CN101469517B - Method for dyeing peony pigment on protein fibre fabric - Google Patents
Method for dyeing peony pigment on protein fibre fabric Download PDFInfo
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- CN101469517B CN101469517B CN2007101733480A CN200710173348A CN101469517B CN 101469517 B CN101469517 B CN 101469517B CN 2007101733480 A CN2007101733480 A CN 2007101733480A CN 200710173348 A CN200710173348 A CN 200710173348A CN 101469517 B CN101469517 B CN 101469517B
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Abstract
The invention discloses a method for dyeing peony flower pigment onto protein fiber fabrics. The method uses peony flower pigment solution with concentration of 5-120g/L, pH value from 2 to 5 to dye the protein fiber fabric through direct dyeing method or mordant dyeing method, that is methods without or with mordant added, wherein the peony flower pigment solution includes a peony flower red pigment solution and a peony flower yellow pigment. The obtained protein fiber fabric has determined color fastness and brightness, which meets the environment protection requirements. The method is suitable for dyeing process for protein fiber fabric such as wool, silk or the like.
Description
Technical field
The present invention relates to the colouring method of a kind of natural colouring matter on protein fibre fabric, more particularly, relate to peony flower pigment, comprise peony red pigment and the peony yellow pigment colouring method on protein fibre fabric.
Background technology
Natural dye is meant and obtains from plant, animal or mineral resources, seldom or not passes through the dyestuff of chemical process, can be divided into vegetable colour, animal dye and mineral dye according to the source, and wherein the application of vegetable colour in fabrics printing and dyeing processing is more.Vegetable colour is meant the coloring matter that extracts root, leaf, flower, trunk or the fruit from plant, and common have madder, Asian puccoon, bush, indigo, safflower, pomegranate, Chinese ilex, red bayberry, persimmon, Yellow Fructus Gardeniae, mulberry, tealeaves etc.
Have a long history in China with natural dye dying, the preparation of period of Ming and Qing China's natural dye and staining technique have all reached very high level.Synthetic dyestuffs because riotous with colour, characteristics such as chromatogram is complete, washable sun-proof, low price have progressively replaced natural dye, have become the topmost colouring agent of textiles since coming out in the middle of the 19th century, promoted the development of textile industry.But the waste water that synthetic dyestuffs discharge in dyeing process has caused serious pollution to environment, and some dyestuff intermediates can cause human body skin irritated and carcinogenic.Along with improving constantly of people's environmental consciousness, the application of natural dye more and more obtains people's attention, however vegetable colour nontoxic, harmless with it, have preferably biodegradability and Environmental compatibility, its color and luster soft, from being subjected to people's attention again.Countries such as Japan, Korea S, Korea, India, Britain, the U.S. use the natural fabric of vegetable colour printing and dyeing to become a kind of fashion.
Tree peony is the special product flowers of China, and big to spend, look gorgeous, and is splendid and extremely common people's favor is thriving and prosperous, and the symbol of peace luckiness has good reputation aromatic, the king in spending.The Peony Culture of Xing Chenging has become wonderful work in the Chinese national culture extended familys over the past thousands of years.Compatriots have gathered around tree peony the throne of " national flower " already.At present, the tree peony vegetable colour is still belonged to blank out in the association area at home and abroad in the development and utilization of dyeing.
Research to peony flower pigment at present mainly concentrates on the extracting method of peony flower pigment and the research of pigment composition, and relevant report is also fewer.In addition, from should being used for of peony flower pigment, peony flower pigment comprises peony red pigment and peony yellow pigment, and the additive mainly as foods and cosmetics uses at present.The printing and dyeing that peony flower pigment are used for textiles are processed, and will promote the development and utilization of this novel plant dyestuff of tree peony dyestuff greatly, further widen the Application Areas of peony flower pigment.
The purpose of this invention is to provide the colouring method of a kind of peony flower pigment on protein fibre fabric.The peony flower pigment that this method adopts is beneficial to environmental protection, colouring method is easy and simple to handle.
Summary of the invention
For realizing purpose of the present invention, technical scheme of the present invention is as follows:
The invention provides the colouring method of a kind of peony flower pigment on protein fibre fabric, comprise and carry out successively that protein fibre fabric dyeing is handled, washing is handled, soap and handle and washing, oven dry are handled, wherein, described dyeing is handled and selected concentration for use is that 5～120g/L, pH value are 2～5 peony flower pigment solution, bath raio 28～30: 1, temperature was handled 45～90 minutes down for 80～100 ℃.
According to the colouring method of peony flower pigment of the present invention on protein fibre fabric, wherein be preferably, the peony red pigment that described peony flower pigment solution can be selected for use is red from Luoyang, it is day red to reflect, extract Hu Hong, SHOUANHONG, red kinds of one or more peonies such as purplish red, and the content of peony red pigment is not less than 25%.
According to the colouring method of peony flower pigment of the present invention on protein fibre fabric, wherein be preferably, described peony flower pigment solution can be selected the peony yellow pigment that extracts for use from the yellow kind of peonies such as the Huanghai Sea, and the content of peony yellow pigment is not less than 50%.
According to the colouring method of peony flower pigment of the present invention on protein fibre fabric, wherein be that described protein fibre fabric is selected wool fabric or silk fabric for use preferably.
According to the colouring method of peony flower pigment of the present invention on protein fibre fabric, wherein be that described peony flower pigment solution adds glacial acetic acid and regulates pH value to 2～5 preferably.
According to the colouring method of peony flower pigment of the present invention on protein fibre fabric, wherein be preferably, it is soaping agent that neutral soap flakes are selected in the described processing of soaping for use, temperature was handled 5～10 minutes down for 90～100 ℃.
According to the colouring method of peony flower pigment of the present invention on protein fibre fabric, wherein be that described method is carried out the mordant dyeing preliminary treatment before also comprising the dyeing processing preferably.
According to the colouring method of peony flower pigment of the present invention on protein fibre fabric, wherein be that described mordant dyeing preliminary treatment is selected for use and contained Cu preferably
2+, Sn
2+, Fe
2+, Fe
3+, Ca
2+, Al
3+, Zn
2+Salt in a kind of be mordant, consumption 5～20%o.w.f., bath raio 28～30: 1,20～80 ℃ of temperature were handled 30～90 minutes down.The use of mordant, form and aspect, COLOR FASTNESS and the colour brightness of fabric have certain influence to dyeing afterwards.
According to the colouring method of peony flower pigment of the present invention on protein fibre fabric, wherein be that described method is carried out the mordant dyeing post processing after also comprising the dyeing processing preferably.
According to the colouring method of peony flower pigment of the present invention on protein fibre fabric, wherein be that described mordant dyeing post processing is selected for use and contained Cu preferably
2+, Sn
2+, Fe
2+, Fe
3+, Ca
2+, Al
3+, Zn
2+Salt in a kind of be mordant, consumption 5～20%o.w.f., bath raio 28～30: 1,20～100 ℃ of temperature were handled 30～90 minutes down.The use of mordant, form and aspect, COLOR FASTNESS and the colour brightness of fabric have certain influence to dyeing afterwards.
After testing, the fabric that colouring method of the present invention obtains, its COLOR FASTNESS is: dried, fastness to wet rubbing can reach more than 3 grades; All can reach more than 3 grades under acid and alkali resistance perspiration fastness--staining, the variable color situation; Color fastness to water--can reach more than 4 grades under the staining situation, can reach more than 3 grades under the variable color situation.Mordant has certain influence to light fastness, and fabric light fastness of the present invention can reach about 4 grades.
The present invention has following advantage:
(1) peony flower pigment of the present invention is taken from the natural plants peony, it is used for the dyeing processing on the protein fibre fabrics such as wool fabric, silk fabric, can satisfy the demand of people to the green ecological textiles;
(2) adopt direct staining method or mordant dying method to the processing of dyeing of protein fibre fabrics such as wool, silk fabric, the fabric that can obtain to have certain vividness and COLOR FASTNESS.
The simple declaration of accompanying drawing
Fig. 1 is the direct dyeing process curve schematic diagram of peony flower pigment of the present invention to wool fabric.
T is a dyeing temperature among the figure; T is a dyeing time.
Fig. 2 is that tree peony pigment of the present invention is to the pre-mordant dying method of wool fabric process curve schematic diagram.
T is a dyeing temperature among the figure; T is a dyeing time; T
1Be the mordant dyeing treatment temperature; t
1Be the mordant dyeing processing time.
Fig. 3 be tree peony pigment of the present invention to wool, silk fabric after mordant dying method process curve schematic diagram.
T is a dyeing temperature among the figure; T is a dyeing time; T
1Be the mordant dyeing treatment temperature; t
1Be the mordant dyeing processing time.
The specific embodiment
With reference to the accompanying drawings, be described more specifically content of the present invention.Should be appreciated that the following examples are used to illustrate content of the present invention, and non-limiting content of the present invention, any pro forma change or change all will fall into protection scope of the present invention.
Embodiment 1
Select for use pure wool fabric to dye, be specially:
Get an amount of peony red pigment (paste or liquid), be dissolved in water, being prepared into concentration is 60g/L peony flower pigment solution, the pH value that adds glacial acetic acid adjusting dye liquor then is 2, wetting wool fabric is put into staining solution, dye bath ratio is 28: 1, and dyeing temperature is 95 ℃, and dyeing time is 45 minutes.After the washing, under 90 ℃ of conditions, soaped 10 minutes, and then wash, dry the wool fabric that processing can obtain having certain vividness and COLOR FASTNESS.The dyeing curve as shown in Figure 1.
Embodiment 2
Select for use pure wool fabric to dye, be specially:
Get an amount of peony yellow pigment (Powdered), be dissolved in water, being prepared into concentration is 5g/L peony flower pigment solution, the pH value that adds glacial acetic acid adjusting dye liquor then is 3, wetting wool fabric is put into staining solution, dye bath ratio is 30: 1, and dyeing temperature is 80 ℃, and dyeing time is 90 minutes.After the washing, under 1 00 ℃ of conditions, soaped 5 minutes, and then wash, dry the wool fabric that processing can obtain having certain vividness and COLOR FASTNESS.The dyeing curve as shown in Figure 1.
Embodiment 3
Select for use pure wool fabric to dye, be specially:
Wetting wool fabric is put into the solution that contains the mordant stannous chloride, and the consumption of mordant is 10% (o.w.f.), and bath raio is 28: 1, and treatment temperature is 25 ℃, and the processing time is 90 minutes.After mordant dyeing is handled wool fabric is taken out, unnecessary mordant is removed in drip washing.
Other operations are with embodiment 1.The dyeing curve as shown in Figure 2.
Embodiment 4
Select for use pure wool fabric to dye, be specially:
Wetting wool fabric is put into the solution that contains the mordant ferrous sulfate, and the consumption of mordant is 1 5% (o.w.f.), and bath raio is 30: 1, and treatment temperature is 40 ℃, and the processing time is 90 minutes.After mordant dyeing is handled wool fabric is taken out, unnecessary mordant is removed in drip washing.
Other operations are with embodiment 2.The dyeing curve as shown in Figure 2.
Embodiment 5
Wetting pure wool fabric is put into the solution that contains mordant alum, and the consumption of mordant is 5% (o.w.f.), and bath raio is 30: 1, and treatment temperature is 60 ℃, and the processing time is 30 minutes.After mordant dyeing is handled wool fabric is taken out, unnecessary mordant is removed in drip washing.
Other operations are with embodiment 1.The dyeing curve as shown in Figure 2.
Embodiment 6
Wetting pure wool fabric is put into the solution that contains mordant copper sulphate, and the consumption of mordant is 10% (o.w.f.), and bath raio is 29: 1, and treatment temperature is 60 ℃, and the processing time is 30 minutes.After mordant dyeing is handled wool fabric is taken out, unnecessary mordant is removed in drip washing.
Other operations are with embodiment 2.The dyeing curve as shown in Figure 2.
Embodiment 7
Get an amount of peony red pigment (paste), be dissolved in water, being prepared into concentration is 70g/L peony flower pigment solution, the pH value that adds glacial acetic acid adjusting dye liquor then is 2, wetting pure wool fabric is put into staining solution, dye bath ratio is 28: 1, and dyeing temperature is 95 ℃, and dyeing time is 45 minutes.After being cooled to 80 ℃, add the mordant stannous chloride, the consumption of mordant is 20% (o.w.f.), is warming up to 95 ℃ of post processings 30 minutes.After the washing, under 100 ℃ of conditions, soaped 5 minutes, and then wash, dry the wool fabric that processing can obtain having certain COLOR FASTNESS and vividness.Dyeing as shown in Figure 3.
Embodiment 8
Get an amount of peony yellow pigment (powder), be dissolved in water, being prepared into concentration is 6g/L peony flower pigment solution, the pH value that adds glacial acetic acid adjusting dye liquor then is 2, wetting pure wool fabric is put into staining solution, dye bath ratio is 30: 1, and dyeing temperature is 90 ℃, and dyeing time is 60 minutes.After being cooled to 80 ℃, add mordant alum, the consumption of mordant is 10% (o.w.f.), is warming up to 90 ℃ of post processings 30 minutes.After the washing, under 100 ℃ of conditions, soaped 5 minutes, and then wash, dry the wool fabric that processing can obtain having certain COLOR FASTNESS and vividness.Dyeing as shown in Figure 3.
Embodiment 9
Get an amount of peony red pigment (paste or liquid), be dissolved in water, being prepared into concentration is 120g/L peony flower pigment solution, the pH value that adds glacial acetic acid adjusting dye liquor then is 5, wetting pure wool fabric is put into staining solution, dye bath ratio is 28: 1, and dyeing temperature is 80 ℃, and dyeing time is 50 minutes.Add mordant zinc sulfate again, the consumption of mordant is 20% (o.w.f.), continues to handle 30 minutes.Washing remove more than mordant after, under 90 ℃ of conditions, soaped 10 minutes, and then wash, dry the wool fabric that processing can obtain having certain COLOR FASTNESS and vividness.Dyeing as shown in Figure 3.
Embodiment 10
Get an amount of peony red pigment (paste or liquid), be dissolved in water, being prepared into concentration is 5g/L peony flower pigment solution, the pH value that adds glacial acetic acid adjusting dye liquor then is 5, wetting silk fabric is put into staining solution, dye bath ratio is 30: 1, and dyeing temperature is 80 ℃, and dyeing time is 90 minutes.Add mordant copper sulphate again, the consumption of mordant is 5% (o.w.f.), continues to handle 30 minutes.Washing remove more than mordant after, under 90 ℃ of conditions, soaped 10 minutes, and then wash, dry the silk fabric that processing can obtain having certain COLOR FASTNESS and vividness.Dyeing as shown in Figure 3.
Claims (8)
1. the colouring method of a peony flower pigment on protein fibre fabric, comprise and carry out successively that protein fibre fabric dyeing is handled, washing is handled, soap and handle and washing, oven dry are handled, described method carries out carrying out the mordant dyeing post processing after mordant dyeing preliminary treatment or the dyeing processing before also comprising the dyeing processing, it is characterized in that
Described dyeing is handled and selected concentration for use is that 5～120g/L, pH value are 2～5 peony flower pigment solution, bath raio 28～30: 1, temperature was handled 45～90 minutes down for 80～100 ℃.
2. colouring method as claimed in claim 1 is characterized in that, described peony flower pigment solution is selected peony red pigment for use, and wherein the content of haematochrome is not less than 25% (weight).
3. colouring method as claimed in claim 1 is characterized in that, described peony flower pigment solution is selected peony yellow pigment for use, and wherein the content of uranidin is not less than 50% (weight).
4. colouring method as claimed in claim 1 is characterized in that described protein fibre fabric is selected wool fabric or silk fabric for use.
5. colouring method as claimed in claim 1 is characterized in that, described peony flower pigment solution adds glacial acetic acid and regulates pH value to 2～5.
6. colouring method as claimed in claim 1 is characterized in that, it is soaping agent that neutral soap flakes are selected in the described processing of soaping for use, and temperature was handled 5～10 minutes down for 90～100 ℃.
7. colouring method as claimed in claim 1 is characterized in that, described mordant dyeing preliminary treatment is selected for use and contained Cu
2+, Sn
2+, Fe
2+, Fe
3+, Ca
2+, Al
3+, Zn
2+Salt in a kind of be mordant, consumption 5～20%o.w.f, bath raio 28～30: 1,20～80 ℃ of temperature were handled 30～90 minutes down.
8. colouring method as claimed in claim 1 is characterized in that, described mordant dyeing post processing is selected for use and contained Cu
2+, Sn
2+, Fe
2+, Fe
3+, Ca
2+, Al
3+, Zn
2+Salt in a kind of be mordant, consumption 5～20%o.w.f, bath raio 28～30: 1,20～100 ℃ of temperature were handled 30～90 minutes down.
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| Application Number | Priority Date | Filing Date | Title |
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| CN2007101733480A CN101469517B (en) | 2007-12-27 | 2007-12-27 | Method for dyeing peony pigment on protein fibre fabric |
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| CN2007101733480A CN101469517B (en) | 2007-12-27 | 2007-12-27 | Method for dyeing peony pigment on protein fibre fabric |
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| CN101469517A CN101469517A (en) | 2009-07-01 |
| CN101469517B true CN101469517B (en) | 2010-11-17 |
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Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102102304B (en) * | 2010-12-30 | 2012-07-04 | 东华大学 | Application of shaddock peel natural dye in cotton fabrics dyeing |
| CN102758350B (en) * | 2011-04-29 | 2014-12-10 | 李晓柯 | Textile product printing and dyeing method |
| CN102391666A (en) * | 2011-08-11 | 2012-03-28 | 太仓市新鹿染整有限公司 | Peony haematochrome dye and cloth dyeing process |
| CN102587153A (en) * | 2011-12-31 | 2012-07-18 | 浙江工业职业技术学院 | Method for dyeing silk broadcloth by using plant dye solution extracted from lily |
| CN103790034B (en) * | 2014-01-16 | 2016-01-13 | 河南科技大学 | A kind of SHOUANHONG tree peony pigment carries out the method dyeed |
| CN103790033B (en) * | 2014-01-16 | 2016-01-27 | 河南科技大学 | A kind of method applying tree peony root pigment dyeing wool fabric |
| CN105625057B (en) * | 2014-10-27 | 2017-12-26 | 恒源祥（集团）有限公司 | A kind of processing method of high color fastness natural dye dying wool fabric |
| CN105625058B (en) * | 2014-10-27 | 2017-12-26 | 恒源祥（集团）有限公司 | A kind of processing method using natural dye dying wool fabric |
| CN105178067A (en) * | 2015-09-28 | 2015-12-23 | 江苏丹毛纺织股份有限公司 | Technology method for wool tops dyed with madder plant dye |
| CN105506861A (en) * | 2015-11-27 | 2016-04-20 | 苏州大学 | Natural colored nanofiber membrane preparation method |
| CN108642912B (en) * | 2018-03-28 | 2020-11-13 | 宜州市壮之都丝绸家纺有限公司 | Silk dyeing method |
| CN112095356A (en) * | 2020-09-22 | 2020-12-18 | 苏州虹锦生态纺织科技有限公司 | High-color-fastness vegetable dye printing method for protein fiber fabric |
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| CN1068160A (en) * | 1991-07-01 | 1993-01-20 | 四川省丝绸工业研究所 | The method of dyeing silk cloth by using plant dye of haematine |
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| CN1068160A (en) * | 1991-07-01 | 1993-01-20 | 四川省丝绸工业研究所 | The method of dyeing silk cloth by using plant dye of haematine |
| CN1712634A (en) * | 2005-07-21 | 2005-12-28 | 上海交通大学 | Process for dyeing silk and wool with skullcap |
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