CN105779033B - Vehicle biological fuel - Google Patents

Vehicle biological fuel Download PDF

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Publication number
CN105779033B
CN105779033B CN201610252321.XA CN201610252321A CN105779033B CN 105779033 B CN105779033 B CN 105779033B CN 201610252321 A CN201610252321 A CN 201610252321A CN 105779033 B CN105779033 B CN 105779033B
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Prior art keywords
fuel
additive
formicester
biological fuel
alcohols material
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CN201610252321.XA
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CN105779033A (en
Inventor
蒙呈星
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Hunan Sinochem Energy Group Co., Ltd
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Guangxi Tonki Energy Technology Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/02Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/18Organic compounds containing oxygen
    • C10L1/188Carboxylic acids; metal salts thereof
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/18Organic compounds containing oxygen
    • C10L1/19Esters ester radical containing compounds; ester ethers; carbonic acid esters
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L10/00Use of additives to fuels or fires for particular purposes
    • C10L10/08Use of additives to fuels or fires for particular purposes for improving lubricity; for reducing wear
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L10/00Use of additives to fuels or fires for particular purposes
    • C10L10/12Use of additives to fuels or fires for particular purposes for improving the cetane number
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L10/00Use of additives to fuels or fires for particular purposes
    • C10L10/14Use of additives to fuels or fires for particular purposes for improving low temperature properties
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2230/00Function and purpose of a components of a fuel or the composition as a whole
    • C10L2230/22Function and purpose of a components of a fuel or the composition as a whole for improving fuel economy or fuel efficiency
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2270/00Specifically adapted fuels
    • C10L2270/02Specifically adapted fuels for internal combustion engines
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2290/00Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
    • C10L2290/24Mixing, stirring of fuel components

Abstract

The invention discloses a kind of vehicle biological fuel, the fuel by weight percentage, including following components:Alcohols material 10 35%, epoxyfatty acid formicester 20 70%, trimethylbenzene 15 65%, additive 1 3%;Wherein, alcohols material is propane diols and/or ethylene glycol;Described additive is mixed by oleic acid and benzoic acid formicester.The present invention is matched using special raw material, after the additive for particularly adding specific proportioning, the problem of effectively improving condensation point higher (be only 10 DEG C or so) for making gained fuel because of the addition of epoxyfatty acid formicester, make the condensation point of fuel of acquisition at 25 DEG C to 35 DEG C, and ensure the flash-point of fuel more than 60 DEG C, Cetane number is more than 60, and lubricity is less than 200 (correction grinding defect diameters (60 DEG C/μm));In addition, the present invention is not only formulated, simple but also preparation method is simple.

Description

Vehicle biological fuel
Technical field
The present invention relates to a kind of automotive fuel, and in particular to the automobile-used biological combustion that a kind of suitable Diesel engine is used Material.
Background technology
With national economy fast development and living standards of the people raising, China to the energy the need for increase increasingly, Sustainable growth is consumed using oil as the liquid fuel of raw material.At the same time, traditional petroleum resources are increasingly deficient.Therefore, study It is imperative with exploitation alternative fuel.International vehicle fuel development trend and China's energy lower part of the body are all explicitly pointed out, and automobile will be by Step reduces the use of fossil fuels, expands the consumption of Aalcohols fuel and bio-fuel.Hamelinck points out, current methanol and Fischer-Tropsch method synthetic fuels are best power fuels.
Diesel engine thermal efficiency ratio gasoline engine is high, low-speed big characteristic, good reliability, but the diesel oil such as 0# of general label The condensation point of diesel oil is higher, it is necessary to the label of diesel oil be selected according to temperature in use interval, if from if it is not, engine In fuel system may wax deposition, block oil circuit, influence engine normal work.Although the label of diesel oil is lower, wax deposition Possibility it is just smaller, but its price is also higher.It is many in order to further reduce the cost of the fuel used suitable for diesel engine Bio-fuel arises at the historic moment.Patent of invention such as Publication No. CN101280231A discloses a kind of biofuel oil and its preparation Method.The invention uses ethanol, methanol, toluene, isopropanol, surfactant, ethyl nitrate, ferrocene, C12 allyl butyrates two The production of the plurality of raw materials such as acid, diesel oil obtains biofuel oil, and gained bio-fuel oil product octane number and Cetane number are higher, rotten Corrosion is low, and its condensation point is between -10 DEG C to -20 DEG C, equivalent to -20# diesel oil at most quite -35# diesel oil, but its formula and preparation Method is complex.
The content of the invention
Simple, Cetane number height and the car with relatively low condensation point are formulated the technical problem to be solved in the present invention is to provide a kind of Use bio-fuel.
Vehicle biological fuel of the present invention, by weight percentage, including following components:
Alcohols material 10-35%, epoxyfatty acid formicester 20-70%, trimethylbenzene 15-65%, additive 1-3%;
Wherein,
Described alcohols material is propane diols and/or ethylene glycol;
Described additive is mixed by oleic acid and benzoic acid formicester.
In technical scheme of the present invention, component epoxy Fatty acid methyl ester freezing point used is 8 DEG C, is added after the component In the case of without above-mentioned additive, the condensation point of gained fuel is only at 10 DEG C or so.Applicant passes through long-term, substantial amounts of examination Test research, find to make after the additive as adding above-mentioned specific composition the condensation point of gained fuel at -25 DEG C extremely -35 DEG C, while ensureing the other performance of gained fuel.
In technical scheme of the present invention, when alcohols material selection for propane diols and ethylene glycol combination when, they it Between proportioning can be any proportioning, preferably the weight ratio of propane diols and ethylene glycol be 1-5:1-5, more preferably propane diols and second two The weight ratio of alcohol is 1:1.
In technical scheme of the present invention, described additive can be with arbitrary proportion group by oleic acid and benzoic acid formicester Into mixture, it is preferable that be by 1-5 by oleic acid and benzoic acid formicester:1-5 weight is more excellent than the mixture that mixes Selection of land, is by 1 by oleic acid and benzoic acid formicester:1 weight is than the mixture that mixes.
In technical scheme of the present invention, the percentage by weight of each component is preferably:
Alcohols material 15-35%, epoxyfatty acid formicester 20-55%, trimethylbenzene 20-55%, additive 1-3%.
Further, the percentage by weight of each component is preferably:
Alcohols material 20-35%, epoxyfatty acid formicester 20-45%, trimethylbenzene 20-45%, additive 1-2%.
Vehicle biological fuel preparation method of the present invention is:Each component is weighed by proportioning, one section is stood after being well mixed Time (being usually more than 5 hours) can be used afterwards.
Compared with prior art, the present invention is matched using special raw material, particularly adds the addition of specific proportioning After agent, not only effectively improve because the addition of epoxyfatty acid formicester makes the condensation point of gained fuel higher (being only 10 DEG C or so) The problem of, make the condensation point of fuel of acquisition at -25 DEG C to -35 DEG C, the flash-point of fuel is maintained at more than 60 DEG C, Cetane number More than 60, lubricity is less than 200 (correction grinding defect diameters (60 DEG C/μm));In addition, the present invention is not only formulated simple but also prepared Method is simple.
Embodiment
With reference to specific embodiment, the present invention is described in further detail, to more fully understand present disclosure, but The present invention is not limited to following examples.
Embodiment 1
Following each components are weighed by following percentage by weights to be sufficiently mixed uniformly, are stood 8 hours, that is, are obtained of the present invention Vehicle biological fuel:
Alcohols material (propane diols) 25%, epoxyfatty acid formicester 23%, trimethylbenzene 50%, additive are (by oleic acid and benzene Methyl formate presses 1:1 weight ratio is mixed) 2%.
Comparative example 1
Following each components are weighed by following percentage by weights to be sufficiently mixed uniformly, are stood 8 hours, that is, are obtained without addition The vehicle biological fuel of agent:
Alcohols material (propane diols) 27%, epoxyfatty acid formicester 23%, trimethylbenzene 50%.
Embodiment 2
Following each components are weighed by following percentage by weights to be sufficiently mixed uniformly, are stood 5 hours, that is, are obtained of the present invention Vehicle biological fuel:
Alcohols material (ethylene glycol) 35%, epoxyfatty acid formicester 45%, trimethylbenzene 17%, additive are (by oleic acid and benzene Methyl formate presses 1:3 weight ratio is mixed) 3%.
Embodiment 3
Following each components are weighed by following percentage by weights to be sufficiently mixed uniformly, are stood 10 hours, that is, are obtained institute of the present invention The vehicle biological fuel stated:
Alcohols material (presses 1 by propane diols and ethylene glycol:1 weight ratio is mixed) 10%, epoxyfatty acid formicester 35%th, trimethylbenzene 54%, additive (press 1 by oleic acid and benzoic acid formicester:5 weight ratio is mixed) 1%.
Embodiment 4
Following each components are weighed by following percentage by weights to be sufficiently mixed uniformly, are stood 6 hours, that is, are obtained of the present invention Vehicle biological fuel:
Alcohols material (presses 5 by propane diols and ethylene glycol:1 weight ratio is mixed) 13%, epoxyfatty acid formicester 70%th, trimethylbenzene 15%, additive (press 5 by oleic acid and benzoic acid formicester:1 weight ratio is mixed) 2%.
Embodiment 5
Following each components are weighed by following percentage by weights to be sufficiently mixed uniformly, are stood 8 hours, that is, are obtained of the present invention Vehicle biological fuel:
Alcohols material (presses 1 by propane diols and ethylene glycol:10 weight ratio is mixed) 14%, epoxyfatty acid formicester 20%th, trimethylbenzene 65%, additive (press 10 by oleic acid and benzoic acid formicester:1 weight ratio is mixed) 1%.
Performance test is carried out to fuel made from above-described embodiment 1-5, as a result as described in Table 1:
Table 1:
Wherein, Cetane number is detected according to GB/T386-91, and copper corrosion is detected according to GB/T5096, and density is according to GB/ T1884-2000 detects that mechanical admixture and moisture detect that flash-point is detected according to GB/T261 by estimating, and condensation point is according to SH/T 0248 detection.

Claims (5)

1. vehicle biological fuel, by weight percentage, including following components:
Alcohols material 10-35%, epoxyfatty acid formicester 20-70%, trimethylbenzene 15-65%, additive 1-3%;
Wherein,
Described alcohols material is propane diols and/or ethylene glycol;
Described additive is mixed by oleic acid and benzoic acid formicester.
2. vehicle biological fuel according to claim 1, it is characterised in that:Described additive is by oleic acid and benzoic acid first Fat presses 1-5:1-5 weight ratio is mixed.
3. vehicle biological fuel according to claim 1, it is characterised in that:Described additive is by oleic acid and benzoic acid first Fat presses 1:1 weight ratio is mixed.
4. the vehicle biological fuel according to any one of claim 1-3, it is characterised in that:The percentage by weight of each component For:
Alcohols material 15-35%, epoxyfatty acid formicester 20-55%, trimethylbenzene 20-55%, additive 1-3%.
5. the vehicle biological fuel according to any one of claim 1-3, it is characterised in that:The percentage by weight of each component For:
Alcohols material 20-35%, epoxyfatty acid formicester 20-45%, trimethylbenzene 20-45%, additive 1-2%.
CN201610252321.XA 2016-04-21 2016-04-21 Vehicle biological fuel Active CN105779033B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
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Application Number Priority Date Filing Date Title
CN201610252321.XA CN105779033B (en) 2016-04-21 2016-04-21 Vehicle biological fuel

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CN105779033A CN105779033A (en) 2016-07-20
CN105779033B true CN105779033B (en) 2017-07-18

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Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100734201B1 (en) * 2006-06-14 2007-07-02 지에스칼텍스 주식회사 Catane improver and manufacturing the same
US8124572B2 (en) * 2007-09-27 2012-02-28 Chevron U.S.A. Inc. Production of biofuels and biolubricants from a common feedstock
CN102041176A (en) * 2011-01-14 2011-05-04 中国林业科学研究院林产化学工业研究所 Method for preparing low temperature epoxy fatty acid branched-chain alcohol ester improver for biodiesel and application thereof
CN103725337B (en) * 2013-12-22 2015-04-01 山西华顿实业有限公司 High-cleanness diesel lubricant
CN104119968B (en) * 2014-08-14 2015-08-05 蒙呈星 A kind of Novel vehicle fuel

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Address after: 541004 the Guangxi Zhuang Autonomous Region City, Chaoyang District, Guilin Qixing Road on the north side, east of the east side of the two ring road, the information industry park office building H block 2-4-1

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Address after: 541100 the Guangxi Zhuang Autonomous Region Lingui County Lu Xing Road 1 Star City 16 Building 2 unit 2401.

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Address before: 541100 the Guangxi Zhuang Autonomous Region Lingui County Lu Xing Road 1 Star City 16 Building 2 unit 2401.

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