CN100462501C - Yellow (red) native mordant agent of natural plant dye and its using method - Google Patents
Yellow (red) native mordant agent of natural plant dye and its using method Download PDFInfo
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- CN100462501C CN100462501C CNB2006100478856A CN200610047885A CN100462501C CN 100462501 C CN100462501 C CN 100462501C CN B2006100478856 A CNB2006100478856 A CN B2006100478856A CN 200610047885 A CN200610047885 A CN 200610047885A CN 100462501 C CN100462501 C CN 100462501C
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Abstract
The natural yellow or red earth mordant fitting natural plant dye is prepared with yellow or red earth, and through crushing, 50-100 mesh sieving, dissolving in water via stirring, eliminating impurity and floatage, 100-300 sieving to obtain fine dispersed liquid, stilling to precipitate, eliminating supernatant, drying in the sun, and grinding. It is used in mordant dyeing while dyeing fabric with natural plant dye at 50-100 deg.c for 10-60 min, before water washing at 40-60 deg.c and stoving at 80-100 deg.c. The present invention has the advantages of environment friendship, good dyeing effect, etc.
Description
Technical field
The invention belongs to the field of fabric being dyeed, particularly use the natural vegetable dye textile printing technique with natural dye; Simultaneously, the present invention also relates to dyestuff by the natural origin of natural material preparation.
Background technology
The application of natural plant dye has long history, but most of natural plant dyes do not have substantivity or direct less to fiber, and the fabric that is dyeed must rely on mordant just can anchor on the fiber.In traditional mordant dyeing technology, mordant commonly used mostly is greatly and contains the heavy metal ion compound, as Cu, Fe, Cr ion etc.Along with the part kind in the synthetic dyestuffs is forbidden, heavy metal ion content in the textiles also is restricted, for this reason, select for use new mordant to replace traditional heavy metal ion, be an important content developing the ecological processing of textiles at present (1. Wang Ji China etc., the application of natural dye and progress thereof, dye industry, the 32nd the 5th phase of volume, nineteen ninety-five; 2. open and build ripple etc., mordant dyeing of cotton fabric with natural dyestuffs, printing and dyeing, 2005 No. 16).Therefore, in the dyeing of natural plant dye, select the mordant of the native compound pollution-free, that consumption is low for use as natural plant dye dyeing, both can satisfy the required fastness requirement of production environmental protection textiles, (1. woods is carefully tender etc., the mordant dyeing application study of rare earth in vegetable colour dyeing can to avoid the pollution that traditional mordant brings environment again, printing and dyeing assistant, the 19th volume, the 1st phase, in February, 2002; 2. poplar east is clean etc., and madder is in the natural fabric Application of Dyeing, silk, 2000 the 12nd phases).
Summary of the invention
At the deficiencies in the prior art, the present invention aims to provide a kind of natural mordant and play the mordant dyeing effect when dyeing with natural plant dye, and the required technical matters of this mordant dyeing.
Present natural plant dye mainly dyes by infusion process, and in order to improve the dyefastness of product, generally uses mordant.Mordant is most of, and its mordant dyeing mechanism is in the mordant dyeing processing procedure in order to contain the compound (as CN1240808) of metals such as aluminium, iron, copper, calcium, chromium, and vegetable colour-mordant-fiber three forms the stable comple metal-complexing.
About loess, it is based on quartzy (accounting for 50%), feldspar (20%) and carbonate mineral, and calcium carbonate content accounts for about 10%.The chemical composition of loess is preponderated with SiO2, is Al secondly
2O
3, CaO, be Fe once more
2O
3, MgO, K
2O, Na
2O, FeO and TiO
2(Korea S special permission 10-0321991).Each metal ion species is many in the loess, and the generation complex compound that reacts of the ion in they and dyestuff and the fabric strengthens the absorption between dyestuff and the fabric, thereby improves the dye-uptake of natural dye.The chemical composition of laterite is similar with loess, and its difference is with SiO
2Preponderating, is Al secondly
2O
3,, Fe
2O
3, be CaO once more, MgO, K
2O, Na
2O, FeO and TiO
2
For loess, it is displaing yellow why, is because the more cause of Ca ion ratio.The Ca ion has played function served as bridge in the mordant dyeing process, the complex structure of its formation is stable.With the fabric of loess powder mordant dyeing, its form and aspect change little, bright.And for laterite, more because of containing the Fe ion, so show red.Iron ion in the laterite is the migration metal ion, and its formed inner orbit type complex compound is very stable, and form and aspect alter a great deal before and after the mordant dyeing.
Yellow (red) native powder as its mordant dying technical matters of mordant of natural plant dye is:
1) yellow (red) native powder is to natural plant dye mordant dying method: can be divided into three kinds:
(1) first mordant dyeing technology
Natural plants dyes material → water or ethanol extraction → distillation and makes concentrate → the join native mordant dyeing → dyeing of dye liquor → Huang (red) → washing → oven dry
(2) back mordant dyeing technology
Natural plants dyes material → water or ethanol extraction → distillation and makes concentrate → the join native mordant dyeing → washing of dye liquor → dyeing → Huang (red) → oven dry
(3) mix mordant dyeing technology
Natural plants dyes material → water or ethanol extraction → distillation and makes that concentrate → joining dye liquor → dyestuff/Huang (red) soil mixes mordant dyeing → washing → oven dry
2) the refining purifying technique of yellow (red) native powder
(1) with hard thing the native block of Huang (red) is pulverized.
(2) with 50～100 eye mesh screens loess, laterite are screened, stay thinner Huang (red) soil particle.(3) water separates with the impurity in the soil dissolving of Huang (red) soil particle, stirring with soil block.
(4) remove impurity floating in the solution.
(5) fully stir yellow (red) native water dispersion solution, use 100～300 eye mesh screens that Huang (red) soil is screened, filters simultaneously, obtain the native turbid liquid of fine Huang (red).
(6) leave standstill, make Huang (red) soil precipitation, the water on upper strata is poured out.Obtain Huang (red) soil of wet shape.
(7) cover ventilative cover, the Huang that will wet (red) soil dries in the sun.
(8) use preceding block to grind, obtain the native powder of pure Huang (red) yellow (red) soil.
1) yellow (red) native powder is to natural plant dye mordant dying technology:
Make usage basic identical with mordant commonly used, its difference is in the mordant dyeing treatment process, stir the native dispersion liquid of Huang (red), and it is uniformly dispersed, and finally obtains the fabric of even dyeing.
Natural plants dyes material → water or ethanol extraction → distillation and makes concentrate → join dye liquor → first mordant dyeing or back mordant dyeing or mix mordant dyeing → washing → oven dry
Dyeing temperature: 50～100 ℃, the time: 10～60min; Washing temperature: 40～60 ℃; Yellow (red) native addition: 5g/L～50g/L, bake out temperature: 80～100 ℃.Wherein with 40～80 ℃ of first or back mordant dyeing temperature, the time, 10～30min was advisable, and other conditions are the same.
Its fibrous material of natural fabric dyed textiles that yellow (red) native powder mordant dyeing is suitable for is:
Natural fabric: cotton, fiber crops, wool, silk etc.;
Chemical fibre: terylene, nylon, acrylic fibers, viscose glue etc.;
Various novel, green fibers: day silk, model, fibre and soya, bamboo fibre etc.; Comprise the nonwoven fabric made from above-mentioned fiber, and leather, specialties.
The present invention is applicable to apparel textile, textiless such as home-use textiles and various decoration, packing.Owing between natural dye, mordant and the fiber three, the metal-complexing effect can take place, so final products have dyefastness such as higher washing, friction.Washable, fastness to rubbing test result: washing fastness: 4 grades; 3～4 grades of dry fastnesses; 2～3 grades of fastness to wet rubbings.
Compared with prior art, the characteristics that the present invention has are: (1) utilizes the native powder of Huang existing in the Nature (red) as mordant, has formulated a kind of existing ecology, safe, nontoxic, and the natural dye dying fabric of health-care effect is arranged again.(2) dyeing is simple, and common dyeing is suitable for the production of product of the present invention fully.[3] inexpensive.
The specific embodiment
The loess mordant dyeing method of example 1 brazilwood dye and technology (back mordant dyeing)
1. dye liquor extracting process and process conditions
(1) natural bush is chopped into less block, calculates the consumption of bush solid according to the densimeter of institute's obtain solution.
(2) load weighted bush is put into the round-bottomed flask of putting well on the electric jacket, and add quantitative water.
(3) equipped condenser is heated to 80 ℃, boils 30min.
(4) stop the heating after, continue to be condensed to no steam.Juice is fried in shallow oil in extraction, filters with three layer of 100 order terylene plain cloth, obtains pure natural bush dye liquor.
2. colouring method and process conditions
(1) the bush dye liquor after will filtering left standstill 2～3 hours, will precipitate discarded.
(2) obtain pure bush dye liquor after, cloth is immersed in the dye liquor, bath raio control is about 40: 1.
(3) in being 70 ℃ water-bath, temperature dyes.Dyeing time is 30min, and the stirring cloth specimen makes and dyes on it evenly.
(4) select one in the cloth specimen after dying and give over to not mordant dyeing processing former state.
3. the preparation of mordanting bath
Take by weighing loess powder 0.5g, 1.0g, 1.5g, 2.0g is measured deionized water 100ml with its stirring and dissolving, and each prepares mordant dyeing concentration is 5g/L, 10g/L, 15g/L, the loess mordanting bath of 20g/L.
4. mordant dyeing method
(1) with the loess mordanting bath of four parts of 5g/L～20g/L concentration, puts into water-bath simultaneously.
(2) temperature with water-bath is controlled at 40 ℃, and the cloth specimen of putting into four brazilwood dyeings respectively carries out mordant dyeing.
(3) the mordant dyeing time is 15min, does not stop in the mordant dyeing process to stir.
(4) after the mordant dyeing cloth specimen is taken out,, clean, dry with clear water respectively together with former dyeing cloth specimen.
The red colour system brazilwood dye at the Color of different mordant dyeing agent shown in table 1,2,3.
Table 1 bush dye liquor concentration 7.0%, and the loess mordant dyeing (5g/L～20g/L)
Table 2 bush dye liquor concentration 7.0%, and the laterite mordant dyeing (5g/L～20g/L)
Table 3 bush dye liquor concentration 7.0%, and the alum mordant dyeing (5g/L～20g/L)
Annotate: 1. former state is represented aberration size (all comparing with the cloth that is unstained with dyeing sample) for loess mordant dyeing processing cloth specimen 2. Δ E values not; L
*Represent the brightness value size; a
*Represent red partially or green partially value size (+a
*: red partially;-a
*: green partially); b
*Yellow partially or blue partially value the size (+b of representative
*: yellow partially;-b
*: blue partially).
The loess mordant dyeing method of example 2 golden cypress dyestuffs and technology (back mordant dyeing)
1. dye liquor extracting process and process conditions
Step is with example 1.
2. colouring method and process conditions
Step is with example 1.
3. the preparation of mordanting bath
Step is with example 1.
4. mordant dyeing method
Step is with example 1.
Yellow is the golden cypress dyestuff at the Color of different mordant dyeing agent shown in table 4,5,6.
Table 4 golden cypress dye liquor concentration 6.3%, and the loess mordant dyeing (5g/L～20g/L)
Table 5 golden cypress dye liquor concentration 6.3%, and the laterite mordant dyeing (5g/L～20g/L)
Table 6 golden cypress dye liquor concentration 6.3%, and the alum mordant dyeing (5g/L～20g/L)
The loess mordant dyeing method of example 3 Chinese gall dyestuffs and technology (back mordant dyeing)
1. dye liquor extracting process and process conditions
Step is with example 1.
2. colouring method and process conditions
Step is with example 1.
3. the preparation of mordanting bath
Step is with example 1.
4. mordant dyeing method
Step is with example 1.
Ash colour system Chinese gall dyestuff at the Color of different mordant dyeing agent shown in table 7,8,9.
Table 7 Chinese gall dye liquor concentration 7.1%, and the loess mordant dyeing (5g/L～20g/L)
Table 8 Chinese gall dye liquor concentration 7.1%, and the laterite mordant dyeing (5g/L～20g/L)
Table 9 Chinese gall dye liquor concentration 7.1%, and the alum mordant dyeing (5g/L～20g/L)
Claims (7)
1. the mordant of a natural plant dye is characterized in that it being yellow, laterite mordant, takes from natural Huang, laterite and makes through following step:
(1) Huang, laterite block are pulverized, by 50～100 eye mesh screens;
(2) water is removed impurity and floating impurity with Huang, the dissolving of laterite particle, stirring;
(3) fully stir yellow, the laterite aqueous solution, with 100～300 eye mesh screens Huang, laterite are screened, filter simultaneously, obtain fine Huang, laterite dispersion liquid;
(4) leave standstill, make Huang, laterite precipitation, the water on upper strata is poured out, obtain Huang, the laterite of wet shape;
(5) cover ventilative cover, the Huang that will wet, laterite dry in the sun, get block yellow, laterite;
(6) block yellow, laterite is ground, obtain pure Huang, laterite powder.
2. the using method of the mordant of natural plant dye is characterized in that fabric fibre is carried out mordant dyeing, and its technology is:
Natural plants dyes that concentrate → join dye liquor is made in material → water or ethanol extraction → distillation and yellow, laterite mordant liquid carries out mordant dyeing → washing → oven dry;
Dyeing temperature: 50～100 ℃; Time: 10～60min; Washing temperature: 40～60 ℃; Bake out temperature: 80～100 ℃.
3. according to the using method of the mordant of the described natural plant dye of claim 2, it is characterized in that its mordant dyeing technology is first mordant dyeing, its technology is:
Natural plants dyes material → water or ethanol extraction → distillation and makes concentrate → join dye liquor → Huang, laterite mordant dyeing → dyeing → washing → oven dry, mordant dyeing temperature: 40～80 ℃, and the time: 10～30min.
4. according to the using method of the mordant of the described natural plant dye of claim 2, it is characterized in that its mordant dyeing technology is the back mordant dyeing, its technology is:
Natural plants dyes material → water or ethanol extraction → distillation and makes concentrate → join dye liquor → dyeing → Huang, laterite mordant dyeing → washing → oven dry, mordant dyeing temperature: 40～80 ℃, and the time: 10～30min.
5. according to the using method of the mordant of the described natural plant dye of claim 2, it is characterized in that its mordant dyeing technology for mixing mordant dyeing, its technology is:
Natural plants dyes material → water or ethanol extraction → distillation and makes concentrate → join dye liquor → dyestuff/Huang, laterite mixing mordant dyeing → washing → oven dry.
6. according to the using method of the mordant of the described natural plant dye of claim 2, it is characterized in that described fabric fibre is: natural fabric; Chemical fibre; Various novel, green fibers;
Wherein: described natural fabric is cotton, fiber crops, wool, silk; Described chemical fibre is terylene, nylon, acrylic fibers, viscose glue; Described various novel, green fiber is a day silk, model, fibre and soya, bamboo fibre.
7. according to the using method of the mordant of the described natural plant dye of claim 2, it is characterized in that described natural plant dye for can and metal ion formation coordination obtain all natural plant dyes of mordant dyeing.
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| CN107354772B (en) * | 2017-08-14 | 2019-07-23 | 温州鞋革职业中等专业学校 | A kind of leather dyeing method of appliable plant primary colour dye |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003049372A (en) * | 2001-08-09 | 2003-02-21 | Doi Manabu | Method of dyeing cellulosic fiber product with natural dye |
| KR20050040670A (en) * | 2003-12-05 | 2005-05-03 | 박현식 | Yellow earth natural dyeing diaper |
| KR20060082777A (en) * | 2005-01-13 | 2006-07-19 | 황승국 | The method of 'ocher complex natural dyeing' and cotton fabric dyed by this method |
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