CN105946313A - 一种复合眼镜片及其制备方法 - Google Patents
一种复合眼镜片及其制备方法 Download PDFInfo
- Publication number
- CN105946313A CN105946313A CN201610319074.0A CN201610319074A CN105946313A CN 105946313 A CN105946313 A CN 105946313A CN 201610319074 A CN201610319074 A CN 201610319074A CN 105946313 A CN105946313 A CN 105946313A
- Authority
- CN
- China
- Prior art keywords
- compound eye
- layer material
- eye eyeglass
- bonding
- eyeglass
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
- B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
- B32B17/10009—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets
- B32B17/10018—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets comprising only one glass sheet
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
- B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
- B32B17/10009—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
- B32B27/306—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl acetate or vinyl alcohol (co)polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
- B32B27/365—Layered products comprising a layer of synthetic resin comprising polyesters comprising polycarbonates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J163/00—Adhesives based on epoxy resins; Adhesives based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
- C09J175/04—Polyurethanes
-
- G—PHYSICS
- G02—OPTICS
- G02C—SPECTACLES; SUNGLASSES OR GOGGLES INSOFAR AS THEY HAVE THE SAME FEATURES AS SPECTACLES; CONTACT LENSES
- G02C7/00—Optical parts
- G02C7/02—Lenses; Lens systems ; Methods of designing lenses
- G02C7/022—Ophthalmic lenses having special refractive features achieved by special materials or material structures
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2250/00—Layers arrangement
- B32B2250/03—3 layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2250/00—Layers arrangement
- B32B2250/40—Symmetrical or sandwich layers, e.g. ABA, ABCBA, ABCCBA
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2270/00—Resin or rubber layer containing a blend of at least two different polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/40—Properties of the layers or laminate having particular optical properties
- B32B2307/412—Transparent
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/40—Properties of the layers or laminate having particular optical properties
- B32B2307/418—Refractive
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
- B32B2307/536—Hardness
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
- B32B2307/554—Wear resistance
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
- B32B2307/558—Impact strength, toughness
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2323/00—Polyalkenes
- B32B2323/04—Polyethylene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2369/00—Polycarbonates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2551/00—Optical elements
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Ophthalmology & Optometry (AREA)
- Physics & Mathematics (AREA)
- General Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Joining Of Glass To Other Materials (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
本发明公开了一种复合眼镜片及其制备方法,复合眼镜片由表层材料、中层材料、内层材料组成;其中表层材料由树脂材料I构成;中层材料由玻璃材料构成;内层材料由树脂材料II材料构成;表层材料与中层材料之间采用粘合剂A粘结而成;中层材料与内层材料之间采用粘合剂B粘结而成。制备方法包括:清洗;一次粘结;二次粘接。本发明制备的复合眼镜片,既能够满足高折射率、高硬度的要求,又兼具抗冲击、塑性佳、耐腐蚀的特点。
Description
技术领域
本发明涉及眼镜领域,具体涉及一种复合眼镜片及其制备方法。
背景技术
以普通硅酸盐玻璃制作眼镜片,具有折射率高、硬度大、耐摩擦等突出优点。但玻璃镜片脆性大、抗冲击性能差,在受到外部撞击时容易破裂,形成尖锐的棱角,对眼部组织造成严重外源性损伤,并且玻璃镜片耐化学腐蚀性能不佳,容易受到佩戴者汗渍及分泌物的腐蚀而变质。因此单独使用普通硅酸盐玻璃镜片的产品较少,市场占有率逐渐下降。
以各种碳烃类和碳酯类聚合物作为原料制作的树脂镜片成为近些年来眼镜市场的重要门类之一。树脂镜片具有塑性好、耐腐蚀性高等显著特色,可方便的进行机加工,重复利用率高。然而树脂镜片的折射率受到聚合程度和单体结晶度的影响,往往不能很高,并且聚碳酸酯类树脂镜片的耐磨性能较弱,很容易形成划痕,影响光线的透过率,使用效果不佳。
中国专利CN201310506380.1公开了一种眼镜片,所述眼镜片为层状结构,所述层状结构的中间层为玻璃材质,所述中间层的上表面和下表面分别设置上表层和下表层。所述上表层和下表层为树脂材料。所述上表层和下表层的厚度相同。所述上表层和下表层的厚度小于所述中间层的厚度。但是该专利没有公开复合眼镜片的材料以及复合方法。
因此,需要发明一种将玻璃眼镜片和树脂眼镜片复合起来的眼镜片,既能够满足高折射率、高硬度的要求,又兼具抗冲击、塑性佳、耐腐蚀的特点。
发明内容
本发明针对上述问题,提供一种复合眼镜片及其制备方法。
本发明解决上述问题所采用的技术方案是:
一种复合眼镜片,复合眼镜片由表层材料、中层材料、内层材料组成;
其中表层材料由树脂材料I构成;
中层材料由玻璃材料构成;
内层材料由树脂材料II材料构成;
表层材料与中层材料之间采用粘合剂A粘结而成;
中层材料与内层材料之间采用粘合剂B粘结而成。
进一步地,树脂材料I材料为:由聚丙烯酸酯和聚苯乙烯嵌段共聚注塑制成的树脂材料。
进一步地,玻璃材料为铈掺杂的钠硼硅酸盐玻璃材料。
进一步地,树脂材料II材料为:由聚碳酸酯和线性低密度聚乙烯共聚压延制成的树脂材料。
进一步地,粘合剂A的原料组分及其质量百分数为:无水乙醇15%~25%,苯5%~10%,丙酮5%~10%,醋酸纤维素1%~5%,聚乙烯醇10%~20%,乙烯-醋酸乙烯共聚物10%~20%,聚氨酯20%~35%。
更进一步地,粘合剂A的粘度范围为10mPa·s~50mPa·s。
进一步地,粘合剂B的原料组分及其质量百分数为:无水乙醇20%~30%,异丙醇5%~10%,二氯甲烷1%~5%,乙醚1%~5%,氰基丙烯酸酯1%~5%,聚氧乙烯10%~20%,硅胶10%~20%,环氧树脂20%~35%。
更进一步地,粘合剂B的粘度范围为300mPa·s~800mPa·s。
根据本发明的另一发明目的,在于提供一种上述复合眼镜片的制备方法,包括以下步骤:
步骤S01,清洗:将所述树脂材料I、玻璃材料、树脂材料II依次以去离子水、无水乙醇为介质进行超声波清洗,然后进行干燥处理;
步骤S02,一次粘结:将表层材料靠近中层材料的一侧涂抹粘合剂A两到三层,将中层材料靠近表层材料的一侧涂抹粘合剂A一到二层;然后对准对正待粘合面,两侧各施加150MPa~300MPa的正压力,保压3min~5min,于80℃~100℃的温度条件下进行保温处理2h~3h,即得一次粘接镜片;
步骤S03,二次粘接:将步骤S02得到的一次粘接镜片靠近内层材料的一侧涂抹粘合剂B一到二层,将内层树脂材料II材料靠近中层的一侧涂抹粘合剂B一到二层,再涂抹一层固化剂,固化剂的添加比例为粘合剂B添加量的0.001%~0.005%,对准对正待粘合面,两侧各施加100MPa~200MPa的正压力,保压1min~3min,于60℃~70℃的温度条件下进行固化处理4h~6h,即得复合眼镜片。
进一步地,步骤S03中,固化剂为:二乙醇胺、苯胺、乙二胺、邻苯二甲酸酐、二月桂酸二丁基锡的任一种或多种。
本发明的优点是:
1.本发明由两种不同的树脂材料和铈掺杂的玻璃材料复合制成,具有光透过率高、折射率大、硬度高、耐冲击、抗刮擦、不易碎裂、结构稳定等突出的优点;
2.本发明普通的硅酸盐玻璃种掺杂了铈元素,提高了中层玻璃材料的硬度和光学特性;
3.本发明使用了两种不同体系的粘合剂粘接树脂材料和玻璃材料,具有透明性佳、强度大、坚固牢靠的优点。
具体实施方式
以下对本发明的实施例进行详细说明,但是本发明可以由权利要求限定和覆盖的多种不同方式实施。
实施例1
一种复合眼镜片,复合眼镜片由表层材料、中层材料、内层材料组成;
表层材料由树脂材料I构成,树脂材料I由聚丙烯酸酯和聚苯乙烯嵌段共聚注塑制成;
中层材料由玻璃材料构成,玻璃材料为铈掺杂的钠硼硅酸盐玻璃材料;
内层材料由树脂材料II材料构成,树脂材料II由聚碳酸酯和线性低密度聚乙烯共聚压延制成;
表层材料与中层材料之间采用粘度范围为10mPa·s的粘合剂A粘结而成,粘合剂A的原料组分及其质量百分数为:无水乙醇15%,苯9%,丙酮10%,醋酸纤维素1%,聚乙烯醇10%,乙烯-醋酸乙烯共聚物20%,聚氨酯35%;
中层材料与内层材料之间采用粘度范围为300mPa·s的粘合剂B粘结而成,粘合剂B的原料组分及其质量百分数为:无水乙醇20%,异丙醇10%,二氯甲烷1%,乙醚5%,氰基丙烯酸酯1%,聚氧乙烯15%,硅胶13%,环氧树脂35%。
实施例2
一种复合眼镜片,复合眼镜片由表层材料、中层材料、内层材料组成;
表层材料由树脂材料I构成,树脂材料I由聚丙烯酸酯和聚苯乙烯嵌段共聚注塑制成;
中层材料由玻璃材料构成,玻璃材料为铈掺杂的钠硼硅酸盐玻璃材料;
内层材料由树脂材料II材料构成,树脂材料II由聚碳酸酯和线性低密度聚乙烯共聚压延制成;
表层材料与中层材料之间采用粘度范围为50mPa·s的粘合剂A粘结而成,粘合剂A的原料组分及其质量百分数为:无水乙醇25%,苯10%,丙酮5%,醋酸纤维素5%,聚乙烯醇20%,乙烯-醋酸乙烯共聚物15%,聚氨酯20%;
中层材料与内层材料之间采用粘度范围为800mPa·s的粘合剂B粘结而成,粘合剂B的原料组分及其质量百分数为:无水乙醇30%,异丙醇5%,二氯甲烷5%,乙醚1%,氰基丙烯酸酯5%,聚氧乙烯20%,硅胶14%,环氧树脂20%。
实施例3
一种复合眼镜片,复合眼镜片由表层材料、中层材料、内层材料组成;
表层材料由树脂材料I构成,树脂材料I由聚丙烯酸酯和聚苯乙烯嵌段共聚注塑制成;
中层材料由玻璃材料构成,玻璃材料为铈掺杂的钠硼硅酸盐玻璃材料;
内层材料由树脂材料II材料构成,树脂材料II由聚碳酸酯和线性低密度聚乙烯共聚压延制成;
表层材料与中层材料之间采用粘度范围为30mPa·s的粘合剂A粘结而成,粘合剂A的原料组分及其质量百分数为:无水乙醇23%,苯5%,丙酮8%,醋酸纤维素4%,聚乙烯醇18%,乙烯-醋酸乙烯共聚物10%,聚氨酯32%;
中层材料与内层材料之间采用粘度范围为550mPa·s的粘合剂B粘结而成,粘合剂B的原料组分及其质量百分数为:无水乙醇25%,异丙醇8%,二氯甲烷3%,乙醚3%,氰基丙烯酸酯3%,聚氧乙烯10%,硅胶20%,环氧树脂28%。
实施例4
一种复合眼镜片的制备方法,包括以下步骤:
步骤S01,清洗:将所述树脂材料I、玻璃材料、树脂材料II依次以去离子水、无水乙醇为介质,进行超声波清洗各1次,取出后置于真空干燥箱中,在60℃的温度条件下进行干燥处理4h;
步骤S02,一次粘结:将表层材料靠近中层材料的一侧涂抹粘合剂A两到三层,将中层材料靠近表层材料的一侧涂抹粘合剂A一到二层;然后对准对正待粘合面,两侧各施加150MPa的正压力,保压3min,移入真空干燥箱中,于80℃的温度条件下进行保温处理2h,取出缓慢冷却至室温,即得一次粘接镜片,备用;
步骤S03,二次粘接:将步骤S02得到的一次粘接镜片靠近内层材料的一侧涂抹粘合剂B一到二层,将内层树脂材料II材料靠近中层的一侧涂抹粘合剂B一到二层,再涂抹一层固化剂,固化剂的添加比例为粘合剂B添加量的0.001%,对准对正待粘合面,两侧各施加100MPa的正压力,保压1min,移入真空干燥箱中,于60℃的温度条件下进行固化处理4h,自然冷却后,即得复合眼镜片。其中固化剂为:二乙醇胺。
实施例5
一种复合眼镜片的制备方法,包括以下步骤:
步骤S01,清洗:将所述树脂材料I、玻璃材料、树脂材料II依次以去离子水、无水乙醇为介质,进行超声波清洗各5次,取出后置于真空干燥箱中,在80℃的温度条件下进行干燥处理6h;
步骤S02,一次粘结:将表层材料靠近中层材料的一侧涂抹粘合剂A两到三层,将中层材料靠近表层材料的一侧涂抹粘合剂A一到二层;然后对准对正待粘合面,两侧各施加300MPa的正压力,保压5min,移入真空干燥箱中,于100℃的温度条件下进行保温处理3h,取出缓慢冷却至室温,即得一次粘接镜片,备用;
步骤S03,二次粘接:将步骤S02得到的一次粘接镜片靠近内层材料的一侧涂抹粘合剂B一到二层,将内层树脂材料II材料靠近中层的一侧涂抹粘合剂B一到二层,再涂抹一层固化剂,固化剂的添加比例为粘合剂B添加量的0.005%,对准对正待粘合面,两侧各施加200MPa的正压力,保压3min,移入真空干燥箱中,于70℃的温度条件下进行固化处理6h,自然冷却后,即得复合眼镜片。其中固化剂为:苯胺和乙二胺,按照质量比为1:1添加。
实施例6
一种复合眼镜片的制备方法,包括以下步骤:
步骤S01,清洗:将所述树脂材料I、玻璃材料、树脂材料II依次以去离子水、无水乙醇为介质,进行超声波清洗各3次,取出后置于真空干燥箱中,在70℃的温度条件下进行干燥处理5h;
步骤S02,一次粘结:将表层材料靠近中层材料的一侧涂抹粘合剂A两到三层,将中层材料靠近表层材料的一侧涂抹粘合剂A一到二层;然后对准对正待粘合面,两侧各施加220MPa的正压力,保压4min,移入真空干燥箱中,于90℃的温度条件下进行保温处理2.5h,取出缓慢冷却至室温,即得一次粘接镜片,备用;
步骤S03,二次粘接:将步骤S02得到的一次粘接镜片靠近内层材料的一侧涂抹粘合剂B一到二层,将内层树脂材料II材料靠近中层的一侧涂抹粘合剂B一到二层,再涂抹一层固化剂,固化剂的添加比例为粘合剂B添加量的0.003%,对准对正待粘合面,两侧各施加150MPa的正压力,保压2min,移入真空干燥箱中,于65℃的温度条件下进行固化处理5h,自然冷却后,即得复合眼镜片。其中固化剂为:邻苯二甲酸酐和二月桂酸二丁基锡,按照质量比为1:1添加。
实验例
对实施例1~6所制的复合眼镜片的性能进行测试,测试结果如表1所示。
表1眼镜片性能测试结果
以上仅为本发明的优选实施例而已,并不用于限制本发明,对于本领域的技术人员来说,本发明可以有各种更改和变化。凡在本发明的精神和原则之内,所作的任何修改、等同替换、改进等,均应包含在本发明的保护范围之内。
Claims (10)
1.一种复合眼镜片,其特征在于,所述复合眼镜片由表层材料、中层材料、内层材料组成;
其中所述表层材料由树脂材料I构成;
所述中层材料由玻璃材料构成;
所述内层材料由树脂材料II材料构成;
所述表层材料与中层材料之间采用粘合剂A粘结而成;
所述中层材料与内层材料之间采用粘合剂B粘结而成。
2.根据权利要求1所述的复合眼镜片,其特征在于,所述树脂材料I材料为:由聚丙烯酸酯和聚苯乙烯嵌段共聚注塑制成的树脂材料。
3.根据权利要求1所述的复合眼镜片,其特征在于,所述玻璃材料为铈掺杂的钠硼硅酸盐玻璃材料。
4.根据权利要求1所述的复合眼镜片,其特征在于,所述树脂材料II材料为:由聚碳酸酯和线性低密度聚乙烯共聚压延制成的树脂材料。
5.根据权利要求1所述的复合眼镜片,其特征在于,所述粘合剂A的原料组分及其质量百分数为:无水乙醇15%~25%,苯5%~10%,丙酮5%~10%,醋酸纤维素1%~5%,聚乙烯醇10%~20%,乙烯-醋酸乙烯共聚物10%~20%,聚氨酯20%~35%。
6.根据权利要求5所述的复合眼镜片,其特征在于,所述粘合剂A的粘度范围为10mPa·s~50mPa·s。
7.根据权利要求1所述的复合眼镜片,其特征在于,所述粘合剂B的原料组分及其质量百分数为:无水乙醇20%~30%,异丙醇5%~10%,二氯甲烷1%~5%,乙醚1%~5%,氰基丙烯酸酯1%~5%,聚氧乙烯10%~20%,硅胶10%~20%,环氧树脂20%~35%。
8.根据权利要求7所述的复合眼镜片,其特征在于,所述粘合剂B的粘度范围为300mPa·s~800mPa·s。
9.一种根据权利要求1~8中任一项所述的复合眼镜片的制备方法,其特征在于,包括以下步骤:
步骤S01,清洗:将所述树脂材料I、玻璃材料、树脂材料II依次以去离子水、无水乙醇为介质进行超声波清洗,然后进行干燥处理;
步骤S02,一次粘结:将表层材料靠近中层材料的一侧涂抹粘合剂A两到三层,将中层材料靠近表层材料的一侧涂抹粘合剂A一到二层;然后对准对正待粘合面,两侧各施加150MPa~300MPa的正压力,保压3min~5min,于80℃~100℃的温度条件下进行保温处理2h~3h,即得一次粘接镜片;
步骤S03,二次粘接:将步骤S02得到的一次粘接镜片靠近内层材料的一侧涂抹粘合剂B一到二层,将内层树脂材料II材料靠近中层的一侧涂抹粘合剂B一到二层,再涂抹一层固化剂,固化剂的添加比例为粘合剂B添加量的0.001%~0.005%,对准对正待粘合面,两侧各施加100MPa~200MPa的正压力,保压1min~3min,于60℃~70℃的温度条件下进行固化处理4h~6h,即得复合眼镜片。
10.根据权利要求9所述的制备方法,其特征在于,步骤S03中,所述固化剂为:二乙醇胺、苯胺、乙二胺、邻苯二甲酸酐、二月桂酸二丁基锡的任一种或多种。
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610319074.0A CN105946313B (zh) | 2016-05-13 | 2016-05-13 | 一种复合眼镜片及其制备方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610319074.0A CN105946313B (zh) | 2016-05-13 | 2016-05-13 | 一种复合眼镜片及其制备方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN105946313A true CN105946313A (zh) | 2016-09-21 |
CN105946313B CN105946313B (zh) | 2017-09-29 |
Family
ID=56912507
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201610319074.0A Active CN105946313B (zh) | 2016-05-13 | 2016-05-13 | 一种复合眼镜片及其制备方法 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN105946313B (zh) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107632409A (zh) * | 2017-11-10 | 2018-01-26 | 江苏黄金屋光学眼镜股份有限公司 | 一种复合高折眼镜镜片 |
CN108384502A (zh) * | 2018-03-02 | 2018-08-10 | 上海浦悠化工有限公司 | 一种太阳眼镜镜面膜用胶黏剂及其制备方法 |
CN109164594A (zh) * | 2018-09-28 | 2019-01-08 | 镇江奥视达光学有限公司 | 一种防蓝光眼镜镜片及其制备方法 |
CN112976706A (zh) * | 2021-03-09 | 2021-06-18 | 京钻(厦门)科技有限公司 | 一种玻璃渐进色镜片及其制备方法 |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1690005A (zh) * | 2004-04-23 | 2005-11-02 | 阳光也 | 高强度防弹夹层玻璃的制造方法 |
WO2010050355A1 (ja) * | 2008-10-31 | 2010-05-06 | 日東電工株式会社 | 液晶表示装置 |
CN102390928A (zh) * | 2011-08-06 | 2012-03-28 | 蚌埠玻璃工业设计研究院 | 一种掺杂稀土元素铈的新型硼硅酸盐聚光玻璃 |
CN103499884A (zh) * | 2013-10-25 | 2014-01-08 | 戴洪杰 | 一种眼镜片 |
CN104898297A (zh) * | 2015-06-17 | 2015-09-09 | 龚永亮 | 一种新型复合眼镜片 |
-
2016
- 2016-05-13 CN CN201610319074.0A patent/CN105946313B/zh active Active
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1690005A (zh) * | 2004-04-23 | 2005-11-02 | 阳光也 | 高强度防弹夹层玻璃的制造方法 |
WO2010050355A1 (ja) * | 2008-10-31 | 2010-05-06 | 日東電工株式会社 | 液晶表示装置 |
CN102390928A (zh) * | 2011-08-06 | 2012-03-28 | 蚌埠玻璃工业设计研究院 | 一种掺杂稀土元素铈的新型硼硅酸盐聚光玻璃 |
CN103499884A (zh) * | 2013-10-25 | 2014-01-08 | 戴洪杰 | 一种眼镜片 |
CN104898297A (zh) * | 2015-06-17 | 2015-09-09 | 龚永亮 | 一种新型复合眼镜片 |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107632409A (zh) * | 2017-11-10 | 2018-01-26 | 江苏黄金屋光学眼镜股份有限公司 | 一种复合高折眼镜镜片 |
CN108384502A (zh) * | 2018-03-02 | 2018-08-10 | 上海浦悠化工有限公司 | 一种太阳眼镜镜面膜用胶黏剂及其制备方法 |
CN109164594A (zh) * | 2018-09-28 | 2019-01-08 | 镇江奥视达光学有限公司 | 一种防蓝光眼镜镜片及其制备方法 |
CN112976706A (zh) * | 2021-03-09 | 2021-06-18 | 京钻(厦门)科技有限公司 | 一种玻璃渐进色镜片及其制备方法 |
Also Published As
Publication number | Publication date |
---|---|
CN105946313B (zh) | 2017-09-29 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN105946313A (zh) | 一种复合眼镜片及其制备方法 | |
CN108230900B (zh) | 图像显示装置 | |
CN102416739B (zh) | 一种飞艇蒙皮材料及其制备方法 | |
CN106716196B (zh) | 偏振膜的制造方法 | |
CN106893129A (zh) | 一种应用于oca胶的pet离型膜及其生产工艺 | |
JP2016153883A (ja) | 偏光フィルム、粘着剤層付偏光フィルム並びに画像表示装置およびその連続製造方法 | |
JP2011248363A (ja) | 液晶表示装置 | |
CN109266237B (zh) | 一种防窥柔性防爆膜及其制备工艺 | |
CN103149610B (zh) | 一种多层复合棱镜片及其制备方法 | |
CN114407547A (zh) | 一种耐水洗防伪烫印膜及其制备方法 | |
KR101887989B1 (ko) | 편광소자, 및 편광판 | |
JP2021062602A (ja) | 熱曲げ加工不要の光硬化曲面スクリーン保護シート | |
KR20190072151A (ko) | 편광판, 편광판-캐리어 필름 적층체, 편광판-캐리어 필름 적층체의 제조방법, 편광판의 제조방법 및 활성 에너지선 경화형 조성물 | |
CN114428416A (zh) | 一种手机背光模块用高抗压高亮度涂布型聚酯反射膜 | |
KR102337430B1 (ko) | 편광막, 편광 필름, 적층 편광 필름, 화상 표시 패널 및 화상 표시 장치, 및 편광막의 제조 방법 | |
CN110172307A (zh) | 一种用于光感屏下指纹解锁的srf薄膜的制作方法 | |
CN210488166U (zh) | 一种专门用胶水粘结的偏光膜和树脂镜片的偏光镜片 | |
CN104635285A (zh) | 一种高挺性涂布反射膜及其制备方法 | |
JP2016153874A (ja) | 偏光フィルム、粘着剤層付偏光フィルムおよび画像表示装置 | |
CN205890093U (zh) | 一种tpu保护膜 | |
CN208860985U (zh) | 一种超薄带偏光效果的oca | |
CN204989516U (zh) | 一种光学薄膜 | |
CN107632373A (zh) | 皮肤测试微距镜头 | |
CN105607175A (zh) | 一种防雾型偏光片及其制备方法 | |
CN107924016A (zh) | 单侧保护偏振膜、带粘合剂层的偏振膜及图像显示装置 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
GR01 | Patent grant | ||
GR01 | Patent grant | ||
TR01 | Transfer of patent right | ||
TR01 | Transfer of patent right |
Effective date of registration: 20191011 Address after: 315000 4th Floor, Building 1177 Lingyun Road, Ningbo High-tech Zone, Zhejiang Province Patentee after: Ningbo Flo Optical Co., Ltd. Address before: 325000, No. 12, Lane 22, Zhang Rong Road, Pu Xi village, Guo Xi Town, Ouhai District, Zhejiang, Wenzhou Patentee before: Zheng Hai Dong |