CN106167361A - A kind of alkaline residue building waste haydite and preparation method thereof - Google Patents
A kind of alkaline residue building waste haydite and preparation method thereof Download PDFInfo
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- CN106167361A CN106167361A CN201610653112.6A CN201610653112A CN106167361A CN 106167361 A CN106167361 A CN 106167361A CN 201610653112 A CN201610653112 A CN 201610653112A CN 106167361 A CN106167361 A CN 106167361A
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- Prior art keywords
- building waste
- alkaline residue
- parts
- haydite
- waste
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Classifications
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B18/00—Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B18/02—Agglomerated materials, e.g. artificial aggregates
- C04B18/027—Lightweight materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
- C04B2201/20—Mortars, concrete or artificial stone characterised by specific physical values for the density
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
- C04B2201/50—Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength
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- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Civil Engineering (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Processing Of Solid Wastes (AREA)
Abstract
The invention discloses a kind of alkaline residue building waste haydite belonging to construction material preparing technical field and preparation method thereof.It is made up of the material of following parts by weight: alkaline residue 100 parts, building waste 150 600 parts, silicon ash 28 parts, cement 10 25 parts, alkali-activator 2.5 8.5 parts, additive 0.06 1.5 parts, 13 35 parts of water.Alkaline residue building waste haydite moulding process of the present invention is simple, it is not necessary to high-temperature calcination, and low-carbon (LC), environmental protection, energy consumption are low, mostly are class zeolite shape hydrated product inside it, light weight porous and also intensity is high.Alkaline residue building waste haydite is rounded, rough surface and hard, there is trickle pore inside, has the advantages such as raw material sources extensive, light weight, apparent density are little, the high and low contraction of intensity, anti-carbonation, good endurance, high temperature resistant, good heat insulating, water resistance are good.
Description
Technical field
The invention belongs to construction material preparing technical field, be specifically related to a kind of alkaline residue building waste haydite and preparation side thereof
Method.
Background technology
Along with industrialization, the acceleration of urbanization process, building industry is the most fast-developing, with this together be building waste day by day
Increasing, a large amount of building wastes not only occupy soil, and bring severe contamination to human habitat.According to statistics, I
The every annual meeting of state increases building waste more than 4,000 ten thousand tons newly, and the quantity of building waste has accounted for more than the 1/3 of municipal refuse total amount, its
Middle concrete construction rubbish has accounted for again more than the 40% of building waste.This phenomenon has been obtained for the extensive pass of the whole society
Note.Land resource is not only wasted in storing up for a long time of building waste, easily produces potential safety hazard, is unfavorable for the sustainable development of resource
Recycling with resource；And the heap of building waste is released and can be polluted water resource, has influence on air quality, and then
Directly influence the living environment of the mankind.
Meanwhile, the high-rise frame structure building of China's fast development does not require nothing more than materials for wall high-strength light, simultaneously
Frame structure to load-bearing it is also proposed the requirement of high-strength light.Haydite as the aggregate of a kind of high-strength light, have unit weight little,
Intensity is high, particle diameter can divide the features such as multistage, hole is abundant, is just meeting the needs of modern architecture industry, and it replaces stone as coagulation
Aggregate in soil, alleviates the 30% of fabric structure weight, improves the economic and technical norms of other side, and for carrying
The shock resistance of high constructure is significant, and currently used haydite need to through 900-1100 DEG C of high-temperature calcination, energy consumption is high,
Environment counter productive is notable, therefore, seeks alkaline residue building waste baking-free ceramicite the most for building further and becomes a reality institute
Need.
Patent CN201110352340.7 discloses a kind of unburned spheroidal attapulgite building rubbish ceramic grain, unburned spheroidal
The dispensing of attapulgite construction waste ceramsite is made up of following component by weight percentage: high viscous attapulgite clay powder 2～15%,
Attapulgite clay mine tailing 5～25%, building waste powder 35～65%, red bentonite in powder 1～15%, kieselguhr mine tailing
1～15% and cement 5～25%；The production method of described unburned spheroidal attapulgite building rubbish ceramic grain: (1) is by unburned ball
The dispensing of shape attapulgite construction waste ceramsite inputs granulating disc pelletize after adding stirrer for mixing, and particle diameter controls
3～30 millimeters；(2) granule after pelletize is transported to concrete curing indoor and carries out the conventional maintenance 28 days of cement products, pass through
Unburned spheroidal attapulgite building rubbish ceramic grain it is packaged as after screening.Its major gelled material is the cement of >=42.5 grades, belongs to
In traditional material, it is unfavorable for energy-conserving and environment-protective；The routine that burning spherical attapulgite construction waste ceramsite needs 28 days after the pelletizing is supported
Protect, in production process store, turn around time oversize.
Summary of the invention
It is an object of the invention to provide a kind of alkaline residue building waste haydite and preparation method thereof.
A kind of alkaline residue building waste haydite, is made up of the material of following parts by weight: alkaline residue 100 parts, building waste 150-
600 parts, silicon ash 2-8 part, cement 10-25 part, alkali-activator 2.5-8.5 part, additive 0.06-1.5 part, water 13-35 part.
Described alkaline residue specific surface area >=350cm2/g。
Described alkali-activator is one or more in Calx, sodium silicate, dihydrate gypsum.
Described additive is organic silicon emulsion and hydroxypropyl methyl cellulose is combined formulated.
Described building waste is one or more in waste concrete, useless brick, waste marble and waste mortar.
Described cement is 42.5 Portland cements.
The preparation method of above-mentioned alkaline residue building waste haydite, is carried out in accordance with the following steps:
(1) building waste is less than 100 millimeters through large-scale broken hammer or crusher in crushing to particle diameter, then uses stone pulverizing
Machine carries out being crushed to fineness of the particles less than 0.1mm；
(2) material is sequentially added into blender according to water, exciting agent, additive, silicon ash, alkaline residue, the order of building waste
Middle stirring 3-5min；
(3) by the mixing material input granulating disc pelletize after stirring, particle diameter controls 1～30mm；
(4) granule after pelletize is transported to maintenance 1-7 days in temperature 20-50 DEG C, relative humidity 70-90% environment, makes
Haydite.
Beneficial effects of the present invention: raw material of the present invention uses industrial residue and building waste, solid waste utilization rate is high, produce into
This is low, it is possible to turns waste into wealth, not only achieves the recycling of the solid waste such as building waste, alkaline residue, improve enterprise
Income, the problem of environmental pollution the most also brought by solid waste has searched out new outlet.Alkaline residue building waste haydite
Moulding process is simple, it is not necessary to high-temperature calcination, and low-carbon (LC), environmental protection, energy consumption are low.Curing cycle is short, and maintenance just can use after 1-7 days, raw
Product efficiency is high.Binder Materials is alkali-activated carbonatite alkaline residue Binder Materials, is different from traditional dense form water mudrock structure, mostly is inside it
Class zeolite shape hydrated product, light weight porous and also intensity is high.Alkaline residue building waste haydite is rounded, rough surface and hard,
There is trickle pore inside, have raw material sources extensively, light weight, apparent density be little, the high and low contraction of intensity, anti-carbonation, durability
The advantages such as good, high temperature resistant, good heat insulating, water resistance are good.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention will be further described.
Embodiment 1
A kind of alkaline residue building waste haydite, is made up of the material of following parts by weight: alkaline residue 100 parts, building waste 300
Part, silicon ash 6 parts, cement 18 parts, alkali-activator 5 parts, additive 1 part, 25 parts of water.Alkaline residue specific surface area >=350cm2/g.Alkali
Property exciting agent be Calx, sodium silicate, dihydrate gypsum according to mass ratio 1:1:1 configuration form.Additive be organic silicon emulsion and
Hydroxypropyl methyl cellulose is combined formulated.Building waste is that waste concrete, useless brick, waste marble, waste mortar are according to quality
Form than 1:1:1:1 configuration.
The preparation method of above-mentioned alkaline residue building waste haydite, is carried out in accordance with the following steps:
(1) building waste is less than 100 millimeters through large-scale broken hammer or crusher in crushing to particle diameter, then uses stone pulverizing
Machine carries out being crushed to fineness of the particles less than 0.1mm；
(2) material is sequentially added into stirs according to water, exciting agent, additive, silicon ash, cement, alkaline residue, the order of building waste
Mix stirring 4min in machine；
(3) by the mixing material input granulating disc pelletize after stirring, particle diameter controls 1～30mm；
(4) granule after pelletize is transported to maintenance 6 days in temperature 35 DEG C, relative humidity 80% environment, makes haydite.
Haydite bulk density prepared by the present embodiment is 220Kg/m3；Cylindrical compress strength: 1.7MPa；Water absorption rate :≤8%.
Embodiment 2
A kind of alkaline residue building waste haydite, is made up of the material of following parts by weight: alkaline residue 100 parts, building waste 150
Part, silicon ash 2 parts, alkali-activator 2.5 parts, cement 10 parts, additive 0.06 part, 13 parts of water.Alkaline residue specific surface area >=350cm2/
g.Alkali-activator be Calx, sodium silicate, dihydrate gypsum according to mass ratio 1:1:1 configuration form.Additive is organosilicon breast
Liquid and hydroxypropyl methyl cellulose are combined formulated.Building waste be waste concrete, useless brick, waste marble, waste mortar according to
Mass ratio 1:1:1:1 configuration forms.
The preparation method of above-mentioned alkaline residue building waste haydite, is carried out in accordance with the following steps:
(1) building waste is less than 100 millimeters through large-scale broken hammer or crusher in crushing to particle diameter, then uses stone pulverizing
Machine carries out being crushed to fineness of the particles less than 0.1mm；
(2) material is sequentially added into stirs according to water, exciting agent, additive, silicon ash, cement, alkaline residue, the order of building waste
Mix stirring 3min in machine；
(3) by the mixing material input granulating disc pelletize after stirring, particle diameter controls 1～30mm；
(4) granule after pelletize is transported to maintenance 1 day in temperature 20 DEG C, relative humidity 70% environment, makes haydite.
Haydite bulk density prepared by the present embodiment is 220Kg/m3；Cylindrical compress strength: 1.7MPa；Water absorption rate :≤8%.
Embodiment 3
A kind of alkaline residue building waste haydite, is made up of the material of following parts by weight: alkaline residue 100 parts, building waste 600
Part, silicon ash 8 parts, alkali-activator 8.5 parts, cement 25 parts, additive 1.5 parts, 35 parts of water.Alkaline residue specific surface area >=350cm2/
g.Alkali-activator be Calx, sodium silicate, dihydrate gypsum according to mass ratio 1:1:1 configuration form.Additive is organosilicon breast
Liquid and hydroxypropyl methyl cellulose are combined formulated.Building waste be waste concrete, useless brick, waste marble, waste mortar according to
Mass ratio 1:1:1:1 configuration forms.
The preparation method of above-mentioned alkaline residue building waste haydite, is carried out in accordance with the following steps:
(1) building waste is less than 100 millimeters through large-scale broken hammer or crusher in crushing to particle diameter, then uses stone pulverizing
Machine carries out being crushed to fineness of the particles less than 0.1mm；
(2) material is sequentially added into stirs according to water, exciting agent, additive, silicon ash, cement, alkaline residue, the order of building waste
Mix stirring 5min in machine；
(3) by the mixing material input granulating disc pelletize after stirring, particle diameter controls 1～30mm；
(4) granule after pelletize is transported to maintenance 7 days in temperature 50 C, relative humidity 90% environment, makes haydite.
Haydite bulk density prepared by the present embodiment is 220Kg/m3；Cylindrical compress strength: 1.8MPa；Water absorption rate :≤8%.
Embodiment 4
A kind of alkaline residue building waste haydite, is made up of the material of following parts by weight: alkaline residue 100 parts, building waste 300
Part, silicon ash 6 parts, cement 18 parts, Pseudobulbus Bletillae (Rhizoma Bletillae) powder 4 parts, alkali-activator 5 parts, additive 1 part, 25 parts of water.Alkaline residue specific surface area >=
350cm2/g.Alkali-activator be Calx, sodium silicate, dihydrate gypsum according to mass ratio 1:1:1 configuration form.Additive is for having
Machine silicon emulsion and hydroxypropyl methyl cellulose are combined formulated.Building waste is waste concrete, useless brick, waste marble, antiquated sand
Starch and form according to mass ratio 1:1:1:1 configuration.Described Pseudobulbus Bletillae (Rhizoma Bletillae) powder preparation method is as follows: collects the stem of the Pseudobulbus Bletillae (Rhizoma Bletillae), dries, grinds
End, crosses 200 mesh sieves and makes.
The preparation method of above-mentioned alkaline residue building waste haydite, is carried out in accordance with the following steps:
(1) building waste is less than 100 millimeters through large-scale broken hammer or crusher in crushing to particle diameter, then uses stone pulverizing
Machine carries out being crushed to fineness of the particles less than 0.1mm；
(2) material is depended on according to water, Pseudobulbus Bletillae (Rhizoma Bletillae) powder, exciting agent, additive, silicon ash, cement, alkaline residue, the order of building waste
Secondary addition blender stirs 4min；
(3) by the mixing material input granulating disc pelletize after stirring, particle diameter controls 1～30mm；
(4) granule after pelletize is transported to maintenance 6 days in temperature 35 DEG C, relative humidity 80% environment, makes haydite.
Haydite bulk density prepared by the present embodiment is 657Kg/m3；Cylindrical compress strength: 5.4MPa；Water absorption rate :≤8%.
Embodiment 5
A kind of alkaline residue building waste haydite, is made up of the material of following parts by weight: alkaline residue 100 parts, building waste 300
Part, silicon ash 6 parts, cement 18 parts, 4 parts of Rhizoma Cyperi powder, alkali-activator 5 parts, additive 1 part, 25 parts of water.Alkaline residue specific surface area >=
350cm2/g.Alkali-activator be Calx, sodium silicate, dihydrate gypsum according to mass ratio 1:1:1 configuration form.Additive is for having
Machine silicon emulsion and hydroxypropyl methyl cellulose are combined formulated.Building waste is waste concrete, useless brick, waste marble, antiquated sand
Starch and form according to mass ratio 1:1:1:1 configuration.Described Rhizoma Cyperi powder, preparation method thereof is as follows: collects the root of Rhizoma Cyperi, dries, grinds
End, crosses 200 mesh sieves and makes.
The preparation method of above-mentioned alkaline residue building waste haydite, is carried out in accordance with the following steps:
(1) building waste is less than 100 millimeters through large-scale broken hammer or crusher in crushing to particle diameter, then uses stone pulverizing
Machine carries out being crushed to fineness of the particles less than 0.1mm；
(2) material is depended on according to water, Rhizoma Cyperi powder, exciting agent, additive, silicon ash, cement, alkaline residue, the order of building waste
Secondary addition blender stirs 4min；
(3) by the mixing material input granulating disc pelletize after stirring, particle diameter controls 1～30mm；
(4) granule after pelletize is transported to maintenance 6 days in temperature 35 DEG C, relative humidity 80% environment, makes haydite.
Haydite bulk density prepared by the present embodiment is 698Kg/m3；Cylindrical compress strength: 5.9MPa；Water absorption rate :≤8%.
Claims (7)
1. an alkaline residue building waste haydite, it is characterised in that be made up of the material of following parts by weight: alkaline residue 100 parts, building
Rubbish 150-600 part, silicon ash 2-8 part, cement 10-25 part, alkali-activator 2.5-8.5 part, additive 0.06-1.5 part, water
13-35 part.
Alkaline residue building waste haydite the most according to claim 1, it is characterised in that described alkaline residue specific surface area >=350cm2/g。
Alkaline residue building waste haydite the most according to claim 1, it is characterised in that described alkali-activator is Calx, sodium water
One or more in glass, dihydrate gypsum.
Alkaline residue building waste haydite the most according to claim 1, it is characterised in that described additive is organic silicon emulsion and hydroxyl
Propyl methocel is combined formulated.
Alkaline residue building waste haydite the most according to claim 1, it is characterised in that described building waste is waste concrete, gives up
One or more in brick, waste marble and waste mortar.
Alkaline residue building waste haydite the most according to claim 1, it is characterised in that described cement is 42.5 normal silicate water
Mud.
7. the preparation method of alkaline residue building waste haydite described in claim 1, it is characterised in that carry out in accordance with the following steps:
(1) building waste is less than 100 millimeters through large-scale broken hammer or crusher in crushing to particle diameter, then enters with stone crusher
Row is crushed to fineness of the particles less than 0.1mm；
(2) material is sequentially added in blender stirs according to water, exciting agent, additive, silicon ash, alkaline residue, the order of building waste
Mix 3-5min；
(3) by the mixing material input granulating disc pelletize after stirring, particle diameter controls 1～30mm；
(4) granule after pelletize is transported to maintenance 1-7 days in temperature 20-50 DEG C, relative humidity 70-90% environment, makes haydite.
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106587765A (en) * | 2016-12-02 | 2017-04-26 | 北京仁创砂业科技有限公司 | Method for preparing ceramsites and ceramsites prepared by method |
| CN108218272A (en) * | 2016-12-22 | 2018-06-29 | 纳米及先进材料研发院有限公司 | Derived from the environmentally friendly artificial aggregate of waste（Aggregate） |
| CN111548111A (en) * | 2020-05-14 | 2020-08-18 | 中建材料技术研究成都有限公司 | Baking-free ceramsite and preparation method thereof |
| CN115925343A (en) * | 2023-01-04 | 2023-04-07 | 生物炭建材有限公司 | Long-acting stable curing industrial solid waste baking-free paving brick and preparation method thereof |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106587765A (en) * | 2016-12-02 | 2017-04-26 | 北京仁创砂业科技有限公司 | Method for preparing ceramsites and ceramsites prepared by method |
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| CN111548111A (en) * | 2020-05-14 | 2020-08-18 | 中建材料技术研究成都有限公司 | Baking-free ceramsite and preparation method thereof |
| CN115925343A (en) * | 2023-01-04 | 2023-04-07 | 生物炭建材有限公司 | Long-acting stable curing industrial solid waste baking-free paving brick and preparation method thereof |
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