CN105994283A - Bactericidal composition containing bixafen and metominostrobin and application thereof - Google Patents

Bactericidal composition containing bixafen and metominostrobin and application thereof Download PDF

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Publication number
CN105994283A
CN105994283A CN201610354942.9A CN201610354942A CN105994283A CN 105994283 A CN105994283 A CN 105994283A CN 201610354942 A CN201610354942 A CN 201610354942A CN 105994283 A CN105994283 A CN 105994283A
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China
Prior art keywords
ssf
bacterium amine
pyrrole bacterium
biphenyl pyrrole
bactericidal composition
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CN201610354942.9A
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Chinese (zh)
Inventor
白杰
石振龙
万维肖
彭永强
高瑞花
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Nanjing Huazhou Pharmaceutical Co Ltd
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Nanjing Huazhou Pharmaceutical Co Ltd
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Priority to CN201610354942.9A priority Critical patent/CN105994283A/en
Publication of CN105994283A publication Critical patent/CN105994283A/en
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/561,2-Diazoles; Hydrogenated 1,2-diazoles
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/44Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
    • A01N37/50Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids the nitrogen atom being doubly bound to the carbon skeleton

Abstract

The invention discloses a bactericidal composition containing bixafen and metominostrobin and application thereof. The bactericidal composition takes bixafen and metominostrobin as the main active ingredients, wherein the mass ratio of bixafen to metominostrobin is (1-70) to (1-50). The bactericidal composition can be applied to controlling cereal, fruit tree and vegetable diseases, has higher synergistic effects, has the effects of overcoming and delaying the drug resistance of germs, is high in bactericidal speed, has long duration, has the effect of reducing the application cost and has obviously better control effects than single agents. The bactericidal composition can be used for controlling fungal diseases of crops, can be especially used for controlling the fungal diseases, such as leaf rust, leaf blight, downy mildew, powdery mildew and rice blast, and has obviously better effects than single agents.

Description

A kind of containing biphenyl pyrrole bacterium amine and the bactericidal composition of SSF 126 and application
Technical field:
The present invention relates to a kind of bactericidal composition and application thereof, especially one is main with biphenyl pyrrole bacterium amine and SSF 126 The bactericidal composition of active component and application thereof.
Background technology
Biphenyl pyrrole bacterium amine (Bixafen), chemical formula: C18H12Cl2F3N3O, chemical name: N-(3 ', 4 '-two chloro-5- Fluorine hexichol-2-base)-3-(difluoromethyl)-1-methylpyrazole-4-Methanamide.Structural formula:
Biphenyl pyrrole bacterium amine is pyrazoles antibacterial, is that the interior absorption that a kind of novel wide spectrum, protection and therapeutic activity have concurrently is killed Microbial inoculum.
SSF 126 (Metominostrobin), molecular formula: C16H16N2O3, chemical name: methyl (E)-Α- Methoxyimino-N-methyl-2-Phenoxyphenyl acetamide.Structural formula:
SSF 126 is methoxy acrylic bactericide, is that a kind of novel spectrum, protection and therapeutic activity have concurrently Systemic fungicide, is mainly used in preventing and treating rice blast etc., is being uninfected by or their early stage is used.The mechanism of action is Mitochondrial respiratory inhibitor i.e. suppresses mitochondrial breathing by electron transfer between cytochrome b and C1.To 14-piptonychia The bacterial strain that base enzyme inhibitor, benzene oxanamide class, dicarboxylic dihydrazides amine and benzimidazole produce resistance is effective.
The difficulty of prevention and cure of phytopathogen is increasing at present, on the one hand, along with the change of pattern of farming, melon fruits and vegetables etc. Industrial crops cultivated area progressively expands, and disease occurrence degree, generation quantity all increase, and in preventing and treating, difficulty strengthens; On the other hand, the resistance of pathogen rises under lasting medicament selection pressure year by year, and the prevention effect of single dose is had a greatly reduced quality, Control of plant disease is faced with significant challenge.
Summary of the invention:
It is an object of the invention to provide a kind of applied widely, low cost for above-mentioned technical problem, effective containing biphenyl Pyrrole bacterium amine and the plant bactericidal composition of SSF 126.
It is a still further object of the present invention to provide this bactericidal composition and cause the application on fungal disease at preventing and treating plant epiphyte, Especially in the purposes prevented and treated on the fungal diseases such as leaf rust, leaf blight, downy mildew, powdery mildew, rice blast.
It is an object of the invention to be achieved through the following technical solutions:
A kind of containing biphenyl pyrrole bacterium amine and the bactericidal composition of SSF 126, this bactericidal composition is with biphenyl pyrrole bacterium amine and benzene oxygen bacterium Amine is principle active component, and wherein biphenyl pyrrole bacterium amine is 1~70:1~50 with the mass ratio of SSF 126, wherein sterilization group In compound, active ingredient is present in compositions with enhancing effective amount.
Described bactericidal composition, wherein biphenyl pyrrole bacterium amine is preferably 1~50:1~30 with the mass ratio of SSF 126, enters One step is preferably 1~30:1~10, the most preferably 1~5:1~10.Biphenyl pyrrole bacterium amine and the preferred matter of SSF 126 Amount proportioning can also be: 70:1,50:1,30:1,20:1,10:1,5:1,2.5:1,1:1,1:2, 1:4,1:6,1:10,1:20,1:30,1:50.
In the compositions of the present invention, the weight/mass percentage composition accounting for compositions both biphenyl pyrrole bacterium amine and SSF 126 is 2~80%.Preferably 5~70%.
Described bactericidal composition, wherein with biphenyl pyrrole bacterium amine and SSF 126 for principle active component and known auxiliary agent and Excipient is re-dubbed on pesticide any one dosage form allowed.Auxiliary agent known to these, excipient have dispersant, diffusant, Defoamer, wetting agent, disintegrating agent etc., can use calcium dodecyl benzene sulfonate, alkylphenol polyoxyethylene, benzylphenol Polyoxyethylene ether, phenethyl phenol polyethenoxy ether, fatty alcohol-polyoxyethylene ether and similar products, aliphatic amine polyoxyethylene Ether, fatty acid ethylene oxide addition product, polyoxyethylene polyoxy propylene block compound, castor oil polyoxyethylene ether, nonyl Phenol polyethenoxy ether, TWEEN Series, fatty alcohol-polyoxyethylene ether, Polyethylene Glycol series, Sulfonates, carboxylate, sulfur Hydrochlorate, phosphate, phosphite, lignosulfonates, xanthan gum, phenol formaldehyde condensate, ammonium salt, quaternary etc. In one or more combinations, excipient includes that Ketohexamethylene, dimethylbenzene, various solvent naphtha, water, antifreezing agent are (such as the third two Alcohol), deionized water etc..Above auxiliary agent, excipient and other adjuvant can be alone or and use.
Described bactericidal composition, its dosage form is cream, wettable powder, suspending agent, aqueous emulsion or water dispersion granule.
The application on preparation preventing and treating fungal diseases of plants medicine of the above-mentioned bactericidal composition.Especially preventing and treating Cereal, Application in terms of fruit tree, vegetable crop disease has significant effect.
Above-mentioned application, described fungal diseases of plants is in leaf rust, leaf blight, downy mildew, powdery mildew, rice blast At least one.
The feature of bactericidal composition of the present invention:
1, the biphenyl pyrrole bacterium amine used by the present invention and SSF 126, the mechanism of action is different, and mutual mixture will not produce low touching, Can Synergistic, reduce dosage, reduce cost.
2, the present composition scope of application increases, it is adaptable to preventing and treating Cereal, fruit tree, the refractory fungal disease of vegetable, Particularly prevent and treat leaf rust, leaf blight, downy mildew, powdery mildew, rice blast etc. and all have significant effect.The present invention sterilizes Compositions has good prevention effect to ascomycetes, basidiomycetes, Fungi Imperfecti and Oomycete fungal disease;And suppress insect Or fungus or the antibacterial drug-fast generation to unitary agent (biphenyl pyrrole bacterium amine and SSF 126 are arbitrary).The present invention sterilizes Compositions can produce higher synergistic function, and the consumption of the independent reactive compound of amount ratio of this mixture is significantly Reducing, i.e. the activity of mixture is more than the activity of independent component.
Compared with prior art beneficial effects of the present invention: (1), compared with single dose, said composition antagonism fungal disease is such as The fungal diseases such as leaf rust, leaf blight, downy mildew, powdery mildew, rice blast have obvious synergistic function, overcome and prolong Having delayed Drug resistance, expanding prevention is composed, hence it is evident that improve prevention effect;(2) preventing and treating recruitment, drug cost are reduced;(3) Alternative routine and the pesticide being easily generated resistance;(4) compared with single dose, produce and use cost reduces;(5) suppression is true The drug-fast generation of bacterium, its effect uses apparently higher than its single dose.
Detailed description of the invention
Below in conjunction with embodiment, the invention will be further described, and in embodiment, the preparation method of dosage form is conventional method, " % " of the present invention is mass percent.
Indoor biometrics is tested:
In indoor employing mycelial growth rate method, measure the different agents EC to bacterial strain50Value, uses co-toxicity coefficient calculating side Method, calculates the co-toxicity coefficient (CTC) of mixture, determines the building performance of mixture, and circular is as follows:
In mixture, a certain single dose (is generally selected EC as standard agent50Junior), calculate:
Single dose toxicity index=standard agent EC50/ certain single dose EC50×100
Toxicity index × A the single dose of theoretical toxicity index=A single dose in mixture the toxicity index of proportion+B single dose × B single dose proportion in mixture
The EC of actual measurement toxicity index=standard single dose50The EC of value/mixture50Value × 100
Co-toxicity coefficient=actual measurement toxicity index/theory toxicity index × 100
When co-toxicity coefficient classification: CTC is more than 120, mixture has synergetic, is antagonism when CTC is less than 80, CTC It it is summation action between 80-120.
According to effective ingredient biphenyl pyrrole bacterium amine (A): SSF 126 (B) quality proportioning is: 80:1,70:1,50: 1,30:1,20:1,10:1,5:1,2.5:1,1:1,1:2,1:4,1:6,1:10,1:20,1: 30,1:50,1:60,1:70 test, and measure it to rice blast (PyriculariaoryaeCav.) Co-toxicity coefficient.
Table 1: biphenyl pyrrole bacterium amine+SSF 126 different ratio indoor biometrics result to rice blast
Medicament Virulence regression equation EC50(mg/L) Co-toxicity coefficient
10% biphenyl pyrrole bacterium amine WP Y=2.619+3.324X 5.202 -
10% SSF 126 WP Y=3.666+2.025X 4.556 -
A:B=80:1 Y=2.225+4.000X 4.939 102.36
A:B=70:1 Y=3.392+2.658X 4.027 125.05
A:B=50:1 Y=4.249+1.547X 3.060 162.52
A:B=30:1 Y=4.025+2.369X 2.580 187.45
A:B=20:1 Y=2.971+3.625X 3.629 128.94
A:B=10:1 Y=4.223+1.565X 3.139 136.63
A:B=5:1 Y=4.271+2.338X 2.050 182.50
A:B=2.5:1 Y=4.683+1.547X 1.603 194.42
A:B=1:1 Y=4.450+3.032X 1.518 157.85
A:B=1:2 Y=4.501+4.112X 1.322 153.63
A:B=1:4 Y=4.711+2.590X 1.293 139.98
A:B=1:6 Y=4.738+3.698X 1.177 146.96
A:B=1:10 Y=5.010+1.426X 0.984 168.85
A:B=1:20 Y=4.995+1.777X 1.007 159.86
A:B=1:30 Y=5.137+2.055X 0.858 185.56
A:B=1:50 Y=4.899+1.542X 1.163 135.62
A:B=1:60 Y=4.707+2.200X 1.359 115.80
A:B=1:70 Y=4.309+4.528X 1.421 110.56
Field control effectiveness test:
The pesticidal preparations preventing and treating rice blast test prepared with above-described embodiment.
1, test processes: this test medicine consumption sets three concentration for the treatment of respectively according to the difference of each composition, compares medicine Agent is pesticide single dose 10% biphenyl pyrrole bacterium amine WP and 10% SSF 126 WP and blank clean water experiment respectively.
2, each plot area of test method is 66.7m2, it is repeated 3 times;Investigation drug effect after investigating before dispenser and preventing and treating Method is: in test treatment region, (every takes 5m to randomization 5 point2), enter according to country's field test relevant criterion Row severity Scaling, calculates preventive effect.Result of the test is shown in Table 2:
Table 2 field test effect
Being shown by indoor biometrics and field efficacy result, biphenyl pyrrole bacterium amine and SSF 126 compositions have the most collaborative Potentiation, the prevention effect of compositions is excellent, and prevention effect is all better than single dose kind, has application in agricultural is applied It is worth.
Two kinds of reactive compounds can be processed into any one dosage form of permission, illustrates that two kinds have with specific embodiment below The preparation that effect composition is processed into, but the preparation that these two kinds of active component can be processed is not limited only to set forth below.
Embodiment 1:15% biphenyl pyrrole bacterium amine SSF 126 wettable powder (1:2)
By biphenyl pyrrole bacterium amine 5g, SSF 126 10g, detergent LS (to methoxyl group fatty acid amido benzene sulfonic acid sodium salt) 2g, Dispersing agent NNO (sodium methylene bis-naphthalene sulfonate) 4g, white carbon 5g, Kaolin adds to 100g mixture and carries out air-flow powder Broken, preparing effective ingredient mass percent is 15% biphenyl pyrrole bacterium amine SSF 126 wettable powder.
Embodiment 2:15% biphenyl pyrrole bacterium amine SSF 126 wettable powder (1:4)
By biphenyl pyrrole bacterium amine 3g, SSF 126 12g, sodium lauryl sulphate 3g, dispersing agent NNO 4g, white carbon 5g, Kaolin adds to 100g mixture and carries out comminution by gas stream, and preparing effective ingredient mass percent is 15% biphenyl pyrrole bacterium amine benzene Oxygen bacterium amine wettable powder.
Embodiment 3:14% biphenyl pyrrole bacterium amine SSF 126 wettable powder (1:6)
By biphenyl pyrrole bacterium amine 2g, SSF 126 12g, sodium lauryl sulphate 3g, dispersing agent NNO 4g, white carbon 5g, Kaolin adds to 100g mixture and carries out comminution by gas stream, and preparing effective ingredient mass percent is 14% biphenyl pyrrole bacterium amine benzene Oxygen bacterium amine wettable powder.
Embodiment 4:20% biphenyl pyrrole bacterium amine SSF 126 suspending agent (1:1)
Weigh 10g biphenyl pyrrole bacterium amine, 10g SSF 126, lignin 2g, polyoxyethylene poly-oxygen propylene aether and sulfate thereof 4g, xanthan gum 0.15g, ethylene glycol 5g, siloxanes 0.10g, aluminium-magnesium silicate 0.5g, complement to 100g with water, at sand Making effective Ingredient percent under the effect of grinding machine is 20% biphenyl pyrrole bacterium amine SSF 126 suspending agent.
Embodiment 5:55% biphenyl pyrrole bacterium amine SSF 126 aqueous emulsion (1:10)
Weigh 5g biphenyl pyrrole bacterium amine, 50g SSF 126, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33#2g, Alkylphenol polyoxyethylene 1g, 150# solvent naphtha 13g, add water to 100g.Above raw material is prepared aqueous emulsion routinely Method puts into the mixing of mixing kettle high speed, and making effective Ingredient percent is 55% biphenyl pyrrole bacterium amine SSF 126 water Emulsion.
Embodiment 6:42% biphenyl pyrrole bacterium amine SSF 126 cream (1:20)
Weigh 2g biphenyl pyrrole bacterium amine, 40g SSF 126, calcium dodecyl benzene sulfonate 8g, phenethyl phenol polyethenoxy ether 5g, 150# solvent naphtha is to 100g.The method that above raw material is prepared cream routinely puts into mixing in mixing kettle, is formed with Effect Ingredient percent is 42% biphenyl pyrrole bacterium amine SSF 126 cream.
Embodiment 7:70% biphenyl pyrrole bacterium amine SSF 126 cream (2.5:1)
Weigh 50g biphenyl pyrrole bacterium amine, 20g SSF 126, calcium dodecyl benzene sulfonate 5g, phenethyl phenol polyethenoxy ether 2g, castor oil polyoxyethylene ether 2g, 150# solvent naphtha to 100g.The method that above raw material is prepared cream routinely is thrown Entering in mixing kettle and mix, making effective Ingredient percent is 70% biphenyl pyrrole bacterium amine SSF 126 cream.
Embodiment 8:18% biphenyl pyrrole bacterium amine SSF 126 water dispersion granule (5:1)
Weigh 15g biphenyl pyrrole bacterium amine, 3g SSF 126, wooden sodium sulfonate 8g, sodium lauryl sulphate 2g, ammonium sulfate 5g, polyvinyl alcohol 5g, Borax 2g, kieselguhr complements to 100g, is made by water dispersible granular agent method by above raw material Effective ingredient mass percent is 17% biphenyl pyrrole bacterium amine SSF 126 water dispersion granule.
Embodiment 9:11% biphenyl pyrrole bacterium amine SSF 126 cream (10:1)
Weigh 10g biphenyl pyrrole bacterium amine, 1g SSF 126, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether 7g, 150# solvent naphtha is to 100g.The method that above raw material is prepared cream routinely puts into mixing in mixing kettle, is formed with Effect Ingredient percent is 11% biphenyl pyrrole bacterium amine SSF 126 cream.
Embodiment 10:31.5% biphenyl pyrrole bacterium amine SSF 126 microemulsion (20:1)
Weigh 30g biphenyl pyrrole bacterium amine, 1.5g SSF 126, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether Phosphate ester 3g, agriculture breast 33#2g, alkylphenol polyoxyethylene 1g, isopropanol 10g, add water to 100g.To be the most former Material is prepared the method for microemulsion routinely and is put into mixing in mixing kettle, and making effective Ingredient percent is 31.5% biphenyl Pyrrole bacterium amine SSF 126 microemulsion.
Embodiment 11:31% biphenyl pyrrole bacterium amine SSF 126 cream (30:1)
Weigh 30g biphenyl pyrrole bacterium amine, 1g SSF 126, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 4g, 150# solvent naphtha is to 100g.The method that above raw material is prepared cream routinely puts into mixing in mixing kettle, is formed with Effect Ingredient percent is 31% biphenyl pyrrole bacterium amine SSF 126 cream.
Embodiment 12:51% biphenyl pyrrole bacterium amine SSF 126 suspending agent (50:1)
Weigh 50g biphenyl pyrrole bacterium amine, 1g SSF 126, lignin 2g, polyoxyethylene poly-oxygen propylene aether and sulfate thereof 4g, xanthan gum 0.15g, ethylene glycol 5g, siloxanes 0.10g, aluminium-magnesium silicate 0.5g, complement to 100g with water, at sand Making effective Ingredient percent under the effect of grinding machine is 51% biphenyl pyrrole bacterium amine SSF 126 suspending agent.
Embodiment 13:32% biphenyl pyrrole bacterium amine SSF 126 microemulsion (1:15)
Weigh 2g biphenyl pyrrole bacterium amine, 30g SSF 126, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether Phosphate ester 3g, agriculture breast 33#2g, alkylphenol polyoxyethylene 1g, isopropanol 10g, add water to 100g.To be the most former Material is prepared the method for microemulsion routinely and is put into mixing in mixing kettle, and making effective Ingredient percent is 32% biphenyl pyrrole Bacterium amine SSF 126 microemulsion.
Embodiment 14:6% biphenyl pyrrole bacterium amine SSF 126 aqueous emulsion (1:5)
Weigh 1g biphenyl pyrrole bacterium amine, 5g SSF 126, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33#2g, Alkylphenol polyoxyethylene 1g, 150# solvent naphtha 13g, add water to 100g.Above raw material is prepared aqueous emulsion routinely Method puts into the mixing of mixing kettle high speed, and making effective Ingredient percent is 6% biphenyl pyrrole bacterium amine SSF 126 water and milk Agent.
Embodiment 15:62% biphenyl pyrrole bacterium amine SSF 126 microemulsion (1:30)
Weigh 2g biphenyl pyrrole bacterium amine, 60g SSF 126, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether Phosphate ester 3g, agriculture breast 33#2g, alkylphenol polyoxyethylene 1g, isopropanol 10g, add water to 100g.To be the most former Material is prepared the method for microemulsion routinely and is put into mixing in mixing kettle, and making effective Ingredient percent is 62% biphenyl pyrrole Bacterium amine SSF 126 microemulsion.
Embodiment 16:51% biphenyl pyrrole bacterium amine SSF 126 suspending agent (1:50)
Weigh 1g biphenyl pyrrole bacterium amine, 50g SSF 126, lignin 2g, polyoxyethylene poly-oxygen propylene aether and sulfate thereof 4g, xanthan gum 0.15g, ethylene glycol 5g, siloxanes 0.10g, aluminium-magnesium silicate 0.5g, complement to 100g with water, at sand Making effective Ingredient percent under the effect of grinding machine is 51% biphenyl pyrrole bacterium amine SSF 126 suspending agent.
Embodiment 17:7% biphenyl pyrrole bacterium amine SSF 126 water dispersion granule (1:2.5)
Weigh 2g biphenyl pyrrole bacterium amine, 5g SSF 126, wooden sodium sulfonate 8g, sodium lauryl sulphate 2g, ammonium sulfate 5g, polyvinyl alcohol 5g, Borax 2g, white carbon 3g, kieselguhr complement to 100g, above raw material are pressed water dispersible granular It is 7% biphenyl pyrrole bacterium amine SSF 126 water dispersion granule that agent method makes effective Ingredient percent.

Claims (10)

1. one kind contains biphenyl pyrrole bacterium amine and the bactericidal composition of SSF 126, it is characterised in that this bactericidal composition is with biphenyl Pyrrole bacterium amine and SSF 126 are principle active component, and wherein biphenyl pyrrole bacterium amine is 1~70:1~50 with the mass ratio of SSF 126.
Bactericidal composition the most according to claim 1, it is characterised in that described biphenyl pyrrole bacterium amine and SSF 126 Mass ratio is 1~50:1~30.
Bactericidal composition the most according to claim 2, it is characterised in that described biphenyl pyrrole bacterium amine and SSF 126 Mass ratio is 1~30:1~10.
Bactericidal composition the most according to claim 3, it is characterised in that described biphenyl pyrrole bacterium amine and SSF 126 Mass ratio is 1~5:1~10.
Bactericidal composition the most according to claim 1, it is characterised in that described biphenyl pyrrole bacterium amine and SSF 126 The two weight/mass percentage composition accounting for compositions is 2-80%.
Bactericidal composition the most according to claim 5, it is characterised in that described biphenyl pyrrole bacterium amine and SSF 126 The two weight/mass percentage composition accounting for compositions is 5-70%.
Bactericidal composition the most according to claim 1, it is characterised in that based on biphenyl pyrrole bacterium amine and SSF 126 Effective ingredient and insecticides adjuvant, excipient is wanted to be configured on pesticide any one dosage form allowed.
Bactericidal composition the most according to claim 7, it is characterised in that described dosage form is cream, suspending agent, water Emulsion, wettable powder or water dispersion granule.
9. the application on preparation preventing and treating fungal diseases of plants medicine of the bactericidal composition described in claim 1.
Application the most according to claim 9, it is characterised in that described fungal diseases of plants is that leaf rust, leaf are withered At least one in disease, downy mildew, powdery mildew, rice blast.
CN201610354942.9A 2016-05-25 2016-05-25 Bactericidal composition containing bixafen and metominostrobin and application thereof Pending CN105994283A (en)

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20070060579A1 (en) * 2003-10-10 2007-03-15 Ulrike Wachendorff-Neumann Synergistic fungicidal active substance combinations
CN102318627A (en) * 2011-06-26 2012-01-18 青岛奥迪斯生物科技有限公司 A kind of innovative efficient bactericidal composite
CN104066335A (en) * 2011-11-09 2014-09-24 斯托克顿(以色列)有限公司 Combinations of antifungal compounds and tea tree oil

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20070060579A1 (en) * 2003-10-10 2007-03-15 Ulrike Wachendorff-Neumann Synergistic fungicidal active substance combinations
CN102318627A (en) * 2011-06-26 2012-01-18 青岛奥迪斯生物科技有限公司 A kind of innovative efficient bactericidal composite
CN104066335A (en) * 2011-11-09 2014-09-24 斯托克顿(以色列)有限公司 Combinations of antifungal compounds and tea tree oil

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