CN106010045A - 一种防腐防水建筑墙体涂料 - Google Patents

一种防腐防水建筑墙体涂料 Download PDF

Info

Publication number
CN106010045A
CN106010045A CN201610494303.2A CN201610494303A CN106010045A CN 106010045 A CN106010045 A CN 106010045A CN 201610494303 A CN201610494303 A CN 201610494303A CN 106010045 A CN106010045 A CN 106010045A
Authority
CN
China
Prior art keywords
parts
butadiene
adds
styrene copolymer
powder
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610494303.2A
Other languages
English (en)
Inventor
胡昌悌
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Wuhu Shuangbao Building Material Co Ltd
Original Assignee
Wuhu Shuangbao Building Material Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Wuhu Shuangbao Building Material Co Ltd filed Critical Wuhu Shuangbao Building Material Co Ltd
Priority to CN201610494303.2A priority Critical patent/CN106010045A/zh
Publication of CN106010045A publication Critical patent/CN106010045A/zh
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04Homopolymers or copolymers of esters
    • C09D133/06Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09D133/08Homopolymers or copolymers of acrylic acid esters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D101/00Coating compositions based on cellulose, modified cellulose, or cellulose derivatives
    • C09D101/08Cellulose derivatives
    • C09D101/26Cellulose ethers
    • C09D101/28Alkyl ethers
    • C09D101/284Alkyl ethers with hydroxylated hydrocarbon radicals
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D161/00Coating compositions based on condensation polymers of aldehydes or ketones; Coating compositions based on derivatives of such polymers
    • C09D161/04Condensation polymers of aldehydes or ketones with phenols only
    • C09D161/06Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

本发明公开了一种防腐防水建筑墙体涂料,其原料按重量份包括:酚醛树脂5‑15份,聚丙烯酸乙烯酯乳液5‑15份,改性丙烯腈‑丁二烯‑苯乙烯共聚物5‑15份,纤维素羟丙基甲基醚5‑15份,铬酸铅2‑6份,环氧丙烷10‑20份,硅灰石粉1‑5份,活性碳酸钙1‑5份,云母粉1‑5份,黏土2‑10份,石墨粉1‑5份。本发明粘结强度高,防腐、防水极好,且对人体无害,成本低。

Description

一种防腐防水建筑墙体涂料
技术领域
本发明涉及涂料技术领域,尤其涉及一种防腐防水建筑墙体涂料。
背景技术
目前,建筑墙体的装饰普遍采用传统的涂料,大部分的涂料防腐、防水性较差,附着力一般,现在人们越来越注重生活环境,室外装饰也越来越受关注,但是由于其不防腐、不防水,粘结强度差,在经过雨水冲刷后漆膜容易整体剥落,目前酸雨的影响越来越大,使得对建筑物外层涂覆的涂料涂层的要求越来越高,建筑物的防水、防腐及粘结强度问题关系到人们的工作和生活环境,并影响着建筑物的使用寿命。
发明内容
基于背景技术存在的技术问题,本发明提出了一种防腐防水建筑墙体涂料,粘结强度高,防腐、防水极好,且对人体无害,成本低。
本发明提出的一种防腐防水建筑墙体涂料,其原料按重量份包括:酚醛树脂5-15份,聚丙烯酸乙烯酯乳液5-15份,改性丙烯腈-丁二烯-苯乙烯共聚物5-15份,纤维素羟丙基甲基醚5-15份,铬酸铅2-6份,环氧丙烷10-20份,硅灰石粉1-5份,活性碳酸钙1-5份,云母粉1-5份,黏土2-10份,石墨粉1-5份。
优选地,改性丙烯腈-丁二烯-苯乙烯共聚物采用如下工艺制备:将丙烯腈-丁二烯-苯乙烯共聚物、熔融尿素、铁粉、水混合搅拌均匀,加入煅烧高岭土、壳聚糖、冰乙酸、羧甲基纤维素钠混合均匀,调节体系pH值至中性,加入对苯二酚、促进剂DM、硅酸钠混合搅拌,降温至室温,加入大豆蛋白,调节体系pH值至8.5-9.5,加入戊二醛胶体磨研磨,加入胶原蛋白、聚乙烯醇混合搅拌,胶体磨研磨,脱气,静置,得到改性丙烯腈-丁二烯-苯乙烯共聚物。
优选地,改性丙烯腈-丁二烯-苯乙烯共聚物采用如下工艺制备:将丙烯腈-丁二烯-苯乙烯共聚物、熔融尿素、铁粉、水混合搅拌均匀,搅拌温度为80-90℃,加入煅烧高岭土、壳聚糖、冰乙酸、羧甲基纤维素钠混合均匀,调节体系pH值至中性,加入对苯二酚、促进剂DM、硅酸钠混合搅拌20-50min,混合温度为92-98℃,降温至室温,加入大豆蛋白,调节体系pH值至8.5-9.5,加入戊二醛胶体磨研磨,研磨温度为55-65℃,加入胶原蛋白、聚乙烯醇混合搅拌10-30min,搅拌速度为400-600r/min,胶体磨研磨,脱气,静置30-60min,得到改性丙烯腈-丁二烯-苯乙烯共聚物。
优选地,改性丙烯腈-丁二烯-苯乙烯共聚物采用如下工艺制备:按重量份将5-15份丙烯腈-丁二烯-苯乙烯共聚物、8-15份熔融尿素、1-2份铁粉、50-90份水混合搅拌均匀,搅拌温度为80-90℃,加入1-5份煅烧高岭土、5-10份壳聚糖、1-2份冰乙酸、1-2份羧甲基纤维素钠混合均匀,调节体系pH值至中性,加入0.5-1.2份对苯二酚、1-2份促进剂DM、1-2份硅酸钠混合搅拌20-50min,混合温度为92-98℃,降温至室温,加入5-10份大豆蛋白,调节体系pH值至8.5-9.5,加入1-2份戊二醛胶体磨研磨,研磨温度为55-65℃,加入1-4份胶原蛋白、1-2份聚乙烯醇混合搅拌10-30min,搅拌速度为400-600r/min,胶体磨研磨,脱气,静置30-60min,得到改性丙烯腈-丁二烯-苯乙烯共聚物。
优选地,酚醛树脂、聚丙烯酸乙烯酯乳液、改性丙烯腈-丁二烯-苯乙烯共聚物、纤维素羟丙基甲基醚的重量比为8-12:10-12:8-10:8-12。
优选地,改性丙烯腈-丁二烯-苯乙烯共聚物、硅灰石粉、活性碳酸钙、云母粉、黏土、石墨粉的重量比为8-10:2-4:2-4:2-4:4-8:2-4。
优选地,其原料按重量份包括:酚醛树脂8-12份,聚丙烯酸乙烯酯乳液10-12份,改性丙烯腈-丁二烯-苯乙烯共聚物8-10份,纤维素羟丙基甲基醚8-12份,铬酸铅3-5份,环氧丙烷13-17份,硅灰石粉2-4份,活性碳酸钙2-4份,云母粉2-4份,黏土4-8份,石墨粉2-4份。
本发明中采用改性丙烯腈-丁二烯-苯乙烯共聚物、酚醛树脂、聚丙烯酸乙烯酯乳液作为基材协同作用,制品与待涂覆底材的粘结强度极高,防腐、防水极好,且对人体无害,成本低;其中改性丙烯腈-丁二烯-苯乙烯共聚物采用一定工艺制备,不仅粘结强度高,且抗腐蚀、抗氧化及耐摩擦性能优异,对人体无害,其中的大豆蛋白与戊二醛、胶原蛋白、聚乙烯醇、微晶纤维素作用形成纤维胶状物,不仅可进一步增强粘结强度,且制品伸缩性好,拉伸强度高,防水性能也极为优异;改性丙烯腈-丁二烯-苯乙烯共聚物与铬酸铅协同作用,制品防腐性能极好,采用环氧丙烷作为稀释剂,纤维素羟丙基甲基醚作为胶黏剂,改性丙烯腈-丁二烯-苯乙烯共聚物与二间苯、纤维素羟丙基甲基醚产生协同作用,制品原料相互间分散性极好,且粘结强度进一步增强;而改性丙烯腈-丁二烯-苯乙烯共聚物与活性碳酸钙、黏土、云母粉、石墨粉、硅灰石粉作用,在增强制品防腐、防水性能的基础上,耐摩擦性能极为优异,力学性能极好,制品的使用寿命长,且成本低。
具体实施方式
下面,通过具体实施例对本发明的技术方案进行详细说明。
实施例1
本发明提出的一种防腐防水建筑墙体涂料,其原料按重量份包括:酚醛树脂5份,聚丙烯酸乙烯酯乳液15份,改性丙烯腈-丁二烯-苯乙烯共聚物5份,纤维素羟丙基甲基醚15份,铬酸铅2份,环氧丙烷20份,硅灰石粉1份,活性碳酸钙5份,云母粉1份,黏土10份,石墨粉1份。
实施例2
本发明提出的一种防腐防水建筑墙体涂料,其原料按重量份包括:酚醛树脂15份,聚丙烯酸乙烯酯乳液5份,改性丙烯腈-丁二烯-苯乙烯共聚物15份,纤维素羟丙基甲基醚5份,铬酸铅6份,环氧丙烷10份,硅灰石粉5份,活性碳酸钙1份,云母粉5份,黏土2份,石墨粉5份。
改性丙烯腈-丁二烯-苯乙烯共聚物采用如下工艺制备:将丙烯腈-丁二烯-苯乙烯共聚物、熔融尿素、铁粉、水混合搅拌均匀,加入煅烧高岭土、壳聚糖、冰乙酸、羧甲基纤维素钠混合均匀,调节体系pH值至中性,加入对苯二酚、促进剂DM、硅酸钠混合搅拌,降温至室温,加入大豆蛋白,调节体系pH值至8.5-9.5,加入戊二醛胶体磨研磨,加入胶原蛋白、聚乙烯醇混合搅拌,胶体磨研磨,脱气,静置,得到改性丙烯腈-丁二烯-苯乙烯共聚物。
实施例3
本发明提出的一种防腐防水建筑墙体涂料,其原料按重量份包括:酚醛树脂12份,聚丙烯酸乙烯酯乳液10份,改性丙烯腈-丁二烯-苯乙烯共聚物10份,纤维素羟丙基甲基醚8份,铬酸铅5份,环氧丙烷13份,硅灰石粉4份,活性碳酸钙2份,云母粉4份,黏土4份,石墨粉4份。
改性丙烯腈-丁二烯-苯乙烯共聚物采用如下工艺制备:按重量份将5份丙烯腈-丁二烯-苯乙烯共聚物、15份熔融尿素、1份铁粉、90份水混合搅拌均匀,搅拌温度为80℃,加入5份煅烧高岭土、5份壳聚糖、2份冰乙酸、1份羧甲基纤维素钠混合均匀,调节体系pH值至中性,加入1.2份对苯二酚、1份促进剂DM、1-2份硅酸钠混合搅拌20-50min,混合温度为92-98℃,降温至室温,加入5-10份大豆蛋白,调节体系pH值至8.5-9.5,加入2份戊二醛胶体磨研磨,研磨温度为55℃,加入4份胶原蛋白、1份聚乙烯醇混合搅拌30min,搅拌速度为400r/min,胶体磨研磨,脱气,静置60min,得到改性丙烯腈-丁二烯-苯乙烯共聚物。
实施例4
本发明提出的一种防腐防水建筑墙体涂料,其原料按重量份包括:酚醛树脂8份,聚丙烯酸乙烯酯乳液12份,改性丙烯腈-丁二烯-苯乙烯共聚物8份,纤维素羟丙基甲基醚12份,铬酸铅3份,环氧丙烷17份,硅灰石粉2份,活性碳酸钙4份,云母粉2份,黏土8份,石墨粉2份。
改性丙烯腈-丁二烯-苯乙烯共聚物采用如下工艺制备:按重量份将15份丙烯腈-丁二烯-苯乙烯共聚物、8份熔融尿素、2份铁粉、50份水混合搅拌均匀,搅拌温度为90℃,加入1份煅烧高岭土、10份壳聚糖、1份冰乙酸、2份羧甲基纤维素钠混合均匀,调节体系pH值至中性,加入0.5份对苯二酚、2份促进剂DM、1份硅酸钠混合搅拌50min,混合温度为92℃,降温至室温,加入10份大豆蛋白,调节体系pH值至8.5-9.5,加入1份戊二醛胶体磨研磨,研磨温度为65℃,加入1份胶原蛋白、2份聚乙烯醇混合搅拌10min,搅拌速度为600r/min,胶体磨研磨,脱气,静置30min,得到改性丙烯腈-丁二烯-苯乙烯共聚物。
实施例5
本发明提出的一种防腐防水建筑墙体涂料,其原料按重量份包括:酚醛树脂10份,聚丙烯酸乙烯酯乳液11份,改性丙烯腈-丁二烯-苯乙烯共聚物9份,纤维素羟丙基甲基醚10份,铬酸铅4份,环氧丙烷15份,硅灰石粉3份,活性碳酸钙3份,云母粉3份,黏土6份,石墨粉3份。
改性丙烯腈-丁二烯-苯乙烯共聚物采用如下工艺制备:按重量份将10份丙烯腈-丁二烯-苯乙烯共聚物、12份熔融尿素、1.5份铁粉、70份水混合搅拌均匀,搅拌温度为85℃,加入3份煅烧高岭土、8份壳聚糖、1.5份冰乙酸、1.6份羧甲基纤维素钠混合均匀,调节体系pH值至中性,加入1份对苯二酚、1.2份促进剂DM、1.8份硅酸钠混合搅拌35min,混合温度为95℃,降温至室温,加入8份大豆蛋白,调节体系pH值至8.5-9.5,加入1.4份戊二醛胶体磨研磨,研磨温度为60℃,加入2份胶原蛋白、1.8份聚乙烯醇混合搅拌20min,搅拌速度为500r/min,胶体磨研磨,脱气,静置45min,得到改性丙烯腈-丁二烯-苯乙烯共聚物。
以上所述,仅为本发明较佳的具体实施方式,但本发明的保护范围并不局限于此,任何熟悉本技术领域的技术人员在本发明揭露的技术范围内,根据本发明的技术方案及其发明构思加以等同替换或改变,都应涵盖在本发明的保护范围之内。

Claims (7)

1.一种防腐防水建筑墙体涂料,其特征在于,其原料按重量份包括:酚醛树脂5-15份,聚丙烯酸乙烯酯乳液5-15份,改性丙烯腈-丁二烯-苯乙烯共聚物5-15份,纤维素羟丙基甲基醚5-15份,铬酸铅2-6份,环氧丙烷10-20份,硅灰石粉1-5份,活性碳酸钙1-5份,云母粉1-5份,黏土2-10份,石墨粉1-5份。
2.根据权利要求1所述的防腐防水建筑墙体涂料,其特征在于,改性丙烯腈-丁二烯-苯乙烯共聚物采用如下工艺制备:将丙烯腈-丁二烯-苯乙烯共聚物、熔融尿素、铁粉、水混合搅拌均匀,加入煅烧高岭土、壳聚糖、冰乙酸、羧甲基纤维素钠混合均匀,调节体系pH值至中性,加入对苯二酚、促进剂DM、硅酸钠混合搅拌,降温至室温,加入大豆蛋白,调节体系pH值至8.5-9.5,加入戊二醛胶体磨研磨,加入胶原蛋白、聚乙烯醇混合搅拌,胶体磨研磨,脱气,静置,得到改性丙烯腈-丁二烯-苯乙烯共聚物。
3.根据权利要求1或2所述的防腐防水建筑墙体涂料,其特征在于,改性丙烯腈-丁二烯-苯乙烯共聚物采用如下工艺制备:将丙烯腈-丁二烯-苯乙烯共聚物、熔融尿素、铁粉、水混合搅拌均匀,搅拌温度为80-90℃,加入煅烧高岭土、壳聚糖、冰乙酸、羧甲基纤维素钠混合均匀,调节体系pH值至中性,加入对苯二酚、促进剂DM、硅酸钠混合搅拌20-50min,混合温度为92-98℃,降温至室温,加入大豆蛋白,调节体系pH值至8.5-9.5,加入戊二醛胶体磨研磨,研磨温度为55-65℃,加入胶原蛋白、聚乙烯醇混合搅拌10-30min,搅拌速度为400-600r/min,胶体磨研磨,脱气,静置30-60min,得到改性丙烯腈-丁二烯-苯乙烯共聚物。
4.根据权利要求1-3任一项所述的防腐防水建筑墙体涂料,其特征在于,改性丙烯腈-丁二烯-苯乙烯共聚物采用如下工艺制备:按重量份将5-15份丙烯腈-丁二烯-苯乙烯共聚物、8-15份熔融尿素、1-2份铁粉、50-90份水混合搅拌均匀,搅拌温度为80-90℃,加入1-5份煅烧高岭土、5-10份壳聚糖、1-2份冰乙酸、1-2份羧甲基纤维素钠混合均匀,调节体系pH值至中性,加入0.5-1.2份对苯二酚、1-2份促进剂DM、1-2份硅酸钠混合搅拌20-50min,混合温度为92-98℃,降温至室温,加入5-10份大豆蛋白,调节体系pH值至8.5-9.5,加入1-2份戊二醛胶体磨研磨,研磨温度为55-65℃,加入1-4份胶原蛋白、1-2份聚乙烯醇混合搅拌10-30min,搅拌速度为400-600r/min,胶体磨研磨,脱气,静置30-60min,得到改性丙烯腈-丁二烯-苯乙烯共聚物。
5.根据权利要求1-4任一项所述的防腐防水建筑墙体涂料,其特征在于,酚醛树脂、聚丙烯酸乙烯酯乳液、改性丙烯腈-丁二烯-苯乙烯共聚物、纤维素羟丙基甲基醚的重量比为8-12:10-12:8-10:8-12。
6.根据权利要求1-5任一项所述的防腐防水建筑墙体涂料,其特征在于,改性丙烯腈-丁二烯-苯乙烯共聚物、硅灰石粉、活性碳酸钙、云母粉、黏土、石墨粉的重量比为8-10:2-4:2-4:2-4:4-8:2-4。
7.根据权利要求1-6任一项所述的防腐防水建筑墙体涂料,其特征在于,其原料按重量份包括:酚醛树脂8-12份,聚丙烯酸乙烯酯乳液10-12份,改性丙烯腈-丁二烯-苯乙烯共聚物8-10份,纤维素羟丙基甲基醚8-12份,铬酸铅3-5份,环氧丙烷13-17份,硅灰石粉2-4份,活性碳酸钙2-4份,云母粉2-4份,黏土4-8份,石墨粉2-4份。
CN201610494303.2A 2016-06-29 2016-06-29 一种防腐防水建筑墙体涂料 Pending CN106010045A (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610494303.2A CN106010045A (zh) 2016-06-29 2016-06-29 一种防腐防水建筑墙体涂料

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610494303.2A CN106010045A (zh) 2016-06-29 2016-06-29 一种防腐防水建筑墙体涂料

Publications (1)

Publication Number Publication Date
CN106010045A true CN106010045A (zh) 2016-10-12

Family

ID=57105131

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610494303.2A Pending CN106010045A (zh) 2016-06-29 2016-06-29 一种防腐防水建筑墙体涂料

Country Status (1)

Country Link
CN (1) CN106010045A (zh)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108003727A (zh) * 2017-12-20 2018-05-08 成都新柯力化工科技有限公司 一种制备仿瓷建筑装饰材料的方法
WO2018121509A1 (zh) * 2016-12-30 2018-07-05 苏州律点信息科技有限公司 一种能够吸附甲醛的建筑涂料

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103289501A (zh) * 2013-06-04 2013-09-11 苏州艾特斯环保材料有限公司 一种含有丙烯腈-丁二烯-苯乙烯共聚物的防水耐热涂料
CN103773167A (zh) * 2013-12-23 2014-05-07 安徽省金盾涂料有限责任公司 一种防腐耐磨涂料

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103289501A (zh) * 2013-06-04 2013-09-11 苏州艾特斯环保材料有限公司 一种含有丙烯腈-丁二烯-苯乙烯共聚物的防水耐热涂料
CN103773167A (zh) * 2013-12-23 2014-05-07 安徽省金盾涂料有限责任公司 一种防腐耐磨涂料

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
叶琳昌: "《防水工程手册》", 30 June 2005, 中国建筑工业出版社 *
杨建忠: "《新型纺织材料及应用》", 31 October 2011, 东华大学出版社 *
高强等: "《大豆蛋白基木材胶黏剂耐水胶接实践与理论》", 30 June 2014, 煤炭工业出版社 *

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2018121509A1 (zh) * 2016-12-30 2018-07-05 苏州律点信息科技有限公司 一种能够吸附甲醛的建筑涂料
CN108003727A (zh) * 2017-12-20 2018-05-08 成都新柯力化工科技有限公司 一种制备仿瓷建筑装饰材料的方法
CN108003727B (zh) * 2017-12-20 2019-11-19 龙元明筑科技有限责任公司 一种制备仿瓷建筑装饰材料的方法

Similar Documents

Publication Publication Date Title
CN107353733A (zh) 一种无毒环保型水性涂料及其制备方法
CN106010045A (zh) 一种防腐防水建筑墙体涂料
CN104356802A (zh) 一种水性丙烯酸氨基烤漆
CN109082184A (zh) 一种高附着力的弹性乳胶漆
CN104356862A (zh) 一种耐紫外老化的防锈环氧面漆及其制备方法
CN103937381A (zh) 一种防腐蚀性涂料及其制备方法
CN105062247A (zh) 一种氟碳乳液树脂防水涂料
CN108485324A (zh) 一种粉体防潮硅藻涂料
CN102627005B (zh) 四氟碳铝单板
CN107936808A (zh) 一种抗空蚀高耐水含氟聚氨酯涂料
CN107987567A (zh) 一种防潮乳胶漆的制备方法
CN104910777A (zh) 一种环保涂料
CN103709967A (zh) 一种环保无毒白乳胶
CN106010081A (zh) 一种建筑墙体用防腐涂料
CN103937376A (zh) 防腐蚀性涂料及其制备方法
CN105802319A (zh) 一种抗菌腻子粉及其制备方法
CN104087128B (zh) 水性底漆组合物
CN106085186A (zh) 一种环保防水涂料
CN104387906A (zh) 一种阻气抗氧化防锈环氧面漆及其制备方法
CN104449320A (zh) 木器面漆
CN104263031A (zh) 一种平整无气泡装饰涂料
CN107365502A (zh) 一种用于冰箱底座的橡胶材料
CN103773197A (zh) 一种新型建筑室内生物涂料
CN107858064A (zh) 一种外墙装饰用水性丙烯酸涂料
CN102372938A (zh) 一种硅丙杀菌乳胶漆

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20161012

RJ01 Rejection of invention patent application after publication