CN105837419B - 一种基于膦功能化聚醚烷基胍盐离子液体的烯烃两相氢甲酰化高选择性制备正构醛的方法 - Google Patents
一种基于膦功能化聚醚烷基胍盐离子液体的烯烃两相氢甲酰化高选择性制备正构醛的方法 Download PDFInfo
- Publication number
- CN105837419B CN105837419B CN201610165823.9A CN201610165823A CN105837419B CN 105837419 B CN105837419 B CN 105837419B CN 201610165823 A CN201610165823 A CN 201610165823A CN 105837419 B CN105837419 B CN 105837419B
- Authority
- CN
- China
- Prior art keywords
- ionic liquid
- phase
- reaction
- alkene
- alkanal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
- C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0277—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature
- B01J31/0278—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature containing nitrogen as cationic centre
- B01J31/0285—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature containing nitrogen as cationic centre also containing elements or functional groups covered by B01J31/0201 - B01J31/0274
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/06—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
- B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
- B01J31/2409—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom
- B01J31/2414—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom comprising aliphatic or saturated rings
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
- B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
- B01J31/2442—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems
- B01J31/2447—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems and phosphine-P atoms as substituents on a ring of the condensed system or on a further attached ring
- B01J31/2452—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems and phosphine-P atoms as substituents on a ring of the condensed system or on a further attached ring with more than one complexing phosphine-P atom
- B01J31/2457—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems and phosphine-P atoms as substituents on a ring of the condensed system or on a further attached ring with more than one complexing phosphine-P atom comprising aliphatic or saturated rings, e.g. Xantphos
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
- B01J2231/32—Addition reactions to C=C or C-C triple bonds
- B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/822—Rhodium
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/584—Recycling of catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Description
Claims (4)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610165823.9A CN105837419B (zh) | 2016-03-19 | 2016-03-19 | 一种基于膦功能化聚醚烷基胍盐离子液体的烯烃两相氢甲酰化高选择性制备正构醛的方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610165823.9A CN105837419B (zh) | 2016-03-19 | 2016-03-19 | 一种基于膦功能化聚醚烷基胍盐离子液体的烯烃两相氢甲酰化高选择性制备正构醛的方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN105837419A CN105837419A (zh) | 2016-08-10 |
CN105837419B true CN105837419B (zh) | 2018-10-12 |
Family
ID=56587696
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201610165823.9A Active CN105837419B (zh) | 2016-03-19 | 2016-03-19 | 一种基于膦功能化聚醚烷基胍盐离子液体的烯烃两相氢甲酰化高选择性制备正构醛的方法 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN105837419B (zh) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111760591B (zh) * | 2020-06-12 | 2023-06-27 | 青岛科技大学 | 一类二氧化硅基材料负载聚醚功能化离子液体催化剂在烯烃氢甲酰化反应中的应用 |
CN111804332B (zh) * | 2020-06-12 | 2023-06-27 | 青岛科技大学 | 一类树脂材料负载的聚醚功能化离子液体催化剂在烯烃氢甲酰化反应中的应用 |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102617308B (zh) * | 2012-03-13 | 2013-11-27 | 青岛科技大学 | 一种烯烃两相氢甲酰化方法 |
CN103483381B (zh) * | 2013-08-22 | 2016-08-17 | 青岛科技大学 | 一类膦功能化离子液体的制备及其在氢甲酰化反应中的应用 |
CN103570514B (zh) * | 2013-10-07 | 2015-11-18 | 青岛科技大学 | 一种均相催化-两相分离烯烃氢甲酰化的方法 |
CN105017314B (zh) * | 2015-05-16 | 2017-11-03 | 青岛科技大学 | 一类膦功能化聚醚哌啶盐离子液体及其在烯烃氢甲酰化反应中的应用 |
-
2016
- 2016-03-19 CN CN201610165823.9A patent/CN105837419B/zh active Active
Also Published As
Publication number | Publication date |
---|---|
CN105837419A (zh) | 2016-08-10 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN105017315B (zh) | 一类膦功能化聚醚咪唑盐离子液体及其在烯烃氢甲酰化反应中的应用 | |
CN105017317B (zh) | 一种基于膦功能化聚醚烷基胍盐离子液体的烯烃两相氢甲酰化的方法 | |
CN105017319B (zh) | 一类膦功能化聚醚季鏻盐离子液体及其在烯烃氢甲酰化反应中的应用 | |
CN109806911A (zh) | 一种高选择性制备直链醛的催化剂及其制备和应用 | |
CN105017314B (zh) | 一类膦功能化聚醚哌啶盐离子液体及其在烯烃氢甲酰化反应中的应用 | |
CN105753669B (zh) | 一种基于膦功能化聚醚咪唑盐离子液体的烯烃两相氢甲酰化高选择性制备正构醛的方法 | |
CN105837419B (zh) | 一种基于膦功能化聚醚烷基胍盐离子液体的烯烃两相氢甲酰化高选择性制备正构醛的方法 | |
CN109836318A (zh) | 一种烯烃氢甲酰化反应制备醛的方法 | |
CN105669403B (zh) | 一种基于膦功能化聚醚吡咯烷盐离子液体的烯烃两相氢甲酰化高选择性制备正构醛的方法 | |
CN105001260B (zh) | 一类膦功能化聚醚吗啉盐离子液体及其在烯烃氢甲酰化反应中的应用 | |
CN105693485B (zh) | 一种基于膦功能化聚醚哌啶盐离子液体的烯烃两相氢甲酰化高选择性制备正构醛的方法 | |
CN105732345B (zh) | 一种基于膦功能化聚醚季铵盐离子液体的烯烃两相氢甲酰化高选择性制备正构醛的方法 | |
CN105669402B (zh) | 一种基于膦功能化聚醚季磷盐离子液体的烯烃两相氢甲酰化高选择性制备正构醛的方法 | |
CN105001407B (zh) | 一类膦功能化聚醚吡咯烷离子液体及其在烯烃氢甲酰化反应中的应用 | |
CN105777509B (zh) | 一种基于膦功能化聚醚吡啶盐离子液体的烯烃两相氢甲酰化高选择性制备正构醛的方法 | |
CN105837418B (zh) | 一种基于膦功能化聚醚吗啉盐离子液体的烯烃两相氢甲酰化高选择性制备正构醛的方法 | |
CN105753670B (zh) | 一种基于聚醚吡啶盐离子液体的烯烃两相氢甲酰化高选择性制备正构醛的方法 | |
CN105669404B (zh) | 一种基于聚醚哌啶盐离子液体的烯烃两相氢甲酰化高选择性制备正构醛的方法 | |
CN105017316B (zh) | 一类膦功能化聚醚吡啶盐离子液体及其在烯烃氢甲酰化反应中的应用 | |
CN105777513B (zh) | 一种基于聚醚吡咯烷盐离子液体的烯烃两相氢甲酰化高选择性制备正构醛的方法 | |
CN105037421B (zh) | 一类膦功能化聚醚季铵盐离子液体及其在烯烃氢甲酰化反应中的应用 | |
CN105777512B (zh) | 一种基于聚醚季磷盐离子液体的烯烃两相氢甲酰化高选择性制备正构醛的方法 | |
CN105669401B (zh) | 一种基于聚醚咪唑盐离子液体的烯烃两相氢甲酰化高选择性制备正构醛的方法 | |
CN105669405B (zh) | 一种基于聚醚吗啉盐离子液体的烯烃两相氢甲酰化高选择性制备正构醛的方法 | |
CN105712852B (zh) | 一种基于聚醚季铵盐离子液体的烯烃两相氢甲酰化高选择性制备正构醛的方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
GR01 | Patent grant | ||
GR01 | Patent grant | ||
TR01 | Transfer of patent right | ||
TR01 | Transfer of patent right |
Effective date of registration: 20210914 Address after: No.7 xiazhou Road, Taocheng Town, Yongchun County, Quanzhou City, Fujian Province Patentee after: Ye Hui Address before: 266000 Qingdao University of Science & Technology, 99 Songling Road, Laoshan District, Qingdao, Shandong Patentee before: QINGDAO University OF SCIENCE AND TECHNOLOGY |
|
TR01 | Transfer of patent right | ||
TR01 | Transfer of patent right |
Effective date of registration: 20211018 Address after: Liu'an Development Zone, Yongchun County, Quanzhou City, Fujian Province (east side of Taoxi bridge) Patentee after: Yongchun County Product Quality Inspection Institute Fujian fragrance product quality inspection center, national incense burning product quality supervision and Inspection Center (Fujian) Address before: No.7 xiazhou Road, Taocheng Town, Yongchun County, Quanzhou City, Fujian Province Patentee before: Ye Hui |