CN105811041A - Recycling and disposal system for waste lithium-ion power battery - Google Patents

Recycling and disposal system for waste lithium-ion power battery Download PDF

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Publication number
CN105811041A
CN105811041A CN201610339476.7A CN201610339476A CN105811041A CN 105811041 A CN105811041 A CN 105811041A CN 201610339476 A CN201610339476 A CN 201610339476A CN 105811041 A CN105811041 A CN 105811041A
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battery
waste lithium
particle
disintegrating machine
lithium ionic
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CN201610339476.7A
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CN105811041B (en
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夏雄伟
薛辛
马成
殷康健
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Jiangsu Dingduan Environmental Protection Technology Co.,Ltd.
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Zhuzhou Dingduan Equipment Co Ltd
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/54Reclaiming serviceable parts of waste accumulators
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/84Recycling of batteries or fuel cells

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  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Secondary Cells (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

The invention discloses a recycling and disposal system for a waste lithium-ion power battery. The disposal system comprises a single battery storage bin, a conveyor belt, a circulating pool, a hammer-type high-speed impact crusher, an environment-friendly blast drying oven, a blade crusher, gas collecting equipment, a first gas treatment device, a wet cylinder, a coarse sundries outlet, a current collector particle outlet, an electrode material water solution storage tank, a pressure filtration device, a reducing smelting furnace, a second gas treatment device, an extraction tank and condensation tower. By the system, the harm of a waste new energy lithium-ion power battery to the ecological environment can be reduced; and the recovery utilization rate of resources is improved.

Description

A kind of applying waste lithium ionic electrokinetic cell recovery and processing system
Technical field
The present invention relates to applying waste lithium ionic power battery technology field, particularly relate to a kind of applying waste lithium ionic electrokinetic cell recovery and processing system.
Background technology
At present, using lithium ion battery ratio constantly to raise in China's new-energy automobile, the lithium battery market space is wide, electric automobile replacing oil by electricity, it is possible to realize " zero-emission " and " low noise ", is the important means solving the energy and environmental problem.Along with the development of the anxiety of petroleum resources and battery technology, electric automobile starts worldwide popularization and application gradually.Common common recognition is had become as with the inexorable trend that a new generation is energy-conservation with environmentally friendly vehicle is automobile industry development that electric automobile is representative, but the performance of electrokinetic cell decays with the increase of access times, when the 80% of electrokinetic cell hydraulic performance decline to originality energy, it is impossible to reach the use standard of electric automobile.Increase along with electric automobile recoverable amount, it is impossible to the power battery pack reaching electric motor car instructions for use will emerge in multitude, and how process the battery eliminating on these electric automobiles, it will is increasingly becoming the contradiction between new-energy automobile industry development and environment, resource.Therefore no matter weigh from protection of natural resources and environment angle; or develop industry angle from new-energy automobile to weigh; the recycling of automobile power cell is all must with important; estimating that the accumulative learies of the year two thousand twenty China only lithium-ion-power cell is just up to 12~170,000 tons, the recycling of automobile power cell will become a significant task of resources conservation environmental conservation.
But the recycling of automobile power cell is faced with the difficulty of recovery technology aspect, it is a thorny difficult problem, prior art lacks the recycling scheme to applying waste lithium ionic electrokinetic cell.
Summary of the invention
It is an object of the invention to provide a kind of applying waste lithium ionic electrokinetic cell recovery and processing system, utilize this system can reduce the harm to ecological environment of the waste and old new forms of energy lithium-ion-power cell, and improve the recovery utilization rate of resource.
A kind of applying waste lithium ionic electrokinetic cell recovery and processing system, described process system includes battery cell storage warehouse, conveyer belt, circulating water pool, hammer high velocity impact disintegrating machine, environment protection-type air blast drying oven, blade type disintegrating machine, collection and confinement of gases equipment, the first gas treatment equipment, Wet type drum, coarse fodder miscellaneous object outlet, the outlet of collector particle, electrode material aqueous solution holding vessel, filtering equipment, reducing and smelting stove, the second gas treatment equipment, extractor and condensing tower, wherein:
Described battery cell storage warehouse is deposited the applying waste lithium ionic electrical core of power battery after sorting process after testing;
Described battery core is taken out from described battery cell storage warehouse, it is delivered to described hammer high velocity impact disintegrating machine through described conveyer belt and carries out break process, described hammer high velocity impact disintegrating machine is connected with described collection and confinement of gases equipment, preventing exhaust gas leakage, described collection and confinement of gases equipment is connected with described first gas treatment equipment;
Particle after described hammer high velocity impact disintegrating machine processes is delivered to described environment protection-type air blast drying oven, and the particle after processing is dried, and dries the alkali liquor on surface and remaining electrolyte;Described environment protection-type air blast drying oven is connected with described first gas treatment equipment after being connected with described collection and confinement of gases equipment again;
Particle after dried enters back into described blade type disintegrating machine, particle after described blade type disintegrating machine two-stage crushing processes enters in described Wet type drum, do not coexist according to proportion and complete sorting under hydraulic action, sub-elect collector, barrier film, plastics respectively, and carried out categorised collection by described coarse fodder miscellaneous object outlet and the outlet of collector particle;
Battery electrode material after sorting process enters described electrode material aqueous solution holding vessel with water, obtains the filter cake of water content≤10% then through described filtering equipment after processing;
Described filter cake is put in described reducing and smelting stove, high temperature reduction under the effect of reducing agent, battery electrode material additive and the slag former added react formation slag, the waste gas produced in reducing and smelting process then enters described second gas treatment equipment, a material part after high temperature reduction forms lithium oxide steam and enters described condensing tower with pipeline, and is collected after condensation process;Another part metal solid is then delivered to described extractor, utilizes described extractor dissolution extraction useful metal therein, completes the cracking and sorting of disassembling of described applying waste lithium ionic electrokinetic cell is reclaimed.
Described process system also includes:
Cutter sweep, for the upper cover of applying waste lithium ionic electrokinetic cell is cut, and utilizes full-automatic corning machine to take out battery battery core after dicing;
Grouping system device, battery battery core for described cutter sweep is taken out carries out performance detection classification, battery battery core low to poor-performing or dump energy is stored in described battery cell storage warehouse and carries out follow-up sorting process after secondary discharge processes, and battery battery core high for dump energy is carried out cascade utilization process.
When utilizing described hammer high velocity impact disintegrating machine to carry out one-level break process, by the particle diameter control after process at 40~50mm, and percentage of damage reaches 100%.
When utilizing described hammer high velocity impact disintegrating machine to carry out one-level break process, continue to spray alkali liquor.
When utilizing described blade type disintegrating machine to carry out two-stage crushing process, the particle particle diameter after broken is controlled at 25~30mm.
The spray angle scalable of the cycle of higher pressure sprinkler head in described Wet type drum, can carry out the comprehensive hydro-peening without dead angle to the particle in each position of Wet type drum and cylinder.
The reducing agent added in described reducing and smelting stove is reproducibility coke, and slag former is Calx.
As seen from the above technical solution provided by the invention, utilize said system can reduce the harm to ecological environment of the waste and old new forms of energy lithium-ion-power cell, and improve the recovery utilization rate of resource.
Accompanying drawing explanation
In order to be illustrated more clearly that the technical scheme of the embodiment of the present invention, below the accompanying drawing used required during embodiment is described is briefly described, apparently, accompanying drawing in the following describes is only some embodiments of the present invention, for those of ordinary skill in the art, under the premise not paying creative work, it is also possible to obtain other accompanying drawings according to these accompanying drawings.
Fig. 1 is the structural representation of the provided applying waste lithium ionic electrokinetic cell recovery and processing system of the embodiment of the present invention.
Detailed description of the invention
Below in conjunction with the accompanying drawing in the embodiment of the present invention, the technical scheme in the embodiment of the present invention is clearly and completely described, it is clear that described embodiment is only a part of embodiment of the present invention, rather than whole embodiments.Based on embodiments of the invention, the every other embodiment that those of ordinary skill in the art obtain under not making creative work premise, broadly fall into protection scope of the present invention.
Below in conjunction with accompanying drawing, the embodiment of the present invention is described in further detail, the structural representation of the provided applying waste lithium ionic electrokinetic cell recovery and processing system of the embodiment of the present invention is provided, described process system includes battery cell storage warehouse 1, conveyer belt 2, circulating water pool 3, hammer high velocity impact disintegrating machine 4, environment protection-type air blast drying oven 5, blade type disintegrating machine 6, collection and confinement of gases equipment 7, first gas treatment equipment 8, Wet type drum 9, coarse fodder miscellaneous object outlet 10, collector particle outlet 11, electrode material aqueous solution holding vessel 12, filtering equipment 13, reducing and smelting stove 14, second gas treatment equipment 15, extractor 16 and condensing tower 17, wherein the annexation of each several part and work process are:
Described battery cell storage warehouse 1 is deposited the applying waste lithium ionic electrical core of power battery after sorting process after testing;
Described battery core is taken out from described battery cell storage warehouse 1, is delivered to described hammer high velocity impact disintegrating machine 4 through described conveyer belt 2 and carries out break process;When utilizing described hammer high velocity impact disintegrating machine to carry out one-level break process, by the particle diameter control after process at 40~50mm, and percentage of damage reaches 100%, thus being conducive to the dry of next step, and the volatilization of electrolyte;Alkali liquor need to be continued to spray simultaneously when above-mentioned one-level break process, maintain the temperature within disintegrating machine on the one hand in suitable scope, electrolyte can be neutralized on the other hand, it is prevented that electrolyte decomposition produces HF etching apparatus.
Described hammer high velocity impact disintegrating machine 4 is connected with described collection and confinement of gases equipment 7, it is prevented that exhaust leak, and described collection and confinement of gases equipment 7 is connected with described first gas treatment equipment 8;
Particle after described hammer high velocity impact disintegrating machine 4 processes is delivered to described environment protection-type air blast drying oven 5; particle after processing is dried; dry the alkali liquor on surface and remaining electrolyte; thus reducing electrolyte to the corrosion of equipment and to the volatilization in air, protection environment, safe and reliable.
Described environment protection-type air blast drying oven 5 is connected with described collection and confinement of gases equipment 7 and is connected with described first gas treatment equipment 8;
Particle after dried enters back into described blade type disintegrating machine 6, particle after described blade type disintegrating machine 6 two-stage crushing processes enters in described Wet type drum 9, do not coexist according to proportion and complete sorting under hydraulic action, sub-elect collector, barrier film, plastics respectively, and carried out categorised collection by described coarse fodder miscellaneous object outlet 10 and collector particle outlet 11;Here; when utilizing described blade type disintegrating machine 6 to carry out two-stage crushing process; because friction can produce substantial amounts of heat; long-time hot operation can make service life of equipment shorten; and the injection of water can reduce the temperature within disintegrating machine; protection equipment, extension device service life, simultaneously particle after crushing is easily being delivered to miscellaneous equipment with water for ambient condition.It addition, when utilizing described blade type disintegrating machine to carry out two-stage crushing process, it is possible to the particle particle diameter after broken is controlled at 25~30mm so that particle diameter is strict controlled in best sorting scope, and the production efficiency of cracking and sorting is up to 15~20t/h.
Battery electrode material after sorting process enters described electrode material aqueous solution holding vessel 12 with water, obtains the filter cake of water content≤10% then through described filtering equipment 13 after processing;
Described filter cake is put in described reducing and smelting stove 13, high temperature reduction under the effect of reducing agent, battery electrode material additive and the slag former added react formation slag, the waste gas produced in reducing and smelting process then enters described second gas treatment equipment 15, battery electrode material material part after high temperature reduction under the effect of reducing agent forms lithium oxide steam and enters described condensing tower 17 with pipeline, and is collected after condensation;Another part metal (nickel, cadmium, manganese etc.) solid is then delivered to described extractor 16, utilizes described extractor 16 dissolution extraction useful metal therein, completes the cracking and sorting of disassembling of described applying waste lithium ionic electrokinetic cell is reclaimed.
The reducing agent added in above-mentioned reducing and smelting stove can be the reducing substanceses such as reproducibility coke, and slag former can be Calx, and above-mentioned material low price, product is pollution-free.
The gases such as the CO produced after organic compound combustion, two English are mainly reprocessed by above-mentioned two gas treatment equipment so that the gas qualified discharge after process.
In implementing process, above-mentioned process system may also include that
Cutter sweep, for the upper cover of applying waste lithium ionic electrokinetic cell is cut, and utilizes full-automatic corning machine to take out battery battery core after dicing;
Grouping system device, battery battery core for described cutter sweep is taken out carries out performance detection classification, battery battery core low to poor-performing or dump energy is stored in described battery cell storage warehouse after secondary discharge processes and carries out follow-up sorting process, and battery battery core high for dump energy is entered cascade utilization process.So-called cascade utilization refers to by the dynamic lithium battery after automobile use being disassembled, detects and the use of sorted secondary, it is mainly used in family's energy storage, new forms of energy distributed power generation energy storage, communication base station etc., electrokinetic cell is worth be not fully exerted, reduces the wasting of resources and environmental pollution.
Additionally, the spray angle scalable of the cycle of higher pressure sprinkler head in above-mentioned Wet type drum 9, particle in each position of Wet type drum 9 and cylinder can be carried out the comprehensive hydro-peening without dead angle, thus solving Wet type drum to screen the clear halfway problem of remaining electrode material in the blocking and particle netted.
In sum, the applying waste lithium ionic electrokinetic cell recovery and processing system that the embodiment of the present invention provides has the advantage that
1) technical barriers such as the disassembling of applying waste lithium ionic electrokinetic cell, broken and metal recovery are solved;
2) automatically disassembling of different model power battery case is solved;
3) solving the cascade utilization of the high cell of lithium-ion-power cell dump energy, electrokinetic cell is worth and is not fully exerted;
4) adopt the airtight forced air drying stove of environment protection-type, the particle after broken is dried, removes the electrolyte on particle surface, reduce electrolyte to the corrosion of equipment and to the volatilization in air, protect environment, safe and reliable;
5) use that Wet type drum and high-pressure water nozzle rinse, solves a sorting difficult problem for electrode material and collector and the residue problem of collector upper electrode material;
6) adopting reducing and smelting stove, the smelting solving metal in electrode material is extracted and organic calcining removal, environmentally safe;
7) adopting full-automatic applying waste lithium ionic electrokinetic cell recovery and processing system, Automated condtrol is more comprehensive, and whole production run only needs 3~5 people, greatly reduces the labor intensity of workman.
The above; being only the present invention preferably detailed description of the invention, but protection scope of the present invention is not limited thereto, any those familiar with the art is in the technical scope of present disclosure; the change that can readily occur in or replacement, all should be encompassed within protection scope of the present invention.Therefore, protection scope of the present invention should be as the criterion with the protection domain of claims.

Claims (7)

1. an applying waste lithium ionic electrokinetic cell recovery and processing system, it is characterized in that, described process system includes battery cell storage warehouse, conveyer belt, circulating water pool, hammer high velocity impact disintegrating machine, environment protection-type air blast drying oven, blade type disintegrating machine, collection and confinement of gases equipment, the first gas treatment equipment, Wet type drum, coarse fodder miscellaneous object outlet, the outlet of collector particle, electrode material aqueous solution holding vessel, filtering equipment, reducing and smelting stove, the second gas treatment equipment, extractor and condensing tower, wherein:
Described battery cell storage warehouse is deposited the applying waste lithium ionic electrical core of power battery after sorting process after testing;
Described battery core is taken out from described battery cell storage warehouse, it is delivered to described hammer high velocity impact disintegrating machine through described conveyer belt and carries out break process, described hammer high velocity impact disintegrating machine is connected with described collection and confinement of gases equipment, preventing exhaust gas leakage, described collection and confinement of gases equipment is connected with described first gas treatment equipment;
Particle after described hammer high velocity impact disintegrating machine processes is delivered to described environment protection-type air blast drying oven, and the particle after processing is dried, and dries the alkali liquor on surface and remaining electrolyte;Described environment protection-type air blast drying oven is connected with described first gas treatment equipment after being connected with described collection and confinement of gases equipment again;
Particle after dried enters back into described blade type disintegrating machine, particle after described blade type disintegrating machine two-stage crushing processes enters in described Wet type drum, do not coexist according to proportion and complete sorting under hydraulic action, sub-elect collector, barrier film, plastics respectively, and carried out categorised collection by described coarse fodder miscellaneous object outlet and the outlet of collector particle;
Battery electrode material after sorting process enters described electrode material aqueous solution holding vessel with water, obtains the filter cake of water content≤10% then through described filtering equipment after processing;
Described filter cake is put in described reducing and smelting stove, high temperature reduction under the effect of reducing agent, battery electrode material additive and the slag former added react formation slag, the waste gas produced in reducing and smelting process then enters described second gas treatment equipment, a material part after high temperature reduction forms lithium oxide steam and enters described condensing tower with pipeline, and is collected after condensation process;Another part metal solid is then delivered to described extractor, utilizes described extractor dissolution extraction useful metal therein, completes the cracking and sorting of disassembling of described applying waste lithium ionic electrokinetic cell is reclaimed.
2. applying waste lithium ionic electrokinetic cell recovery and processing system according to claim 1, it is characterised in that described process system also includes:
Cutter sweep, for the upper cover of applying waste lithium ionic electrokinetic cell is cut, and utilizes full-automatic corning machine to take out battery battery core after dicing;
Grouping system device, battery battery core for described cutter sweep is taken out carries out performance detection classification, battery battery core low to poor-performing or dump energy is stored in described battery cell storage warehouse and carries out follow-up sorting process after secondary discharge processes, and battery battery core high for dump energy is carried out cascade utilization process.
3. applying waste lithium ionic electrokinetic cell recovery and processing system according to claim 1, it is characterised in that
When utilizing described hammer high velocity impact disintegrating machine to carry out one-level break process, by the particle diameter control after process at 40~50mm, and percentage of damage reaches 100%.
4. applying waste lithium ionic electrokinetic cell recovery and processing system according to claim 1, it is characterised in that
When utilizing described hammer high velocity impact disintegrating machine to carry out one-level break process, continue to spray alkali liquor.
5. applying waste lithium ionic electrokinetic cell recovery and processing system according to claim 1, it is characterised in that
When utilizing described blade type disintegrating machine to carry out two-stage crushing process, the particle particle diameter after broken is controlled at 25~30mm.
6. applying waste lithium ionic electrokinetic cell recovery and processing system according to claim 1, it is characterised in that
The spray angle scalable of the cycle of higher pressure sprinkler head in described Wet type drum, can carry out the comprehensive hydro-peening without dead angle to the particle in each position of Wet type drum and cylinder.
7. applying waste lithium ionic electrokinetic cell recovery and processing system according to claim 1, it is characterised in that
The reducing agent added in described reducing and smelting stove is reproducibility coke, and slag former is Calx.
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Cited By (12)

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CN106099240A (en) * 2016-08-24 2016-11-09 合肥国轩高科动力能源有限公司 A kind of waste and old lithium ion battery core and the separation method of housing and equipment thereof
CN106207267A (en) * 2016-08-12 2016-12-07 合肥国轩高科动力能源有限公司 A kind of lithium ion cell positive discards slurry recovery system and recovery method
CN106785176A (en) * 2017-03-10 2017-05-31 广东纳玛逊科技有限公司 A kind of new energy resource power battery detaching equipment
CN106391267B (en) * 2016-11-29 2018-04-03 哈尔滨巴特瑞资源再生科技有限公司 One kind scraps the powered broken combination unit of lithium ion power lithium battery
CN108461855A (en) * 2018-02-26 2018-08-28 荆门市格林美新材料有限公司 A kind of the dismantling recovery system and dismantling recovery method of waste lithium cell
CN108899606A (en) * 2018-07-16 2018-11-27 孙东江 Useless power battery comprehensive reutilization method
CN109103527A (en) * 2018-08-23 2018-12-28 清华四川能源互联网研究院 Waste and old power battery electric discharge device and method
CN109346790A (en) * 2018-09-20 2019-02-15 王志强 A kind of waste and old hard shell lithium-ion-power cell controlled discharge safety automation disassembling method
CN113097592A (en) * 2021-03-16 2021-07-09 深圳清研装备科技有限公司 Flexible and accurate separation method and system for positive and negative electrode materials of waste lithium battery
CN113745685A (en) * 2021-09-07 2021-12-03 派尔森环保科技有限公司 Waste battery recycling system and process thereof
CN114094223A (en) * 2021-11-25 2022-02-25 东莞市汉维科技股份有限公司 Method for recycling residual electric quantity of waste power battery
CN115090659A (en) * 2022-07-22 2022-09-23 江西华昊新能源有限公司 Broken recovery unit of lithium ion battery

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CN106207267A (en) * 2016-08-12 2016-12-07 合肥国轩高科动力能源有限公司 A kind of lithium ion cell positive discards slurry recovery system and recovery method
CN106207267B (en) * 2016-08-12 2018-07-17 合肥国轩高科动力能源有限公司 A kind of lithium ion cell positive discards slurry recovery system and recovery method
CN106099240A (en) * 2016-08-24 2016-11-09 合肥国轩高科动力能源有限公司 A kind of waste and old lithium ion battery core and the separation method of housing and equipment thereof
CN106099240B (en) * 2016-08-24 2018-07-17 合肥国轩高科动力能源有限公司 A kind of separation method and its equipment of waste and old lithium ion battery core and shell
CN106391267B (en) * 2016-11-29 2018-04-03 哈尔滨巴特瑞资源再生科技有限公司 One kind scraps the powered broken combination unit of lithium ion power lithium battery
CN106785176A (en) * 2017-03-10 2017-05-31 广东纳玛逊科技有限公司 A kind of new energy resource power battery detaching equipment
CN108461855A (en) * 2018-02-26 2018-08-28 荆门市格林美新材料有限公司 A kind of the dismantling recovery system and dismantling recovery method of waste lithium cell
CN108899606A (en) * 2018-07-16 2018-11-27 孙东江 Useless power battery comprehensive reutilization method
CN109103527A (en) * 2018-08-23 2018-12-28 清华四川能源互联网研究院 Waste and old power battery electric discharge device and method
CN109346790A (en) * 2018-09-20 2019-02-15 王志强 A kind of waste and old hard shell lithium-ion-power cell controlled discharge safety automation disassembling method
CN113097592A (en) * 2021-03-16 2021-07-09 深圳清研装备科技有限公司 Flexible and accurate separation method and system for positive and negative electrode materials of waste lithium battery
CN113745685A (en) * 2021-09-07 2021-12-03 派尔森环保科技有限公司 Waste battery recycling system and process thereof
CN114094223A (en) * 2021-11-25 2022-02-25 东莞市汉维科技股份有限公司 Method for recycling residual electric quantity of waste power battery
CN115090659A (en) * 2022-07-22 2022-09-23 江西华昊新能源有限公司 Broken recovery unit of lithium ion battery
CN115090659B (en) * 2022-07-22 2024-03-19 江西华昊新能源有限公司 Broken recovery unit of lithium ion battery

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