CN103725337B - High-cleanness diesel lubricant - Google Patents
High-cleanness diesel lubricant Download PDFInfo
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- CN103725337B CN103725337B CN201310710182.7A CN201310710182A CN103725337B CN 103725337 B CN103725337 B CN 103725337B CN 201310710182 A CN201310710182 A CN 201310710182A CN 103725337 B CN103725337 B CN 103725337B
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Abstract
The invention discloses a high-cleanness diesel lubricant which is formed by mixing the following components: 40-70 percent of C12-C20 unsaturated fatty acid monoester, 10-20 percent of C12-C18 saturated fatty acid, 10-20 percent of organic monoamine, 5-15 percent of dihydric alcohol, 5-10 percent of nitrate and 1-3 percent of ethylene-vinyl acetate copolymer. The high-cleanness diesel lubricant is used for improving the lubricating property of diesel, and has good low temperature fluidity and good lubricating property; the diesel has the condensation point of being less than -5 DEG C when the using amount of the high-cleanness diesel lubricant is 50-100ppm.
Description
Technical field
The present invention relates to a kind of diesel-dope, particularly a kind of additive for improvement of diesel fuel lubricity performance.
Background technology
Compared with petrol engine, diesel motor has the advantages such as efficiency is high, clean, durable, maintenance cost is low.Along with the raising that China requires the processed oil feature of environmental protection, in order to avoid in diesel engine vent gas, toxic substance is to the pollution of environment, and national compulsory ground reduces sulphur content in diesel oil, and within 2015, come into effect diesel oil state four standard, its sulphur content is 50mg/kg.
In diesel motor, diesel oil is fuel and lubricant.Reduce the sulphur content in diesel oil by hydrofining, the lubricity of diesel oil can be caused simultaneously to decline.If diesel fuel lubricity is too low, easily occur the adhesive wear of pump, pump performance quickly falls to the degree that cannot use subsequently, has had a strong impact on the performance and used life of engine.
Foreign petroleum company is a lot of about the research of non-acid type slip additive, once uses the oiliness additive of ester as low-sulfur diesel-oil of Carboxylic acid and alcohol synthesis, as glyceryl monooleate and caproic acid two isodecyl ester.Find in application, in this synthetic ester, add the low temperature flow improver for diesel fuel of 0.001 ~ 1%, can further improve the oilness of diesel oil.The domestic report also had about non-acid type slip additive, this lubricant is primarily of castor-oil plant grease composition, and molecular weight is large, characterization of molecules does not meet diesel oil character, and sticky valve, is unfavorable for burning, in diesel engine combusts process, produce black smoke, be not easily used as diesel fuel lubricity improving agent.
Summary of the invention
The object of this invention is to provide a kind of consumption few, condensation point is low, and low-temperature fluidity is good, the high-cleanness diesel oil lubricant that lubricity is good.
Diesel fuel lubricity agent of the present invention is made up of C12 ~ C20 unsaturated fatty acids acid monoester, C12 ~ C18 saturated fatty acid, unitary organic amine, dibasic alcohol, nitric ether and vinyl-vinyl acetate copolymer, and the mass percent of each constitutive material is:
C12 ~ C20 unsaturated fatty acids acid monoester 40 ~ 70% unitary organic amine 10 ~ 20%
C12 ~ C18 saturated fatty acid 10 ~ 20% dibasic alcohol 5 ~ 15%
Nitric ether 5 ~ 10% vinyl-vinyl acetate copolymer 1 ~ 3%.
Wherein, described unsaturated fatty acids acid monoester mainly refers to unsaturated fatty acid methyl ester or the ethyl ester of C12 ~ C20, as Linolenic acid methylester or ethyl ester, and methyl linoleate or ethyl ester; Described saturated fatty acid mainly refers to the saturated fatty acid of C12 ~ C18, as lauric acid, myristic acid, Palmiticacid, stearic acid; Described unitary organic amine mainly refers to the senior unitary organic amine of C8 ~ C18, as amino dodecane, tetradecy lamine, cetylamine, stearylamine; Described dibasic alcohol mainly refers to the dibasic alcohol of C2 ~ C6, as ethylene glycol, 1,3-PD, pentanediol etc.; Described nitric ether mainly refers to the nitric ether of C4 ~ C10, as cyclohexyl nitrate or isooctyl ester nitrate; The number-average molecular weight of described vinyl-vinyl acetate copolymer is 4000 ~ 8000.
The preparation method of diesel fuel lubricity agent of the present invention is: according to above-mentioned mass percent, adds C12 ~ C18 saturated fatty acid and unitary organic amine according to this in reaction vessel, within 2 hours, makes it fully react in 60 ~ 80 DEG C of stirrings; Add dibasic alcohol and C12 ~ C20 unsaturated fatty acids acid monoester more successively, stir after 20 ~ 30 minutes, add nitric ether and continue stirring 10 ~ 15 minutes, finally add vinyl-vinyl acetate copolymer, stir cooling and make material clear, obtain high-cleanness diesel oil lubricant.
The present invention is mainly used in the lubricity improving diesel oil, and consumption 50 ~ 100ppm, condensation point <-5 DEG C, low-temperature fluidity is good, and lubricity is good.
Join in GB diesel oil by the present invention with the addition of 50ppm, and do not add agent GB diesel oil and contrast, its properties is listed as follows.
Embodiment
Embodiment 1
Get Palmiticacid 10kg, tetradecy lamine 10kg adds in stirring tank, in 80 DEG C of stirring reactions after 2 hours, add ethylene glycol 10kg, Linolenic acid methylester 60kg, continue stirring 20 minutes, add isooctyl ester nitrate 9kg and stir 10 minutes, finally add vinyl-vinyl acetate copolymer (molecular weight 4000) 1kg, stirring is cooled to envrionment temperature, and barrelling is stand-by.
Embodiment 2
Get myristic acid 15kg, cetylamine 15kg adds in stirring tank, in 70 DEG C of stirring reactions 2 hours, add 1, ammediol 10kg, methyl linoleate 50kg, continue stirring 20 minutes, add cyclohexyl nitrate 8kg and stir 10 minutes, finally add vinyl-vinyl acetate copolymer (molecular weight 8000) 2kg, stir and be cooled to envrionment temperature, barrelling is stand-by.
Embodiment 3
Get stearic acid 15kg, amino dodecane 15kg adds in stirring tank, in 80 DEG C of stirring reactions after 2 hours, add pentanediol 5kg, ethyl linolenate 57kg, continue stirring 20 minutes, add cyclohexyl nitrate 5kg and stir 10 minutes, finally add vinyl-vinyl acetate copolymer (molecular weight 4500) 3kg, stirring is cooled to envrionment temperature, and barrelling is stand-by.
Embodiment 4
Get lauric acid 18kg, stearylamine 18kg adds in stirring tank, in 60 DEG C of stirring reactions after 2 hours, add 1,3-PD 10kg, ethyl linoleate 44kg, continue stirring 20 minutes, add isooctyl ester nitrate 8kg, stir 10 minutes, finally add vinyl-vinyl acetate copolymer (molecular weight 6000) 2kg, stirring is cooled to envrionment temperature, and barrelling is stand-by.
Claims (10)
1. a high-cleanness diesel oil lubricant, is made up of C12 ~ C20 unsaturated fatty acids acid monoester, C12 ~ C18 saturated fatty acid, unitary organic amine, dibasic alcohol, nitric ether and vinyl-vinyl acetate copolymer, and the mass percent of each constitutive material is:
C12 ~ C20 unsaturated fatty acids acid monoester 40 ~ 70% unitary organic amine 10 ~ 20%
C12 ~ C18 saturated fatty acid 10 ~ 20% dibasic alcohol 5 ~ 15%
Nitric ether 5 ~ 10% vinyl-vinyl acetate copolymer 1 ~ 3%
And above each constitutive material mass percent sum equals 100%.
2. high-cleanness diesel oil lubricant according to claim 1, is characterized in that described C12 ~ C20 unsaturated fatty acids acid monoester is Linolenic acid methylester or ethyl ester, methyl linoleate or ethyl ester.
3. high-cleanness diesel oil lubricant according to claim 1, is characterized in that described C12 ~ C18 saturated fatty acid is lauric acid, myristic acid, Palmiticacid or stearic acid.
4. high-cleanness diesel oil lubricant according to claim 1, is characterized in that described unitary organic amine is C8 ~ C18 unitary organic amine.
5. high-cleanness diesel oil lubricant according to claim 1, is characterized in that described dibasic alcohol is C2 ~ C6 dibasic alcohol.
6. high-cleanness diesel oil lubricant according to claim 5, is characterized in that described dibasic alcohol is ethylene glycol, 1,3-PD or pentanediol.
7. high-cleanness diesel oil lubricant according to claim 1, is characterized in that described nitric ether is the nitric ether of C4 ~ C10.
8. high-cleanness diesel oil lubricant according to claim 7, is characterized in that described nitric ether is cyclohexyl nitrate or isooctyl ester nitrate.
9. high-cleanness diesel oil lubricant according to claim 1, is characterized in that the number-average molecular weight of described vinyl-vinyl acetate copolymer is 4000 ~ 8000.
10. the preparation method of high-cleanness diesel oil lubricant according to claim 1, is characterized in that according to described mass percent, adds C12 ~ C18 saturated fatty acid and unitary organic amine according to this in reaction vessel, within 2 hours, makes it fully react in 60 ~ 80 DEG C of stirrings; Add dibasic alcohol and C12 ~ C20 unsaturated fatty acids acid monoester more successively, stir after 20 ~ 30 minutes, add nitric ether and continue stirring 10 ~ 15 minutes, finally add vinyl-vinyl acetate copolymer, stir cooling and make material clear, obtain high-cleanness diesel oil lubricant.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310710182.7A CN103725337B (en) | 2013-12-22 | 2013-12-22 | High-cleanness diesel lubricant |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310710182.7A CN103725337B (en) | 2013-12-22 | 2013-12-22 | High-cleanness diesel lubricant |
Publications (2)
| Publication Number | Publication Date |
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| CN103725337A CN103725337A (en) | 2014-04-16 |
| CN103725337B true CN103725337B (en) | 2015-04-01 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201310710182.7A Active CN103725337B (en) | 2013-12-22 | 2013-12-22 | High-cleanness diesel lubricant |
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Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN105779033B (en) * | 2016-04-21 | 2017-07-18 | 广西东奇能源技术有限公司 | Vehicle biological fuel |
| CN107227192A (en) * | 2017-07-21 | 2017-10-03 | 马健 | A kind of high-cleanness diesel oil lubricant |
| CN107267233A (en) * | 2017-07-21 | 2017-10-20 | 马健 | Low-sulfur diesel-oil lubricant |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN100478373C (en) * | 2004-08-31 | 2009-04-15 | 中国石油化工股份有限公司 | Method for preparing multi-effect additive of low-sulfur diesel |
| FR2968011B1 (en) * | 2010-11-26 | 2014-02-21 | Total Raffinage Marketing | LUBRICATING COMPOSITION FOR ENGINE |
| CN103031165B (en) * | 2012-12-12 | 2015-01-07 | 深圳英迪创新科技有限公司 | Fuel additive as well as preparation method and application of fuel additive |
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Effective date of registration: 20160705 Address after: 030006, Wharton building, 88 development road, 12 hi tech Development Zone, Shanxi, Taiyuan Patentee after: Shanxi alcohol ether cleaning fuel industry technology center (Co., Ltd.) Address before: 030006 Shanxi city of Taiyuan province Jinyang street saiding road high tech Zone Wharton building Patentee before: Shanxi Huadun Industry Co., Ltd. |
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Effective date of registration: 20190717 Address after: Room 410, Office Building, Venous Industry Park, Zhenjiang New District, Jiangsu Province Patentee after: CRPC Innovation Energy Co., Ltd. Address before: 030006, Wharton building, 88 development road, 12 hi tech Development Zone, Shanxi, Taiyuan Patentee before: Shanxi alcohol ether cleaning fuel industry technology center (Co., Ltd.) |