CN105908497A - 一种毛涤面料的亲水整理方法 - Google Patents

一种毛涤面料的亲水整理方法 Download PDF

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CN105908497A
CN105908497A CN201610329293.7A CN201610329293A CN105908497A CN 105908497 A CN105908497 A CN 105908497A CN 201610329293 A CN201610329293 A CN 201610329293A CN 105908497 A CN105908497 A CN 105908497A
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fabric
hydrophilic
terylene fabric
hydrophilic finiss
wool
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曹秀明
石小正
费根娣
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Jiangsu Sunshine Co Ltd
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Abstract

本发明公开了一种毛涤面料的亲水整理方法，包括胺解预处理、湿蒸、亲水整理等步骤。本发明中首先对毛涤面料进行胺解，胺解处理可在织物表面形成沟槽，利于涤纶纤维与亲水整理液中的亲水组分粘附，湿蒸有助于进一步对涤纶进行蚀刻，而且湿蒸处理后的羊毛纤维亲水性基团外露，羊毛纤维结构发生松弛，可增加亲水整理液在纤维表面的润湿程度，增加整理后面料的增重率和亲水耐洗涤能力，还能改善面料中羊毛纤维的抗起球性能。

Description

一种毛涤面料的亲水整理方法
技术领域
本发明涉及纺织品生产技术领域，具体涉及一种毛涤面料的亲水整理方法。
背景技术
精纺的毛涤面料中羊毛具有天然的拒水特性，而涤纶纤维是疏水性和成纤维，穿着舒适度较差，因此面料的回潮率低。现有技术中改善涤纶织物服用性能主要有两种方法：一是利用纤维的合成技术在纤维的纺织过程中对聚酯纤维的结构进行改性，使纤维本身具有亲水性和抗静电性；二是利用织物后整理技术达到改性的目的。整理改性是在聚酯大分子链上引入亲水基团，使涤纶表面形成亲水的保护层，主要包括表面接枝聚合和亲水整理剂吸附固着两种形式。接枝聚合的主要方式为等离子轰击纺织品表面，产业化推广存在设备等限制因素。常用的亲水性整理剂包括聚乙二醇、聚酯聚醚树脂、环氧类树脂、聚硅氧烷类、聚氨酯类和壳聚糖。上述亲水整理剂多为合成材质，纤维表面亲水性薄膜在水中会发生溶胀，从而将羊毛鳞片包覆起来，导致面料手感枯燥，精纺面料的柔软度风格欠缺。
发明内容
本发明的目的在于克服现有技术中存在的缺陷，提供一种毛涤面料的亲水整理方法，整理后的面料亲水性强、手感丰满柔软，也有利于人体健康。
为实现上述技术效果，本发明的技术方案为：一种毛涤面料的亲水整理方法，其特征在于，包括以下步骤：
S1：胺解预处理，胺解预处理液的组成为氢氧化钠0.2～0.3%、季铵盐型阳离子表面活性剂0.02～0.2%、三乙醇胺0.8～1.2%和余量水，将精纺毛涤面料置于胺解预处理液中，升温至75～85℃，保温处理3～4h，水洗轧液；
S2：将S2所得带液的毛涤面料置于蒸汽温度为110～130℃的汽蒸机中湿蒸处理8～12min，其中汽蒸机中的相对湿度控制在55～65%，然后将面料取出烘干；
S3：将S2所得面料置于60～70℃的亲水整理液中两浸两轧，经预烘、水洗烘干，得毛涤面料成品。
优选的技术方案为，亲水整理液的组成包括羊毛角蛋白、交联剂和水，亲水整理液中交联剂的重量百分比为1～5%。
优选的技术方案为，交联剂为乙二醇缩水甘油醚和/或戊二醛。
优选的技术方案为，S1中季铵盐型阳离子表面活性剂为选自十八烷基三甲基溴化铵、十六烷基三甲基溴化铵、双十八烷基二甲基氯化铵、十六烷基三甲基氯化铵中的至少一种。
优选的技术方案为，S3中预烘温度为70～90℃，预烘时间为3～5min。
本发明的优点和有益效果在于：
本发明中首先对毛涤面料进行胺解，胺解处理可在织物表面形成沟槽，利于涤纶纤维与亲水整理液中的亲水组分粘附，湿蒸有助于进一步对涤纶进行蚀刻，而且湿蒸处理后的羊毛纤维亲水性基团外露，羊毛纤维结构发生松弛，可增加亲水整理液在纤维表面的润湿程度，增加整理后面料的增重率和亲水耐洗涤能力，还能改善面料中羊毛纤维的抗起球性能。
具体实施方式
下面结合实施例，对本发明的具体实施方式作进一步描述。以下实施例仅用于更加清楚地说明本发明的技术方案，而不能以此来限制本发明的保护范围。
实施例1
为实现上述技术效果，实施例1中毛涤面料的亲水整理方法包括以下步骤：
S1：胺解预处理，胺解预处理液的组成为氢氧化钠0.2%、季铵盐型阳离子表面活性剂0.02%、三乙醇胺0.8%和余量水，将精纺毛涤面料置于胺解预处理液中，升温至75℃，保温处理3h，水洗轧液；
S2：将S2所得带液的毛涤面料置于蒸汽温度为110℃的汽蒸机中湿蒸处理8min，其中汽蒸机中的相对湿度控制在55%，然后将面料取出烘干；
S3：将S2所得面料置于60℃的亲水整理液中两浸两轧，经预烘、水洗烘干，得毛涤面料成品。
亲水整理液的组成包括羊毛角蛋白、交联剂和水，亲水整理液中交联剂的重量百分比为1%。
交联剂为乙二醇缩水甘油醚。
S1中季铵盐型阳离子表面活性剂为十八烷基三甲基溴化铵
S3中预烘温度为70℃，预烘时间为3min。
实施例2
实施例2与实施例1的区别为：
S1：胺解预处理，胺解预处理液的组成为氢氧化钠0.3%、季铵盐型阳离子表面活性剂0.2%、三乙醇胺1.2%和余量水，将精纺毛涤面料置于胺解预处理液中，升温至85℃，保温处理4h，水洗轧液；
S2：将S2所得带液的毛涤面料置于蒸汽温度为130℃的汽蒸机中湿蒸处理12min，其中汽蒸机中的相对湿度控制在65%，然后将面料取出烘干；
S3：将S2所得面料置于70℃的亲水整理液中两浸两轧，经预烘、水洗烘干，得毛涤面料成品。
亲水整理液的组成包括羊毛角蛋白、交联剂和水，亲水整理液中交联剂的重量百分比为5%。
交联剂为戊二醛。
S1中季铵盐型阳离子表面活性剂为十八烷基三甲基溴化铵和十六烷基三甲基溴化铵以重量比1:1组合而成。
S3中预烘温度为90℃，预烘时间为5min。
实施例3
实施例3与实施例1的区别为：
S1：胺解预处理，胺解预处理液的组成为氢氧化钠0.25%、季铵盐型阳离子表面活性剂0.1%、三乙醇胺1%和余量水，将精纺毛涤面料置于胺解预处理液中，升温至80℃，保温处理3.5h，水洗轧液；
S2：将S2所得带液的毛涤面料置于蒸汽温度为120℃的汽蒸机中湿蒸处理10min，其中汽蒸机中的相对湿度控制在60%，然后将面料取出烘干；
S3：将S2所得面料置于65℃的亲水整理液中两浸两轧，经预烘、水洗烘干，得毛涤面料成品。
亲水整理液的组成包括羊毛角蛋白、交联剂和水，亲水整理液中交联剂的重量百分比为3%。
交联剂由乙二醇缩水甘油醚和戊二醛组成，其中乙二醇缩水甘油醚的重量百分比为80%。
S1中季铵盐型阳离子表面活性剂为十八烷基三甲基溴化铵、十六烷基三甲基溴化铵和双十八烷基二甲基氯化铵以1:1:1的重量比混合。
S3中预烘温度为70～90℃，预烘时间为3～5min。
对比例
对比例1中不包含S1，其余工艺参数同实施例3；
对比例2中不包含S2，其余工艺参数同实施例3
将实施例1-3和对比例1-2所得整理后的毛涤面料亲水性能进行对比，其中，对比例1-2的亲水性能均略差与实施例1-3，其中，对比例2试样的抗起球性能和亲水性能优于对比例1。
以上所述仅是本发明的优选实施方式，应当指出，对于本技术领域的普通技术人员来说，在不脱离本发明技术原理的前提下，还可以做出若干改进和润饰，这些改进和润饰也应视为本发明的保护范围。

Claims (5)

1.一种毛涤面料的亲水整理方法，其特征在于，包括以下步骤：
S1：胺解预处理，胺解预处理液的组成为氢氧化钠0.2～0.3%、季铵盐型阳离子表面活性剂0.02～0.2%、三乙醇胺0.8～1.2%和余量水，将精纺毛涤面料置于胺解预处理液中，升温至75～85℃，保温处理3～4h，水洗轧液；
S2：将S2所得带液的毛涤面料置于蒸汽温度为110～130℃的汽蒸机中湿蒸处理8～12min，其中汽蒸机中的相对湿度控制在55～65%，然后将面料取出烘干；
S3：将S2所得面料置于60～70℃的亲水整理液中两浸两轧，经预烘、水洗烘干，得毛涤面料成品。
2.根据权利要求1所述的毛涤面料的亲水整理方法，其特征在于，亲水整理液的组成包括羊毛角蛋白、交联剂和水，亲水整理液中交联剂的重量百分比为1～5%。
3.根据权利要求2所述的毛涤面料的亲水整理方法，其特征在于，交联剂为乙二醇缩水甘油醚和/或戊二醛。
4.根据权利要求1所述的毛涤面料的亲水整理方法，其特征在于，S1中季铵盐型阳离子表面活性剂为选自十八烷基三甲基溴化铵、十六烷基三甲基溴化铵、双十八烷基二甲基氯化铵、十六烷基三甲基氯化铵中的至少一种。
5.根据权利要求1所述的毛涤面料的亲水整理方法，其特征在于，S3中预烘温度为70～90℃，预烘时间为3～5min。
CN201610329293.7A 2016-05-18 2016-05-18 一种毛涤面料的亲水整理方法 Pending CN105908497A (zh)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111893769A (zh) * 2020-08-20 2020-11-06 江苏阳光股份有限公司 一种抗静电毛涤精纺面料的生产工艺

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111893769A (zh) * 2020-08-20 2020-11-06 江苏阳光股份有限公司 一种抗静电毛涤精纺面料的生产工艺
CN111893769B (zh) * 2020-08-20 2024-03-08 江苏阳光股份有限公司 一种抗静电毛涤精纺面料的生产工艺

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Application publication date: 20160831