CN105970678A - Manufacturing method of winter shirt fabric - Google Patents

Manufacturing method of winter shirt fabric Download PDF

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Publication number
CN105970678A
CN105970678A CN201610377960.9A CN201610377960A CN105970678A CN 105970678 A CN105970678 A CN 105970678A CN 201610377960 A CN201610377960 A CN 201610377960A CN 105970678 A CN105970678 A CN 105970678A
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CN
China
Prior art keywords
winter
bombax cotton
polyster fibre
shirt fabric
fabric
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201610377960.9A
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Chinese (zh)
Other versions
CN105970678B (en
Inventor
包新姐
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Xuzhou Rongsheng textile finishing Co., Ltd.
Original Assignee
CHANGXING ZHIHENG CLOTHING MATERIAL Co Ltd
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Priority to CN201610377960.9A priority Critical patent/CN105970678B/en
Publication of CN105970678A publication Critical patent/CN105970678A/en
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Publication of CN105970678B publication Critical patent/CN105970678B/en
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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/34General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using natural dyestuffs
    • DTEXTILES; PAPER
    • D02YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02GCRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/02Yarns or threads characterised by the material or by the materials from which they are made
    • D02G3/04Blended or other yarns or threads containing components made from different materials
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/46General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing natural macromolecular substances or derivatives thereof
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/46General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing natural macromolecular substances or derivatives thereof
    • D06P1/48Derivatives of carbohydrates
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/64General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
    • D06P1/651Compounds without nitrogen
    • D06P1/65106Oxygen-containing compounds
    • D06P1/65118Compounds containing hydroxyl groups
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/58Material containing hydroxyl groups
    • D06P3/60Natural or regenerated cellulose
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2201/00Cellulose-based fibres, e.g. vegetable fibres
    • D10B2201/01Natural vegetable fibres
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/04Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET]

Abstract

The invention provides a manufacturing method of winter shirt fabric. Polyester fiber and kapok fiber are blended to achieve excellent heat-preserving and antibacterial effect and excellent drapability, the kapok fiber is processed in an environment-friendly mode, so that the kapok fiber is high in heat-preserving property, no chemical agents are needed except a food-grade glycerol and the method is a novel environment-friendly fiber preparing method.

Description

A kind of winter shirt fabric preparation method
Technical field
The present invention relates to functional type garment material field, particularly relate to the preparation side of shirt fabric in a kind of winter Method.
Background technology
Polyster fibre is as most widely used chemical fibre, and it has good fibre-forming performance and mechanical performance, Intensity is high, fast light, heat-resisting and resistance to acids and bases is good, has good processability and Yi Fangxing, can pure spin, blending And intertexture.Polyester fabric washable and wearable, ironing and anti-crease, at field quilts such as clothing, home textile, decoration and product use Extensively application.But, polyster fibre there is also that hygroscopicity is poor, fabric not absorbing sweat, dress have feeling of oppression and heat, anti-quiet The shortcomings such as power difference and easily contamination dust, constrain application and the development of polyster fibre the most significantly.For improving The snugness of fit of polyster fibre, improves the application added value of polyster fibre, it is common that to polyster fibre Improvement in terms of or physics, and then the moisture absorbing and sweat releasing property that endowing terylene fiber is higher, improve dacron dress Comfort level.
Shirt can singly wear liquid can within wear arrange in pairs or groups western-style clothes, jacket etc., owing to shirt is thiner, temperature Time relatively low, needs are separately put on more clothes warming inside shirt or western-style clothes, but it is too fat to move to seem in appearance, therefore, and city A kind of Dow shirt occurs on field, inside shirt, sews one layer of inner bag filled by eider down, wear the clothes with minimizing Number of packages, can reach again warming effect simultaneously, but Dow shirt still shows for present youngster Obtain thick, although warming, but be so that the preferable man of original stature or schoolgirl seem the most fat, and the plumage of internal layer Floss easily exposes along with the activity of wearer, destroys makings and the demeanour of wearer.
Along with improving constantly of people's quality of the life, warming, the antibacterial and pendency of fabric especially shirt fabric Property increasingly obtains thinking highly of of people, and the fabric being currently known cannot take into account function above.
Summary of the invention
In view of this, it is an object of the invention to provide and a kind of there is the most warming, shirt in the winter face of anti-microbial property The preparation method of material.
A kind of winter shirt fabric preparation method, carry out as steps described below:
A, by bombax cotton disperse after be placed in the environmental protection treatment liquid prepared dipping 2-3h, be then passed through water Wash and 40-50 DEG C of drying;
B, treated bombax cotton and polyster fibre are carried out blending, obtain blend polyester yarn;
C, scribbled is weaved, obtain blending blank, then carry out stamp, rear shaping and drying, obtain Winter shirt fabric.
Preferably, the environmental protection treatment liquid of described bombax cotton, including the composition of following percentage by weight:
Food grade glycerin 3-5%
Olive oil 1-3%
Vegetable colour 2-5%
Broussonetia papyrifera juice 0.5-0.8%
Guar gum 8-12%
Extract from fructus polygoni orientalis 1-2%
Deionized water surplus.
Chinese invention patent CN101982584A discloses the processing method of a kind of high hollow ratio kapok yarn, should Method is by overcoming traditional bombax cotton through spinning process at the surface-coated elastic film of bombax cotton The shortcoming that rear degree of hollowness cannot keep.
But the method is to have employed polyurethane, dimethylformamide during the surface-coated of bombax cotton, containing The Organic substance such as fluoro water proofing agent, octadecanol, even across post processing, still has part residual can have potential danger to human body Evil, has increased the weight of the burden to environment simultaneously.The invention provides the bombax cotton processing method of a kind of environment protection health, The method uses guar gum as binding agent, food grade glycerin and olive oil as dispersant, Broussonetia papyrifera juice and bright pink Beggar's extract is as antibacterial and mixing waterproofing agent, thus reaches to keep the degree of hollowness of bombax cotton Effect.
The polyster fibre of blending is dyeed in advance simultaneously, thus only need fabric is carried out simply after blending Stamp and shape, it is not necessary to through complicated dyeing and arrangement, reduce environmental pollution, while also alleviate Destruction to bombax cotton degree of hollowness, makes the blended yarn weaved fabric of preparation possess extraordinary thermal property.
Preferably, described polyster fibre i.e. uses vegetable colour to dye it at the preparatory phase of fiber.
Preferably, in described blended yarn weaved fabric, the percentage by weight of polyster fibre and bombax cotton is respectively 65-75% and 25-35%.
Winter provided by the present invention shirt fabric preparation method, have the advantage that
1, in addition to food grade glycerin, do not use chemicals, be the tencel preparation method of a kind of environmental protection;
2, add olive oil and food grade glycerin, strengthen the dispersion effect of bombax cotton treatment fluid;
3, blended yarn weaved fabric needs not move through dyeing and Final finishing stage, maintains the heat-insulating property that bombax cotton is good;
4, add Broussonetia papyrifera juice and extract from fructus polygoni orientalis and bombax cotton phase separation, make fabric possess good resisting Bacterium performance.
The good drapability of the existing polyster fibre of shirt fabric in winter 5, being made into, also possesses bombax cotton good Heat-insulating property, the most also there is good anti-microbial property.
Detailed description of the invention
Embodiment 1
A kind of winter shirt fabric preparation method, carry out as steps described below:
A, by bombax cotton disperse after be placed in the environmental protection treatment liquid prepared dipping 2.5h, be then passed through water Wash and 45 DEG C of drying;
B, treated bombax cotton and polyster fibre are carried out blending, obtain blend polyester yarn;
C, scribbled is weaved, obtain blending blank, then carry out stamp, rear shaping and drying, obtain Winter shirt fabric.
The environmental protection treatment liquid of described bombax cotton, including the composition of following percentage by weight:
Food grade glycerin 4%
Olive oil 2%
Vegetable colour 5%
Broussonetia papyrifera juice 0.7%
Guar gum 10%
Extract from fructus polygoni orientalis 2%
Deionized water surplus.
Described polyster fibre i.e. uses vegetable colour to dye it at the preparatory phase of fiber.
In described blended yarn weaved fabric, the percentage by weight of polyster fibre and bombax cotton is respectively 70% and 30%.
Embodiment 2
A kind of winter shirt fabric preparation method, carry out as steps described below:
A, by bombax cotton disperse after be placed in the environmental protection treatment liquid prepared dipping 2h, be then passed through washing With 50 DEG C of drying;
B, treated bombax cotton and polyster fibre are carried out blending, obtain blend polyester yarn;
C, scribbled is weaved, obtain blending blank, then carry out stamp, rear shaping and drying, obtain Winter shirt fabric.
The environmental protection treatment liquid of described bombax cotton, including the composition of following percentage by weight:
Food grade glycerin 3%
Olive oil 3%
Vegetable colour 2%
Broussonetia papyrifera juice 0.8%
Guar gum 8%
Extract from fructus polygoni orientalis 1%
Deionized water surplus.
Described polyster fibre i.e. uses vegetable colour to dye it at the preparatory phase of fiber.
In described blended yarn weaved fabric, the percentage by weight of polyster fibre and bombax cotton is respectively 65% and 35%.
Embodiment 3
A kind of winter shirt fabric preparation method, carry out as steps described below:
A, by bombax cotton disperse after be placed in the environmental protection treatment liquid prepared dipping 3h, be then passed through washing With 40 DEG C of drying;
B, treated bombax cotton and polyster fibre are carried out blending, obtain blend polyester yarn;
C, scribbled is weaved, obtain blending blank, then carry out stamp, rear shaping and drying, obtain Winter shirt fabric.
The environmental protection treatment liquid of described bombax cotton, including the composition of following percentage by weight:
Food grade glycerin 5%
Olive oil 1%
Vegetable colour 2%
Broussonetia papyrifera juice 0.6%
Guar gum 12%
Extract from fructus polygoni orientalis 1.5%
Deionized water surplus.
Described polyster fibre i.e. uses vegetable colour to dye it at the preparatory phase of fiber.
In described blended yarn weaved fabric, the percentage by weight of polyster fibre and bombax cotton is respectively 75% and 25%.
Comparative example 1
Being removed by Broussonetia papyrifera juice in embodiment 1, remaining preparation condition is same as in Example 1.
Comparative example 2
Being removed by extract from fructus polygoni orientalis in embodiment 1, remaining preparation condition is same as in Example 1.
The anti-microbial property of embodiment and the fabric of comparative example is tested, obtains following data:
The examination criteria of biocidal property be GB/T20944.3-2008 " the evaluation third portion of antibacterial textile performance: Succusion ", use color fastness to washing testing machine washing methods, test to wash the bacteriostasis rate of fabric after 30 times.
By testing data above it is recognised that be individually added into Broussonetia papyrifera juice or extract from fructus polygoni orientalis, resisting of fabric Bacterium performance all ratios are simultaneously introduced two kinds of materials, and antibacterial effect is far short of what is expected, therefore the antibacterial effect of fabric of the present invention is wood Cotton fiber and Broussonetia papyrifera juice and the coefficient result of extract from fructus polygoni orientalis.
The above, the only present invention preferably detailed description of the invention, but protection scope of the present invention is not limited to In this, any those familiar with the art is in the technical scope that the invention discloses, according to the present invention Technical scheme and inventive concept equivalent or change in addition, all should contain protection scope of the present invention it In.

Claims (5)

1. one kind winter shirt fabric preparation method, it is characterised in that carry out as steps described below:
A, by bombax cotton disperse after be placed in the environmental protection treatment liquid prepared dipping 2-3h, be then passed through washing and 40-50 DEG C of drying;
B, treated bombax cotton and polyster fibre are carried out blending, obtain blend polyester yarn;
C, scribbled is weaved, obtain blending blank, then carry out stamp, rear shaping and drying, obtain shirt fabric in winter.
Winter the most according to claim 1 shirt fabric preparation method, it is characterised in that the environmental protection treatment liquid of described bombax cotton, including the composition of following percentage by weight:
Food grade glycerin 3-5%
Olive oil 1-3%
Vegetable colour 2-5%
Broussonetia papyrifera juice 0.5-0.8%
Guar gum 8-12%
Extract from fructus polygoni orientalis 1-2%
Deionized water surplus.
Winter the most according to claim 1 shirt fabric preparation method, it is characterised in that described polyster fibre i.e. uses vegetable colour to dye at the preparatory phase of fiber.
Winter the most according to claim 1 shirt fabric preparation method, it is characterised in that in described blended yarn weaved fabric, the percentage by weight of polyster fibre and bombax cotton is respectively 65-75% and 25-35%.
Winter the most according to claim 1 shirt fabric preparation method, it is characterised in that carry out as steps described below:
A, by bombax cotton disperse after be placed in the environmental protection treatment liquid prepared dipping 2.5h, be then passed through washing and 45 DEG C of drying;
B, treated bombax cotton and polyster fibre are carried out blending, obtain blend polyester yarn;
C, scribbled is weaved, obtain blending blank, then carry out stamp, rear shaping and drying, obtain shirt fabric in winter;
The environmental protection treatment liquid of described bombax cotton, including the composition of following percentage by weight:
Food grade glycerin 4%
Olive oil 2%
Vegetable colour 5%
Broussonetia papyrifera juice 0.7%
Guar gum 10%
Extract from fructus polygoni orientalis 2%
Deionized water surplus;
Described polyster fibre i.e. uses vegetable colour to dye it at the preparatory phase of fiber;
In described blended yarn weaved fabric, the percentage by weight of polyster fibre and bombax cotton is respectively 70% and 30%.
CN201610377960.9A 2016-05-31 2016-05-31 A kind of preparation method of winter shirt fabric Active CN105970678B (en)

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Application Number Priority Date Filing Date Title
CN201610377960.9A CN105970678B (en) 2016-05-31 2016-05-31 A kind of preparation method of winter shirt fabric

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CN105970678A true CN105970678A (en) 2016-09-28
CN105970678B CN105970678B (en) 2018-05-25

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109457508A (en) * 2018-10-23 2019-03-12 李双友 A kind of sub- colouring method of environment-friendly type paper mulberry of polyester cotton
CN107254734B (en) * 2017-05-27 2019-03-29 陈方 The method for weaving and purposes of tatting cloth based on plant dyeing yarn
CN115074891A (en) * 2022-07-18 2022-09-20 阜阳市豹子头服饰科技有限公司 Shirt and three-dimensional high-temperature high-pressure ironing process
CN116607247A (en) * 2023-04-13 2023-08-18 南通明富纺织品有限公司 Moisture-absorbing antibacterial polyester and kapok blended fabric and preparation process thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101165245A (en) * 2006-10-17 2008-04-23 晏国新 Cowboy plus material containing kawo fiber and producing technique thereof
CN101624741A (en) * 2008-07-07 2010-01-13 张家港市金陵纺织有限公司 Organic cotton fiber, kapok fiber and regenerated polyester fiber yarn-dyed fabric and production process
CN104902865A (en) * 2013-01-09 2015-09-09 莱雅公司 Dyeing composition free of chemical oxidizing agent, comprising oxidation dye, alkyl sulfate, alkylpolyglycoside, fatty substance and non-ionic guar gum
CN105178064A (en) * 2015-10-30 2015-12-23 朱忠良 Denim printing and dyeing method

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101165245A (en) * 2006-10-17 2008-04-23 晏国新 Cowboy plus material containing kawo fiber and producing technique thereof
CN101624741A (en) * 2008-07-07 2010-01-13 张家港市金陵纺织有限公司 Organic cotton fiber, kapok fiber and regenerated polyester fiber yarn-dyed fabric and production process
CN104902865A (en) * 2013-01-09 2015-09-09 莱雅公司 Dyeing composition free of chemical oxidizing agent, comprising oxidation dye, alkyl sulfate, alkylpolyglycoside, fatty substance and non-ionic guar gum
CN105178064A (en) * 2015-10-30 2015-12-23 朱忠良 Denim printing and dyeing method

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107254734B (en) * 2017-05-27 2019-03-29 陈方 The method for weaving and purposes of tatting cloth based on plant dyeing yarn
CN109457508A (en) * 2018-10-23 2019-03-12 李双友 A kind of sub- colouring method of environment-friendly type paper mulberry of polyester cotton
CN115074891A (en) * 2022-07-18 2022-09-20 阜阳市豹子头服饰科技有限公司 Shirt and three-dimensional high-temperature high-pressure ironing process
CN115074891B (en) * 2022-07-18 2024-01-02 阜阳市豹子头服饰科技有限公司 Stereoscopic high-temperature high-pressure ironing process for shirt fabric
CN116607247A (en) * 2023-04-13 2023-08-18 南通明富纺织品有限公司 Moisture-absorbing antibacterial polyester and kapok blended fabric and preparation process thereof
CN116607247B (en) * 2023-04-13 2023-12-22 南通明富纺织品有限公司 Moisture-absorbing antibacterial polyester and kapok blended fabric and preparation process thereof

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Effective date of registration: 20190214

Address after: 313000 1403, room 14, B building, free port, 1188 headquarters, Wuxing District, Huzhou, Zhejiang.

Patentee after: Zhejiang creation Intellectual Property Service Co., Ltd.

Address before: 313000 the thick village of Hongxing bridge, Changxing County, Huzhou, Zhejiang.

Patentee before: CHANGXING ZHIHENG CLOTHING MATERIAL CO., LTD.

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Effective date of registration: 20190419

Address after: 221400 Weiba Road, Xinyi Economic Development Zone, Xuzhou City, Jiangsu Province

Patentee after: Xuzhou Rongsheng textile finishing Co., Ltd.

Address before: 313000 1403, room 14, B building, free port, 1188 headquarters, Wuxing District, Huzhou, Zhejiang.

Patentee before: Zhejiang creation Intellectual Property Service Co., Ltd.

TR01 Transfer of patent right