CN1058158A - Harmless treatment and utilization method of garbage - Google Patents

Harmless treatment and utilization method of garbage Download PDF

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CN1058158A
CN1058158A CN 91107235 CN91107235A CN1058158A CN 1058158 A CN1058158 A CN 1058158A CN 91107235 CN91107235 CN 91107235 CN 91107235 A CN91107235 A CN 91107235A CN 1058158 A CN1058158 A CN 1058158A
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rubbish
treatment
slag
cement
brick
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CN1032737C (en
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张钧博
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Abstract

The garbage is first treated aerobically and anaerobically in treating pool to sterilize, disinfect and deodorize and biologically degrade and convert organic matter into fuel gas as side product, which is then screened and separated to produce solid fuel, coal saving additive, inorganic matter, building material and liquid fuel, paint and adhesive. The method eliminates the pollution of garbage, makes full use of the garbage, changes waste into valuable, and has the advantages of investment saving, high benefit, pollution prevention, energy conservation and the like. Is suitable for harmless treatment and utilization of household garbage and partial industrial garbage.

Description

The harmless treatment of rubbish with utilize method
The present invention relates to the harmless treatment of the processing of solid waste, particularly rubbish and utilize method.
At present, the processing to domestic waste generally is the employing compost, burns, buries even be poured among the rivers,lakes and seas that these methods not can solve the pollution of environment in the world.As, to bury and with the method for toppling over a large amount of biological bacteriums is drifted about in the water or mix in the underground water, the severe contamination water source has enlarged pollution range artificially, causes even more serious secondary pollution; Compost treatment is not only taken up an area of wide, and the obnoxious flavour that produced in the septic process of heap fermentation of rubbish can polluted air, the sewage polluted-water in the water that permeates the ground; It is limited to burn handled component of refuse, and wastes combustible material, and flue dust has a large amount of 3.4-benzopyrene pollution atmosphere.Prior art is to the processing of solid waste, generally be adopt respectively that methods such as chemistry, physics, biological and magnetic sort, screen, pulverize, the difficulty of burning, pressing treatment, refuse treatment engineering is big, investment is big, income is few, wherein majority only is in order to dwindle the volume of rubbish, shift or change blowdown mode, product after the only useful refuse treatment is done material of construction or thermal utilization, and rubbish is not carried out comprehensive harmless treatment and comprehensive utilization.
The objective of the invention is to overcome the shortcoming of prior art, a kind of harmless treatment of rubbish is provided and utilizes technology, domestic waste is carried out harmless treatment, eliminate the secondary pollution of rubbish, turn waste into wealth, all comprehensive utilizations, save energy again when curbing environmental pollution makes rubbish become fuel and fuel dope and material of construction.
The present invention is achieved in that at first rubbish to be poured into and carries out aerobic treatment and anaerobic treatment in the treating pond, add chemical reagent, with biochemical method (accounting for more than 70% of rubbish total amount) used in the burning that the organic matter degradation in the rubbish changes into solid fuel and inflammable gas.After carrying out harmless treatment three days make rubbish slag drying, water content 5-10% by high temperature.Again exsiccant rubbish is transported in the multilayer sifting machine with e Foerderanlage from treating pond and screens, sub-elect plastic waste, aphlogistic inorganics and organic matter rubbish slags such as the brick and tile that granularity is big, pottery, glass with hydrometer method and granularity method.Carry out processing and utilization then respectively: will be in the organic matter rubbish slag add the organism (as rice husk, wheat straw, wood chip etc.) after pulverizing and the ignition dope (as SODIUMNITRATE, saltpetre, magnesium etc.) that burns, make coal-saving additive after, mix and burn in the raw coal; Sand, lime stone, slag ash and brick and tile through after the grinding and processing, are added lime powder and terra alba and make slag ashes cement; With brick and tile, pottery, ash, sand add cement through after the grinding and processing, the cement solidifies agent and water, be pressed into brick on the unburned coal ash sand after stirring evenly again; Broken cullet, pottery are added the unsaturated polyester resin tackiness agent and auxiliary material is made finishing material,, plastic waste handled through chemical industry make liquid fuel, paint, tackiness agent as artificial marble.
The invention provides a kind of harmless treatment of rubbish and utilize method, eliminated the secondary pollution of rubbish, all comprehensive utilization is turned waste into wealth, and when curbing environmental pollution, makes rubbish become fuel and fuel dope and material of construction.The moisture content that just carries out in screening and separating, the rubbish after rubbish process aerobic treatment and the anaerobic treatment has reduced about 90%, the weight saving of rubbish, volume-diminished, 70% is fuel, reduced the screening and separating kind, screening and separating, the volume that can reduce screening installation and power are reduced investment outlay easily, high efficiency, harmless to environment and operator simultaneously.The coal-saving additive of making mixes when burning in the raw coal according to the ratio of 30-60%, and through simultaneous test, its thermo-efficiency meets or exceeds equal raw coal, and obnoxious flavoures such as sulfurous gas reduce 50-70%, and smoke discharge amount reduces 30%, saves raw coal 20-40%.Be applicable to the harmless treatment of domestic refuse and organic industry rubbish and the processing and utilizing of utilization and inorganic industrial waste.
The present invention further describes below with reference to embodiment:
The embodiment of aerobic treatment
Rubbish is poured into the top, and to have opening for feed and venting port, top be that gas storage storehouse, bottom or bottom side have discharge port and be the well-ventilated and can carry out aerobic treatment 10-12 days in the treating pond of strict seal.Meanwhile, according to the composition of rubbish, add sodium bicarbonate 8-12Kg, potassium permanganate 0.5-3Kg, unslaked lime 20-40Kg in the rubbish per ton.The big I for the treatment of pond determines that according to need treating refuse amount at least two mouthfuls of ponds are built side by side.The pond four-hole is built side by side in the example, and every mouthful of long 25m in pond, wide 10m, dark 4m, the high 1-1.5m in gas storage storehouse are provided with opening for feed at the top, pond, long 4m, wide 2m, and opening for feed can be used water-lute.The venting port of every mouthful of Chi Ding connects gas pipe line to gas treatment chamber.Discharge port is arranged at the bottom in every mouthful of pond, long 1.5m, wide 1m, at the bottom of the pond to discharge port angle of inclination 20-30 degree, to make things convenient for discharging garbage.Rubbish pack into 10-12 days sealed feed inlets in back and discharge port enter anaerobic treatment stage.
Add the fermentation rate that sodium bicarbonate can quicken aerobic treatment, impel the part organism in the rubbish to generate ethanol.Potassium permanganate is disinfected in early days to rubbish, simultaneously, meets ethanol and decomposes, and emits oxygen, increases suitable oxygen concentration, gives the aerobic microbiological oxygen supply.Moisture content generation chemical reaction in unslaked lime and the rubbish generates white lime, moisture content in the rubbish is remained on about 30%, and emit a large amount of heat and improve temperature in the pond, make that temperature remains on 35-45 ℃ in the pond, regulate pH value simultaneously, remain on the scope of 6-7, the optimal environmental condition of growth and breeding is provided to aerobic bacteria.Through aerobic treatment, the organism in the rubbish (except that minority Mierocrystalline cellulose, xylogen) is all degraded.The waste gas (being mainly hydrogen sulfide) that the aerobic treatment stage is produced is sent into gas treatment chamber from gas storage storehouse, venting port with pneumatic tube, is discharged in the atmosphere after handling with dioxide peroxide method and active carbon adsorption again.
The embodiment of anaerobic treatment
Behind the opening for feed in sealing treatment pond and discharge port about 3 days, just enter anaerobic treatment.Treatment time 8-12 days.Anaerobic treatment stage is organism is further degraded and to be converted into inflammable gas (as methane) by anerobe.Connect by the venting port on the top, gas storage storehouse for the treatment of pond and to use for burning after pneumatic tube is transported to the gas treatment chamber purification process with combustion gas.During anaerobic treatment; Make the needs of high-grade fuel according to rubbish ingredient and whole finished product, rubbish per ton adds iron powder 8-12Kg, gac 0.7-1.5Kg, sodium-chlor 8-15Kg, aluminium powder or aluminum shot 1-5Kg.In treating processes, because the biological heat in the organic matter degradation process, unslaked lime and the water chemical heat that the heat of emitting and the quick oxidation of iron powder are produced that reacts, temperature in the treating pond remains at 45-60 ℃, last 3 days is 70-80 ℃, this persistent high temperature had both quickened organic degradation rate, killed the poisonous germ in the rubbish again, particularly strong carcinogens such as aflatoxin and nitrosamine compound are had unique killing effect because aflatoxin belong in the warm nature aerobic microorganism, under anaerobic promptly lost the survival environment condition and all killed; Microorganism that nitrosamine compound is only grown under the anaerobic environment condition such as the decomposition of capsula Rhodopseudomonas ability, the rate of decomposition after the processing reaches more than 90%.Simultaneously, the roundworm egg in the rubbish, fly pupa mortality ratio reach 100%, and the 3.4-benzopyrene reduces more than 30%, and colititre is below 0.01%.Reached the purpose of harmless treatment.Organism biochemical reaction under anaerobic is:
Figure 9110723500071
The gas production rate of domestic refuse per ton can reach 200M 3
The embodiment of screening and separating
Rubbish after the harmless treatment is transported to e Foerderanlage from the discharge port for the treatment of pond carries out screening and separating in the multistage screening machine.Through the rubbish after aerobic treatment and the anaerobic treatment, institute's water content is 5-10%, adopts hydrometer method and granularity method to screen, screen and tell plastic waste (accounting for the 0.5-1% of rubbish) to it; Aphlogistic inorganicss such as brick and tile, pottery, glass (account for rubbish total amount 2.5%); Organic matter rubbish slag (account for rubbish total amount 70%).The multistage screening machine is an oscillatory type multilayer separating screen, and the first layer is a big particle diameter sieve, particle diameter 50mm, and classification again after big particle diameter rubbish separated separates inorganicss such as plastics, brick and tile, pottery, glass with organism; The second layer is middle particle diameter sieve, particle diameter 10mm, classification again after rubbish is screened once more; The 3rd layer is the fine grain size sieve, the 50-100 order, and isolate is made solid fuel---coal-saving additive; The 4th layer is the fine grain size sieve, the 100-150 order, and isolate is made solid fuel---coal-saving additive; Make ashes cement or brick usefulness less than 150 purposes.
The embodiment of comprehensive processing and utilization
(1), the preparation of coal-saving additive: the every 800-900Kg of the organic matter rubbish slag that screening and separating is gone out adds organism slag 80-180Kg such as rice husk after pulverizing, wheat straw, wood chip, SODIUMNITRATE 8-12Kg, saltpetre 8-12Kg, magnesium powder 1-2Kg, after stirring, mix in the raw coal in the ratio of 30-60% again and burn.Its combustion principle is:
(1), organic matter rubbish slag itself just can burn, general combustion heat value is in (3000-5500) * 10 3Cdl;
(2), sterilization, oxygenation, the heating agent that is used for aerobic treatment and anaerobic treatment stage is again ignition dope or incendiary material in burning, in burning, aluminium powder or the bits of the aluminium in aluminum shot and the rubbish that can emit oxygen and aiding combustion, ferric oxide and increase hydrogen concentration when temperature reaches 250 ℃ become the high thermite of heat in burning as potassium permanganate;
(3), the magnesium powder is sweetening agent, except that itself easy firing, combining with aluminium has more increased combustion efficacy;
(4), the various scrap metal grains in the rubbish produce a large amount of radiant heat in burning, under the acting in conjunction of ignition dope and incendiary material, very fast formation heat build-up family;
(5), after rubbish process aerobic treatment and the anaerobic treatment, by biochemical combined reaction, in coal-saving additive, increased the proportion (accounting for 28-33%) of volatile matter composition, in the burning of coal process, volatile matter has bigger influence to catching fire and burning, it catches fire rapidly coal, fully perfect combustion.
The desulfurization measure of coal-saving additive is: the lime desulfurization when (1), aerobic treatment, and (2), lime add the sodium bicarbonate desulfurization; (3), ferric oxide desulfurization and magnesium desulfurization, desulfurization be abundant, the quantity discharged of sulfurous gas reduces 50-70%.
(2), preparation slag ashes cement: with the sand that filters out, lime stone, slag ash (various slags all can) and brick and tile crushing screening, granularity 100-150 order accounts for 50-70%; Lime powder granularity 100-150 order accounts for 25-40%; Terra alba granularity 100-150 order accounts for 5%, and preparation in proportion driedly stirs well evenly, and dress envelope is stand-by.Label can reach the 300-400 order, is used to pave or beats Horizon and use.
(3), the manufacturing of unburned coal ash sand brick: with pulverizing such as the brick and tile that screen, pottery, ash, sands, granularity 50-100 purpose accounts for the 20-30%100-150 purpose and accounts for 25-35%, the 150-180 purpose accounts for 20-30%, slag ashes cement accounts for 10-20%, silicate cement or slag cement account for 10-20% and mix 5-10% and the cement solidifies after agent stirs evenly, add water 10-20% stirring again and deposit about 1-2 hour after 20-50 minute, again with 500Kg/M 2Above pressure forming maintenance seven days, its label can reach the 100-150 order, and folding strength is not less than 25Kg/cm 2
(4), the manufacturing of artificial marble: with glass, pottery, brick and tile or flyash crushing screening, more than granularity 100 orders, account for 60-70%, add unsaturated polyester resin tackiness agent (as 195,196,197,306,307 etc.) and account for 10-15%, Tetra hydro Phthalic anhydride accounts for 7-15%.Yellow soda ash or calcium chloride account for 7-15%, the mixed stirring, and the model of packing into the moulding of vibrating, is gone up cured polishing at the demoulding after 8 hours, finishing, ambient cure.
(5), Treatment of Waste Plastics:
Vinyl plastics and propylene plastics can utilize prior art to make the reprocessed plastic(s) goods.
Porous plastics (accounting for the 1-2% of rubbish total amount) adds different linking agents again and can produce tackiness agent with after toluene or the xylene soluble, adds various pigment again and can produce paint, waterproof paint and moisture-proofing agent for paperboard box or liquid fuel.

Claims (6)

1, the harmless treatment of rubbish with utilize method, it is characterized in that at first rubbish being poured into carrying out aerobic treatment and anaerobic treatment in the treating pond, add chemical reagent, with biochemical method the organic matter degradation in the rubbish being changed into solid fuel and inflammable gas uses for burning, after carrying out harmless treatment three days make rubbish slag drying, water content 5-10% by high temperature; Again exsiccant rubbish is transported in the multilayer sifting machine with e Foerderanlage from treating pond, screens, sub-elect plastic waste, aphlogistic inorganics and organic matter rubbish slags such as the brick and tile that granularity is big, pottery, glass with hydrometer method and granularity method; Carry out processing and utilization then respectively.Organism such as rice husk, wheat straw, wood chip and burning ignition dope such as SODIUMNITRATE, saltpetre and magnesium after the organic matter rubbish slag add pulverized are made coal-saving additive and are mixed in the raw coal and burn; With sand, lime, slag ash and brick and tile through adding lime powder after the grinding and processing and terra alba is made slag ashes cement; With brick and tile, pottery, ash, sand add cement through after the grinding and processing, the cement solidifies agent and water, be pressed into unburned coal ash sand brick after stirring evenly again; Broken cullet, pottery are added the unsaturated polyester resin tackiness agent and auxiliary material is made finishing material, as artificial marble: plastic waste handled through chemical industry make liquid fuel, paint, tackiness agent.
2, the harmless treatment of rubbish according to claim 1 and the aerobic treatment of utilizing method, it is characterized in that rubbish put into that the top has opening for feed and venting port, top are that gas storage storehouse, bottom or bottom side have discharge port, and be well-ventilated and can carrying out aerobic treatment 10-12 days in the treating pond of strict seal, composition according to rubbish, add sodium bicarbonate 8-12Kg, potassium permanganate 0.5-3Kg, unslaked lime 20-40Kg in the rubbish per ton, make that 35-45 ℃ of temperature maintenance, pH value are 6-7 in the pond in.Waste gas is sent into by pneumatic tube through gas storage storehouse, venting port and is discharged in the atmosphere after gas treatment chamber is handled with dioxide peroxide method and active carbon adsorption again.
3, the harmless treatment of rubbish according to claim 1 and the anaerobic treatment of utilizing method, it is characterized in that rubbish per ton in the rubbish after the aerobic treatment is added iron powder 8-12Kg, gac 0.7-1.5Kg, sodium-chlor 8-1Kg and aluminium powder or aluminum shot 1-5Kg, mixing even back carries out the opening for feed for the treatment of pond and discharge port sealing anaerobic treatment 8-12 days, venting port by the top, gas storage storehouse for the treatment of pond connects pneumatic tube, uses for burning after the inflammable gas that organism is changed into is transported to the gas treatment chamber purification process.
4, the harmless treatment of rubbish according to claim 1 and the coal-saving additive that utilizes method, organism after adding is pulverized in the every 800-900Kg of organic matter rubbish slag that it is characterized in that screening and separating is gone out such as rice husk, wheat straw, wood chip 80-180Kg, burning ignition dope SODIUMNITRATE 8-12Kg, saltpetre 8-12Kg, magnesium powder 1-2Kg, after stirring, mix in the raw coal in the ratio of 30-60% again and burn.
5, the harmless treatment of rubbish according to claim 1 and the slag ashes cement that utilizes method is characterized in that the sand, lime stone, slag ash and the brick and tile crushing screening that filter out.Granularity 100-150 order accounts for 55-70%, and lime powder granularity 100-150 order accounts for 25-40%, and terra alba granularity 100-150 order accounts for 5-10%, and preparation in proportion, dry mixing is even, packed for standby use.
6, the harmless treatment of rubbish according to claim 1 and the unburned coal ash sand brick that utilizes method, it is characterized in that brick and tile, pottery, ash, sand grinding and processing, granularity 50-100 purpose accounts for 20-30%, the 100-150 purpose accounts for 25-35%, the 150-180 purpose accounts for 20-30%, slag ashes cement accounts for 10-20%, silicate cement or slag cement account for 10-20%, and the agent that thes cement solidifies of mixing 5-10%, add water 10-20% after mixing thoroughly again, stir and deposited 1-2 hour after 20-50 minute, again with 500Kg/m 2Maintenance is seven days after the above pressure forming.
CN 91107235 1991-06-24 1991-06-24 Harmless treatment method for municipal refuse Expired - Fee Related CN1032737C (en)

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Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1094802C (en) * 1997-06-27 2002-11-27 深圳市市政环卫综合处理厂 House refuse treatment method for city
CN100450954C (en) * 2000-05-10 2009-01-14 章亮庄 Making color paving tile by utilizing city domestic refuse
CN101195121B (en) * 2007-02-28 2010-07-28 李华 Method for pollution-free processing, recycling urban pollutant and producing regeneration product
CN102030567A (en) * 2010-10-25 2011-04-27 赵泽明 Processing method for comprehensive utilization of solid household refuse
CN1968765B (en) * 2004-06-17 2011-05-25 索瑞恩切克尼环境股份公司 Method and system for the recycling of municipal solid wastes, and exploitation of the wasted solid recovery fuel
CN102688875A (en) * 2012-05-24 2012-09-26 广州伟烨船舶设备有限公司 Solid-liquid-gas all-state garbage treatment method
CN103056148A (en) * 2013-01-15 2013-04-24 东莞市伟烨船舶设备有限公司 Efficient non-peculiar-smell kitchen waste disposal method
CN103551367A (en) * 2013-10-24 2014-02-05 江苏维尔利环保科技股份有限公司 Integrated municipal solid waste treatment method
CN103624055A (en) * 2012-08-22 2014-03-12 黄广禧 Method for inhibiting generation of dioxin through mixed cracking of straw and household garbage
CN105233321A (en) * 2015-11-16 2016-01-13 广西捷佳润农业科技有限公司 Automatic disinfection and deodorization method and equipment for workshop environment of waste transfer station
CN105271935A (en) * 2015-11-03 2016-01-27 陶祖岐 Decoration board and packaging box board manufactured by domestic garbage
CN105272013A (en) * 2015-11-03 2016-01-27 陶祖岐 Heat-insulation and sound-isolation building block manufactured by domestic garbage

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ITMI20052430A1 (en) * 2005-12-21 2007-06-22 Sorain Cecchini Ambiente Sca S P A NONE

Cited By (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1094802C (en) * 1997-06-27 2002-11-27 深圳市市政环卫综合处理厂 House refuse treatment method for city
CN100450954C (en) * 2000-05-10 2009-01-14 章亮庄 Making color paving tile by utilizing city domestic refuse
CN1968765B (en) * 2004-06-17 2011-05-25 索瑞恩切克尼环境股份公司 Method and system for the recycling of municipal solid wastes, and exploitation of the wasted solid recovery fuel
CN101195121B (en) * 2007-02-28 2010-07-28 李华 Method for pollution-free processing, recycling urban pollutant and producing regeneration product
CN102030567A (en) * 2010-10-25 2011-04-27 赵泽明 Processing method for comprehensive utilization of solid household refuse
CN102688875A (en) * 2012-05-24 2012-09-26 广州伟烨船舶设备有限公司 Solid-liquid-gas all-state garbage treatment method
CN102688875B (en) * 2012-05-24 2014-12-10 广州伟烨船舶设备有限公司 Solid-liquid-gas all-state garbage treatment method
CN103624055A (en) * 2012-08-22 2014-03-12 黄广禧 Method for inhibiting generation of dioxin through mixed cracking of straw and household garbage
CN103056148A (en) * 2013-01-15 2013-04-24 东莞市伟烨船舶设备有限公司 Efficient non-peculiar-smell kitchen waste disposal method
CN103551367A (en) * 2013-10-24 2014-02-05 江苏维尔利环保科技股份有限公司 Integrated municipal solid waste treatment method
CN103551367B (en) * 2013-10-24 2016-05-18 江苏维尔利环保科技股份有限公司 Municipal living refuse comprehensive treatment method
CN105271935A (en) * 2015-11-03 2016-01-27 陶祖岐 Decoration board and packaging box board manufactured by domestic garbage
CN105272013A (en) * 2015-11-03 2016-01-27 陶祖岐 Heat-insulation and sound-isolation building block manufactured by domestic garbage
CN105272013B (en) * 2015-11-03 2017-05-24 陶祖岐 Heat-insulation and sound-isolation building block manufactured by domestic garbage
CN105271935B (en) * 2015-11-03 2017-06-30 陶祖岐 Decorative panel and packaging boxboard that a kind of house refuse is made
CN105233321A (en) * 2015-11-16 2016-01-13 广西捷佳润农业科技有限公司 Automatic disinfection and deodorization method and equipment for workshop environment of waste transfer station
CN105233321B (en) * 2015-11-16 2018-01-16 广西捷佳润科技股份有限公司 Garbage transfer station workshop condition automatic disinfection deodorizing method

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