CN105970697A - Color fixing process method for natural dyeing of textiles - Google Patents
Color fixing process method for natural dyeing of textiles Download PDFInfo
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- CN105970697A CN105970697A CN201610387666.6A CN201610387666A CN105970697A CN 105970697 A CN105970697 A CN 105970697A CN 201610387666 A CN201610387666 A CN 201610387666A CN 105970697 A CN105970697 A CN 105970697A
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/02—After-treatment
- D06P5/04—After-treatment with organic compounds
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/34—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using natural dyestuffs
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/02—After-treatment
- D06P5/04—After-treatment with organic compounds
- D06P5/06—After-treatment with organic compounds containing nitrogen
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/02—After-treatment
- D06P5/04—After-treatment with organic compounds
- D06P5/08—After-treatment with organic compounds macromolecular
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/02—After-treatment
- D06P5/10—After-treatment with compounds containing metal
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Abstract
The invention provides a color fixing process method for natural dyeing of textiles, and the method is a two-step color fixing treatment method of the textiles dyed with natural dye. The method comprises the steps that 1, the dyed textiles are dipped in a first treatment fluid, and conventional pad-dry process treatment is conducted; 2, the textiles in the first step are dipped in a second treatment fluid, conventional pad-dry process treatment is conducted, and a dyed finished product is obtained finally, wherein the first treatment fluid comprises a penetrant JFC, glyoxal, alchlor and citric acid or tartaric acid, and the second treatment fluid comprises polyvinyl alcohol or urea. According to the color fixing process method for natural dyeing of the textiles, technical indicators of color fastnesses such as a soaping fastness, a rubbing fastness, a perspiration fastness and a color fastness to light are improved, in the composed whole dyeing treatment process, no auxiliary is used, index requirements of environmental protection and biocompatibility of China and European Union countries are met, and the method has the technical advantages of being high in natural dye utilization rate and high in technical economy integrative optimization.
Description
Technical field
The present application relates to dyeing and its post-processing approach, the in particular sky of textile fabric or its fabric
So color-fixing method of dyeing.
Background technology
Textile dyeing experienced by the technology development course that natural dyeing to chemosynthesis is dyeed, in this course, people
More awareness and understanding chemosynthesis is dyeed the harm brought to health, especially its environmental pollution that cannot avoid
The technology drawback of aspect, the highest along with returning natural cry now, natural dyeing technology is again introduced into the visual field of people.
Re-recognize natural dyeing, how to maximize favourable factors and minimize unfavourable ones, new step develops weaving pollution-free industry further, is technical staff face
Face new research topic.
Natural dye and dyeing thereof are despite many advantages, but chemosynthesis dyeing replaces natural dye the most comprehensively
Material and dyeing thereof, be because natural dye dying and face three big technical barriers, constrains the application of its scale industry: one is natural
Dye material source is rare, cost of material occupy high-leveled and difficult under, owing to can be Chinese herbal medicine as the raw material majority of dyestuff, medicinal occupancy
Greatly, and medicinal economic worth constantly raises cost of material, therefore, for economy and resource provisioning, these natural materials
Dope dyeing application does not have economic advantages；Two is to compare chemical synthetic dye, and natural dye is weak with interfibrous affinity, leads
Cause dye-uptake is low, and a large amount of dyestuffs discharge with dyeing residual liquid, and dye utilization rate is low, and wastage is big, is subject high cost of material
Meanwhile, dyeing production cost is to make the matter worse；Three is that natural dye dying fastness is not good enough, between natural dye and fiber predominantly
Hydrogen bonded, hydrogen bond energy is little, and natural pigment easily comes off from fiber, and then the business that have impact on natural dyeing textile is real
The property used；It addition, natural pigment itself there is also the instable technical characteristic of color, colour tone can be by temperature, Exposure to Sunlight, pH value
Change etc. multiple such environmental effects, cause yarn fabric variable color, be color fastness another technical reason on the low side.
Research worker has carried out substantial amounts of technical research for the problem that natural dye exists, it has been suggested that solution master
Have:
Improve natural dye dying fastness, generally use mordant carry out mordant dyeing or use color fixing agent fixation treatment.Though mordant dyeing
So there is certain effect, but, mordant typically contains heavy metal ion, in attachment fabric, to human health, Er Qieran
Color technique contains the waste liquid of heavy metal ion, its exhaust emission environment, does not meets various countries about ecological textile content of beary metal
Technical requirement, objective natural, environmental protection is runed counter to dyeing；Furthermore, improving dyefastness simultaneously, the interpolation of mordant is also
Can change the tone of dyestuff itself, after mordant dyeing, fabric color changes the most greatly；Other method is to use color fixing agent fixation treatment to carry
High dyefastness, is also the fixation technological means that natural dyeing is conventional, but generally contains formaldehyde or the process of use in color fixing agent
The middle technical problem that there is release formaldehyde.
It addition, low for solving natural dye dye-uptake, general employing mordant carries out mordant dyeing, furthermore is to implement before dyeing
Fabric cation pretreatment modification.The technical problem of mordant dyeing is as previously mentioned.Pretreatment modification method is complex, and cation changes
After property, fiber is when dyeing, easily brings in dye bath by the modifying agent of non-set, and these modifying agent compositions are directly and anionic property
Natural dye reaction, have impact on the stability of dye liquor.As a whole, two kinds of method effects on dye utilization rate improves are equal
Very limited.
Summary of the invention
It is an object of the invention to provide a kind of application natural dye and implement textile dyeing, the dyed textiles obtained contaminates
Color fastness is high, and a whole set of dyeing meets the color fixing process method of textile natural dyeing of biocompatibility environmental protection concept.
The color fixing process method and technology scheme of the textile natural dyeing that the present invention provides, its main technical content is: one
Planting the color fixing process method of textile natural dyeing, the textile after natural dye dying completes fixation treatment through following two steps,
Step one: the textile after dyeing is immersed the first treatment fluid, rolls baking PROCESS FOR TREATMENT through conventional；Step 2: by step one place
Textile after reason immerses the second treatment fluid, processes through the conventional baking process that rolls, and with conventional washing, soaps, again after washing
Dry or dry, preparing dyeing product；The first described treatment fluid by penetrating agent JFC, Biformyl, aluminum chloride, citric acid or
One of tartaric acid is uniformly mixed with water, in the first treatment fluid, containing penetrating agent JFC 0.5 ~ 1 grams per liter, containing 40 % matter
The Biformyl of amount percentage concentration is 2 ~ 10 grams per liters, containing aluminum chloride 1 ~ 2 grams per liter, containing citric acid or 1 ~ 3 gram of tartaric acid/
Rise；Described second treatment fluid is uniformly mixed with water by the glacial acetic acid of one of polyvinyl alcohol or carbamide, pH value regulation, the
In two treatment fluids, being 2 ~ 10 grams per liters or the grams per liter in carbamide 5 ~ 10 containing polyvinyl alcohol 1750, its pH value is 3 ~ 4.
In above-mentioned overall technical architecture, described natural dye is the natural dye containing two and above phenolic hydroxyl group
Material, as Querci Mongolicae bark and leaves extract dyestuff, Folium Camelliae sinensis extraction dyestuff, fructus zizaniae caduciflorae extraction dyestuff, Flos Carthami extraction dyestuff, Lignum Sappan extraction dye
Material etc., or according to mixing color needs, two or more phase of described natural dye the mixing natural dye allocated.
In above-mentioned overall technical architecture, described textile is silkworm silk, Pilus Caprae seu Ovis, chinlon, cotton or regenerated cellulose
Fiber and knitted fabric thereof or woven fabric.
The color fixing process method and technology scheme of the textile natural dyeing of the present patent application, has a following technological merit:
This color fixing process method is with the Biformyl in the first treatment fluid for fiber and dyestuff, fiber and being total to that polyvinyl alcohol or carbamide couple
" bridge " that valence link combines, high bond energy enables dyestuff to be firmly bonded on fiber, and in this programme, rolling by step 2
Baking process processes, on the basis of step one rolls baking pretreatment, further contribute to Biformyl and fiber and dyestuff, Biformyl with
Polyvinyl alcohol or urea condensation polyreaction, the highest bond energy combines, and the cross-linked network on the other hand formed on fiber is protected
Protecting outer layer, strengthen the combination of dyestuff and fiber the most comprehensively, it is to avoid coming off of dyestuff, this protection outer layer is also simultaneously
Constitute isolation structure outside environmental elements and dyestuff being isolated, it is suppressed that staining tendencies or the generation of decolouring, this fixation work
Process the most effectively inhibits the reactive functional groups in dye structure, adds the stability of dye dyestuff.That is, this technology
The color fixing process method of scheme, its rational technological design and step design have played its comprehensive synergism, improve dyeing
The textile every color fastness technology including fastness to soaping, fastness to rubbing, fastness to perspiration and color fastness to light refers to
Mark.Another big technological merit of the technical program is: this color fixing process method can be configured as the back segment of Pure natural dye dyeing
Operation, produces pure natural dyed textiles, and described Pure natural dye dyeing is in dyeing process, and natural dye liquid is without appointing
What auxiliary agent, the dyed textiles obtained, through the color fixing process method process of this programme, its dyed textiles finished product not only has excellent
Good dyefastness, this process also maintains natural dye liquid original dyestuff composition, and middle need to be by dyeing consumption
Supplement the stock staining solution of respective amount, continue to implement the dyeing process of next round, thus, there is dye utilization rate high, substantially without wave
The technological merit taken.Combining before and after the technical program and natural dye dying operation, a whole set of dyeing of composition processes technique, its stream
Journey technique whole process does not use any auxiliary agent, and such as accelerant, mordant, color fixing agent etc., the dyed textiles finished product prepared accords with completely
Closing country and the environmental protection of American-European countries, biocompatibility index request, natural dye utilization rate is high, has Technological Economy the most excellent
The property changed, is suitable for industrial scale application.
Detailed description of the invention
To be described in detail the color fixing process method of the textile natural dyeing of the present patent application below by each embodiment.
Before the color fixing process method of this textile natural dyeing is implemented, it is textile natural dye dying operation, including
The preparation of natural dye stock solution and dyeing.Described natural dye is containing two and the natural dye of above phenolic hydroxyl group, including
Querci Mongolicae bark and leaves extraction dyestuff, Folium Camelliae sinensis extraction dyestuff, fructus zizaniae caduciflorae extraction dyestuff, Flos Carthami extraction dyestuff, Lignum Sappan extraction dyestuff etc.,
Or according to mixing color needs, two or more phase of described natural dye the mixing natural dye allocated.
The preparation of natural dye stock solution:
Take dry natural plant raw material, remove impurity, clean after naturally dry or dry, pulverizing, be typically crushed to 0.1 ~ 1cm, with
The mass ratio of water is that 1:5 ~ 15 are immersed in the water, and soaks 2 ~ 8 hours, reflux thereafter at a temperature of 60 DEG C ~ 105 DEG C in room temperature
Extracting 40 ~ 80 minutes, be filtered to remove residue, the filtrate obtained is natural dye stock solution, wherein, and also can be according to different resistance to of plant
Thermal property, such as Querci Mongolicae bark and leaves, its reflux, extract, temperature control is at 90 ~ 102 DEG C.
Dyeing:
It is 50% ~ 100% that natural dye liquid, the mass percent of natural dye stock solution therein are used in dyeing, and remaining is water, described
Natural dye stock solution can be the extracting solution of single a kind of natural plant raw material, it is also possible to is that two or more natural is planted
Raw material extracts the mixed liquor of stock staining solution.Dyeing is: bath raio 1:30 ~ 80, dyeing pH value are 3.0 ~ 6.5, by ice vinegar
One of acid, citric acid or dilute sulfuric acid regulation pH value, dyeing temperature is 80 ~ 102 DEG C, dyeing time 40 ~ 80 minutes, takes out water
Wash, prepare dyed textiles；Supplementing the stock staining solution amount consumed in dyeing residual liquid, dyeing cycle uses, and makes natural dye
Utilized comprehensively.
The following is a whole set of dyeing handling process including the preparation of natural dye stock solution, dyeing and color fixing process method composition
Specific embodiment.
Embodiment 1
The textile of the present embodiment is mulberry silk or Light of Mulberry Silk Fabrics, and natural dye raw material is Folium Querci Mongolicae.
1, the preparation of natural dye stock solution: collecting the Querci Mongolicae fallen leaves in winter, clean and dry, pulverize, Folium Querci Mongolicae and water are by 1:
10 mass ratioes mixing, soak 3 hours in room temperature, in 100 DEG C of reflux, extract, 60 minutes, filter extracting solution, obtain Folium Querci Mongolicae natural
Stock staining solution；
2, dyeing: by glacial acetic acid regulation natural dye stock solution pH value to 3.5, immerse mulberry silk or Bombyxmori Linnaeus silk weaving by bath raio 1:60
Thing, dyes 45 minutes at a temperature of 98 DEG C, takes out mulberry silk or Light of Mulberry Silk Fabrics, washing；
3, color fixing process method:
Step one: mulberry silk after dyeing or Light of Mulberry Silk Fabrics are immersed in the first treatment fluid, after impregnating 2 minutes under room temperature, two leachings
Two roll, pick-up 100 %, 80 DEG C of drying.The first described treatment fluid is by penetrating agent JFC, Biformyl, aluminum chloride, citric acid
It is uniformly mixed with water, in the first treatment fluid, containing penetrating agent JFC 0.6 grams per liter, containing 40 % mass percentage concentration Biformyls
3 grams per liters, containing aluminum chloride 1 grams per liter, containing citric acid 1 grams per liter.Biformyl therein can also choose other concentration finished product, with
The consumption of 40 % concentration Biformyl 3 grams per liters converts usage amount, and following embodiment in like manner, repeats no more；
Step 2: the mulberry silk processed through step one or Light of Mulberry Silk Fabrics are immersed in the second treatment fluid, after impregnating 2 minutes, two
Leaching two is rolled, liquid carrying rate 90 %, 80 DEG C of drying, and 110 DEG C bake 2.5 minutes, then wash, soap, wash after dry, prepared Mulberry
Silkworm silk or Light of Mulberry Silk Fabrics dyeing product.The second described treatment fluid by polyvinyl alcohol, regulate its pH value glacial acetic acid equal with water
Even mixing, in the second treatment fluid, be 3 grams per liters containing polyvinyl alcohol 1750, pH value is 3.8.
Embodiment 2.
The textile of the present embodiment is nylon fabric, and the natural dye original is Cortex Querci Mongolicae.
1, the preparation of natural dye stock solution: take and discarded be dried Cortex Querci Mongolicae, is crushed to the fragment of 0.1 ~ 1 cm, Cortex Querci Mongolicae with
Water is immersed in the water by 1:8 mass ratio, soaks 5 hours under room temperature, then at 102 DEG C of reflux, extract, 70 minutes, crosses and filters residue, system
Obtain Cortex Querci Mongolicae natural dye stock solution；
2, dyeing: taking above-mentioned natural dye stock solution and mix with water as dye bath, it is 60 % that natural dye stock solution accounts for mass percent,
It is 3 by the pH value of dilute sulfuric acid regulation dye bath.Nylon fabric and bath raio 1:50 of dye bath, dye 80 minutes at temperature 100 DEG C,
Take out water washing dyeing nylon fabric；
3, color fixing process method:
Step one. being immersed by nylon fabric after dyeing in the first treatment fluid, after impregnating 2.5 minutes under room temperature, two leachings two are rolled, and roll
Remaining rate 100 %, 90 DEG C of drying.The first described treatment fluid is equal with water by penetrating agent JFC, Biformyl, aluminum chloride, tartaric acid
Even mix, in the first treatment fluid, containing penetrating agent JFC 0.75 grams per liter, containing 40 % mass percentage concentration Biformyl 7 grams/
Rise, containing aluminum chloride 1.5 grams per liter, containing tartaric acid 2 grams per liter；
Step 2: nylon fabric step one processed immerses in the second treatment fluid, after impregnating 5 minutes, 2 leachings 2 are rolled, liquid carrying rate
100 %, 90 DEG C of drying, 120 DEG C bake 2 minutes, nylon fabric is again through washing, soap, wash post-drying, and prepared chinlon is knitted
Thing dyeing product.Described second treatment fluid is uniformly mixed with water by the glacial acetic acid of carbamide, regulation pH value, containing carbamide is wherein
5 grams per liters, pH value is 3.3.
Embodiment 3
The textile of the present embodiment is bafta, and natural dye raw material is Cortex Querci Mongolicae.
1, the preparation of natural dye stock solution: take dry Cortex Querci Mongolicae, is crushed to the fragment of 0.1 ~ 0.5 cm, with water by 1:
The mass ratio of 10 is immersed in the water, and soaks 6 hours under room temperature, then in 100 DEG C of reflux, extract, 40 minutes, crosses and filters residue,
To Cortex Querci Mongolicae natural dye stock solution；
2, dyeing: taking above-mentioned Cortex Querci Mongolicae natural dye stock solution and mix with water as dye bath, natural dye stock solution accounts for gross mass 70 %,
Dyeing condition is: bath raio 1:60, and dyeing pH value is 6.5, dyeing temperature 98 DEG C, and dyeing time is 70 minutes, and washing prepares sky
So dyeing bafta；
3, color fixing process method:
Step one: during bafta immerses the first treatment fluid after dyeing, after impregnating 2 ~ 5 minutes under room temperature, two leachings two are rolled, pick-up 90
%, 100 DEG C of drying；The first described treatment fluid uniformly mixed with water by penetrating agent JFC, Biformyl, aluminum chloride, citric acid and
Become, in the first treatment fluid, containing penetrating agent JFC 0.5 grams per liter, containing 40 % mass percentage concentration Biformyl 8 grams per liters, containing tri-chlorination
Aluminum 2 grams per liter, containing citric acid 1.3 grams per liter；
Step 2: the bafta after step one being processed immerses in the second treatment fluid, after impregnating 4 minutes, two leachings two are rolled, liquid carrying rate
85 %, 85 DEG C of drying, 125 DEG C bake 2 minutes, bafta, through washing, soap, washing post-drying, prepares bafta natural
Dyeing product.Described second treatment fluid is uniformly mixed with water by the glacial acetic acid of polyvinyl alcohol 1750, regulation pH value, Qi Zhonghan
Polyvinyl alcohol 1750 is 10 grams per liters, and its pH value is 3.5.
Embodiment 4
The textile of the present embodiment is tussah silk, and natural dye raw material is Folium Querci Mongolicae and fructus zizaniae caduciflorae.
1, the preparation of natural dye stock solution: take dry Folium Querci Mongolicae, cleans post-drying, is crushed to the fragment of 0.5 ~ 1 cm,
Fragment is immersed in the water by 1:12 mass ratio with water, soaks 5 hours under room temperature, then in 95 DEG C of reflux, extract, 50 minutes, and mistake
Filter residue, obtain natural Folium Querci Mongolicae stock staining solution；Separately taking fructus zizaniae caduciflorae, mix by 1:12 mass ratio with water, same method extracts black
Rice stock staining solution；
2, dyeing: be dye bath by mass mixings such as above two natural dye stock solutions, is immersed in natural dye mixing by tussah silk
In stock solution, bath raio 1:60, with glacial acetic acid regulation dyeing pH value for 4.0, dye 50 minutes under 95 DEG C of temperature conditionss, washing；
3, color fixing process method:
Step one: above-mentioned dyeing tussah silk textiles is immersed in the first treatment fluid, after impregnating 2.5 minutes under room temperature, two leachings two are rolled,
Pick-up 90 %, 95 DEG C of drying；The first described treatment fluid is equal with water by penetrating agent JFC, Biformyl, aluminum chloride, citric acid
Even mix, in the first treatment fluid, containing penetrating agent JFC 0.5 grams per liter, containing 40 % mass percentage concentration Biformyl 5 grams per liters,
Containing aluminum chloride 1.2 grams per liter, containing citric acid 3 grams per liter；
Step 2: the tussah silk after step one being processed is immersed in the second treatment fluid, after soaking 3 minutes, two leachings two are rolled, liquid carrying rate 90
%, 85 DEG C of drying, 115 DEG C bake 2.5 minutes, tussah silk is through washing, soap, wash post-drying, and prepared tussah silk is coloured to
Product.Described second treatment fluid is uniformly mixed with water by the glacial acetic acid of polyvinyl alcohol 1750, regulation pH value, wherein containing polyethylene
Alcohol 1750 is 10 grams per liters, and its pH value is 3.5.
Embodiment 5
The textile of the present embodiment is wool fabric, and natural dye plant material is Cortex Querci Mongolicae and Lignum Sappan.
1, the preparation of natural dye stock solution: take dry Cortex Querci Mongolicae, is crushed to the fragment of 0.1 ~ 1cm, and fragment and water are by 1:
8 mass ratioes are immersed in the water, and soak 6 hours under room temperature, then in 98 DEG C of reflux, extract, 60 minutes, cross and filter residue, prepare toothed oak
Bark natural dye stock solution；Lignum Sappan is immersed in the water by the mass ratio of 1:8 with water, after soaking 6 hours, extracts 50 points at 90 DEG C
Clock, prepares Lignum Sappan natural dye stock solution；
2, dyeing: following two natural dye stock solution is mixed as dye bath with water, in mass ratio, Cortex Querci Mongolicae stock staining solution: Soviet Union
Wood stain stock solution: water is 6: 3: 1, is 3.2 by dilute sulfuric acid regulation pH value, is immersed by wool fabric in above-mentioned dye bath, bath raio
1:80, at dyeing temperature 90 DEG C 50 minutes, takes out, water washing dyeing wool fabric；
3, color fixing process method:
Step one: above-mentioned dyeing wool fabric immerses in the first treatment fluid, after impregnating 4 minutes under room temperature, two leachings two are rolled, pick-up
100 %, 98 DEG C of drying.The first described treatment fluid is uniformly mixed with water by penetrating agent JFC, Biformyl, aluminum chloride, citric acid
Conjunction forms, wherein, containing penetrating agent JFC 0.8 grams per liter, containing 40 % mass percentage concentration Biformyl 10 grams per liters, containing aluminum chloride
1.6 grams per liters, containing citric acid 2.5 grams per liter；
Step 2: the wool fabric after step one being processed immerses in the second treatment fluid, after impregnating 3.5 minutes, two leachings two are rolled, band
Liquid rate 100 %, 85 DEG C of drying, 110 DEG C bake 4 minutes, then dry after washing, soap, washing, prepare wool fabric dye
Color finished product.Described second treatment fluid by carbamide, regulation pH value glacial acetic acid be uniformly mixed with water, wherein contain 8 grams of carbamide/
Rising, its pH value is 4.
Dyefastness test result:
Claims (5)
1. the color fixing process method of a textile natural dyeing, it is characterised in that the textile after natural dye dying is through following
Two steps complete fixation treatment, step one: the textile after dyeing is immersed the first treatment fluid, rolls baking PROCESS FOR TREATMENT through conventional；
Step 2: the textile after step one being processed immerses the second treatment fluid, processes through the conventional baking process that rolls, with conventional water
Wash, soap, dry after washing again or dry, prepared dyeing product；The first described treatment fluid by penetrating agent JFC, Biformyl, three
One of aluminum chloride, citric acid or tartaric acid and water are uniformly mixed, in the first treatment fluid, containing penetrating agent JFC 0.5 ~ 1
Grams per liter, the Biformyl containing 40 % mass percentage concentration is 2 ~ 10 grams per liters, containing aluminum chloride 1 ~ 2 grams per liter, containing citric acid or
Tartaric acid 1 ~ 3 grams per liter；Described second treatment fluid is uniform with water by one of polyvinyl alcohol or carbamide, pH value regulation glacial acetic acid
Mixing, in the second treatment fluid, be 2 ~ 10 grams per liters or the grams per liter in carbamide 5 ~ 10 containing polyvinyl alcohol 1750, its pH value is 3 ~
4。
The color fixing process method of textile natural dyeing the most according to claim 1, it is characterised in that described natural dye
Material is for containing two and the natural dye of above phenolic hydroxyl group.
The color fixing process method of textile natural dyeing the most according to claim 1 and 2, it is characterised in that described is natural
Dyestuff is Querci Mongolicae bark and leaves extraction dyestuff, Folium Camelliae sinensis extraction dyestuff, fructus zizaniae caduciflorae extraction dyestuff, Flos Carthami extraction dyestuff, Lignum Sappan extraction
Dyestuff, or the mixing natural dye allocated by two or more phase of described natural dye.
The color fixing process method of textile natural dyeing the most according to claim 1, it is characterised in that described textile
For the fiber of silkworm silk, Pilus Caprae seu Ovis, chinlon, cotton or regenerated cellulose and knitted fabric thereof or woven fabric.
The color fixing process method of textile natural dyeing the most according to claim 1, it is characterised in that with 40 % concentration second
The consumption of dialdehyde 3 grams per liter converts the usage amount of other concentration of Biformyl.
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| CN110129897A (en) * | 2019-05-22 | 2019-08-16 | 广西柳城县鹏翔茧丝绸有限责任公司 | A kind of high-light-fastness silk and preparation method thereof |
| CN112521769A (en) * | 2020-11-25 | 2021-03-19 | 清华大学 | Safflower red pigment and preparation method and dyeing method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5951719A (en) * | 1998-06-15 | 1999-09-14 | Callaway Corporation | Process of after-treating dyed cellulose fabrics with a glyoxalated acrylamide polymer |
| US6830593B1 (en) * | 1998-08-03 | 2004-12-14 | The Procter & Gamble Company | Fabric care compositions |
| CN102505521A (en) * | 2011-09-26 | 2012-06-20 | 陕西科技大学 | Method for dyeing superfine fibre synthetic leather by utilizing tannin extract |
| CN103966861A (en) * | 2014-05-19 | 2014-08-06 | 常州美胜生物材料有限公司 | Environment-friendly digital printing ink and preparation method thereof |
| CN104674544A (en) * | 2015-01-21 | 2015-06-03 | 辽东学院 | Tussah silk fabric functional finishing agent, finishing method and finished tussah silk fabric |
-
2016
- 2016-06-02 CN CN201610387666.6A patent/CN105970697B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5951719A (en) * | 1998-06-15 | 1999-09-14 | Callaway Corporation | Process of after-treating dyed cellulose fabrics with a glyoxalated acrylamide polymer |
| US6830593B1 (en) * | 1998-08-03 | 2004-12-14 | The Procter & Gamble Company | Fabric care compositions |
| CN102505521A (en) * | 2011-09-26 | 2012-06-20 | 陕西科技大学 | Method for dyeing superfine fibre synthetic leather by utilizing tannin extract |
| CN103966861A (en) * | 2014-05-19 | 2014-08-06 | 常州美胜生物材料有限公司 | Environment-friendly digital printing ink and preparation method thereof |
| CN104674544A (en) * | 2015-01-21 | 2015-06-03 | 辽东学院 | Tussah silk fabric functional finishing agent, finishing method and finished tussah silk fabric |
Non-Patent Citations (2)
| Title |
|---|
| 周 超等: "三种天然食用色素棉织物染色的研究", 《天津纺织科技》 * |
| 杜宗良等: "真丝织物的无甲醛抗皱整理", 《印染》 * |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109577027A (en) * | 2016-10-09 | 2019-04-05 | 天津工业大学 | A kind of method of the black dyes dyeing wool fabric of plant origin |
| CN109577027B (en) * | 2016-10-09 | 2021-06-18 | 天津工业大学 | Method for dyeing wool fabric by black dye from plant sources |
| CN107964810A (en) * | 2017-12-05 | 2018-04-27 | 英泰时尚服饰（苏州）有限公司 | A kind of tea dyeing technique |
| CN108277661A (en) * | 2018-02-26 | 2018-07-13 | 海宁安裕纺织品有限公司 | A kind of colouring method of textile |
| CN109082905A (en) * | 2018-07-05 | 2018-12-25 | 佛山市衣香蒂丝服装设计有限公司 | A kind of dyeing of textile |
| CN109811560A (en) * | 2019-01-26 | 2019-05-28 | 桐乡市钜汪家纺有限公司 | A kind of production technology of seven color silk cottons |
| CN109811560B (en) * | 2019-01-26 | 2022-06-03 | 桐乡市钜汪家纺有限公司 | Production process of colorful silk floss |
| CN110129897A (en) * | 2019-05-22 | 2019-08-16 | 广西柳城县鹏翔茧丝绸有限责任公司 | A kind of high-light-fastness silk and preparation method thereof |
| CN110129897B (en) * | 2019-05-22 | 2022-01-14 | 广西柳城县鹏翔茧丝绸有限责任公司 | High-light-resistance silk and preparation method thereof |
| CN112521769A (en) * | 2020-11-25 | 2021-03-19 | 清华大学 | Safflower red pigment and preparation method and dyeing method thereof |
| CN112521769B (en) * | 2020-11-25 | 2021-11-30 | 清华大学 | Safflower red pigment and preparation method and dyeing method thereof |
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