CN105943463A - Mild shampoo and bath bubbles for infants - Google Patents
Mild shampoo and bath bubbles for infants Download PDFInfo
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- CN105943463A CN105943463A CN201610466729.7A CN201610466729A CN105943463A CN 105943463 A CN105943463 A CN 105943463A CN 201610466729 A CN201610466729 A CN 201610466729A CN 105943463 A CN105943463 A CN 105943463A
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
- A61K8/97—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
- A61K8/442—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof substituted by amido group(s)
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/60—Sugars; Derivatives thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/60—Sugars; Derivatives thereof
- A61K8/604—Alkylpolyglycosides; Derivatives thereof, e.g. esters
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
- A61K8/922—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/52—Stabilizers
- A61K2800/524—Preservatives
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Abstract
The invention discloses mild shampoo and bath bubbles for infants. According to the characteristics of hair and skin of infants, the shampoo and bath bubbles are prepared by selecting disodium cocoyl glutamate, cocamidopropyl betaine and sodium lauryl and glycoside hydroxypropylsulfonate as a surfactant system, selecting camellia-seed oil, alpha-glucan oligosaccharide/inulin compound as a regulating component and selecting flos chrysanthemi indici extract and ethyl lauroyl arginate HCl as a preservative system. The shampoo and bath bubbles are prepared from compatible raw materials, have good cleaning effect and mild and non-irritant performance, and can be used for reinforcing skin barrier to give intimate care to infants.
Description
Technical field
The present invention relates to the baby child of a kind of gentleness have one's hair wash shower bubble, belong to baby child's article of everyday use technical field.
Background technology
Compared to adult skin, baby child's skin is thin, iuntercellular attachment is weak, water content is high, fat secretion is few,
High to the sensitivity of external irritant.On hair, baby child is few compared with terminal hair, by external irritant (as
Hair dryer, dyeing and perm stretch) influence factor is few.Therefore have one's hair wash bath product most important of baby child is exactly temperature
With non-stimulated.
1, the zest of hair washing bath product is mainly derived from surfactant and preservative
Surfactant: baby child's bath product of having one's hair wash mostly is sulfate surfactant system in the market,
Zest is big, skin is had absorption, can introduce the harmful substances such as dioxane.Although some product uses temperature
The amino acid surfactant system of sum, because its cost is high, promotes less at present, and amino acid surface is lived
Property agent system difficulty thickening also become a big difficult point of industry, by add thickening agent such as carbomer SF-1,
PEG-120 methyl glucose dioleate, PEG-18 glycerol oleic acid/cocos nucifera oil acid esters etc. or enlarged surface are lived
Property agent consumption adjust PH and all can increase baby child's skin burden from the behave of thickening.
Preservative: generally use parabens, formaldehyde donor class or Kazon etc. in the market, according to report
Certain zest is all there is in these preservative of road to human body.Select suitable surfactant system and prevent
Rotten system ensures that product safety is effective, and give the gentle care of baby child is the technology being badly in need of at present solving simultaneously
Problem.
2, the care of skin Tiny ecosystem
Although baby child has one's hair wash, bath product typically can add oils and fats, moisturizing, submissive composition are nursed one's health, but
Have ignored baby's another important skin protection path i.e. skin Tiny ecosystem virgin.Micro-life of the skin surface that baby is virgin
The thing process of growing surely originates in birth process, and after birth along with the maturation of neonatal immune system,
Gradually consolidate at skin surface.The common structure of the Ecological niche that the microorganism settled down on skin is different with skin surface
Become the Tiny ecosystem that skin is complicated.The flora of skin surface is divided into resident flora and flora of staying temporarily, most of right
Body is all useful, as cleared up the rubbish (cell of apoptosis) of skin surface;Decompose unnecessary lipid;
By the immune system of competitive inhibition stimulation of host simultaneously, strengthen immunity and the resistance of host, come
Resist the invasion of external pathogen.But skin function will be disorderly when the relation of balancing each other is broken when,
Thus cause the allergic skin diseases frequently occurred such as baby child.Therefore the strong of baby child's skin Tiny ecosystem is paid close attention to
Health is significant.
In order to solve the deficiencies in the prior art, one is needed in market badly can maximize performance raw material spy
Property jointly build and give the gentle non-stimulated watch box of washing of baby child and test and eco-friendly washing protects product.
Summary of the invention
It is an object of the invention to overcome above-mentioned the deficiencies in the prior art, it is provided that baby child's hair washing of a kind of gentleness
Shower bubble.
For achieving the above object, the present invention is by the following technical solutions:
The baby child of a kind of gentleness has one's hair wash shower bubble, is made up of following component by weight percentage: cocos nucifera oil acyl
Disodium glutamate 5~20%, cocamido propyl betaine 5~20%, sulfonic acid hydroxypropyl acrylate lauryl glucose
Glycosides cross linked polymer sodium 3~10%, Camellia oil 0.1~0.4%, alpha-glucans oligosaccharide/inulin compound
0.5~2.5%, Flos Chrysanthemi Indici extract 1~10%, lauroyl arginine ethyl ester HCl 0.5~2.0%, remaining
Amount is deionized water.
Preferably, it is made up of following component by weight percentage: Disodium N-Coco acy-L-Glutamate 10~20%,
Cocamido propyl betaine 10~20%, sulfonic acid hydroxypropyl acrylate lauryl glucoside cross linked polymer sodium 4~
8%, Camellia oil 0.1~0.3%, alpha-glucans oligosaccharide/inulin compound 0.8~2.0%, Flos Chrysanthemi Indici carries
Taking thing 3~8%, lauroyl arginine ethyl ester HCl 0.8~1.5%, surplus is deionized water.
After using technique scheme, the present invention, compared with background technology, has the advantage that
1, with natural origin composition Disodium N-Coco acy-L-Glutamate, cocamido propyl betaine and sulfonic acid hydroxypropyl
Ester lauryl glucoside cross linked polymer sodium is compounding as surfactant system.Rise and soak, cleaning effect
Good, easily rinse, solve following problem: (1) is gentle, with rear hair and skin comfort, silk simultaneously
Sliding.Avoid using the zest of traditional Sulfates surfactant, to the absorption of skin and dioxane
Bringing into Deng harmful substance.(2) this system can use in bubble shape after pump head squeezes out, effectively
Solve amino acid surfactant system difficulty thickening, by using thickening agent or enlarged surface activating agent consumption
Adjust PH from thickening, the problem increasing the burden of skin.When adding baby bath simultaneously convenience with
Enjoyment.(3) consumer's demand to natural origin composition is met.(4) more environmentally friendly.Strengthen surface activity
The research of agent biological degradability, efficiently controls the deterioration of the ecological environment, it has also become current important topic it
One.Three kinds of compounding surfactants derive from biological substance, and renewable, biological degradability is good, from
Biodegradation pressure is alleviated on source.
2, add alpha-glucans oligosaccharide/inulin compound 0.5~2.5%, safeguard the skin Tiny ecosystem that baby is virgin
Health, and as the important channel of strengthening baby child's skin barrier.Our experiments show that, alpha-glucans oligosaccharide/chrysanthemum
Powder compound can be as probiotics nutrient substance so that it is mushroom out breeding, maintains the status of dominant bacteria,
Make pathogen there is no enough nourishing and growing, thus suppress pathogen to breed, strengthen baby child's skin barrier.
3, use compounding natural origin composition as protective system.In shelf life, for guarantee, it pacifies cosmetics
Complete effective, all can add preservative.Generally use parabens, formaldehyde donor class or Kazon etc., according to
Report that these preservative all exist certain zest to human body.Baby child bears a pretty, delicate skin, it should selects and has
The natural origin composition of fungistatic effect is compounding forms protective system.Our experiments show that, by Flos Chrysanthemi Indici extract
Compounding with lauroyl arginine ethyl ester HCl as protective system, it is possible to obtain gentle watch box of washing is tested and has
The anticorrosion of effect.Various pathogens, virus are killed or inhibitory activity by Flos Chrysanthemi Indici extract, the most preferably
Add gram positive bacteria, gram negative bacteria, pathogen, yeast and mycete had good antibacterial
Effect, and the lauroyl arginine ethyl ester HCl that minimum inhibitory concentration is the most relatively low.Flos Chrysanthemi Indici extracts simultaneously
Thing contains the various active compositions such as flavonoid, half terpenes, polysaccharide, alantol, aminoacid and trace element,
There is the activity of antiinflammatory, Repercusion analgesia.
4, natural plants Camellia oil it is especially added with.Camellia oil is the advantage oil product of China, and it contains
Unsaturated fatty acid content is up to 90%, and the trace element such as rich in vitamin E and calcium, ferrum, zinc, has
Effect skin care and hair.Serve not only as the moisturizing of baby child's skin at Camellia oil among the people, be also used for skin
Allergy and the antibacterial treatment of antiinflammatory.Therefore, Camellia oil can rise in prescription as excellent plant origin
To multiple action.
Detailed description of the invention
In order to make the purpose of the present invention, technical scheme and advantage clearer, below in conjunction with embodiment,
The present invention is further elaborated.Should be appreciated that specific embodiment described herein is only used
To explain the present invention, it is not intended to limit the present invention.
Embodiment 1
Prepare baby child by following percentage by weight proportioning to have one's hair wash shower bubble: Disodium N-Coco acy-L-Glutamate 5%,
Cocamido propyl betaine 20%, sulfonic acid hydroxypropyl acrylate lauryl glucoside cross linked polymer sodium 3%, mountain
Oleum Camelliae 0.1%, alpha-glucans oligosaccharide/inulin compound 0.5%, Flos Chrysanthemi Indici extract 10%, lauroyl
Arginine ethyl ester HCl 0.5%, surplus are deionized water.
Wherein in alpha-glucans oligosaccharide/inulin compound, the weight ratio of alpha-glucans oligosaccharide and inulin is
: 1, (0.3-2) the preferred 1:1 of the present embodiment.
Embodiment 2
Prepare baby child by following percentage by weight proportioning to have one's hair wash shower bubble: Disodium N-Coco acy-L-Glutamate 9%,
Cocamido propyl betaine 15%, sulfonic acid hydroxypropyl acrylate lauryl glucoside cross linked polymer sodium 10%, mountain
Oleum Camelliae 0.15%, alpha-glucans oligosaccharide/inulin compound 0.7%, Flos Chrysanthemi Indici extract 9%, lauroyl
Arginine ethyl ester HCl 0.8%, surplus are deionized water.
Embodiment 3
Prepare baby child by following percentage by weight proportioning to have one's hair wash shower bubble: Disodium N-Coco acy-L-Glutamate 13%,
Cocamido propyl betaine 16%, sulfonic acid hydroxypropyl acrylate lauryl glucoside cross linked polymer sodium 6%, mountain
Oleum Camelliae 0.25%, alpha-glucans oligosaccharide/inulin compound 1.0%, Flos Chrysanthemi Indici extract 7.5%, Laurel
Acyl arginine ethyl ester HCl 1.1%, surplus are deionized water.
Embodiment 4
Prepare baby child by following percentage by weight proportioning to have one's hair wash shower bubble: Disodium N-Coco acy-L-Glutamate 15%,
Cocamido propyl betaine 16%, sulfonic acid hydroxypropyl acrylate lauryl glucoside cross linked polymer sodium 4%, mountain
Oleum Camelliae 0.2%, alpha-glucans oligosaccharide/inulin compound 1.5%, Flos Chrysanthemi Indici extract 6%, lauroyl
Arginine ethyl ester HCl 1.4%, surplus are deionized water.
Embodiment 5
Prepare baby child by following percentage by weight proportioning to have one's hair wash shower bubble: Disodium N-Coco acy-L-Glutamate 18%,
Cocamido propyl betaine 15%, sulfonic acid hydroxypropyl acrylate lauryl glucoside cross linked polymer sodium 5%, mountain
Oleum Camelliae 0.3%, alpha-glucans oligosaccharide/inulin compound 1.8%, Flos Chrysanthemi Indici extract 4%, lauroyl
Arginine ethyl ester HCl 1.6%, surplus are deionized water.
Embodiment 6
Prepare baby child by following percentage by weight proportioning to have one's hair wash shower bubble: Disodium N-Coco acy-L-Glutamate 20%,
Cocamido propyl betaine 10%, sulfonic acid hydroxypropyl acrylate lauryl glucoside cross linked polymer sodium 7%, mountain
Oleum Camelliae 0.4%, alpha-glucans oligosaccharide/inulin compound 2.2%, Flos Chrysanthemi Indici extract 3%, lauroyl
Arginine ethyl ester HCl 1.8%, surplus are deionized water.
Embodiment 7
Prepare baby child by following percentage by weight proportioning to have one's hair wash shower bubble: Disodium N-Coco acy-L-Glutamate 20%,
Cocamido propyl betaine 8%, sulfonic acid hydroxypropyl acrylate lauryl glucoside cross linked polymer sodium 5%, Flos Camelliae Japonicae
Seed oil 0.35%, alpha-glucans oligosaccharide/inulin compound 2.5%, Flos Chrysanthemi Indici extract 1%, lauroyl essence
Propylhomoserin ethyl ester HCl 2.0%, surplus are deionized water.
The preparation method of embodiment 1-7 is: by surface active agent composition, compose fat component and water phase components liter
Temperature, to 80 ± 1 DEG C, is lowered the temperature after being incubated 15 minutes;Conditioning component and main is added when cooling to less than 45 DEG C
Antibacterial component stirs, physical and chemical index discharging after the assay was approved.The physical and chemical index of the present invention is: outward appearance
For transparent flow liquid, pH value is 6.5-7.2, and it is qualified that cold-resistant stability (-20 DEG C × 24h) is investigated.
Shower bubble of having one's hair wash the baby child prepared by embodiment 1-7 detects:
1. use Semen Maydis alcohol molten method of testing baby child that embodiment 1-7 is obtained shower bubble of having one's hair wash to carry out table
The irritating detection of face activating agent.
Its water when zein (zein) the most completely insoluble in water interacts with surfactant
Dissolubility strengthens, and according to the situation of change of nitrogen content in aqueous solution, can determine zein and surfactant
Dissolubility after effect, the surfactant that zest is stronger is more readily soluble than weak irritating surfactant
Solve zein, thus it is known that the irritating power of surfactant.When Zein value is at N2g/L~4g/L
The surfactant of solution is low irritant, is nonirritant less than the surfactant of 2g/L solution.
Test result such as following table:
Embodiment | 1 | 2 | 3 | 4 | 5 | 6 | 7 |
Zein value (g/L) | 0.221 | 0.202 | 0.198 | 0.173 | 0.165 | 0.162 | 0.196 |
It can be seen that the zein value of embodiment 1-7 is respectively less than 2g/L, nonirritant.
2, use European Pharmacopoeia (Ph.Eur.general text 5.1.3) that embodiment 1-7 is once added
Its inhibitor effectiveness of bacterium the effects.
Test result such as following table:
It can be seen that the antibacterial of embodiment 1-7 was reduced more than 2 orders of magnitude, the 7th day fall at the 2nd day
Low being more than 3 orders of magnitude, the 28th day without clearly visible growth;Mycete was reduced more than 2 at the 14th day
The order of magnitude, the 28th day without clearly visible growth.It can thus be appreciated that embodiment 1-7 is all tested by preservation challenge,
Possess antiseptic effect thus ensure product quality.
3, foam satisfaction, easily flushing degree and the test of the moist performance to skin.
Due to baby virgin can not precise expression use time sensory experience and effect after using, choose 7 groups of years
Age between 18-22 year between the delicate young woman of skin, often organize 6 people, respectively embodiment 1-7 entered
Row test.
Test result such as following table:
It can be seen that it is satisfied, without eyes and skin to the foam of pump extrusion during 7 groups of librarian use embodiments 1-7
Skin stimulates, and easily rinses well, and after trying out, skin moisturizing is the most dry stretches tight.
4, the test of alpha-glucans oligosaccharide/inulin compound strengthening skin barrier.
With the addition of 0.5% alpha-glucans oligosaccharide, 0.5% inulin, 0.5% alpha-glucans oligosaccharide/inulin respectively
In the culture medium of compound, inoculation kirschner Kocuria kristinae ad (probiotics) simultaneously and staphylococcus aureus are (sick
Former bacterium), cultivate 24 hours.
Test result such as following table:
It can be seen that contain in the culture medium of probiotics and pathogen at the same time, alpha-glucans oligosaccharide/inulin
Compound, compared with alone alpha-glucans oligosaccharide, inulin, subtracts indirectly selectively promoting the growth of probiotics
The effect of few pathogen is more excellent, reaches to strengthen the effect of skin barrier.
The above, the only present invention preferably detailed description of the invention, but protection scope of the present invention is not
Being confined to this, any those familiar with the art, can in the technical scope that the invention discloses
The change readily occurred in or replacement, all should contain within protection scope of the present invention.Therefore, the present invention
Protection domain should be as the criterion with scope of the claims.
Claims (2)
1. a gentle baby child has one's hair wash shower bubble, it is characterised in that by weight percentage by following component
Composition: Disodium N-Coco acy-L-Glutamate 5~20%, cocamido propyl betaine 5~20%, sulfonic acid hydroxypropyl acrylate
Lauryl glucoside cross linked polymer sodium 3~10%, Camellia oil 0.1~0.4%, alpha-glucans oligosaccharide/inulin
Compound 0.5~2.5%, Flos Chrysanthemi Indici extract 1~10%, lauroyl arginine ethyl ester HCl 0.5~2.0%,
Surplus is deionized water.
The baby child of a kind of gentleness the most according to claim 1 has one's hair wash shower bubble, it is characterised in that press
Percentage by weight is made up of following component: Disodium N-Coco acy-L-Glutamate 10~20%, cocamidopropyl propyl amide Radix Betae
Alkali 10~20%, sulfonic acid hydroxypropyl acrylate lauryl glucoside cross linked polymer sodium 4~8%, Camellia oil 0.1~
0.3%, alpha-glucans oligosaccharide/inulin compound 0.8~2.0%, Flos Chrysanthemi Indici extract 3~8%, lauroyl essence
Propylhomoserin ethyl ester HCl 0.8~1.5%, surplus is deionized water.
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Cited By (15)
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CN106473958A (en) * | 2016-11-04 | 2017-03-08 | 深圳市婴缘健康有限公司 | A kind of two-in-one hair washing bath oil of infant |
CN107496262A (en) * | 2017-10-09 | 2017-12-22 | 广西三椿生物科技有限公司 | A kind of tea seed nurses shampoo |
CN107550820A (en) * | 2017-10-09 | 2018-01-09 | 广西三椿生物科技有限公司 | A kind of baby shampoo and preparation method containing tea seed |
CN108434079A (en) * | 2018-06-01 | 2018-08-24 | 广州澳希亚实业有限公司 | A kind of baby child's hair washing bath foam composition |
CN109431913A (en) * | 2018-12-27 | 2019-03-08 | 湖南御家化妆品制造有限公司 | Skin microecological balance composition and application thereof |
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CN110787091A (en) * | 2019-12-03 | 2020-02-14 | 株洲千金药业股份有限公司 | Itching-relieving and anti-allergy infant washing and protecting preparation and application thereof |
CN110885717A (en) * | 2019-12-16 | 2020-03-17 | 株洲千金药业股份有限公司 | Natural antibacterial detergent for lady clothes |
CN111135125A (en) * | 2020-01-10 | 2020-05-12 | 广州贝玛生物科技有限公司 | Composition capable of improving stretch marks, postpartum repair moisturizer containing composition and preparation method of postpartum repair moisturizer |
CN111973522A (en) * | 2019-05-22 | 2020-11-24 | 思蓝(北京)科技有限公司 | Bubble shampoo and shower gel for children |
CN112245338A (en) * | 2020-11-25 | 2021-01-22 | 广州环亚化妆品科技有限公司 | Self-heating bath bubble and preparation method thereof |
US11129785B2 (en) | 2018-08-10 | 2021-09-28 | The Procter And Gamble Company | Rinse-off cleansing compositions |
CN114259416A (en) * | 2021-12-27 | 2022-04-01 | 卡莱丽化妆品有限公司 | Surfactant composition, and preparation method and application thereof |
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