CN105801157B - A kind of permeable ceramic wafer and preparation method thereof - Google Patents
A kind of permeable ceramic wafer and preparation method thereof Download PDFInfo
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B38/00—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
- C04B38/0003—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof containing continuous channels, e.g. of the "dead-end" type or obtained by pushing bars in the green ceramic product
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
- C04B33/1305—Organic additives
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
- C04B33/132—Waste materials; Refuse; Residues
- C04B33/1324—Recycled material, e.g. tile dust, stone waste, spent refractory material
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- C—CHEMISTRY; METALLURGY
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- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3217—Aluminum oxide or oxide forming salts thereof, e.g. bauxite, alpha-alumina
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- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3418—Silicon oxide, silicic acids, or oxide forming salts thereof, e.g. silica sol, fused silica, silica fume, cristobalite, quartz or flint
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- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
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- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3427—Silicates other than clay, e.g. water glass
- C04B2235/3463—Alumino-silicates other than clay, e.g. mullite
- C04B2235/3472—Alkali metal alumino-silicates other than clay, e.g. spodumene, alkali feldspars such as albite or orthoclase, micas such as muscovite, zeolites such as natrolite
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P40/00—Technologies relating to the processing of minerals
- Y02P40/60—Production of ceramic materials or ceramic elements, e.g. substitution of clay or shale by alternative raw materials, e.g. ashes
Abstract
The present invention discloses a kind of permeable ceramic wafer and preparation method thereof.The permeable ceramic wafer, which is characterized in that by mass percentage, including following substance: useless porcelain A 45% ~ 52%；Useless porcelain B 30% ~ 40%；High-temperature agglomerant 6% ~ 8%；CMC 3%~4%；Rice hulls 5% ~ 6%；Rice flour 3% ~ 4%.Products obtained therefrom of the present invention can play recharge of groundwater, and adjusting air humidity, temperature absorb city noise pollution, facilitate the multiple functions such as pedestrian especially rainy season walking, moreover it is possible to which the living environment for improving people is improved the quality of living.Present invention gained ceramic water-permeable brick reduces influence of the useless porcelain stacking to environment, so that resource is recycled, saved resource using useless porcelain as primary raw material simultaneously.
Description
Technical field
The present invention relates to a kind of ceramic wafers and preparation method thereof, and in particular to a kind of permeable ceramic wafer and preparation method thereof.
Background technique
With the development of economy with the process of modernization construction, many cities and towns are gradually by reinforced concrete building, large-scale base
Infrastructure and various fluid-tight places and road are covered.Data shows that the coverage rate of China's urban road has reached 7 %
~15 %, megalopolis can exceed that 20 %.While providing convenient for people, city is also given on these fluid-tight ground
Ecological environment bring many negative effects.If using the dank material various places of (concrete or brick) making and road surface,
Increase water-permeable and air permeable area, so that it may the negative effect caused by urban ecology of the waterproof hardened ground in city is effectively relieved,
Make the sustainable development path in city with the maintaining ecological balance that develops in harmony, walks naturally.
Ceramic industry is a resource consumption rich and influential family.By taking Chaozhou as an example, annual waste ceramic fragment to be processed is no less than 3
Ten thousand tons.If these can be all fully utilized, will play a positive role to the development of social economy.
Therefore a kind of environment-friendly construction material suitable for city square road surface and pedestrian's sidewalk is provided, to building rubbish
The utilization of rubbish and the holding of level of ground water are of great importance.Ceramic water-permeable brick is water-saving and pollution administration dual function as having concurrently
New decorative material for building and be concerned.
Summary of the invention
The present invention overcomes drawbacks described above, provides a kind of permeable ceramic wafer and preparation method thereof.The present invention is based on waste ceramic
Raw material is wanted, development water permeability is good, intensity is high, firing temperature is appropriate, low in cost, both artistic and practical, structure is excellent, is suitable for city
The environment-friendly construction material on city, road surface, square and pedestrian's sidewalk.
The purpose of the present invention is realized at least through one of following technical solution.
A kind of permeable ceramic wafer, by mass percentage, including following substance:
Useless porcelain A 45% ~ 52%
Useless porcelain B 30% ~ 40%
High-temperature agglomerant 6% ~ 8%
CMC 3%~4%
Rice hulls 5% ~ 6%
Rice flour 3% ~ 4%；
The high-temperature agglomerant is according to mass percent meter, including following substance:
Useless porcelain C 25% ~ 35%
Quartz 10% ~ 20%
Aluminium oxide 9% ~ 10%
Albite 35% ~ 45%
Waste gypsum mold 3% ~ 7%
Kaolin 2% ~ 3%.
Above-mentioned permeable ceramic wafer, by mass percentage, preferred proportion is as follows:
Useless porcelain A 47.9%
Useless porcelain B 33.5%
High-temperature agglomerant 6.7%
CMC(carboxymethyl cellulose) 3.3%
Rice hulls 5.2%
Rice flour 3.4%；
The high-temperature agglomerant is according to mass percent meter, including following substance:
Useless porcelain C 30%
Quartz 15%
Aluminium oxide 9.5%
Albite 38%
Waste gypsum mold 5%
Kaolin 2.5%.
Preferably, it is the useless porcelain of 10 purposes that the useless porcelain A, which is fineness,；The useless porcelain B is the useless porcelain of 20 mesh of fineness；The useless porcelain C
For the useless porcelain of 240 mesh.
Preferably, the waste gypsum mold is calcium sulfate.
Preferably, the useless porcelain A and useless porcelain B gives up porcelain by sanitary ware and daily useless porcelain forms；The sanitary ware is useless
The ratio of porcelain and daily useless porcelain is 1 ~ 3:1.
A kind of preparation method of permeable ceramic wafer, includes the following steps:
(1) useless porcelain is crossed into 10 mesh, 20 mesh and 240 meshes respectively；
(2) high temperature bond agent prescription is weighed, is put into ball grinder, abrasive body is added, is tamping and carries out 5 ~ 7h of ball milling, obtain height
Warm binder；
(3) weigh the permeable ceramic plate prescription in addition to rice flour into container, stir evenly, obtain mixture；
(4) rice flour is weighed into another container, and water is added, is cooked into paste；
(5) paste is added in mixture, is stirred evenly；
(6) 1000g mixture is weighed into pressure mould, and pressure mould is 30mm × 30mm square mold, uses desktop
Dynamic tablet press machine obtains mixture after molding with the pressure press molding of 1MPa ~ 2MPa；With distilled water flushing, to remove surface
Vitreous bond object；
(7) 8 ~ 12h of mixture naturally dry after molding is allowed；
(8) dry again, after be put into baking oven and dry；
(9) by the samples weighing after drying, the resistance kiln roasting that is rapidly heated is placed into, obtains permeable ceramic wafer.
The above method, in step (4), the mass ratio of the rice flour and water is 1:2 ~ 3.
The above method, in step (8), the drying specific steps are as follows: oven temperature setting is by 45 ~ 55 DEG C, with 10
DEG C/heating rate of h, 65 ~ 75 DEG C are risen to, then temperature remains unchanged.
The above method, in step (9), the firing temperature is 1150 DEG C ~ 1250 DEG C.
The mechanism of the high permeability rate of waste ceramic water-permeable brick is mainly a large amount of of the particle packing effect generation of waste ceramic itself
The hole of connection, and its high intensity is attributed to the fact that high-temperature agglomerant generates suitable glass phase inside waste ceramic water-permeable brick under high temperature,
Waste ceramic particle is bonded together.In the research of water permeable ceramic tile, it has been found that tableting pressure, firing temperature, high temperature bond
The ratio and sanitary ware of rice flour and water are given up suction of the ratio to ceramic tile of porcelain and daily useless porcelain in the formula and dosage of agent, paste
Water rate has an impact with hardness.
Compared with prior art, present invention has an advantage that
Products obtained therefrom of the present invention can play recharge of groundwater, and adjusting air humidity, temperature absorb city noise pollution,
Facilitate the multiple functions such as pedestrian especially rainy season walking, moreover it is possible to which the living environment for improving people is improved the quality of living.Simultaneously originally
Invention gained ceramic water-permeable brick reduces influence of the useless porcelain stacking to environment, enables resource again using useless porcelain as primary raw material
It utilizes, has saved resource.
Specific embodiment
The present invention will be further specifically described in detail with reference to specific embodiments, but embodiments of the present invention are not
It is limited to this, for not specifically specified technological parameter, can refer to routine techniques progress.
Embodiment 1
Permeable ceramic wafer, according to as following formula:
10 mesh give up porcelain 47.9%
20 mesh give up porcelain 33.5%
High-temperature agglomerant 6.7%
CMC(carboxymethyl cellulose) 3.3%
Rice hulls 5.2%
Rice flour 3.4%；
Wherein, the high-temperature agglomerant is according to mass percent meter, including following substance:
240 mesh give up porcelain (using sanitary ware give up porcelain) 30%
Quartz 15%
Aluminium oxide 9.5%
Albite 38%
Waste gypsum mold 5%
Kaolin 2.5%.
The useless porcelain of 10 mesh in above-mentioned formula gives up porcelain according to mass ratio by the useless porcelain of sanitary ware of 10 mesh and the household china of 10 mesh
For 3:1 composition, wherein 20 mesh give up, porcelain is 3:1 group according to mass ratio by the useless porcelain of sanitary ware of 20 mesh and the useless porcelain of household china of 20 mesh
At.Waste gypsum mold is calcium sulfate；The present embodiment weighs altogether the above-mentioned formula of 1000g.
(1) the useless porcelain in above-mentioned formula is crossed into 10 mesh, 20 mesh and 240 meshes, obtains corresponding useless porcelain；
(2) according to high temperature bond agent prescription precise ingredient, be put into ball grinder, be added abrasive body 500g, be tamping into
Row ball milling 6h, the good powder of ball milling are high-temperature agglomerant；
(3) it is stirred evenly, is obtained to a plastic containers by above-mentioned permeable ceramic plate prescription precise ingredient (except rice flour)
To mixture.
(4) 34g rice flour is weighed into another plastic containers, and 100ml water is added, is cooked into paste；
(5) paste is added in mixture, is stirred evenly；
(6) 1000g mixture is weighed into pressure mould, and pressure mould 30mm × 30mm square mold uses desktop electric
Tablet press machine, with the pressure press molding of 1MPa, mixture after molding；With distilled water flushing, glued with removing the glassy of surface
Tie object；
(7) sample naturally dry 8h is allowed；
(8) dry half a day again, after be put into baking oven and dry half a day, oven temperature setting is by 50 DEG C, per half an hour
5 DEG C are increased, is gradually increased to 70 DEG C, then temperature remains unchanged；
(9) it by the samples weighing after drying, places into be rapidly heated in resistance furnace and is burnt into finished product by setup program, firing temperature
Degree is 1180 DEG C, obtains permeable ceramic wafer；
It takes out finished product to be weighed, places into the 5min that absorbs water in the disk for fill with water, take out and weigh after standing 1min, calculate
Water absorption rate is 36.8%.
The mechanism of the high permeability rate of waste ceramic water-permeable brick is mainly a large amount of of the particle packing effect generation of waste ceramic itself
The hole of connection, and its high intensity is attributed to the fact that high-temperature agglomerant generates suitable glass phase inside waste ceramic water-permeable brick under high temperature,
Waste ceramic particle is bonded together.Consumption of binder is more, that is, the glass phase generated is more, and the gap of connection is gradually filled out
It fills, product is further fine and close, to further improve product compression strength, reduces its water permeability.
Embodiment 2
A kind of permeable ceramic wafer, by mass percentage, including following substance:
Useless porcelain A 52%
Useless porcelain B 30%
High-temperature agglomerant 6%
CMC 4%
Rice hulls 5%
Rice flour 3%；
The high-temperature agglomerant is according to mass percent meter, including following substance:
Useless porcelain C 35%
Quartz 12%
Aluminium oxide 9%
Albite 35%
Waste gypsum mold 6%
Kaolin 3%.
The useless porcelain of 10 mesh in above-mentioned formula gives up porcelain according to mass ratio by the useless porcelain of sanitary ware of 10 mesh and the household china of 10 mesh
For 2:1 composition, wherein 20 mesh give up, porcelain is 2:1 group according to mass ratio by the useless porcelain of sanitary ware of 20 mesh and the useless porcelain of household china of 20 mesh
At.Waste gypsum mold is calcium sulfate；
(1) the useless porcelain in above-mentioned formula is crossed into 10 mesh, 20 mesh and 240 meshes, obtains corresponding useless porcelain；
(2) according to high temperature bond agent prescription precise ingredient, be put into ball grinder, be added abrasive body 500g, be tamping into
Row ball milling 6h, the good powder of ball milling are high-temperature agglomerant；
(3) it is stirred evenly, is obtained to a plastic containers by above-mentioned permeable ceramic plate prescription precise ingredient (except rice flour)
To mixture.
(4) 30g rice flour is weighed into another plastic containers, and 100ml water is added, is cooked into paste；
(5) paste is added in mixture, is stirred evenly；
(6) 1000g mixture is weighed into pressure mould, and pressure mould 30mm × 30mm square mold uses desktop electric
Tablet press machine, with the pressure press molding of 1MPa, mixture after molding；With distilled water flushing, glued with removing the glassy of surface
Tie object；
(7) sample naturally dry 8h is allowed；
(8) dry half a day again, after be put into baking oven and dry half a day, oven temperature setting is by 50 DEG C, per half an hour
5 DEG C are increased, is gradually increased to 70 DEG C, then temperature remains unchanged；
(9) it by the samples weighing after drying, places into be rapidly heated in resistance furnace and is burnt into finished product by setup program, firing temperature
Degree is 1250 DEG C, obtains permeable ceramic wafer；
It takes out finished product to be weighed, places into the 5min that absorbs water in the disk for fill with water, take out and weigh after standing 1min, calculate
Water absorption rate is 22.8%.
Embodiment 3
A kind of permeable ceramic wafer, by mass percentage, including following substance:
Useless porcelain A 45%
Useless porcelain B 38%
High-temperature agglomerant 6%
CMC 3%
Rice hulls 5%
Rice flour 3%；
The high-temperature agglomerant is according to mass percent meter, including following substance:
Useless porcelain C 30%
Quartz 15%
Aluminium oxide 10%
Albite 37%
Waste gypsum mold 5%
Kaolin 3%.
The useless porcelain of 10 mesh in above-mentioned formula gives up porcelain according to mass ratio by the useless porcelain of sanitary ware of 10 mesh and the household china of 10 mesh
For 2:1 composition, wherein 20 mesh give up, porcelain is 2:1 group according to mass ratio by the useless porcelain of sanitary ware of 20 mesh and the useless porcelain of household china of 20 mesh
At.Waste gypsum mold is calcium sulfate；
(1) the useless porcelain in above-mentioned formula is crossed into 10 mesh, 20 mesh and 240 meshes, obtains corresponding useless porcelain；
(2) according to high temperature bond agent prescription precise ingredient, be put into ball grinder, be added abrasive body 500g, be tamping into
Row ball milling 6h, the good powder of ball milling are high-temperature agglomerant；
(3) it is stirred evenly, is obtained to a plastic containers by above-mentioned permeable ceramic plate prescription precise ingredient (except rice flour)
To mixture.
(4) 30g rice flour is weighed into another plastic containers, and 70ml water is added, is cooked into paste；
(5) paste is added in mixture, is stirred evenly；
(6) 1000g mixture is weighed into pressure mould, and pressure mould 30mm × 30mm square mold uses desktop electric
Tablet press machine, with the pressure press molding of 1MPa, mixture after molding；With distilled water flushing, glued with removing the glassy of surface
Tie object；
(7) sample naturally dry 8h is allowed；
(8) dry half a day again, after be put into baking oven and dry half a day, oven temperature setting is by 50 DEG C, per half an hour
5 DEG C are increased, is gradually increased to 70 DEG C, then temperature remains unchanged；
(9) it by the samples weighing after drying, places into be rapidly heated in resistance furnace and is burnt into finished product by setup program, firing temperature
Degree is 1250 DEG C, obtains permeable ceramic wafer；
It takes out finished product to be weighed, places into the 5min that absorbs water in the disk for fill with water, take out and weigh after standing 1min, calculate
Water absorption rate is 22.4%.
The above embodiment of the present invention be only to clearly illustrate example of the present invention, and not be to the present invention
Embodiment restriction.For those of ordinary skill in the art, it can also make on the basis of the above description
Other various forms of variations or variation.There is no necessity and possibility to exhaust all the enbodiments.It is all of the invention
Made any modifications, equivalent replacements, and improvements etc., should be included in the protection of the claims in the present invention within spirit and principle
Within the scope of.
Claims (5)
1. a kind of permeable ceramic wafer, which is characterized in that by mass percentage, including following substance:
Useless porcelain A 45% ~ 52%
Useless porcelain B 30% ~ 40%
High-temperature agglomerant 6% ~ 8%
CMC 3%~4%
Rice hulls 5% ~ 6%
Rice flour 3% ~ 4%；The sum of each component meets 100%；
The high-temperature agglomerant is according to mass percent meter, including following substance:
Useless porcelain C 25% ~ 35%
Quartz 10% ~ 20%
Aluminium oxide 9% ~ 10%
Albite 35% ~ 45%
Waste gypsum mold 3% ~ 7%
Kaolin 2% ~ 3%；
The useless porcelain A and useless porcelain B gives up porcelain by sanitary ware and daily useless porcelain forms；The useless porcelain of the sanitary ware and daily useless porcelain
Ratio be 1 ~ 3:1；
The useless porcelain A is that fineness is the useless porcelain of 10 purposes；The useless porcelain B is the useless porcelain of 20 mesh of fineness；The useless porcelain C is 240 mesh health
Sanitary ware gives up porcelain；
The waste gypsum mold is calcium sulfate；
The preparation method of the permeable ceramic wafer, includes the following steps:
(1) useless porcelain is crossed into 10 mesh, 20 mesh and 240 meshes respectively；
(2) high temperature bond agent prescription is weighed, is put into ball grinder, abrasive body is added, is tamping and carries out 5 ~ 7h of ball milling, it is viscous to obtain high temperature
Tie agent；
(3) the permeable ceramic plate prescription in addition to rice flour is weighed into container, is stirred evenly, is obtained mixture；
(4) rice flour is weighed into another container, and water is added, is cooked into paste；
(5) paste is added in mixture, is stirred evenly；
(6) weigh 1000g mixture into pressure mould, with desktop electric tablet press machine, with the pressure pressurization of 1MPa ~ 2MPa at
Shape obtains mixture after molding；With distilled water flushing, to remove the vitreous bond object on surface；
(7) 8 ~ 12h of mixture naturally dry after molding is allowed；
(8) dry again, after be put into baking oven and dry；
(9) by the samples weighing after drying, the resistance kiln roasting that is rapidly heated is placed into, obtains permeable ceramic wafer.
2. the preparation method of permeable ceramic wafer described in claim 1, which comprises the steps of:
(1) useless porcelain is crossed into 10 mesh, 20 mesh and 240 meshes respectively；
(2) high temperature bond agent prescription is weighed, is put into ball grinder, abrasive body is added, is tamping and carries out 5 ~ 7h of ball milling, it is viscous to obtain high temperature
Tie agent；
(3) the permeable ceramic plate prescription in addition to rice flour is weighed into container, is stirred evenly, is obtained mixture；
(4) rice flour is weighed into another container, and water is added, is cooked into paste；
(5) paste is added in mixture, is stirred evenly；
(6) weigh 1000g mixture into pressure mould, with desktop electric tablet press machine, with the pressure pressurization of 1MPa ~ 2MPa at
Shape obtains mixture after molding；With distilled water flushing, to remove the vitreous bond object on surface；
(7) 8 ~ 12h of mixture naturally dry after molding is allowed；
(8) dry again, after be put into baking oven and dry；
(9) by the samples weighing after drying, the resistance kiln roasting that is rapidly heated is placed into, obtains permeable ceramic wafer.
3. the preparation method of permeable ceramic wafer according to claim 2, which is characterized in that in step (4), the rice flour and water
Mass ratio be 1:2 ~ 3.
4. the preparation method of permeable ceramic wafer according to claim 2, which is characterized in that in step (8), the drying is specific
Step are as follows: oven temperature setting is by 45 ~ 55 DEG C, with the heating rate of 10 DEG C/h, rise to 65 ~ 75 DEG C, then temperature is kept
It is constant.
5. the preparation method of permeable ceramic wafer according to claim 2, which is characterized in that in step (9), the firing temperature
It is 1150 DEG C ~ 1250 DEG C.
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| CN106242503B (en) * | 2016-08-10 | 2019-06-18 | 于娜 | It is a kind of with permeable and water retention property ceramic panel and preparation method thereof |
| CN106747311A (en) * | 2016-12-21 | 2017-05-31 | 任敏 | A kind of ceramic water-permeable brick and its production method |
| CN108610084A (en) * | 2018-05-02 | 2018-10-02 | 江苏宏发海绵城市科技有限公司 | A kind of manufacturing method of ceramic water-permeable brick |
| CN113716971A (en) * | 2021-07-09 | 2021-11-30 | 景德镇市祎柏新材料研发有限公司 | Water permeable brick prepared from domestic ceramic waste porcelain and preparation method thereof |
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| CN1919564A (en) * | 2006-09-20 | 2007-02-28 | 景德镇陶瓷学院 | Manufacture method of environment friendly composite ceramic water-permeable brick |
| CN101205133A (en) * | 2006-12-18 | 2008-06-25 | 周松青 | Method for manufacturing high-performance permeable bricks by using ceramic waste |
| CN101318805A (en) * | 2008-06-25 | 2008-12-10 | 南昌大学 | Method for manufacturing and sintering brick permeable to water with urban sewage sludge and wet-discharged coal ash |
| CN105367042A (en) * | 2015-10-29 | 2016-03-02 | 合肥正拓装饰材料有限公司 | Environment-friendly permeable floor tile capable of purifying air |
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2016
- 2016-03-19 CN CN201610163487.4A patent/CN105801157B/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1919564A (en) * | 2006-09-20 | 2007-02-28 | 景德镇陶瓷学院 | Manufacture method of environment friendly composite ceramic water-permeable brick |
| CN101205133A (en) * | 2006-12-18 | 2008-06-25 | 周松青 | Method for manufacturing high-performance permeable bricks by using ceramic waste |
| CN101318805A (en) * | 2008-06-25 | 2008-12-10 | 南昌大学 | Method for manufacturing and sintering brick permeable to water with urban sewage sludge and wet-discharged coal ash |
| CN105367042A (en) * | 2015-10-29 | 2016-03-02 | 合肥正拓装饰材料有限公司 | Environment-friendly permeable floor tile capable of purifying air |
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| CN105801157A (en) | 2016-07-27 |
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