A kind of preparation method of solaode
Technical field
The present invention relates to a kind of solaode, be specifically related to the preparation method of a kind of solaode, belong to solaode skill
Art field.
Background technology
Solaode is that one effectively absorbs solar radiant energy, utilizes photovoltaic effect to convert optical energy into the device of electric energy,
When solar irradiation is in quasiconductor P-N junction (P-N Junction), form new hole-electron to (V-E pair), in P-N junction
Under the effect of electric field, hole is flowed to P district by N district, and electronics is flowed to N district by P district, is formed for electric current after connecting circuit.
The manufacturing process of crystal silicon solar batteries has six procedures, respectively making herbs into wool, spread, etch, plated film, silk screen printing,
Sintering.Making herbs into wool is that front side of silicon wafer is etched into rough matte, increases the absorption of sunlight;Diffusion is in front side of silicon wafer shape
Become PN junction, produce photovoltaic effect;Etching is to remove silicon chip back side and the PN junction at edge and the phosphorosilicate glass in front;Plated film is
In front side of silicon wafer silicon nitride film, reduce the reflection of sunlight;Silk screen printing is to starch at front side of silicon wafer and back up anelectrode
Material, back electrode slurry and Al-back-surface-field (BSF) paste;Sintering is the slurry curing by front side of silicon wafer and back up, forms electrode.
The photoelectric transformation efficiency preparing solaode in existing preparation method is relatively low.
Summary of the invention
The problem existed for above-mentioned prior art, the present invention provides the preparation method of a kind of solaode, the solar energy of preparation
Battery can improve sunlight absorbance, thus improves photoelectric transformation efficiency.
To achieve these goals, the preparation method of a kind of solaode that the present invention uses, comprise the following steps:
1) P-type silicon is chosen as silicon chip, and in the front making herbs into wool of silicon chip;
2) front at silicon chip is diffused forming N-type emitter stage;
3) removal step 2) diffusion process formed phosphorosilicate glass;
4) backside passivation layer is formed at silicon chip back side;
5) passivating film is formed at front side of silicon wafer;
6) on passivating film, silver nano-grain is deposited;
7) back of the body electric field and back electrode are formed at silicon chip back side;
8) anelectrode is formed at front side of silicon wafer;
9) silicon chip is sintered.
As improvement, described step 6) concrete operations be:
Silicon chip after plated film is placed in silver nitrate solution, after standing 1-10min, takes out silicon chip and put into citric acid and polyethylene pyrrole
In the mixed solution of pyrrolidone, after reaction 1-10min, take out silicon chip, clean up with deionized water, dry up.
As improvement, the concentration of described silver nitrate is 0.5-2.0mol/L.
As improvement, the concentration of described citric acid is 3-5mol/L, and the consumption of citric acid is 5-10L.
As improvement, the consumption of described polyvinylpyrrolidone is 0.02-0.20g.
As improvement, described silicon chip time of repose in silver nitrate solution is 1-5min.
As improvement, described silicon chip response time in mixed solution is 1-5min.
As improvement, described step 6) in formed silver nano-grain be square, spheroid or pyramid shape.
As improvement, a diameter of 20-80nm of described silver nano-grain.
As improvement, described step 8) positive electrode surface be electroplate with at least one silver layer, described silver layer is wrapped in described anelectrode
On.
Compared with prior art, the present invention, by chemical deposition silver nano-grain on front side of silicon wafer passivating film, relies on incident illumination to swash
Send out the surface plasma vibration of silver nano-grain, the absorbance of sunlight can be obviously enhanced, simultaneously plus the astigmatism effect of Argent grain,
Thus promote the photoelectric transformation efficiency of battery.
Accompanying drawing explanation
Fig. 1 is the process chart of the present invention;
Fig. 2 is the structural representation that the inventive method prepares solaode;
In figure: 1, P-type silicon, 2, N-type emitter stage, 3, passivating film, 4, anelectrode, 5, backside passivation layer, 6, back of the body electric field,
7, back electrode.
Detailed description of the invention
For making the object, technical solutions and advantages of the present invention of greater clarity, below by drawings and Examples, to the present invention
It is further elaborated.However, it should be understood that specific embodiment described herein is only in order to explain the present invention, not
For limiting the scope of the present invention.
Unless otherwise defined, the skill of all of technical term used herein and scientific terminology and the technical field belonging to the present invention
The implication that art personnel are generally understood that is identical, and the term used the most in the description of the invention is intended merely to describe concrete
The purpose of embodiment, it is not intended that in limiting the present invention.
Embodiment one
As it is shown in figure 1, the preparation method of a kind of solaode, comprise the following steps:
1) P-type silicon is chosen as silicon chip, and in the front making herbs into wool of silicon chip;
2) front at silicon chip is diffused forming N-type emitter stage;
3) removal step 2) diffusion process formed phosphorosilicate glass;
4) backside passivation layer is formed at silicon chip back side;
5) passivating film is formed at front side of silicon wafer;
6) silicon chip after plated film is placed in the silver nitrate solution that concentration is 0.5mol/L, after standing 10min, takes out, then will
Silicon chip puts into the mixed solution (citric acid in mixed solution of citric acid that concentration is 3mol/L and polyvinylpyrrolidone (PVP)
Consumption be 5L, the consumption of polyvinylpyrrolidone is 0.02g) in, reaction 10min after, take out silicon chip, use deionized water
Clean up, dry up, the silicon chip of silver nano-grain, wherein a diameter of 20-80nm of silver nano-grain must be deposited, formation
Silver nano-grain is square, spheroid or pyramid shape;
7) back of the body electric field and back electrode are formed at silicon chip back side;
8) forming anelectrode at front side of silicon wafer, positive electrode surface is electroplate with at least one silver layer, and described silver layer is wrapped in described anelectrode
On, make anelectrode become silver electrode;
9) silicon chip is sintered.
Embodiment two
The step 6 of this embodiment) in, the silicon chip after plated film is placed in the silver nitrate solution that concentration is 2.0mol/L, stands 1min
After, take out, then silicon chip is put into the citric acid and the mixed solution (mixed solution of polyvinylpyrrolidone that concentration is 5mol/L
The consumption of middle citric acid is 8L, and the consumption of polyvinylpyrrolidone is 0.10g) in, after reaction 1min, take out silicon chip, spend
Ionized water cleans up, and dries up, and must deposit the silicon chip of silver nano-grain, wherein a diameter of 20-80nm of silver nano-grain,
The silver nano-grain formed is square, spheroid or pyramid shape;Remaining operating procedure is identical with embodiment one.
Embodiment three
The step 6 of this embodiment) in, the silicon chip after plated film is placed in the silver nitrate solution that concentration is 1.0mol/L, stands 5min
After, take out, then silicon chip is put into the citric acid and the mixed solution (mixed solution of polyvinylpyrrolidone that concentration is 4mol/L
The consumption of middle citric acid is 10L, and the consumption of polyvinylpyrrolidone is 0.20g) in, after reaction 5min, take out silicon chip, use
Deionized water cleans up, and dries up, and must deposit the silicon chip of silver nano-grain, wherein a diameter of 20-80nm of silver nano-grain,
The silver nano-grain formed is square, spheroid or pyramid shape;Remaining operating procedure is identical with embodiment one.
The structure of solaode is obtained as in figure 2 it is shown, this battery includes P-type silicon 1 by provider's legal system of the present invention;
The front of P-type silicon 1 is provided with N-type emitter stage 2, and the front of described N-type emitter stage 2 is provided with passivating film 3, described passivating film
The front of 3 is provided with anelectrode 4, and the front deposition of passivating film 3 has silver nano-grain;
The back side of described P-type silicon 1 is provided with backside passivation layer 5, and described backside passivation layer 5 is provided with back of the body electric field 6 and back electrode 7,
Described back electrode 7 is positioned at the back side of back of the body electric field 6.
The present invention, by chemical deposition silver nano-grain on front side of silicon wafer passivating film, relies on incident illumination to excite the table of silver nano-grain
Face plasma oscillation, can be obviously enhanced the absorbance of sunlight, simultaneously plus the astigmatism effect of Argent grain, thus promote battery
Photoelectric transformation efficiency.
The foregoing is only presently preferred embodiments of the present invention, not in order to limit the present invention, all spirit in the present invention and former
Any amendment, equivalent or the improvement etc. made within then, should be included within the scope of the present invention.