CN105974732A - Embossing mask plate and nano-embossing method - Google Patents

Embossing mask plate and nano-embossing method Download PDF

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Publication number
CN105974732A
CN105974732A CN201610596067.5A CN201610596067A CN105974732A CN 105974732 A CN105974732 A CN 105974732A CN 201610596067 A CN201610596067 A CN 201610596067A CN 105974732 A CN105974732 A CN 105974732A
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CN
China
Prior art keywords
embossing
nano
mask version
platen
stamp mask
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610596067.5A
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Chinese (zh)
Inventor
周婷婷
姚继开
关峰
王英涛
何晓龙
张斌
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BOE Technology Group Co Ltd
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BOE Technology Group Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BOE Technology Group Co Ltd filed Critical BOE Technology Group Co Ltd
Priority to CN201610596067.5A priority Critical patent/CN105974732A/en
Publication of CN105974732A publication Critical patent/CN105974732A/en
Pending legal-status Critical Current

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    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/0002Lithographic processes using patterning methods other than those involving the exposure to radiation, e.g. by stamping

Abstract

The invention provides an embossing mask plate and a nano-embossing method and belongs to the technical field of embossing. The embossing mask plate comprises an embossing plate and a light shielding layer. The embossing plate is provided with a work region and a peripheral region surrounding the work region. The light shielding layer is arranged in the peripheral region of the embossing plate. Due to the fact that the light shielding layer is arranged in the peripheral region of the embossing plate of the embossing mask plate, when large-area nano-embossing is conducted through the embossing mask plate, embossing glue at the position corresponding to the peripheral region of the embossing plate is shielded by the light shielding layer, the embossing glue is not cured in the ultraviolet curing process, only embossing glue at the position corresponding to the work region of the embossing plate is cured, the non-cured embossing glue is washed away in the developing process, embossing can be conducted at the completely-attached position in the next embossing process, the size of a splicing seam only depends on alignment precision and cannot be affected by the embossing glue at the position corresponding to the peripheral region of the embossing plate in the last embossing process, the splicing seam can be effectively reduced, and splicing precision is improved.

Description

Imprint mask version and nano-imprinting method
Technical field
The invention belongs to stamping technique field, be specifically related to a kind of imprint mask version and nanometer Method for stamping.
Background technology
The manufacturing cost of the high-precision nano impression formboard of large area is expensive, how to reduce mould Version cost of manufacture is always the problem of people's research, to this end, 1999, Willson etc. opens Send out stepping-flash of light ultraviolet stamping technology.Generally nano impression can only replicate and theastencil region Structure of the same size, stepping-flash of light ultraviolet stamping nano impression of one area the least Masterplate, by multi-impression, mobile alignment splicing, it is achieved answering of large-area nano structure System.
There is the problem that splicing precision is not enough in stepping-flash of light ultraviolet stamping, this is due to impressing During can be expelled from unnecessary photoresist, outside coining pattern region, have inactive area, Upper once imprint time, will result in bigger splicing seams, this be by improve alignment essence Degree cannot solve problem.
Summary of the invention
It is contemplated that at least solve one of technical problem present in prior art, it is provided that a kind of Imprint mask version that splicing seams is little and nano-imprinting method.
Solve the technology of the present invention problem and be employed technical scheme comprise that a kind of stamp mask version, Including platen, described platen has working region and is surrounded described working region Marginal area;Described stamp mask version also includes the marginal area being arranged on described platen Light shield layer.
Preferably, the side in the working region of described platen has nano-pattern list Unit;Described light shield layer and described nano-pattern unit are positioned at the same side.
Preferably, the side in the working region of described platen has nano-pattern list Unit;Described light shield layer is positioned at the marginal area of described platen and deviates from described nano-pattern list The side of unit.
Preferably, the material of described platen is transparent material.
It may further be preferable that described transparent material includes quartz.
Preferably, the material of described light shield layer is metal.
It may further be preferable that described metal include in chromium, molybdenum, aluminum any number of or Multiple combination.
Solve the technology of the present invention problem and be employed technical scheme comprise that a kind of nano impression side Method, it uses above-mentioned stamp mask version;Described method for stamping includes:
One substrate, and coating impressing glue in substrate are provided;
Described stamp mask version is directed at described substrate pressure, so that described stamp mask version It is stamped on described impressing glue;
By ultraviolet light, described stamp mask version is irradiated, so that described working region The impressing adhesive curing of position;
Described stamp mask version is separated with described impressing glue;
Remove uncured impressing glue, complete an imprinting cycles;
Repeat described imprinting cycles several times, so that forming nano-pattern battle array in described substrate Row.
Preferably, the material of described impressing glue is ultraviolet photocureable material.
Preferably, described ultraviolet photocureable material is siliceous ultraviolet photocureable material.
There is advantages that
Owing to the platen marginal area of the imprint mask version in the present invention arranges light shield layer, Therefore at the UV curing process being carried out large-area nano impressing by this imprint mask version In, it is blocked layer with the impressing glue of the marginal area correspondence position of platen and blocks, thus UV curing process will not be cured, only with platen working region correspondence position Impressing glue be cured, wash uncured impressing glue off at developing process, i.e. remove and press The impressing glue of printing forme marginal area correspondence position so that useful nano-pattern unit is able to Retain, can imprint in the position fitted completely in upper once moulding process, spell The size of seam is solely dependent upon aligning accuracy, will not be subject in last moulding process and pressure The impressing glue impact of the marginal area correspondence position of printing forme, can effectively reduce splicing seams, Improve splicing precision.
Accompanying drawing explanation
Fig. 1 is the plane graph of the stamp mask plate in embodiments of the invention 1;
Fig. 2 is a kind of schematic cross-section of the stamp mask plate of embodiments of the invention 1;
Fig. 3 is the another kind of schematic cross-section of the stamp mask plate of embodiments of the invention 1;
Fig. 4 is the process chart of the nano-imprinting method of the 2 of embodiments of the invention;
Fig. 5 is the flow chart of the nano-imprinting method of the 2 of embodiments of the invention.
Wherein reference is: 1, platen;2, light shield layer.
Detailed description of the invention
For making those skilled in the art be more fully understood that technical scheme, knot below Close the drawings and specific embodiments the present invention is described in further detail.
Embodiment 1:
As it is shown in figure 1, the present embodiment provides one in large-area nano method for stamping Imprint mask version should, this mask plate stamp mask version includes platen 1, this platen 1 There is working region and the marginal area surrounded described working region;Described stamp mask Version also includes the light shield layer 2 being arranged on the marginal area of described platen 1.
Owing to platen 1 marginal area in the imprint mask version of the present embodiment arranges shading Layer 2, therefore in the ultra-violet curing mistake being carried out large-area nano impressing by this imprint mask version Cheng Zhong, is blocked layer 2 with the impressing glue of the marginal area correspondence position of platen 1 and blocks, Thus will not be cured in UV curing process, only with platen 1 working region pair The impressing glue answering position is cured, and washes uncured impressing glue off at developing process, i.e. goes Except the impressing glue with platen 1 marginal area correspondence position so that useful nano-pattern Unit is retained, and can carry out in the position fitted completely in upper once moulding process Impressing, the size of splicing seams is solely dependent upon aligning accuracy, will not be imprinted by the last time With the impressing glue impact of the marginal area correspondence position of platen 1 in journey, can effectively subtract Little splicing seams, improves splicing precision.
Wherein, the light shield layer 2 in the imprint mask version of the present embodiment can be arranged on and press The side with nano-pattern unit of printing forme 1, as shown in Figure 2;Or, light shield layer 2 The marginal area being positioned at described platen 1 deviates from the side of described nano-pattern unit, as Shown in Fig. 3.
Wherein, the material of platen 1 is transparent material.Preferably, platen 1 uses Quartz material.Other materials can certainly be used.
Wherein, the material of light shield layer 2 is metal.Preferably, light shield layer 2 be chromium, molybdenum, An any number of or multiple combination in aluminum.It is of course also possible to use other metal materials
Embodiment 2:
Shown in Figure 4 and 5, the present embodiment provides a kind of nano-imprinting method, at this Method uses the imprint mask version in embodiment 1.This nano-imprinting method specifically includes Following steps:
S1, provide a substrate, and coating impressing glue in substrate.
Concrete, in substrate, by spin coating technique, impressing glue is coated in substrate On.Wherein, impressing glue is ultraviolet photocureable material, and the most siliceous ratio is higher, viscosity Ratio is relatively low, and ultra-violet curing required dosage is little, the material that etch resistance is strong.S2, by described Stamp mask version is directed at described substrate pressure, so that described stamp mask version is stamped into described On impressing glue.
Concrete, in this step, first, it is right first imprint mask version and substrate to be carried out Position;Afterwards, imprint mask version is pressed, by stamp mask version by gas or solid Nano-pattern unit be stamped on the impressing glue of substrate.
S3, by ultraviolet light, described stamp mask version is irradiated, so that described work The impressing adhesive curing of the position in region.
Concrete, owing to the working region of imprint mask version is without light shield layer 2, therefore work as purple Outer light is imprinted with mask plate when exposing to imprint glue so that impressing glue and imprint mask version The impressing glue of working region correspondence position be cured.Marginal zone due to imprint mask version Territory arranges light shield layer 2, hence in so that impressing glue laminated is corresponding with the marginal area of print mask plate Position will not be irradiated by ultraviolet light, thus this partially embossed glue will not be cured.
S4, by stamp mask version with impressing glue separate.
In this step, namely stamp mask version is taken out from impressing glue, now press It has been stamped nano-pattern unit on print glue.
S5, remove uncured impressing glue, complete an imprinting cycles.
Concrete, by developing process, remove position corresponding with the marginal area printing mask plate The impressing glue put, so far completes an imprinting cycles.
S6, repeat described imprinting cycles several times, so that forming nanometer figure in described substrate Case array.
Owing to the impressing in applying embodiment 1 at the nano-imprinting method of the present embodiment is covered Film version, i.e. platen 1 marginal area in imprint mask version are provided with light shield layer 2, therefore In the UV curing process being carried out large-area nano impressing by this imprint mask version, with The impressing glue of the marginal area correspondence position of platen 1 is blocked layer 2 and blocks, thus UV curing process will not be cured, only with platen 1 working region correspondence position Impressing glue be cured, wash uncured impressing glue off at developing process, i.e. remove and press The impressing glue of printing forme 1 marginal area correspondence position so that useful nano-pattern unit obtains To retain, can imprint in the position fitted completely in upper once moulding process, The size of splicing seams is solely dependent upon aligning accuracy, will not by last moulding process with The impressing glue impact of the marginal area correspondence position of platen 1, can effectively reduce splicing Seam, improves splicing precision.
Explanation is needed, formed in nano-imprinting method in the present embodiment at this Nano-pattern array can also be as the mask plate of a big type, by this mask plate to pressure Print glue imprints, and is formed identical with the nano-pattern array formed in step S1~S6 Pattern, it is not necessary to multi-impression, the most just can complete nano-pattern array, the most permissible Improve production efficiency.
It is understood that the principle that embodiment of above is intended to be merely illustrative of the present And the illustrative embodiments used, but the invention is not limited in this.For ability For those of ordinary skill in territory, in the situation without departing from spirit and substance of the present invention Under, various modification and improvement can be made, these modification and improvement are also considered as the present invention's Protection domain.

Claims (10)

1. a stamp mask version, including platen, it is characterised in that described platen There is working region and the marginal area surrounded described working region;Described stamp mask Version also includes the light shield layer being arranged on the marginal area of described platen.
Stamp mask version the most according to claim 1, it is characterised in that described The side of the working region of platen has nano-pattern unit;Described light shield layer is with described Nano-pattern unit is positioned at the same side.
Stamp mask version the most according to claim 1, it is characterised in that described The side of the working region of platen has nano-pattern unit;Described light shield layer is positioned at institute The marginal area stating platen deviates from the side of described nano-pattern unit.
Stamp mask version the most according to claim 1, it is characterised in that described pressure The material of printing forme is transparent material.
Stamp mask version the most according to claim 4, it is characterised in that described Bright material includes quartz.
Stamp mask version the most according to claim 1, it is characterised in that described screening The material of photosphere is metal.
Stamp mask version the most according to claim 6, it is characterised in that described gold Belong to any number of or multiple combination including in chromium, molybdenum, aluminum.
8. a nano-imprinting method, it is characterised in that use in claim 1-7 and appoint One described stamp mask version;Described method for stamping includes:
One substrate, and coating impressing glue in substrate are provided;
Described stamp mask version is directed at described substrate pressure, so that described stamp mask version It is stamped on described impressing glue;
By ultraviolet light, described stamp mask version is irradiated, so that described working region The impressing adhesive curing of position;
Described stamp mask version is separated with described impressing glue;
Remove uncured impressing glue, complete an imprinting cycles;
Repeat described imprinting cycles several times, so that forming nano-pattern battle array in described substrate Row.
Nano-imprinting method the most according to claim 8, it is characterised in that described The material of impressing glue is ultraviolet photocureable material.
Nano-imprinting method the most according to claim 9, it is characterised in that institute Stating ultraviolet photocureable material is siliceous ultraviolet photocureable material..
CN201610596067.5A 2016-07-26 2016-07-26 Embossing mask plate and nano-embossing method Pending CN105974732A (en)

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Application Number Priority Date Filing Date Title
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Cited By (9)

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CN107179620A (en) * 2017-06-07 2017-09-19 京东方科技集团股份有限公司 The preparation method of ultra thin substrate bonding structure and preparation method thereof, display device
CN107357133A (en) * 2017-09-15 2017-11-17 京东方科技集团股份有限公司 Photoetching agent pattern forming method and impressing mould
CN108277454A (en) * 2018-04-23 2018-07-13 京东方科技集团股份有限公司 Fine mask plate and preparation method thereof
CN108445711A (en) * 2018-03-13 2018-08-24 京东方科技集团股份有限公司 A kind of display base plate and preparation method thereof, display device
CN109188863A (en) * 2018-11-05 2019-01-11 京东方科技集团股份有限公司 The method of film pattern
CN111061124A (en) * 2019-12-23 2020-04-24 杭州欧光芯科技有限公司 Ultraviolet curing nano-imprinting mold with cutting channel and method
CN111610694A (en) * 2020-06-22 2020-09-01 京东方科技集团股份有限公司 Manufacturing method of embossing template and embossing template
CN111624851A (en) * 2020-06-16 2020-09-04 京东方科技集团股份有限公司 Imprint template and preparation method thereof
CN112074784A (en) * 2018-03-19 2020-12-11 应用材料公司 Method and apparatus for producing seamless large-area imprints

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CN103226288A (en) * 2013-04-27 2013-07-31 苏州大学 UV-curing micro-nano-structure template-splicing device and template-splicing process
CN105319840A (en) * 2015-11-23 2016-02-10 南通天鸿镭射科技有限公司 Apparatus and method for manufacturing ultraviolet-light-cured seamless-moulded roller wheel through replication technology
CN105789118A (en) * 2016-04-14 2016-07-20 京东方科技集团股份有限公司 Display substrate and manufacturing method thereof

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WO2012018045A1 (en) * 2010-08-06 2012-02-09 綜研化学株式会社 Resin mold, production method thereof, and use thereof
CN202563242U (en) * 2011-11-25 2012-11-28 宏濂科技有限公司 Photomask of exposure machine
CN103226288A (en) * 2013-04-27 2013-07-31 苏州大学 UV-curing micro-nano-structure template-splicing device and template-splicing process
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Publication number Priority date Publication date Assignee Title
CN107179620A (en) * 2017-06-07 2017-09-19 京东方科技集团股份有限公司 The preparation method of ultra thin substrate bonding structure and preparation method thereof, display device
CN107357133A (en) * 2017-09-15 2017-11-17 京东方科技集团股份有限公司 Photoetching agent pattern forming method and impressing mould
CN108445711A (en) * 2018-03-13 2018-08-24 京东方科技集团股份有限公司 A kind of display base plate and preparation method thereof, display device
TWI717692B (en) * 2018-03-19 2021-02-01 美商應用材料股份有限公司 Methods and apparatus for creating a large area imprint without a seam
CN112074784A (en) * 2018-03-19 2020-12-11 应用材料公司 Method and apparatus for producing seamless large-area imprints
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CN108277454A (en) * 2018-04-23 2018-07-13 京东方科技集团股份有限公司 Fine mask plate and preparation method thereof
CN109188863A (en) * 2018-11-05 2019-01-11 京东方科技集团股份有限公司 The method of film pattern
CN109188863B (en) * 2018-11-05 2021-11-26 京东方科技集团股份有限公司 Method for patterning film layer
CN111061124A (en) * 2019-12-23 2020-04-24 杭州欧光芯科技有限公司 Ultraviolet curing nano-imprinting mold with cutting channel and method
CN111624851A (en) * 2020-06-16 2020-09-04 京东方科技集团股份有限公司 Imprint template and preparation method thereof
CN111610694A (en) * 2020-06-22 2020-09-01 京东方科技集团股份有限公司 Manufacturing method of embossing template and embossing template

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