OF GRAIN FOR MILLING
    • B02CCRUSHING, PULVERISING, OR DISINTEGRATING IN GENERAL; MILLING GRAIN
    • B02C21/00Disintegrating plant with or without drying of the material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B02CRUSHING, PULVERISING, OR DISINTEGRATING; PREPARATORY TREATMENT OF GRAIN FOR MILLING
    • B02CCRUSHING, PULVERISING, OR DISINTEGRATING IN GENERAL; MILLING GRAIN
    • B02C18/00Disintegrating by knives or other cutting or tearing members which chop material into fragments
    • B02C18/06Disintegrating by knives or other cutting or tearing members which chop material into fragments with rotating knives
    • B02C18/14Disintegrating by knives or other cutting or tearing members which chop material into fragments with rotating knives within horizontal containers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B02CRUSHING, PULVERISING, OR DISINTEGRATING; PREPARATORY TREATMENT OF GRAIN FOR MILLING
    • B02CCRUSHING, PULVERISING, OR DISINTEGRATING IN GENERAL; MILLING GRAIN
    • B02C23/00Auxiliary methods or auxiliary devices or accessories specially adapted for crushing or disintegrating not provided for in preceding groups or not specially adapted to apparatus covered by a single preceding group
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B02CRUSHING, PULVERISING, OR DISINTEGRATING; PREPARATORY TREATMENT OF GRAIN FOR MILLING
    • B02CCRUSHING, PULVERISING, OR DISINTEGRATING IN GENERAL; MILLING GRAIN
    • B02C23/00Auxiliary methods or auxiliary devices or accessories specially adapted for crushing or disintegrating not provided for in preceding groups or not specially adapted to apparatus covered by a single preceding group
    • B02C23/08Separating or sorting of material, associated with crushing or disintegrating
    • B02C23/14Separating or sorting of material, associated with crushing or disintegrating with more than one separator
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B02CRUSHING, PULVERISING, OR DISINTEGRATING; PREPARATORY TREATMENT OF GRAIN FOR MILLING
    • B02CCRUSHING, PULVERISING, OR DISINTEGRATING IN GENERAL; MILLING GRAIN
    • B02C23/00Auxiliary methods or auxiliary devices or accessories specially adapted for crushing or disintegrating not provided for in preceding groups or not specially adapted to apparatus covered by a single preceding group
    • B02C23/08Separating or sorting of material, associated with crushing or disintegrating
    • B02C23/16Separating or sorting of material, associated with crushing or disintegrating with separator defining termination of crushing or disintegrating zone, e.g. screen denying egress of oversize material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B03SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03CMAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03C1/00Magnetic separation
    • B03C1/02Magnetic separation acting directly on the substance being separated
    • B03C1/30Combinations with other devices, not otherwise provided for
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B07SEPARATING SOLIDS FROM SOLIDS; SORTING
    • B07BSEPARATING SOLIDS FROM SOLIDS BY SIEVING, SCREENING, SIFTING OR BY USING GAS CURRENTS; SEPARATING BY OTHER DRY METHODS APPLICABLE TO BULK MATERIAL, e.g. LOOSE ARTICLES FIT TO BE HANDLED LIKE BULK MATERIAL
    • B07B1/00Sieving, screening, sifting, or sorting solid materials using networks, gratings, grids, or the like
    • B07B1/28Moving screens not otherwise provided for, e.g. swinging, reciprocating, rocking, tilting or wobbling screens
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/54Reclaiming serviceable parts of waste accumulators
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B02CRUSHING, PULVERISING, OR DISINTEGRATING; PREPARATORY TREATMENT OF GRAIN FOR MILLING
    • B02CCRUSHING, PULVERISING, OR DISINTEGRATING IN GENERAL; MILLING GRAIN
    • B02C23/00Auxiliary methods or auxiliary devices or accessories specially adapted for crushing or disintegrating not provided for in preceding groups or not specially adapted to apparatus covered by a single preceding group
    • B02C23/08Separating or sorting of material, associated with crushing or disintegrating
    • B02C23/16Separating or sorting of material, associated with crushing or disintegrating with separator defining termination of crushing or disintegrating zone, e.g. screen denying egress of oversize material
    • B02C2023/165Screen denying egress of oversize material
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/84Recycling of batteries or fuel cells

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  • Engineering & Computer Science (AREA)
  • Food Science & Technology (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

The present invention relates to waste lithium cell recovery technology field,Disclose a kind of waste lithium cell recovery and tear up processing equipment and its handling process,Including physical decomposition equipment,Second cyclopentane gas detector,Tunnel-type hot air circulates baking oven,Pulverizer,Vibrating screener,Cyclone separator below vibrating screener,En-masse conveyer,Mutually transmitted and connected by screw rod conveyor between the physical decomposition equipment and the second cyclopentane gas detector,Second cyclopentane gas detector connects with tunnel-type hot air circulation baking oven transmission,Tunnel-type hot air circulates baking oven and connected with pulverizer transmission,Pulverizer connects with vibrating screener transmission,Vibrating screener connects with cyclone separator,Cyclone separator connects with en-masse conveyer,Broken decomposition is carried out to reach safety to lithium battery,Extremely environmentally friendly purpose in processing waste lithium cell and the processing removal process of can in high volume going into operation.

Description

Processing equipment and its handling process are torn up in a kind of waste lithium cell recovery
Technical field
The present invention relates to waste lithium cell recovery technology field, is torn up in particular to a kind of recovery of waste lithium cell Processing equipment and its handling process.
Background technology
Old and useless battery, which recycles, refers to used battery to be reused by recovery, domestic most commonly used industry Battery is lead accumulator, and lead accounts for battery totle drilling cost more than 50%, mainly takes pyrogenic process, hydrometallurgical processes and Solid phase electrolysis Reduction technique.Shell is plastics, can regenerate, realize non-secondary pollution substantially.Small-sized secondary batteries using it is more have NI-G, Ni-mh and lithium ion battery, the cadmium in nickel-cadmium cell is one of heavy metal element that environmental protection strictly controls, in lithium ion battery Organic bath, alkali in NI-G, Ni-MH battery and manufactures the heavy metals such as the auxiliary material copper of battery, all forms the dirt to environment Dye.Small-sized secondary batteries use total amount domestic at present only has several hundred million, and most of small volumes, refuse battery value compared with Low, scattered plus using, the overwhelming majority makees domestic rubbish disposal, and it is reclaimed there is the problem of cost and management aspect, is regenerated Using there is also certain technical problem.
The old and useless battery treatment mode of generally use substantially has three kinds:Solidify it is buried, deposit in abandoned mine well, recycle, Do that lithium battery recovery is most of to use fractionation in the market, its handling process is as follows:Included metal ingredient point From to reach recycling, but pollution of the fractionation to environment and water has the drawbacks of very big, it is impossible to reaches Corresponding environmental requirement, it is also not suitable for large batch of production.
What some did is the broken apart method of physics, but broken apart method will be in process of production due to that will give up at present Old lithium battery is directly placed into the inside of crushing chamber, and spark is easily produced so as to send out in the extruding, shattering process in crushing cutter Raw explosion phenomenon, extremely hazardous for the staff of waste and old processing, dust exhaust emission is also quite serious, lacks corresponding powder Dirt processing system, dust, which is largely emitted into air, to be caused in removal process extremely not environmentally.
The content of the invention
In order to solve the above technical problems, the invention provides a kind of recovery of waste lithium cell to tear up processing equipment and its processing Technique carries out broken decomposition to reach safety to lithium battery, can in high volume go into operation processing waste lithium cell and processing removal process In extremely environmentally friendly purpose, solve do not reach during existing recycling environmental requirement, can not carry out it is large batch of The problem of security incident easily occurs for production and recycling process.
In order to realize above-mentioned technique effect, technical scheme provided by the present invention is:A kind of waste lithium cell recovery is torn up Processing equipment, including physical decomposition equipment, the second cyclopentane gas detector, tunnel-type hot air circulation baking oven, pulverizer, vibration screening Machine, cyclone separator, en-masse conveyer, the physical decomposition equipment include water tank, the first cyclopentane gas detector and screw rod transmission Machine, first cyclopentane gas detector include tearing up room and motor, described to tear up room and motor is respectively placed in water tank In water and above the water surface, and tear up room and be mutually connected with motor;The discharging opening for tearing up room is torn up with the second twin shaft Connection, the discharging opening and tunnel-type hot air of the second cyclopentane gas detector are mutually transmitted by the screw rod conveyor between the charging aperture of machine The charging port transmission connection of baking oven is circulated, the discharging opening of tunnel-type hot air circulation baking oven connects with the charging port transmission of pulverizer, The discharging opening of pulverizer connects with the charging port transmission of vibrating screener, the discharging opening of vibrating screener and en-masse conveyer Charging aperture connects;Strong magnets corresponding thereto are provided with above the internal transport channel of the en-masse conveyer;The rotation The material sucking port of wind separator is located above the screen cloth of the vibrating screener.
Further, it is in addition to the first transfer mechanism, the second transfer mechanism, the 3rd transfer mechanism, the 4th automatic Conveyer, the 5th transfer mechanism, the feed end top of first transfer mechanism are provided with feed hopper, and its discharge end is located at institute Above the charging aperture for stating the first cyclopentane gas detector;The feed end and discharge end of second transfer mechanism respectively with the screw rod The discharging opening of conveyer and the connection of the charging aperture of the second cyclopentane gas detector;The feed end and discharge end of 3rd transfer mechanism The charging aperture for circulating baking oven with the discharging opening and tunnel-type hot air of the second cyclopentane gas detector respectively connects;4th automatic transport Discharging opening of the feed end and discharge end of machine respectively with tunnel-type hot air circulation baking oven connects with the charging port transmission of pulverizer;Institute The feed end and discharge end for stating the 5th transfer mechanism connect with the discharging opening of pulverizer with the charging aperture of vibrating screener respectively.
Further, the tunnel-type hot air circulation baking oven includes the first tunnel-type hot air circulation baking oven and the second tunnel type Heated-air circulation oven, the discharging opening and the second tunnel-type hot air circulation baking oven charging aperture of the first tunnel-type hot air circulation baking oven Between pass through the 6th transfer mechanism transmission connection.
Further, in addition to filter cartridge dust remover, the charging aperture of the dust-exhausting port of the pulverizer and the filter cartridge dust remover It is connected.
Further, it is described tear up chamber interior rotate be provided with the first chopping rotor and with first chopping rotor drive connection Second chopping rotor, the motor pass through chain with described first chopping rotor be connected.
Further, first cyclopentane gas detector and the second cyclopentane gas detector are made of stainless steel material.
The invention also discloses the handling process that a kind of recovery of waste lithium cell is torn up, the handling process is applied to above-mentioned Waste lithium cell recovery tear up processing equipment, including following processing step:
(1) waste and old lithium battery is subjected to discharge process;
(2) DECOMPOSED OPTIMIZATION:The material of step (1) is passed through into the first transfer mechanism transmission transport to the first cyclopentane gas detector Charging aperture in, and the room of tearing up of the first cyclopentane gas detector is placed in water and carries out preliminary exposition, and the first cyclopentane gas detector goes out The material of material mouth discharge is transmitted to the second transfer mechanism by screw rod conveyor;
(3) broken differentiation in:Second transfer mechanism is by the charging aperture of the material transferring of step (2) to the second cyclopentane gas detector It is interior, and carry out it is secondary tear up, the discharging opening through the second cyclopentane gas detector is emitted into the feed end of the 3rd transfer mechanism;
(4) nickel Cobalt lithiums material forms optimization:
A. the discharge of materials of step (3) to the first tunnel-type hot air is circulated baking oven by the discharge end of the 3rd transfer mechanism In charging aperture and preliminary high temperature drying is carried out, the discharging opening of the first tunnel-type hot air circulation baking oven is defeated by the 6th transfer mechanism Deliver in the charging aperture of the second tunnel-type hot air circulation baking oven and carry out secondary high-temperature drying;
B. the discharging opening of the second tunnel-type hot air circulation baking oven is conveyed the material in step a by the 4th transfer mechanism Into pulverizer, crushing fine powder is carried out to material;
(5) material forms optimization:The discharging opening of pulverizer is delivered to entering for vibrating screener by the 5th transfer mechanism In material mouth, nickel, Cobalt, lithium dressing sieve are selected and by space encapsulations by vibrating screener, and above the screen cloth of vibrating screener Material sucking port provided with the cyclone separator, cyclone separator is broken to film/paper to carry out separating discharge and passes through space encapsulation;
(6) closed automatic transport separation:En-masse conveyer is by its internal strong magnets for step (5) output Material in carry out iron powder separation, and iron powder is packaged by space bag;
(7) copper, nickel, aluminium packing:The output material conveying of step (6) is discharged and copper, nickel, aluminium flake entered by space bag Row encapsulation.
Further, the pulverizer in the step (4) is circumscribed with filter cartridge dust remover, row of the filter cartridge dust remover to pulverizer Dirt mouth carries out dust-filtering.
Further, the vibrating screener in the step (5) includes the first vibrating screener and the second vibrating screener, The discharging opening of first vibrating screener connects with the charging aperture of the second vibrating screener, and the discharging of the second vibrating screener Mouth connects with the charging aperture of the cyclone separator.
Compared to prior art, the beneficial effects of the invention are as follows:
1. the novel physical separation method of the present invention is used for lithium battery recovery industry, by DECOMPOSED OPTIMIZATION system by lithium battery Carry out broken process is placed in water, can either prevent from polluting, turn avoid during physics is broken, because of high temperature or generation Spark and explode, and the danger of blast when existing physics tears up broken lithium battery in existing market all be present, for The threat of security be present in staff;
2. the product of our company's production can in high volume go into operation and (can handle waste lithium cell about 400kg per hour), relatively All can in high volume it be gone into operation in battery recycling industry in existing fractionation and other physical partition methods;
3. the application optimizes to be formed in system in nickel Cobalt lithium materials circulates baking oven, the second tunnel by the first tunnel-type hot air Formula heated-air circulation oven carries out high temperature baking operation to material respectively, and the lithium battery fragment containing moisture is carried out thoroughly high temperature Drying, good processing guarantee is provided for the precious metal element in follow-up refinement material;
4. the present invention need to strictly be controlled and torn up when broken Differentiation System carries out processing raw material with by DECOMPOSED OPTIMIZATION system The time of material and outputting material is set, and ensures that excessive waste gas will not be produced to cause air ambient to pollute in production, and Complete machine is made using stainless steel, and the recovery processing for waste lithium cell has etch-proof effect;
5. the application enters one in the process of crushing, using dust treatment system to dust caused by crushing machining Walk and filtering emission is carried out to the dust during recycling, the dust during the recycling of old and useless battery is arranged with realizing The effective management and control of row is put into, to meet the discharge standard of national regulation.
Brief description of the drawings
Fig. 1 is the overall structure diagram that processing equipment is torn up in waste lithium cell recovery provided by the invention;
Fig. 2 is the structural representation that physical decomposition equipment in processing equipment is torn up in waste lithium cell recovery provided by the invention Figure;
Fig. 3 is the structural representation that cyclone separator in processing equipment is torn up in waste lithium cell recovery provided by the invention;
Fig. 4 is the structural representation that space bag support in processing equipment is torn up in waste lithium cell recovery provided by the invention;
Fig. 5 is the process chart for the handling process that waste lithium cell recovery provided by the invention is torn up.
Embodiment
The present invention is further described in detail with reference to specific embodiment, following word is intended to indicate that this hair Protection domain that is bright, being not intended to limit the present invention.
As Figure 1-Figure 5, the present invention can be implemented as follows, and a kind of waste lithium cell recovery is torn up processing and set It is standby, including physical decomposition equipment 2, the second cyclopentane gas detector 4, tunnel-type hot air circulation baking oven, pulverizer 11, vibrating screener 13rd, the cyclone separator 14 corresponding with vibrating screener 13, en-masse conveyer 15, the physical decomposition equipment 2 include water Case, the first cyclopentane gas detector and screw rod conveyor, first cyclopentane gas detector includes tearing up room and motor 18, described to tear Broken room and motor 18 are respectively placed in the water of water tank and water surface top, and tears up room and the drive connection of the phase of motor 18; Mutually transmitted and connected by the screw rod conveyor between the discharging opening for tearing up room and the charging aperture of the second cyclopentane gas detector 4, The charging aperture of the screw rod conveyor is below the discharging opening for tearing up room, due to carrying out tearing up the waste and old of processing in water The noble metal fragment of battery can directly be drowned into bottom and be transmitted by the screw rod conveyor of lower section be delivered to it is next In manufacturing procedure, the discharging opening of the second cyclopentane gas detector 4 connects with the charging port transmission of tunnel-type hot air circulation baking oven, tunnel type Heated-air circulation oven carries out high temperature drying to the lithium battery fragment containing moisture, and tunnel-type hot air circulates the discharging opening and powder of baking oven The charging port transmission connection of broken machine 11, the discharging opening of pulverizer 11 connect with the charging port transmission of vibrating screener 13, pulverizer The lithium battery fragment of 11 pairs of upper processes carries out ultra-fine grinding processing, i.e. pulverizer 11 is by between active disc and fixation cutter head High speed relative motion, make pulverized material through impact, shearing, friction and the material between active disc and solid cutterhead to each other The comprehensive function such as shock obtain the crushing of material;The vibrating screener 13 includes screening frame, in screening frame Screen cloth, the screen cloth top of the vibrating screener 13 are provided with the material sucking port 17 of the cyclone separator 14, and cyclone separator 14 is right The lighter paper scrap or film mixed in material carries out separation discharge, mixes the light material in material in vibrating screener 13 Emersion surface under strength effect of vibration, it can be sucked into the material sucking port 17 of the cyclone separator 14, vibrating screener 13 Discharging opening connects with the charging aperture of en-masse conveyer 15;Be provided with above the internal transport channel of the en-masse conveyer 15 with Its corresponding strong magnets, the strong magnets use the strong magnets of 10000 Gausses, can isolate the iron in material Come.In actual production process, wherein, the material of the discharging opening discharge of en-masse conveyer 15 can enter to eddy current separator In 16, the operation principle of the eddy current separator 16 is as follows:Produced using conductor in high-frequency alternating magnetic field faradic What principle was designed, during work, the magnetic field of high-frequency alternating is produced on sorting magnetic roller surface, when conductive non-ferrous metal passes through When crossing magnetic field, vortex flow can be induced in non-ferrous metal, this vortex flow can produce the magnetic field opposite with magnetic field in itself, If non-ferrous metal (such as copper, aluminium etc.) can because of magnetic field repulsive force effect and be leaped forward along its transporting direction, realize and other The separation of non-conductor thing or non-metal kind material, reach the purpose of sorting.
The en-masse conveyer 15 includes automatic delivering mechanism and the roller being coated on outside automatic delivering mechanism, described Automatic delivering mechanism includes conveyer belt and drives the carrying roller of conveyer belt motion, and the inside of the roller is provided with corresponding with conveyer belt The strong magnets, strong magnets can carry out adsorbing separation to the iron powder that is transmitted on conveyer belt, and the iron powder separated leads to Space bag 19 is crossed to be packaged it.
The operation principle of the cyclone separator 14 is as follows:Material is discharged by the discharging opening of the vibrating screener 13 When, cyclone separator 14 will gently expect that (film/paper broken etc.) enters cyclone separation, when light material (film/paper broken etc.) enters whirlwind After separating pipe, air-flow is produced strong rotation by the guide functions of guide vane, and air-flow is twist downwardly into rotation along cylinder Air duct body, light material (film/paper broken etc.) is thrown toward wall under the action of the centrifugal force, and under gravity, is fallen along barrel defeated Go out, the air-flow of rotation, to center flow, is upwardly formed secondary vortex flow and exported through equipment top exit in cylinder contract.
The operation principle of the vibrating screener 13 is as follows:Linear vibrating screen by the use of vibrating motor exciting as vibration source, Material is set to be tossed on screen cloth, while for linear motion forward, charging aperture of the material from batcher evenly into screening machine, The oversizes of several specifications, screenings are produced, respectively from respective outlet discharge by multilayer screen cloth.With the low, yield that consumes energy High, simple in construction, easy-maintaining, full-closed structure, no dust, which overflows, to be dissipated, and carries out automatic discharge.
Also include the first transfer mechanism 1, the second transfer mechanism 3, the 3rd transfer mechanism 5, the 4th transfer mechanism 9th, the 5th transfer mechanism 12, the feed end top of first transfer mechanism 1 are provided with feed hopper, and its discharge end is positioned at described Above the charging aperture of first cyclopentane gas detector;The feed end and discharge end of second transfer mechanism 3 respectively with the screw rod The discharging opening of conveyer and the connection of the charging aperture of the second cyclopentane gas detector 4;The feed end of 3rd transfer mechanism 5 and discharging The charging aperture that baking oven is circulated at end with the discharging opening and tunnel-type hot air of the second cyclopentane gas detector 4 respectively connects;Described 4th is automatic The feed end and discharge end of conveyer 9 circulate the charging port transmission of the discharging opening and pulverizer 11 of baking oven with tunnel-type hot air respectively Connection;The feed end and discharge end of 5th transfer mechanism 12 respectively with the discharging opening of pulverizer 11 and vibrating screener 13 Charging aperture connection.
The tunnel-type hot air circulation baking oven includes the circulation baking oven 6 and second tunnel-type hot air circulation of the first tunnel-type hot air Baking oven 8, between the discharging opening and the second tunnel-type hot air circulation charging aperture of baking oven 8 of the first tunnel-type hot air circulation baking oven 6 Transmitted and connected by the 6th transfer mechanism 7, the first tunnel-type hot air circulation baking oven 6 and second tunnel-type hot air circulation baking oven 8 Carry out preliminary drying and processing and secondary drying optimization respectively to material.First tunnel-type hot air circulates the tunnel type of baking oven 6 and second The operation principle of heated-air circulation oven 8 is as follows:When material is during device interior is conveyed, while machine internal is installed There are electrothermal tube and blower fan;Electrothermal tube produces hot blast and is applied on raw material, and caused hot moisture is blown into recover, recover Interior to be provided with cleaner, by the dust-filtering containing band in hot blast, outside moisture natural evaporation discharge machine, clean hot blast is again by blower fan Circulation work in machine is blown back, reaches the effect that circulating-heating drying is carried out to material.
Also include filter cartridge dust remover 10, the charging aperture phase of the dust-exhausting port of the pulverizer 11 and the filter cartridge dust remover 10 Even.The dust of the dust-exhausting port discharge of the pulverizer 11 is entered by the side of the middle cylinder body of filter cartridge dust remover 10, and dust is by the filter After filter cylinder retention inside cylinder deduster 10, clean gas is discharged in air through filter cylinder by exhaust duct.With filtering operating mode Progress, when filter cartridge dust remover 10 operation reach certain time when, open filter cartridge dust remover 10 inside electromagnetic impulse valve progress Injection, shakes off the dust on filter cylinder and fiber and enters in dust stratification bucket;When laying dust reaches a certain amount of in dust stratification bucket, shut down with Tear clear dust stratification bucket open.
It is described tear up chamber interior and rotate be provided with the first chopping rotor and second cut with the first chopping rotor drive connection Broken rotor, the motor 18 are connected by chain and the described first chopping rotor, the first chopping rotor and the Two chopping rotors rotate to be arranged at by stainless steel bearing to be torn up on room, and the first chopping rotor and second shreds the relative of rotor Rotation carries out tearing up treatment process to reach to old and useless battery.As preferable, can be installed additional on the stainless steel bearing and its The bearing sealed ring being adapted, bearing sealed ring prevent the water for tearing up pollution from entering stainless steel bearing, and stainless steel bearing is produced Raw damage.
First cyclopentane gas detector and the second cyclopentane gas detector 4 are made of stainless steel material, can be prevented to useless Used batteries play etch-proof effect during being recycled;First cyclopentane gas detector and the second cyclopentane gas detector 4 chamber interior of tearing up shreds rotor matching design, the first shredder bar using shearing the first chopping rotor and second of double-pole Roller and the second chopping rotor are torn up in the case where the transmission of motor 18 drives to waste and old lithium battery.
As preferable, above-described first transfer mechanism 1, the second transfer mechanism 3, the 3rd transfer mechanism 5, 4th transfer mechanism 9, the 5th transfer mechanism 12 and the 6th transfer mechanism 7 are by the way of belt transmission, its work It is as follows to make principle:Conveyer belt is tensed by drive device, middle part framework and carrying roller composition conveyer belt are used as traction and bearing carrier With continuous conveying material.
The invention also discloses the handling process that a kind of recovery of waste lithium cell is torn up, it is characterised in that the processing work Skill is applied to above-mentioned waste lithium cell recovery and tears up processing equipment, including following processing step:
(1) waste and old lithium battery is subjected to discharge process;
(2) DECOMPOSED OPTIMIZATION:The material of step (1) is torn up by the first transfer mechanism 1 transmission transport to the first twin shaft In the charging aperture of machine, and the room of tearing up of the first cyclopentane gas detector is placed in water and carries out preliminary exposition and is torn up, the first twin shaft is torn The material of the discharging opening discharge of broken machine is transmitted to the second transfer mechanism 3 by screw rod conveyor below;
(3) broken differentiation in:Charging of second transfer mechanism 3 by the material transferring of step (2) to the second cyclopentane gas detector 4 It is intraoral, and carry out it is secondary tear up, the discharging opening through the second cyclopentane gas detector 4 is emitted into the feed end of the 3rd transfer mechanism 5;By In it is secondary tear up be lithium battery fragment caused by step (2) and itself have substantial amounts of moisture, so in the second twin shaft The secondary generation torn up and just will not cause the security incident such as spontaneous combustion and blast is carried out in shredder 4.
(4) nickel Cobalt lithiums material forms optimization:
A. the discharge of materials of step (3) to the first tunnel-type hot air is circulated baking oven 6 by the discharge end of the 3rd transfer mechanism 5 Charging aperture in and carry out preliminary high temperature drying, the discharging opening of the first tunnel-type hot air circulation baking oven 6 passes through the 6th automatic transport Machine 7 is delivered in the charging aperture of the second tunnel-type hot air circulation baking oven 8 and carries out secondary high-temperature drying again;
B. the discharging opening of the second tunnel-type hot air circulation baking oven 8 is defeated by the material in step a by the 4th transfer mechanism 9 Deliver in pulverizer 11, crushing fine powder is carried out to material;
(5) material forms optimization:The discharging opening of pulverizer 11 is delivered to vibrating screener by the 5th transfer mechanism 12 In 13 charging aperture, nickel, Cobalt, lithium dressing sieve are selected and encapsulated by space bag 19 by vibrating screener 13, and in vibrating screener The material sucking port 17 of the cyclone separator 14 is provided with above 13 screen cloth, cyclone separator 14 is broken to film/paper to carry out separation row Go out and encapsulated by space bag 19;
(6) closed automatic transport separation:En-masse conveyer 15 is produced by its internal strong magnets for step (5) Iron powder separation is carried out in the material gone out, and iron powder is packaged by space bag 19;
(7) copper, nickel, aluminium packing:The output material conveying of step (6) is discharged and copper, nickel, aluminium flake entered by space bag Row encapsulation.
In actual production or processing procedure, the output material after step (7) encapsulates can be delivered to eddy current separation In machine 16, the copper in material, nickel, aluminium powder are carried out separation discharge by eddy current separator 16, and by space bag 19 respectively to copper, Nickel, aluminium powder are packaged.
As preferable, the pulverizer 11 in the step (4) is circumscribed with filter cartridge dust remover 10, and filter cartridge dust remover 10 is to powder The dust-exhausting port of broken machine 11 carries out dust-filtering.The inner parameter of filter cartridge dust remover 10 setting is as follows:Its internal compressed air Pressure be preferably adjusted to 4-5kg/cm2, compressed air pressure is the setting value for the most standard that can meet deashing functional requirement. The setting value of compressed air pressure is smaller, and the air consumption of pulse valve is smaller, and pulsation blowing control instrument is typically adjustable to 25S cleanings One row filter core;(such as ash quantity is less, pulse spacing duration can be adjusted long point, such as 50S/60S etc.;Conversely, such as ash quantity is larger, Pulse spacing duration can be adjusted short point, such as 15S/10S etc.).
As preferable, the vibrating screener 13 in the step (5) includes the first vibrating screener and the second vibratory sieve Machine is selected, the discharging opening of first vibrating screener connects with the charging aperture of the second vibrating screener, and the second vibrating screener Discharging opening connected with the charging aperture of the cyclone separator 14, pass through the first vibrating screener and the second vibrating screener and distinguish The process that preliminary screening and double optimization screening are carried out to the nickel in material, Cobalt, lithium powder, twice in time to sieve in screening process Nickel, Cobalt, the lithium powder elected are packaged by space bag 19.
As preferable, the outside of the space bag 19 is provided with the space bag support 20 supported, space bag branch Frame 20 is positioned over the opening position for needing to be packaged to material.
Any one skilled in the art the invention discloses technical scope in, can readily occur in change or Replace, should all be included within the scope of the present invention.Therefore, protection scope of the present invention should be with the guarantor described in claim Shield scope is defined.

Claims (9)

1. processing equipment is torn up in a kind of waste lithium cell recovery, it is characterised in that is torn up including physical decomposition equipment, the second twin shaft Machine, tunnel-type hot air circulation baking oven, pulverizer, vibrating screener, cyclone separator, en-masse conveyer, the physical decomposition Equipment includes water tank, the first cyclopentane gas detector and screw rod conveyor, and first cyclopentane gas detector includes tearing up room and driving electricity Machine, it is described tear up room and motor be respectively placed in the water of water tank and the water surface above, and tear up room and be mutually driven with motor Connection;Pass through the screw rod conveyor mutually company of transmission between the discharging opening for tearing up room and the charging aperture of the second cyclopentane gas detector Logical, the discharging opening of the second cyclopentane gas detector connects with the charging port transmission of tunnel-type hot air circulation baking oven, tunnel-type hot air circulation The discharging opening of baking oven connects with the charging port transmission of pulverizer, and the discharging opening of pulverizer and the charging port transmission of vibrating screener connect Logical, the discharging opening of vibrating screener connects with the charging aperture of en-masse conveyer;The delivered inside of the en-masse conveyer is led to Strong magnets corresponding thereto are provided with above road;The material sucking port of the cyclone separator is located at the screen cloth of the vibrating screener Top.
2. processing equipment is torn up in waste lithium cell recovery according to claim 1, it is characterised in that also automatic including first Conveyer, the second transfer mechanism, the 3rd transfer mechanism, the 4th transfer mechanism, the 5th transfer mechanism, described first certainly Feed hopper is provided with above the feed end of dynamic conveyer, its discharge end is located above the charging aperture of first cyclopentane gas detector;Institute State the feed end and the discharge end discharging opening and the second cyclopentane gas detector with the screw rod conveyor respectively of the second transfer mechanism Charging aperture connection;The feed end and discharge end of 3rd transfer mechanism respectively with the discharging opening of the second cyclopentane gas detector and The charging aperture connection of tunnel-type hot air circulation baking oven;The feed end and discharge end of 4th transfer mechanism respectively with tunnel type The discharging opening of heated-air circulation oven connects with the charging port transmission of pulverizer;The feed end of 5th transfer mechanism and discharging End connects with the discharging opening of pulverizer with the charging aperture of vibrating screener respectively.
3. processing equipment is torn up in waste lithium cell recovery according to claim 1, it is characterised in that the tunnel-type hot air Circulating baking oven includes the first tunnel-type hot air circulation baking oven and the second tunnel-type hot air circulation baking oven, first tunnel-type hot air Circulate to transmit by the 6th transfer mechanism between the discharging opening of baking oven and the second tunnel-type hot air circulation baking oven charging aperture and connect.
4. processing equipment is torn up in waste lithium cell recovery according to claim 1, it is characterised in that also including filtering drum dust removing Device, the dust-exhausting port of the pulverizer are connected with the charging aperture of the filter cartridge dust remover.
5. processing equipment is torn up in waste lithium cell recovery according to claim 1, it is characterised in that described to tear up chamber interior Rotate and be provided with the first chopping rotor and the second chopping rotor with the first chopping rotor drive connection, the motor passes through Chain and the described first chopping rotor drive connection.
6. processing equipment is torn up in waste lithium cell recovery according to claim 1, it is characterised in that first twin shaft is torn Broken machine and the second cyclopentane gas detector are made of stainless steel material.
7. the handling process that a kind of waste lithium cell recovery is torn up, it is characterised in that the handling process is applied to claim Processing equipment, including following processing step are torn up in waste lithium cell recovery described in 1-6 any one:
(1) waste and old lithium battery is subjected to discharge process;
(2) DECOMPOSED OPTIMIZATION:The material of step (1) is transmitted into transport entering to the first cyclopentane gas detector by the first transfer mechanism In material mouth, and the room of tearing up of the first cyclopentane gas detector is placed in water and carries out preliminary exposition, the discharging opening of the first cyclopentane gas detector The material of discharge is transmitted to the second transfer mechanism by screw rod conveyor;
(3) broken differentiation in:Second transfer mechanism by the charging aperture of the material transferring of step (2) to the second cyclopentane gas detector, And carry out it is secondary tear up, the discharging opening through the second cyclopentane gas detector is emitted into the feed end of the 3rd transfer mechanism;
(4) nickel Cobalt lithiums material forms optimization:
A. the discharge end of the 3rd transfer mechanism circulates the discharge of materials of step (3) to the first tunnel-type hot air the charging of baking oven Intraoral and carry out preliminary high temperature drying, the discharging opening of the first tunnel-type hot air circulation baking oven is delivered to by the 6th transfer mechanism The charging aperture of second tunnel-type hot air circulation baking oven is interior and carries out secondary high-temperature drying;
B. the material in step a is delivered to powder by the discharging opening of the second tunnel-type hot air circulation baking oven by the 4th transfer mechanism In broken machine, crushing fine powder is carried out to material;
(5) material forms optimization:The discharging opening of pulverizer is delivered to the charging aperture of vibrating screener by the 5th transfer mechanism Interior, nickel, Cobalt, lithium dressing sieve are selected and by space encapsulations by vibrating screener, and are provided with above the screen cloth of vibrating screener The material sucking port of the cyclone separator, cyclone separator is broken to film/paper to carry out separating discharge and passes through space encapsulation;
(6) closed automatic transport separation:Thing of the en-masse conveyer by its internal strong magnets for step (5) output Iron powder separation is carried out in material, and iron powder is packaged by space bag;
(7) copper, nickel, aluminium packing:The output material conveying of step (6) is discharged and copper, nickel, aluminium flake sealed by space bag Dress.
8. the handling process that waste lithium cell recovery according to claim 7 is torn up, it is characterised in that the step (4) In pulverizer be circumscribed with filter cartridge dust remover, filter cartridge dust remover carries out dust-filtering to the dust-exhausting port of pulverizer.
9. the handling process that waste lithium cell recovery according to claim 7 is torn up, it is characterised in that the step (5) In vibrating screener include the first vibrating screener and the second vibrating screener, the discharging opening of first vibrating screener with The charging aperture connection of second vibrating screener, and the charging aperture of the discharging opening of the second vibrating screener and the cyclone separator connects It is logical.
CN201711132986.8A 2017-09-20 2017-11-15 Processing equipment and its handling process are torn up in a kind of waste lithium cell recovery Pending CN107890937A (en)

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CN109037824A (en) * 2018-08-08 2018-12-18 广州市联冠机械有限公司 A kind of system and its recovery process for old and useless battery material recovery
CN109046720A (en) * 2018-08-20 2018-12-21 绵阳鼎天机电科技有限公司 A kind of waste lithium cell freezing crushing and the complexes and method of metal sorting
CN109092868A (en) * 2018-10-30 2018-12-28 江西省庭发再生能源有限公司 A kind of house refuse environmental protection treatment regeneration energy resource system and technique
CN109174293A (en) * 2018-09-20 2019-01-11 王志强 A kind of waste power lithium battery core material electromagnetism combined sorting equipment
CN109226185A (en) * 2018-09-13 2019-01-18 如东中惠再生资源有限公司 Paint slag recycling system device and its production technology
CN110124815A (en) * 2019-04-29 2019-08-16 浙江华友钴业股份有限公司 A kind of lithium ion battery electrification pre-processing device and method
CN110496689A (en) * 2019-06-27 2019-11-26 广州市联冠机械有限公司 A kind of system for old and useless battery material recovery
CN112820969A (en) * 2020-12-22 2021-05-18 深圳清华大学研究院 Charged crushing method and device for waste lithium ion power battery
CN113477684A (en) * 2021-07-29 2021-10-08 安徽巡鹰新能源集团有限公司 Integrative mobile device is torn up in electrified of lithium cell
CN114308347A (en) * 2022-01-14 2022-04-12 张金庆 Automatic production line and process for extracting lithium battery anode
CN117754776A (en) * 2024-02-22 2024-03-26 辽宁龙源新能源发展有限公司 Smashing device and recycling system for waste wind power blades
EP4417313A1 (en) * 2023-02-15 2024-08-21 Ha Baik Lee Lithium-ion battery cathode material recovery system and lithium-ion battery cathode material recovery method using
WO2024169003A1 (en) * 2023-02-14 2024-08-22 广东邦普循环科技有限公司 Lithium battery recovery device

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CN205236131U (en) * 2015-12-07 2016-05-18 湖南万容科技股份有限公司 Broken line of old and useless refrigerator
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CN109037824A (en) * 2018-08-08 2018-12-18 广州市联冠机械有限公司 A kind of system and its recovery process for old and useless battery material recovery
CN109037824B (en) * 2018-08-08 2023-08-08 广州市联冠机械有限公司 System for recycling waste battery materials and recycling process thereof
CN109046720A (en) * 2018-08-20 2018-12-21 绵阳鼎天机电科技有限公司 A kind of waste lithium cell freezing crushing and the complexes and method of metal sorting
CN109226185A (en) * 2018-09-13 2019-01-18 如东中惠再生资源有限公司 Paint slag recycling system device and its production technology
CN109174293A (en) * 2018-09-20 2019-01-11 王志强 A kind of waste power lithium battery core material electromagnetism combined sorting equipment
CN109092868A (en) * 2018-10-30 2018-12-28 江西省庭发再生能源有限公司 A kind of house refuse environmental protection treatment regeneration energy resource system and technique
CN109092868B (en) * 2018-10-30 2024-03-26 江西省庭发再生能源有限公司 A renewable energy system and process for environmentally friendly treatment of domestic waste
CN110124815B (en) * 2019-04-29 2024-08-06 浙江华友钴业股份有限公司 Lithium ion battery charged pretreatment equipment and method
CN110124815A (en) * 2019-04-29 2019-08-16 浙江华友钴业股份有限公司 A kind of lithium ion battery electrification pre-processing device and method
CN110496689A (en) * 2019-06-27 2019-11-26 广州市联冠机械有限公司 A kind of system for old and useless battery material recovery
CN110496689B (en) * 2019-06-27 2024-07-30 广州市联冠机械有限公司 System for be used for old and useless battery material to retrieve
CN112820969A (en) * 2020-12-22 2021-05-18 深圳清华大学研究院 Charged crushing method and device for waste lithium ion power battery
CN112820969B (en) * 2020-12-22 2022-05-31 深圳清华大学研究院 Charged crushing method and device for waste lithium ion power battery
CN113477684A (en) * 2021-07-29 2021-10-08 安徽巡鹰新能源集团有限公司 Integrative mobile device is torn up in electrified of lithium cell
CN114308347A (en) * 2022-01-14 2022-04-12 张金庆 Automatic production line and process for extracting lithium battery anode
WO2024169003A1 (en) * 2023-02-14 2024-08-22 广东邦普循环科技有限公司 Lithium battery recovery device
EP4417313A1 (en) * 2023-02-15 2024-08-21 Ha Baik Lee Lithium-ion battery cathode material recovery system and lithium-ion battery cathode material recovery method using
CN117754776A (en) * 2024-02-22 2024-03-26 辽宁龙源新能源发展有限公司 Smashing device and recycling system for waste wind power blades

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Application publication date: 20180410